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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Therm. Eng.</journal-id>
<journal-title>Frontiers in Thermal Engineering</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Therm. Eng.</abbrev-journal-title>
<issn pub-type="epub">2813-0456</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">882941</article-id>
<article-id pub-id-type="doi">10.3389/fther.2022.882941</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Thermal Engineering</subject>
<subj-group>
<subject>Hypothesis and Theory</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Deep Heating of a Snowpack by Solar Radiation</article-title>
<alt-title alt-title-type="left-running-head">Dombrovsky and Kokhanovsky</alt-title>
<alt-title alt-title-type="right-running-head">Deep Solar Heating of Snowpack</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Dombrovsky</surname>
<given-names>Leonid A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/886458/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Kokhanovsky</surname>
<given-names>Alexander A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/81071/overview"/>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>
<institution>Department of Chemical Engineering, Biotechnology and Materials</institution>, <institution>Engineering Science Faculty</institution>, <institution>Ariel University</institution>, <addr-line>Ariel</addr-line>, <country>Israel</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>
<institution>Heat Transfer Laboratory</institution>, <institution>Research Centre of Physical and Thermal Engineering</institution>, <institution>Joint Institute for High Temperatures</institution>, <addr-line>Moscow</addr-line>, <country>Russia</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>
<institution>Microhydrodynamic Technologies Laboratory</institution>, <institution>X-BIO Institute</institution>, <institution>University of Tyumen</institution>, <addr-line>Tyumen</addr-line>, <country>Russia</country>
</aff>
<aff id="aff4">
<label>
<sup>4</sup>
</label>
<institution>Brockmann Consult</institution>, <addr-line>Hamburg</addr-line>, <country>Germany</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1394622/overview">Boxiang Wang</ext-link>, Shanghai Jiao Tong University, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1494313/overview">Cun-Hai Wang</ext-link>, University of Science and Technology Beijing, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1507816/overview">Linyang Wei</ext-link>, Northeastern University, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Leonid A. Dombrovsky, <email>ldombr@yandex.ru</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Heat Transfer and Thermal Power, a section of the journal Frontiers in Thermal Engineering</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>29</day>
<month>04</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>2</volume>
<elocation-id>882941</elocation-id>
<history>
<date date-type="received">
<day>24</day>
<month>02</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>18</day>
<month>03</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Dombrovsky and Kokhanovsky.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Dombrovsky and Kokhanovsky</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The observed gradual change in the Earth&#x2019;s climate most noticeably affects the snow cover and ice sheets in the polar regions, especially during the long polar summer, when solar radiation leads to considerable increase in temperature and partial melting at some distance from the snow or ice surface. This effect, which in the polar regions is more pronounced in the snow cover, deserves serious attention as an important geophysical problem. In this article, for the first time, a theoretical analysis is made of the conditions under which the absorption of directional radiation penetrating a weakly absorbing scattering medium has a maximum at some distance from the illuminated surface. It is shown that the maximum absorption of radiation inside an optically thick medium exists only at illumination angles less than 60&#xb0; from the normal. An analytical solution was obtained that gives both the magnitude of this maximum absorption and its depth below the illuminated surface. Calculations of solar radiation transfer and heat propagation in the snow layer are also performed. Various experimental data on the ice absorption index in the visible range are taken into account when determining the optical properties of snow. To calculate the transient temperature profile in the snow layer, the heat conduction equation with volumetric absorption of radiation is solved. The boundary conditions take into account the variation of solar irradiation, convective heat transfer, and radiative cooling of snow in the infrared transparency window of the cloudless atmosphere. The calculations show that the radiative cooling should be taken into account even during the polar summer.</p>
</abstract>
<kwd-group>
<kwd>solar irradiance</kwd>
<kwd>snow</kwd>
<kwd>scattering</kwd>
<kwd>radiative transfer</kwd>
<kwd>deep heating</kwd>
<kwd>computational modeling</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>In recent years, there has been a marked melting of snow and ice in the polar and circumpolar regions, which is a significant factor in overall climate change (<xref ref-type="bibr" rid="B3">Barry and Hall-McKim 2018</xref>; <xref ref-type="bibr" rid="B1">Kokhanovsky and Tomasi 2020</xref>). One of the problems deserving special attention is the solar heating and even melting of snow at a depth below the surface of the snow cover. This effect was probably first discussed by <xref ref-type="bibr" rid="B6">Brandt and Warren (1993)</xref> and the term &#x201c;solid-state greenhouse&#x201d; was suggested for this phenomenon which was discussed also by <xref ref-type="bibr" rid="B38">Liston and Winther (2005)</xref>. The physical explanation for this effect, typical of a long polar summer, is based on the interaction of two factors. First of all, it is the very weak absorption of visible radiation by the ice particles that form the snow. Therefore, a part of the visible solar radiation is absorbed several centimeters from the surface of the snow cover (<xref ref-type="bibr" rid="B28">Kokhanovsky, 2021a</xref>; <xref ref-type="bibr" rid="B29">2021b</xref>). The absorption maximum turns out to be at some distance from the surface, and a special attention is paid to this issue in the article. Second, due to the low thermal conductivity of snow, much of this heat does not escape to the surface. This heat is continuously transferred by heat conduction to a considerable depth, where it accumulates and can even lead to snow melting away from the surface, which is usually cooled by convective heat transfer to the cold air above snow, as well as by radiative cooling in the infrared transparency window of the cloudless atmosphere.</p>
<p>Let us first consider the conditions under which the absorption maximum of the shortwave external radiation is located at some distance from the surface of the scattering medium illuminated by the directional radiation. To solve this problem, we can use the approach for arbitrary oblique illumination proposed in (<xref ref-type="bibr" rid="B15">Dombrovsky and Randrianalisoa 2018</xref>) and used in (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>) to calculate the radiative transfer in a layer of snow. The computational results obtained by <xref ref-type="bibr" rid="B11">Dombrovsky et al. (2019)</xref> make clear the role of convective cooling or heating of snow, mid-infrared radiative cooling of snow surface, and continuous heating of deep snow layers due to heat conduction. Some numerical results for the effect of a sloping snow surface on solar heating of snow were also obtained.</p>
<p>In the layer of isotropic snow, the general radiative transfer equation (RTE) is as follows (<xref ref-type="bibr" rid="B8">Dombrovsky and Baillis 2010</xref>; <xref ref-type="bibr" rid="B26">Howell et al., 2021</xref>; <xref ref-type="bibr" rid="B41">Modest and Mazumder 2021</xref>):<disp-formula id="e1">
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<p>The weak absorption of short-wave radiation in an optically thick layer of snow leads to the strong multiple light scattering. As a result, it is sufficient to use the simplest transport model for the single scattering (<xref ref-type="bibr" rid="B22">Dombrovsky 2012</xref>):<disp-formula id="e2">
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</inline-formula> is satisfied by function (2). The transport model proved to be sufficiently accurate for many problems of radiative transfer in weakly absorbing and strongly scattering media (<xref ref-type="bibr" rid="B8">Dombrovsky and Baillis 2010</xref>; <xref ref-type="bibr" rid="B37">Dombrovsky and Lipi&#x144;ski 2010</xref>). Interestingly, the computational results obtained using the transport model are normally very close to those obtained with the more complex Henyey&#x2013;Greenstein analytical model (<xref ref-type="bibr" rid="B16">Dombrovsky et al., 2011a</xref>; <xref ref-type="bibr" rid="B17">Dombrovsky et al., 2013</xref>). This statement is also correct in the case under study.</p>
<p>The transport form of the RTE, which follows from <xref ref-type="disp-formula" rid="e1">Eqs 1</xref>&#x2013;<xref ref-type="disp-formula" rid="e3">3</xref>, is similar to that for a hypothetical isotropic scattering (<xref ref-type="bibr" rid="B22">Dombrovsky 2012</xref>; <xref ref-type="bibr" rid="B18">Dombrovsky 2019</xref>):<disp-formula id="e4">
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<p>Consider a semi-infinite plane-parallel layer of a scattering medium, such as snow, illuminated directly by solar radiation. In the case of oblique incidence, the radiation field in the medium is three-dimensional. Fortunately, the 3D problem can be radically simplified. Let us note that the irradiance field in snow at illumination at the same angle relative to the normal to the surface, but at different azimuthal angle differs only in the rotation relative to the normal. As a result, the irradiance field is the same as in the case of uniform radiation along a conical surface. This cone with a vertical axis is formed by solar rays with the same zenith angle. Hence, we can solve the equivalent axisymmetric problem as it was done by <xref ref-type="bibr" rid="B19">Dombrovsky et al. (2011b)</xref>, <xref ref-type="bibr" rid="B15">Dombrovsky and Randrianalisoa (2018)</xref> and <xref ref-type="bibr" rid="B11">Dombrovsky et al. (2019)</xref>. The axial symmetry allows us to integrate the RTE over the azimuthal angle:<disp-formula id="e6a">
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<p>It is important that the radiative transfer equation is linear. This allows us to separately consider the contribution of direct radiation from the Sun and radiation scattered by the atmosphere. For the direct irradiation we have:<disp-formula id="e7a">
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<label>(7b)</label>
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<label>(9)</label>
</disp-formula>
</p>
<p>The radiative transfer problem for the diffuse radiation component can be written as:<disp-formula id="e10a">
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<label>(10a)</label>
</disp-formula>
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<label>(10b)</label>
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</p>
<p>This problem can be further simplified because the source function in <xref ref-type="disp-formula" rid="e10a">Eq. 10a</xref> is independent of <inline-formula id="inf18">
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</inline-formula> and the two-flux (Schwarzschild&#x2013;Schuster) model is applicable. The detailed analysis of this model in (<xref ref-type="bibr" rid="B8">Dombrovsky and Baillis 2010</xref>) showed its sufficiently high accuracy. For the considered problem of radiative transfer in a snowpack this approach was proved to be also applicable (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>). The two-flux method is based on the following approximation of the diffuse radiation intensity:<disp-formula id="e11">
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<label>(11)</label>
</disp-formula>
</p>
<p>Integrating <xref ref-type="disp-formula" rid="e10a">Eq. 10a</xref>, one can obtain the boundary-value problem for the irradiance <inline-formula id="inf19">
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</inline-formula> (<xref ref-type="bibr" rid="B8">Dombrovsky and Baillis 2010</xref>). It the case of vertically homogeneous snow, one can obtain the analytical solution:<disp-formula id="e12a">
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<label>(12a)</label>
</disp-formula>
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<label>(12b)</label>
</disp-formula>where <inline-formula id="inf20">
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</inline-formula> is a parameter. There are two different exponential functions in <xref ref-type="disp-formula" rid="e12a">Eq. 12a</xref>: <inline-formula id="inf21">
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</inline-formula> is related to the not-scattered collimated radiation, whereas <inline-formula id="inf22">
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</mml:mrow>
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</inline-formula> corresponds to the diffuse radiation. It is not difficult to see that the depth of propagation of collimated radiation is smaller than that of the diffuse one when <inline-formula id="inf23">
<mml:math id="m39">
<mml:mrow>
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<mml:mi>&#x3c9;</mml:mi>
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<mml:mo>&#x3e;</mml:mo>
<mml:mn>0.75</mml:mn>
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</mml:math>
</inline-formula>. This makes clear the evolution of the radiation field with the depth. After entering a strongly scattering medium, the directional solar radiation in the vicinity of snow surface is converted into diffuse (but not isotropic) radiation. Due to multiple scattering, absorption of diffuse radiation is enhanced in a medium with a very small absorption coefficient. As a result of this absorption, the radiation flux decreases, and with it the absorbed power of radiation also decreases. The absorbed radiation power is determined using the calculated irradiance profiles for direct solar radiation:<disp-formula id="e13">
<mml:math id="m40">
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<label>(13)</label>
</disp-formula>where <inline-formula id="inf24">
<mml:math id="m41">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>min</mml:mi>
</mml:mrow>
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</mml:mrow>
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</inline-formula> and <inline-formula id="inf25">
<mml:math id="m42">
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</mml:mrow>
</mml:msub>
</mml:mrow>
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</inline-formula> are the boundaries of the main wavelength range that contributes to the radiative transfer in the layer.</p>
</sec>
<sec id="s2">
<title>Absorption Maximum in a Scattering Medium</title>
<p>In the case of an optically thick homogeneous medium layer, the position of the maximum (along the optical coordinate <inline-formula id="inf26">
<mml:math id="m43">
<mml:mrow>
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</inline-formula>) of the spectral component of the absorbed radiation energy, <inline-formula id="inf27">
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<mml:mo>(</mml:mo>
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</mml:mrow>
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</inline-formula>, inside the layer is determined from the condition <inline-formula id="inf28">
<mml:math id="m45">
<mml:mrow>
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</mml:mrow>
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<mml:mo>&#x3d;</mml:mo>
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</inline-formula>, where<disp-formula id="e14">
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<mml:mo>&#x2b;</mml:mo>
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<mml:mn>2</mml:mn>
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</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
<label>(14)</label>
</disp-formula>
</p>
<p>It the case of a strongly scattering medium, it follows that the maximum of the absorbed radiation power occurs at:<disp-formula id="e15">
<mml:math id="m47">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">a</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mi>ln</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mtext>when</mml:mtext>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>&#x226a;</mml:mo>
<mml:mn>1</mml:mn>
<mml:mo>/</mml:mo>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
<label>(15)</label>
</disp-formula>
</p>
<p>The value <inline-formula id="inf29">
<mml:math id="m48">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula> was excluded using the formula <inline-formula id="inf30">
<mml:math id="m49">
<mml:mrow>
<mml:mn>4</mml:mn>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>4</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msubsup>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mn>2</mml:mn>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula>. <xref ref-type="disp-formula" rid="e15">Equation 15</xref> makes sense only when <inline-formula id="inf31">
<mml:math id="m50">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x3e;</mml:mo>
<mml:mn>0.5</mml:mn>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b8;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x3c;</mml:mo>
<mml:mn>60</mml:mn>
<mml:mo>&#xb0;</mml:mo>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> but this restriction suits us fine. The formal use of this equation may give zero or negative values of <inline-formula id="inf32">
<mml:math id="m51">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula>. The latter means that there is no maximum of absorbed power inside the medium layer at the angle of incidence less than <inline-formula id="inf33">
<mml:math id="m52">
<mml:mrow>
<mml:mn>60</mml:mn>
<mml:mo>&#xb0;</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> (e.g., at the Sun in the zenith). The condition of <inline-formula id="inf34">
<mml:math id="m53">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> gives the boundary of the region of <inline-formula id="inf35">
<mml:math id="m54">
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> where the maximum of the absorbed radiation power exists at some distance under the irradiated surface of the medium layer. This boundary can be obtained analytically as a solution for the second-order algebraic equation:<disp-formula id="e16">
<mml:math id="m55">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mn>2</mml:mn>
</mml:msubsup>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>2</mml:mn>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
</mml:mrow>
</mml:math>
<label>(16)</label>
</disp-formula>
</p>
<p>The resulting solution is as follows:<disp-formula id="e17">
<mml:math id="m56">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msqrt>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:msqrt>
</mml:mrow>
</mml:math>
<label>(17)</label>
</disp-formula>
</p>
<p>Obviously, the deepest penetration of the collimated radiation into the medium takes place at the normal incidence <inline-formula id="inf36">
<mml:math id="m57">
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> when <xref ref-type="disp-formula" rid="e17">Eq. 17</xref> gives <inline-formula id="inf37">
<mml:math id="m58">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf38">
<mml:math id="m59">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.75</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>. The large boundary value of transport albedo shows that the internal maximum of absorption takes place for highly-scattering media only. The results of calculations in the most interesting range of <inline-formula id="inf39">
<mml:math id="m60">
<mml:mrow>
<mml:mn>0</mml:mn>
<mml:mo>&#x2264;</mml:mo>
<mml:msub>
<mml:mi>&#x3b8;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
<mml:mo>&#x2264;</mml:mo>
<mml:mn>45</mml:mn>
<mml:mo>&#xb0;</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> are presented in <xref ref-type="fig" rid="F1">Figure 1</xref>, where the curve <inline-formula id="inf40">
<mml:math id="m61">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b8;</mml:mi>
<mml:mi>i</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> separates the regions corresponding to the absorption maximum directly at the surface of the illuminated medium and below this surface. Interestingly, the absorption maximum can occur only at a distance from the irradiated surface when the angle of incidence is less than 60<sup>o</sup> even the case of a weakly scattering medium.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Predominant surface or internal absorption of collimated radiation (regions below and above the line).</p>
</caption>
<graphic xlink:href="fther-02-882941-g001.tif"/>
</fig>
<p>It is also interesting to calculate the ratio of the maximum local absorption of radiation to that on the surface of the medium illuminated along the normal:<disp-formula id="e18">
<mml:math id="m62">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">a</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2b;</mml:mo>
<mml:mi>&#x3b6;</mml:mi>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:mo>&#x2b;</mml:mo>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mi mathvariant="normal">e</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
<mml:mi mathvariant="normal">p</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">a</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>3</mml:mn>
<mml:mi>&#x3b6;</mml:mi>
<mml:mi mathvariant="normal">e</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
<mml:mi mathvariant="normal">p</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">a</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:mo>&#x2b;</mml:mo>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>&#x3b6;</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:mfrac>
<mml:mo>,</mml:mo>
<mml:mi>&#x3b6;</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>4</mml:mn>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>/</mml:mo>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3be;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mn>2</mml:mn>
</mml:msubsup>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
<label>(18)</label>
</disp-formula>where <inline-formula id="inf41">
<mml:math id="m63">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula> is determined by <xref ref-type="disp-formula" rid="e15">Eq. 15</xref>. The increase at the optical depth <inline-formula id="inf42">
<mml:math id="m64">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula> where the absorption maximum is located, as well as the relative value of <inline-formula id="inf43">
<mml:math id="m65">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> of this maximum for media with high values of the transport albedo of single scattering <inline-formula id="inf44">
<mml:math id="m66">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula> is shown in <xref ref-type="fig" rid="F2">Figure 2</xref>. It can be seen that the effect of deep absorption of radiation is most pronounced for media with <inline-formula id="inf45">
<mml:math id="m67">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3e;</mml:mo>
<mml:mn>0.99</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>. For example, when <inline-formula id="inf46">
<mml:math id="m68">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.999</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>9, the absorption maximum is at the optical depth <inline-formula id="inf47">
<mml:math id="m69">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>3.23</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> and its relative value <inline-formula id="inf48">
<mml:math id="m70">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1.85</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>. This seemingly exotic situation takes place for pure snow in the visible part of the solar spectrum. Against this background, the application of Bouguer&#x2019;s law in some publications on radiation propagation in scattering and weakly absorbing media looks especially inappropriate.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Location and magnitude of maximum absorption of directional radiation in scattering and weakly absorbing medium.</p>
</caption>
<graphic xlink:href="fther-02-882941-g002.tif"/>
</fig>
<p>
<xref ref-type="fig" rid="F3">Figure 3</xref> shows several profiles of the absorption of external radiation in highly scattering media illuminated along the normal. The absorption of radiation is large at optical depths much greater than the depth of the absorption maximum. For example, at <inline-formula id="inf49">
<mml:math id="m71">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0,9999</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> even at <inline-formula id="inf50">
<mml:math id="m72">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c4;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>30</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> the absorbed power of radiation is higher than near the illuminated surface.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Profiles of radiation absorption at normal incidence: 1 &#x2013; <inline-formula id="inf51">
<mml:math id="m73">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>t</mml:mi>
<mml:mi>r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.99</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>, 2 &#x2013; <inline-formula id="inf52">
<mml:math id="m74">
<mml:mrow>
<mml:mn>0.999</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>, 3 &#x2013; <inline-formula id="inf53">
<mml:math id="m75">
<mml:mrow>
<mml:mn>0.9999</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>.</p>
</caption>
<graphic xlink:href="fther-02-882941-g003.tif"/>
</fig>
</sec>
<sec id="s3">
<title>Spectral Optical Properties OF Snow</title>
<p>To calculate the absorption of solar radiation in snowpack, one needs the spectral local optical properties of snow. These properties, in turn, can be determined only with the known spectral optical constants of ice as the only substance for pure snow. The optical constants are considered as real and imaginary parts of the complex index of refraction, <inline-formula id="inf54">
<mml:math id="m76">
<mml:mrow>
<mml:mi>m</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mi>n</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>i</mml:mi>
<mml:mi>&#x3ba;</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula>, where <inline-formula id="inf55">
<mml:math id="m77">
<mml:mi>n</mml:mi>
</mml:math>
</inline-formula> is the index of refraction and <inline-formula id="inf56">
<mml:math id="m78">
<mml:mi>&#x3ba;</mml:mi>
</mml:math>
</inline-formula> is the index of absorption. The optical constants of ice obtained by <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref> are plotted in <xref ref-type="fig" rid="F4">Figure 4</xref>. The presented wavelength range is wider than that required to solve the problem of radiative heating and includes the near-ultraviolet spectral range considered in (<xref ref-type="bibr" rid="B20">Dombrovsky et al., 2022</xref>). Note that the measurements by <xref ref-type="bibr" rid="B42">Picard et al. (2016)</xref> showed larger values of <inline-formula id="inf57">
<mml:math id="m79">
<mml:mi>&#x3ba;</mml:mi>
</mml:math>
</inline-formula> in the wavelength range of <inline-formula id="inf58">
<mml:math id="m80">
<mml:mrow>
<mml:mn>0.39</mml:mn>
<mml:mo>&#x3c;</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3c;</mml:mo>
<mml:mn>0.6</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m than those obtained by <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref> (see <xref ref-type="fig" rid="F4">Figure 4</xref>). In this paper, for the first time, we compare the calculated data on the transfer of shortwave radiation in the snow layer for the different dependences of <inline-formula id="inf59">
<mml:math id="m81">
<mml:mrow>
<mml:mi>&#x3ba;</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> in the visible.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Spectral optical constants of pure ice. Two sets of data for the index of absorption are plotted: 1 &#x2013; <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref>, 2 &#x2013; <xref ref-type="bibr" rid="B42">Picard et al. (2016)</xref>.</p>
</caption>
<graphic xlink:href="fther-02-882941-g004.tif"/>
</fig>
<p>The transition from very small values of the absorption index in the visible range to its large values in the near-infrared determines quite different optical properties of ice and snow in these spectral ranges. In particular, the high value of snow albedo in the visible range is a result of high transparency of pure ice. Note that even very small impurities such as aerosol particles may strongly affect the albedo of snow (<xref ref-type="bibr" rid="B28">Kokhanovsky, 2021c</xref>). In this regard, one can recommend the following recent papers: <xref ref-type="bibr" rid="B32">Kokhanovsky et al. (2018)</xref>, <xref ref-type="bibr" rid="B23">He and Flanner (2020)</xref>, <xref ref-type="bibr" rid="B28">Kokhanovsky (2021a)</xref>, <xref ref-type="bibr" rid="B43">Pu et al. (2021)</xref>. Note that the optical properties of snow polluted with atmospheric dust or soot particles (<xref ref-type="bibr" rid="B24">He et al., 2018</xref>; <xref ref-type="bibr" rid="B10">Dombrovsky and Kokhanovsky 2020a</xref>; <xref ref-type="bibr" rid="B44">Shi et al., 2021</xref>) do not depend on the choice between the absorption data for pure snow in the short-wave range. However, in this paper, we consider only pure snow, for which this choice may matter.</p>
<p>Modeling of the optical properties of various scattering media is often based on classical Mie theory (<xref ref-type="bibr" rid="B5">Bohren and Huffman 1998</xref>). However, in many cases one can use the geometric optics (GO), which works well for large particles, as well as some combined methods (<xref ref-type="bibr" rid="B4">Bi et al., 2011</xref>; <xref ref-type="bibr" rid="B35">Lindqvist et al., 2018</xref>; <xref ref-type="bibr" rid="B30">Kokhanovsky, 2021c</xref>). Such a possibility is important for ice grains of complex shape (<xref ref-type="bibr" rid="B34">Libois et al., 2013</xref>; <xref ref-type="bibr" rid="B36">Liou and Yang 2016</xref>; <xref ref-type="bibr" rid="B27">Ishimoto et al., 2018</xref>). Interestingly, in some cases reliable results can be obtained from physically sound approximate solutions (<xref ref-type="bibr" rid="B29">Kokhanovsky 2021b</xref>).</p>
<p>
<xref ref-type="bibr" rid="B11">Dombrovsky et al. (2019)</xref> have considered the spherical ice grains of different size instead of nonspherical ice particles in random orientation. It was assumed that the complex shape of the ice grains has little effect on solar heating of the snowpack. The different sizes of ice grains were treated as those corresponding to different snow morphology. It was shown that the monodisperse model can be used instead of the detailed calculations for polydisperse grains. Therefore, we restrict ourselves to the calculation results for the case of monodispersed spheres with <inline-formula id="inf60">
<mml:math id="m82">
<mml:mrow>
<mml:mi>a</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>100</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m. A comparison with the Mie theory in (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>) showed that the GO approximation is very accurate and one can use a relatively simple analytical solution derived in the early paper by <xref ref-type="bibr" rid="B31">Kokhanovsky and Zege (1995)</xref>. In some cases, it is convenient to use the simplest analytical approximations for the main optical properties of weakly absorbing spherical particles suggested in (<xref ref-type="bibr" rid="B21">Dombrovsky 2002</xref>) and in the recent paper by <xref ref-type="bibr" rid="B29">Kokhanovsky (2021b)</xref>. In particular, following (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>) we use simpler relations in the region of weakest absorption, where a formal application of a more general solution yields erroneous results.</p>
<p>For calculations of radiation transport in the transport approximation we need only two dimensionless characteristics of absorption and scattering of light by individual particles: the absorption efficiency factor, <inline-formula id="inf61">
<mml:math id="m83">
<mml:mrow>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, and the transport efficiency factor of scattering, <inline-formula id="inf62">
<mml:math id="m84">
<mml:mrow>
<mml:msubsup>
<mml:mi>Q</mml:mi>
<mml:mi>s</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>s</mml:mi>
</mml:msub>
<mml:mo>&#xd7;</mml:mo>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>&#x3bc;</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> where <inline-formula id="inf63">
<mml:math id="m85">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>&#x3bc;</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:math>
</inline-formula> is the asymmetry factor of scattering. Note that the values of <inline-formula id="inf64">
<mml:math id="m86">
<mml:mrow>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf65">
<mml:math id="m87">
<mml:mrow>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>s</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> are introduced as absorption or scattering cross sections divided by <inline-formula id="inf66">
<mml:math id="m88">
<mml:mrow>
<mml:mi>&#x3c0;</mml:mi>
<mml:msup>
<mml:mi>a</mml:mi>
<mml:mn>2</mml:mn>
</mml:msup>
</mml:mrow>
</mml:math>
</inline-formula>, where <inline-formula id="inf67">
<mml:math id="m89">
<mml:mi>a</mml:mi>
</mml:math>
</inline-formula> is the particle radius (<xref ref-type="bibr" rid="B5">Bohren and Huffman 1998</xref>). We consider also the transport efficiency factor of extinction, <inline-formula id="inf68">
<mml:math id="m90">
<mml:mrow>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mo>&#x2b;</mml:mo>
<mml:msubsup>
<mml:mi>Q</mml:mi>
<mml:mi>s</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula>, and transport albedo, <inline-formula id="inf69">
<mml:math id="m91">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c9;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msubsup>
<mml:mi>Q</mml:mi>
<mml:mi>s</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>/</mml:mo>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. It is known that these characteristics depend not only on optical constants but also on the dimensionless diffraction parameter <inline-formula id="inf70">
<mml:math id="m92">
<mml:mrow>
<mml:mi>x</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>2</mml:mn>
<mml:mi>&#x3c0;</mml:mi>
<mml:mi>a</mml:mi>
<mml:mo>/</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula>.</p>
<p>Calculations show that light scattering significantly dominates over absorption in the visible range (<xref ref-type="fig" rid="F5">Figure 5</xref>). This leads to the reflection of most of the shortwave solar radiation from the snow. At the same time, the remaining part of the solar radiation is scattered in a snowpack (<xref ref-type="bibr" rid="B29">Kokhanovsky 2021b</xref>; <xref ref-type="bibr" rid="B30">2021c</xref>). As a result, visible light contributes significantly to heating the deep layers of snow, while infrared radiation from the Sun is absorbed in a relatively thin surface layer.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Efficiency factor of absorption and transport albedo of ice grain. Calculations using different data for the ice absorption index in the visible range: <italic>1</italic> &#x2013; <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref>, <italic>2</italic> &#x2013; <xref ref-type="bibr" rid="B42">Picard et al. (2016)</xref>.</p>
</caption>
<graphic xlink:href="fther-02-882941-g005.tif"/>
</fig>
<p>Note that the hypothesis of independent scattering by single ice grains in snow is true (<xref ref-type="bibr" rid="B40">Mishchenko 2018</xref>). It is really the case because of a high porosity of snow and large sizes of ice grains. Therefore, the optical properties of snow can be calculated as follows (<xref ref-type="bibr" rid="B8">Dombrovsky and Baillis 2010</xref>): <disp-formula id="e19">
<mml:math id="m93">
<mml:mrow>
<mml:mrow>
<mml:mo>{</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b1;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msubsup>
<mml:mi>&#x3c3;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>,</mml:mo>
<mml:msubsup>
<mml:mi>&#x3b2;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
</mml:mrow>
<mml:mo>}</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.75</mml:mn>
<mml:msub>
<mml:mi>f</mml:mi>
<mml:mi>v</mml:mi>
</mml:msub>
<mml:mrow>
<mml:mo>{</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msubsup>
<mml:mi>Q</mml:mi>
<mml:mi mathvariant="normal">s</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>Q</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mo>}</mml:mo>
</mml:mrow>
<mml:mo>/</mml:mo>
<mml:mi>a</mml:mi>
</mml:mrow>
</mml:math>
<label>(19)</label>
</disp-formula>
</p>
<p>The transport albedo of scattering for snow coincides with the same value for a single ice grain: <inline-formula id="inf71">
<mml:math id="m94">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>&#x3c9;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. Returning to <xref ref-type="fig" rid="F5">Figure 5</xref>, we note that the calculated value of the snow albedo in the short-wave region is very close to unity for both the absorption data (<xref ref-type="bibr" rid="B45">Warren and Brandt 2008</xref>) and the data (<xref ref-type="bibr" rid="B42">Picard et al., 2016</xref>). For example, at wavelength <inline-formula id="inf72">
<mml:math id="m95">
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.4</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m in the first case we have <inline-formula id="inf73">
<mml:math id="m96">
<mml:mrow>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1.4</mml:mn>
<mml:mo>&#xd7;</mml:mo>
<mml:msup>
<mml:mrow>
<mml:mn>10</mml:mn>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>5</mml:mn>
</mml:mrow>
</mml:msup>
</mml:mrow>
</mml:math>
</inline-formula> and in the second case &#x2013; <inline-formula id="inf74">
<mml:math id="m97">
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msubsup>
<mml:mi>&#x3c9;</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msubsup>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>2.9</mml:mn>
<mml:mo>&#xd7;</mml:mo>
<mml:msup>
<mml:mrow>
<mml:mn>10</mml:mn>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>5</mml:mn>
</mml:mrow>
</mml:msup>
</mml:mrow>
</mml:math>
</inline-formula>. This means that regardless of the initial absorption data, we are dealing with a deep and strong absorption maximum for the visible radiation.</p>
</sec>
<sec id="s4">
<title>Absorption of Solar Radiation in Snowpack</title>
<p>In this section, we limit ourselves to calculating the absorption of direct solar radiation, neglecting the relatively small contribution of radiation scattered by the atmosphere. The vertical profile of the normalized absorbed power is illustrated in <xref ref-type="fig" rid="F6">Figure 6</xref> for the normal incidence separately for the visible and near-infrared spectral ranges. It is not necessary to consider the real spectrum of solar radiation that has passed through the atmosphere in order to make a qualitative estimate. Instead, we will use the Planck spectrum at temperature <inline-formula id="inf75">
<mml:math id="m98">
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mrow>
<mml:mi>s</mml:mi>
<mml:mi>o</mml:mi>
<mml:mi>l</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>6000</mml:mn>
<mml:mtext>K</mml:mtext>
</mml:mrow>
</mml:math>
</inline-formula>. It is interesting to calculate separately the contributions of the visible and the near-infrared ranges to the absorbed power of radiation:<disp-formula id="e20">
<mml:math id="m99">
<mml:mrow>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>P</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>z</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>P</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">v</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">s</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>z</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x2b;</mml:mo>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>P</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">n</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>z</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>P</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">v</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">s</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi mathvariant="normal">n</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>P</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">v</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">s</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi mathvariant="normal">n</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>/</mml:mo>
<mml:munderover>
<mml:mstyle displaystyle="true">
<mml:mo>&#x222b;</mml:mo>
</mml:mstyle>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">i</mml:mi>
<mml:mi mathvariant="normal">n</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">a</mml:mi>
<mml:mi mathvariant="normal">x</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:munderover>
<mml:msub>
<mml:mi>I</mml:mi>
<mml:mi>b</mml:mi>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mrow>
<mml:mi>sol</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#xa0;</mml:mo>
<mml:mi mathvariant="normal">d</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
</mml:mrow>
</mml:math>
<label>(20)</label>
</disp-formula>where <inline-formula id="inf76">
<mml:math id="m100">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>m</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi>n</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.4</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m and <inline-formula id="inf77">
<mml:math id="m101">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>m</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>x</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>2.8</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m and <inline-formula id="inf78">
<mml:math id="m102">
<mml:mrow>
<mml:mo>&#xa0;</mml:mo>
<mml:msub>
<mml:mi>P</mml:mi>
<mml:mrow>
<mml:mi>v</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi>s</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>n</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is calculated using <xref ref-type="disp-formula" rid="e13">Eq. 13</xref> for the spectral ranges 0.4&#x2013;0.78 and 0.78&#x2013;2.8 &#xb5;m, respectively. Of course, one can use more accurate values for the conventional solar temperature and the boundaries of the visible and near-infrared ranges as it was recommended in the monograph by <xref ref-type="bibr" rid="B30">Kokhanovsky (2021c)</xref>. However, it is not important for the presented estimations. According to (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>), we introduce the normalized coordinates <inline-formula id="inf79">
<mml:math id="m103">
<mml:mrow>
<mml:msub>
<mml:mi>f</mml:mi>
<mml:mtext>v</mml:mtext>
</mml:msub>
<mml:mi>z</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf80">
<mml:math id="m104">
<mml:mrow>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>P</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mo>/</mml:mo>
<mml:msub>
<mml:mi>f</mml:mi>
<mml:mtext>v</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> in <xref ref-type="fig" rid="F6">Figure 6A</xref>, where <inline-formula id="inf81">
<mml:math id="m105">
<mml:mrow>
<mml:msub>
<mml:mi>f</mml:mi>
<mml:mi>v</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the volume fraction of ice is a snow layer.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Contributions of different spectral ranges to the absorbed radiation power. Calculations using different data for the ice absorption index in the visible subrange A: <italic>1</italic> &#x2013; <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref>, <italic>2</italic> &#x2013; <xref ref-type="bibr" rid="B42">Picard et al. (2016)</xref> are performed. Spectral ranges are as follows: left panel - visible (0.4&#x2013;0.78 micron), near-infrared (0.78&#x2013;2.8 micron); right panel - <bold>(A)</bold> (0.4&#x2013;0.6 micron), <bold>(B)</bold> (0.6&#x2013;0.78 micron).</p>
</caption>
<graphic xlink:href="fther-02-882941-g006.tif"/>
</fig>
<p>As one might expect, infrared radiation is absorbed mostly in a thin surface layer, while visible light is absorbed almost uniformly in a relatively thick layer. The result is in good agreement with the work of <xref ref-type="bibr" rid="B33">Munneke et al. (2009)</xref>, which discusses the deep penetration of shortwave solar radiation and its role in the thermal balance of the snow cover.</p>
<p>For better clarity, <xref ref-type="fig" rid="F6">Figure 6B</xref> shows similar dependences for the two parts of the visible spectrum: <inline-formula id="inf82">
<mml:math id="m106">
<mml:mrow>
<mml:mn>0.4</mml:mn>
<mml:mo>&#x3c;</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3c;</mml:mo>
<mml:mn>0.6</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m (A) and <inline-formula id="inf83">
<mml:math id="m107">
<mml:mrow>
<mml:mn>0.6</mml:mn>
<mml:mo>&#x3c;</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3c;</mml:mo>
<mml:mn>0.78</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m (B). In the calculations for the sub-range A, different data on the ice absorption index are used, which give similar dependences of the absorbed power on depth, differing slightly only in the absolute value. As we have already discussed, the position and relative magnitude of the absorption maximum are the same for the two variants of the ice absorption index in the visible range. The calculations using the data by <xref ref-type="bibr" rid="B42">Picard et al. (2016)</xref> give a slightly greater absorption of the shortwave radiation.</p>
<p>Of course, knowing the local value of the absorbed radiation power is not enough to calculate the snow temperature. The next step in solving the problem requires the transient energy equation with appropriate initial and boundary conditions. The wide-range spectral dependence of <inline-formula id="inf84">
<mml:math id="m108">
<mml:mrow>
<mml:mi>&#x3ba;</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> as given by <xref ref-type="bibr" rid="B45">Warren and Brandt (2008)</xref> will be used in these calculations.</p>
</sec>
<sec id="s5">
<title>Transient Heat Transfer Model</title>
<p>Consider now the 1D problem of heat transfer. As in (<xref ref-type="bibr" rid="B13">Dombrovsky and Kokhanovsky 2021</xref>), we will not consider such processes as ice sublimation and water vapor diffusion in the snow layer, which may be of interest for studying the changing microstructure of snow. The problem statement for the transient temperature field, <inline-formula id="inf85">
<mml:math id="m109">
<mml:mrow>
<mml:mi>T</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>z</mml:mi>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> in a layer of snow is:<disp-formula id="e21a">
<mml:math id="m110">
<mml:mrow>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>c</mml:mi>
<mml:mfrac>
<mml:mrow>
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<mml:mi>T</mml:mi>
</mml:mrow>
<mml:mrow>
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<mml:mi mathvariant="normal">t</mml:mi>
</mml:mrow>
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<mml:mo>&#x3d;</mml:mo>
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</mml:mrow>
</mml:mfrac>
</mml:mrow>
<mml:mo>)</mml:mo>
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<mml:mo>&#x2b;</mml:mo>
<mml:mi>P</mml:mi>
<mml:mo>,</mml:mo>
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<mml:mo>&#x3e;</mml:mo>
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<mml:mi>z</mml:mi>
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<mml:mi mathvariant="normal">h</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
<label>(21a)</label>
</disp-formula>
<disp-formula id="e21b">
<mml:math id="m111">
<mml:mrow>
<mml:mi>T</mml:mi>
<mml:mrow>
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</mml:msub>
<mml:mrow>
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<mml:mi>z</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
<label>(21b)</label>
</disp-formula>
<disp-formula id="e21c">
<mml:math id="m112">
<mml:mrow>
<mml:mi>z</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
<mml:mo>,</mml:mo>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>k</mml:mi>
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<mml:mi mathvariant="normal">i</mml:mi>
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</mml:msub>
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<mml:mi>T</mml:mi>
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<mml:mo>)</mml:mo>
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<mml:mo>&#xa0;</mml:mo>
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<mml:mstyle displaystyle="true">
<mml:mo>&#x222b;</mml:mo>
</mml:mstyle>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">w</mml:mi>
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</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">w</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:munderover>
<mml:msub>
<mml:mi>I</mml:mi>
<mml:mi>b</mml:mi>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mi>T</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#xa0;</mml:mo>
<mml:mi mathvariant="normal">d</mml:mi>
<mml:mi>&#x3bb;</mml:mi>
<mml:mi>z</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi mathvariant="normal">h</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mo>&#x2202;</mml:mo>
<mml:mi>T</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x2202;</mml:mo>
<mml:mi>z</mml:mi>
</mml:mrow>
</mml:mfrac>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
</mml:mrow>
</mml:math>
<label>(21c)</label>
</disp-formula>
</p>
<p>where <inline-formula id="inf86">
<mml:math id="m113">
<mml:mi>z</mml:mi>
</mml:math>
</inline-formula> is the coordinate measured from the irradiated surface, <inline-formula id="inf87">
<mml:math id="m114">
<mml:mi>&#x3c1;</mml:mi>
</mml:math>
</inline-formula>, <inline-formula id="inf88">
<mml:math id="m115">
<mml:mi>c</mml:mi>
</mml:math>
</inline-formula>, and <inline-formula id="inf89">
<mml:math id="m116">
<mml:mi>k</mml:mi>
</mml:math>
</inline-formula> are the density, the specific heat capacity, and the thermal conductivity of snow or ice, <inline-formula id="inf90">
<mml:math id="m117">
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mrow>
<mml:mi>a</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> is the temperature of ambient air (outside the thermal boundary layer), and <inline-formula id="inf91">
<mml:math id="m118">
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> is the convective heat transfer coefficient. The adiabatic condition at the boundary <inline-formula id="inf92">
<mml:math id="m119">
<mml:mrow>
<mml:mi>z</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi>h</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3e;</mml:mo>
<mml:mo>&#x3e;</mml:mo>
<mml:mi>d</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> means that we neglect heat transfer at <inline-formula id="inf93">
<mml:math id="m120">
<mml:mrow>
<mml:mi>z</mml:mi>
<mml:mo>&#x3e;</mml:mo>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi>h</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. Of course, the value of <inline-formula id="inf94">
<mml:math id="m121">
<mml:mrow>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">t</mml:mi>
<mml:mi>h</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> increases with time and should be estimated using additional calculations. The heat transfer coefficient is determined by a wind speed. The last term in the right-hand side of the boundary condition at <inline-formula id="inf95">
<mml:math id="m122">
<mml:mrow>
<mml:mi>z</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> is the mid-infrared radiative cooling due to thermal radiation of snowpack or ice sheet in the atmospheric transparency window of <inline-formula id="inf96">
<mml:math id="m123">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>w</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3c;</mml:mo>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3c;</mml:mo>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>w</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> (<inline-formula id="inf97">
<mml:math id="m124">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>w</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>8</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m, <inline-formula id="inf98">
<mml:math id="m125">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mrow>
<mml:mi>w</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>13</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> &#xb5;m) (<xref ref-type="bibr" rid="B25">Hossain and Gu 2016</xref>). The radiative cooling is limited during the night time when it is not compensated by solar mid-infrared radiation. Therefore, the coefficient <inline-formula id="inf99">
<mml:math id="m126">
<mml:mi>&#x3b5;</mml:mi>
</mml:math>
</inline-formula> varies from zero in the day time to the unity at night. The absorbed radiation power, <inline-formula id="inf100">
<mml:math id="m127">
<mml:mrow>
<mml:mi>P</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mi>z</mml:mi>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula>, at arbitrary conditions of solar illumination should be recalculated during the combined problem solution.</p>
<p>The latent heat of ice melting was accounted for by an equivalent increase in the heat capacity in a narrow temperature range near the melting temperature. This technique was successfully used in (<xref ref-type="bibr" rid="B9">Dombrovsky et al., 2009</xref>; <xref ref-type="bibr" rid="B14">Dombrovsky et al. 2015</xref>; <xref ref-type="bibr" rid="B11">Dombrovsky et al. 2019</xref>). It is interesting that the three cited papers considered completely different problems: the first of them dealt with the solidification of core melt droplets in a severe nuclear reactor accident, the second one with the freezing and thawing of biological tissues in cryosurgery, and the third one with the melting of freezing snow under periodic solar heating.</p>
<p>In numerical calculations, an implicit finite-difference scheme of the second order of approximation was used. Note that the model should be generalized in the case of significant snow melt or rain over snow, as water penetrates through the snow and solidifies at a greater depth.</p>
</sec>
<sec id="s6">
<title>Analysis of Solar Heating of a Snowpack</title>
<p>We used the algorithm and input data from (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>) to calculate the solar heating of snow. Because of the considerable uncertainty in the snow thermal conductivity (<xref ref-type="bibr" rid="B2">Arenson et al., 2015</xref>), there may be a systematic error. At the same time, changes in solar illumination conditions over time in the summer solstice and the local altitude of 70<sup>o</sup> were calculated accurately and the light scattered by cloudless atmosphere was taken into account as it was done by <xref ref-type="bibr" rid="B11">Dombrovsky et al. (2019)</xref>.</p>
<p>As an example, we consider the case of windless weather, when the heat transfer coefficient can be assumed to be <inline-formula id="inf101">
<mml:math id="m128">
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>6</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> W/(m<sup>2</sup> K) (<xref ref-type="bibr" rid="B7">Defraeye et al., 2011</xref>; <xref ref-type="bibr" rid="B39">Mirsadeghi et al., 2013</xref>). The temperature profiles in a snowpack calculated for the conventional first day of solar irradiation at <inline-formula id="inf102">
<mml:math id="m129">
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mrow>
<mml:mi>a</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi mathvariant="normal">r</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mn>0</mml:mn>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>10</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>&#xb0;C are presented in <xref ref-type="fig" rid="F7">Figure 7</xref>.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Typical profiles of temperature in snowpack in the evening: Solid lines&#x2014;complete calculations, dotted lines&#x2014;without radiative cooling.</p>
</caption>
<graphic xlink:href="fther-02-882941-g007.tif"/>
</fig>
<p>The calculations showed that the melting temperature is reached at noon near the surface (it is not shown in the figure) and temperature maximum is shifted to the depth about 5&#xa0;mm at 6 p.m. due to convective cooling (see <xref ref-type="fig" rid="F7">Figure 7</xref>). Further moving of the temperature maximum to the larger depth is accompanied by cooling of the surface layer of the snow cover. Convective cooling predominates in the evening hours, and radiative cooling is strongly manifested closer to midnight. Obviously, radiative cooling under cloudless skies should be taken into account during the period of weak solar irradiation.</p>
<p>Following (<xref ref-type="bibr" rid="B11">Dombrovsky et al., 2019</xref>), similar calculations can be made for solar heating of snow, for example, over 3&#xa0;days. However, the calculation of snow cover heating over many days and, even more so, over a long polar summer is associated with serious difficulties and requires the development of a special physical model. This task is beyond the scope of the present study. A simple physical estimate using the Fourier number for snow shows that it takes about 10 years for snow to warm to a depth of 100&#xa0;m. Note that the heating time is directly proportional to the square of the depth and the solar heat &#x201c;stored&#x201d; at depth during the summer continues to spread deep into the depths even during the polar winter.</p>
<p>Of course, the real process is more complicated and is not reduced to simple heat conduction. It is interesting to discuss briefly the main stages of the process for the case of a very thick snow layer. Most likely, at a not very deep depth, the snow will begin to melt. The resulting water will flow down between the snow particles. This flow is very slow because of the high hydraulic resistance of the dispersed medium with small pores and water will freeze at a slightly deeper depth, where the snow temperature is noticeably lower. This is how the ice layer will start to form, probably with gas bubbles scattering the radiation (<xref ref-type="bibr" rid="B12">Dombrovsky and Kokhanovsky 2020b</xref>). Solar heating in several years increases the thickness of the ice layer. Over many years, conditions may develop in which ice melting will lead to the formation of a gas cavity and a lake under the ice sheet. It is possible that deep solar heating is one of the reasons (along with ice melting under pressure and geothermal heat) for the formation of some of the many discovered lakes under the Greenland and Antarctic ice sheets.</p>
</sec>
<sec sec-type="conclusion" id="s7">
<title>Conclusion</title>
<p>A theoretical analysis of the conditions under which the absorption of collimated radiation penetrating into a weakly absorbing scattering medium has a maximum at a considerable distance from the illuminated surface was presented for the first time. It is shown that the maximum absorption of radiation inside an optically thick medium exists only at illumination angles less than 60&#xb0; from the normal. Both the depth at which the local absorption of solar radiation is maximum and the magnitude of this maximum are greatest at illumination along the normal. The greatest optical depth of the maximum location (by transport attenuation coefficient) is 3.23. In this case, the maximum local power of absorbed radiation energy is 85% higher than that at the illuminated surface of the medium. The obtained approximate analytical solution is general and applicable to various scattering media.</p>
<p>The possibility of deep heating of the pure snow cover by solar radiation during the polar summer is confirmed by calculations based on a general physical model, which is not limited to determining the solution for the absorbed radiation power. The transient problem of combined heat transfer was solved taking into account the change in the zenith angle of the Sun with time as well as the heat conduction in snow and both convective and radiative cooling of the snow surface.</p>
<p>The obtained numerical solution can be used for studies of the propagation of heat into the depth of the snowpack. It was shown that the computational results are not very sensitive to the choice between the published data for the absorption index of pure ice in the visible range. It is interesting that by the evening of the first sunny day, the snow temperature at a depth of 4&#xa0;mm becomes about 2&#xb0; higher than on the surface, and by midnight this temperature difference can reach 6&#xb0;, while the zone of maximum heating shifts to a depth of about 12&#xa0;cm. This process continues during the long polar summer, leading to heating and possible melting of snow at a considerable depth.</p>
<p>The calculations have shown that the radiative cooling of snow in the transparency window of the cloudless atmosphere should be taken into account during periods of relatively low solar illumination, even during the polar summer.</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s8">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec sec-type="author-contributions" id="s9">
<title>Author Contributions</title>
<p>LD and AK contributed to conception and design of the study. LD made the calculations and wrote the draft manuscript. Both authors contributed to manuscript revision, read, and approved the submitted version.</p>
</sec>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of Interest</title>
<p>Author AAK is employed by Brockman Consult.</p>
<p>The remaining author declares that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
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</person-group> (<year>2021</year>). <article-title>Enhanced Light Absorption and Reduced Snow Albedo Due to Internally Mixed mineral Dust in Grains of Snow</article-title>. <source>Atmos. Chem. Phys.</source> <volume>21</volume> (<issue>8</issue>), <fpage>6035</fpage>&#x2013;<lpage>6051</lpage>. <pub-id pub-id-type="doi">10.5194/acp-21-6035-2021</pub-id>
</citation>
</ref>
<ref id="B45">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Warren</surname>
<given-names>S. G.</given-names>
</name>
<name>
<surname>Brandt</surname>
<given-names>R. E.</given-names>
</name>
</person-group> (<year>2008</year>). <article-title>Optical Constants of Ice from the Ultraviolet to the Microwave: A Revised Compilation</article-title>. <source>J. Geophys. Res.</source> <volume>113</volume> (<issue>D14</issue>), <fpage>D14220</fpage>. <pub-id pub-id-type="doi">10.1029/2007JD009744</pub-id>
</citation>
</ref>
</ref-list>
<sec id="s12">
<title>Nomenclature</title>
<def-list>
<def-item>
<term id="G1-fther.2022.882941">
<inline-formula id="inf103">
<mml:math id="m130">
<mml:mi>a</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>radius of ice grain, &#xb5;m</p>
</def>
</def-item>
<def-item>
<term id="G2-fther.2022.882941">
<inline-formula id="inf104">
<mml:math id="m131">
<mml:mi>c</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>specific heat capacity, J/(kg K)</p>
</def>
</def-item>
<def-item>
<term id="G3-fther.2022.882941">
<inline-formula id="inf105">
<mml:math id="m132">
<mml:mi>d</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>thickness, m</p>
</def>
</def-item>
<def-item>
<term id="G4-fther.2022.882941">
<inline-formula id="inf106">
<mml:math id="m133">
<mml:mi>E</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>exponential function</p>
</def>
</def-item>
<def-item>
<term id="G5-fther.2022.882941">
<inline-formula id="inf107">
<mml:math id="m134">
<mml:mrow>
<mml:msub>
<mml:mi>f</mml:mi>
<mml:mi>v</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>volume fraction</p>
</def>
</def-item>
<def-item>
<term id="G6-fther.2022.882941">
<inline-formula id="inf108">
<mml:math id="m135">
<mml:mi>G</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>spectral irradiance, W/(m<sup>2</sup> &#xb5;m)</p>
</def>
</def-item>
<def-item>
<term id="G7-fther.2022.882941">
<inline-formula id="inf109">
<mml:math id="m136">
<mml:mi>h</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>heat transfer coefficient, W/(m<sup>2</sup> K)</p>
</def>
</def-item>
<def-item>
<term id="G8-fther.2022.882941">
<inline-formula id="inf110">
<mml:math id="m137">
<mml:mi>I</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>spectral radiation intensity, W/(m<sup>2</sup> &#xb5;m)</p>
</def>
</def-item>
<def-item>
<term id="G9-fther.2022.882941">
<inline-formula id="inf111">
<mml:math id="m138">
<mml:mi>J</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>diffuse radiation intensity, W/(m<sup>2</sup> &#xb5;m)</p>
</def>
</def-item>
<def-item>
<term id="G10-fther.2022.882941">
<inline-formula id="inf112">
<mml:math id="m139">
<mml:mi>k</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>thermal conductivity, W/(m K)</p>
</def>
</def-item>
<def-item>
<term id="G11-fther.2022.882941">
<inline-formula id="inf113">
<mml:math id="m140">
<mml:mi>m</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>complex index of refraction</p>
</def>
</def-item>
<def-item>
<term id="G12-fther.2022.882941">
<inline-formula id="inf114">
<mml:math id="m141">
<mml:mi>n</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>index of refraction</p>
</def>
</def-item>
<def-item>
<term id="G13-fther.2022.882941">
<inline-formula id="inf115">
<mml:math id="m142">
<mml:mi>P</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>absorbed radiative power, W/m<sup>3</sup>
</p>
</def>
</def-item>
<def-item>
<term id="G14-fther.2022.882941">
<inline-formula id="inf116">
<mml:math id="m143">
<mml:mi>p</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>spectral radiative power, W/(m<sup>3</sup> &#xb5;m)</p>
</def>
</def-item>
<def-item>
<term id="G15-fther.2022.882941">
<inline-formula id="inf117">
<mml:math id="m144">
<mml:mi>Q</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>efficiency factor</p>
</def>
</def-item>
<def-item>
<term id="G16-fther.2022.882941">
<inline-formula id="inf118">
<mml:math id="m145">
<mml:mi>T</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>temperature, K or &#xb0;C</p>
</def>
</def-item>
<def-item>
<term id="G17-fther.2022.882941">
<inline-formula id="inf119">
<mml:math id="m146">
<mml:mi mathvariant="normal">t</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>time, h</p>
</def>
</def-item>
<def-item>
<term id="G18-fther.2022.882941">
<inline-formula id="inf120">
<mml:math id="m147">
<mml:mi>x</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>diffraction parameter</p>
</def>
</def-item>
<def-item>
<term id="G19-fther.2022.882941">
<inline-formula id="inf121">
<mml:math id="m148">
<mml:mi>z</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>coordinate, m</p>
</def>
</def-item>
</def-list>
</sec>
<sec id="s13">
<title>Greek Symbols</title>
<def-list>
<def-item>
<term id="G20-fther.2022.882941">
<inline-formula id="inf122">
<mml:math id="m149">
<mml:mi>&#x3b1;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>absorption coefficient, m<sup>&#x2212;1</sup>
</p>
</def>
</def-item>
<def-item>
<term id="G21-fther.2022.882941">
<inline-formula id="inf123">
<mml:math id="m150">
<mml:mi>&#x3b2;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>extinction coefficient, m<sup>&#x2212;1</sup>
</p>
</def>
</def-item>
<def-item>
<term id="G22-fther.2022.882941">
<inline-formula id="inf124">
<mml:math id="m151">
<mml:mi>&#x3b4;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>Dirac delta and declination of the Sun, rad</p>
</def>
</def-item>
<def-item>
<term id="G23-fther.2022.882941">
<inline-formula id="inf125">
<mml:math id="m152">
<mml:mi>&#x3b5;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>coefficient in <xref ref-type="disp-formula" rid="e21c">Eq. 21c</xref>
</p>
</def>
</def-item>
<def-item>
<term id="G24-fther.2022.882941">
<inline-formula id="inf126">
<mml:math id="m153">
<mml:mi>&#x3b6;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>coefficient introduced by <xref ref-type="disp-formula" rid="e18">Eq. 18</xref>
</p>
</def>
</def-item>
<def-item>
<term id="G25-fther.2022.882941">
<inline-formula id="inf127">
<mml:math id="m154">
<mml:mi>&#x3b8;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>zenith angle, rad</p>
</def>
</def-item>
<def-item>
<term id="G26-fther.2022.882941">
<inline-formula id="inf128">
<mml:math id="m155">
<mml:mi>&#x3ba;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>index of absorption</p>
</def>
</def-item>
<def-item>
<term id="G27-fther.2022.882941">
<inline-formula id="inf129">
<mml:math id="m156">
<mml:mi>&#x3bb;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>radiation wavelength, &#xb5;m</p>
</def>
</def-item>
<def-item>
<term id="G28-fther.2022.882941">
<inline-formula id="inf130">
<mml:math id="m157">
<mml:mi>&#x3bc;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>cosine of an angle</p>
</def>
</def-item>
<def-item>
<term id="G29-fther.2022.882941">
<inline-formula id="inf131">
<mml:math id="m158">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>&#x3bc;</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>asymmetry factor of scattering</p>
</def>
</def-item>
<def-item>
<term id="G30-fther.2022.882941">
<inline-formula id="inf132">
<mml:math id="m159">
<mml:mi>&#x3be;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>parameter introduced by <xref ref-type="disp-formula" rid="e12b">Eq. 12b</xref>
</p>
</def>
</def-item>
<def-item>
<term id="G31-fther.2022.882941">
<italic>&#x3c1;</italic>
</term>
<def>
<p>density, kg/m<sup>3</sup>
</p>
</def>
</def-item>
<def-item>
<term id="G32-fther.2022.882941">
<inline-formula id="inf133">
<mml:math id="m160">
<mml:mi>&#x3c3;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>scattering coefficient, m<sup>&#x2212;1</sup>
</p>
</def>
</def-item>
<def-item>
<term id="G33-fther.2022.882941">
<inline-formula id="inf134">
<mml:math id="m161">
<mml:mi>&#x3c4;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>optical thickness</p>
</def>
</def-item>
<def-item>
<term id="G34-fther.2022.882941">
<inline-formula id="inf135">
<mml:math id="m162">
<mml:mi>&#x3a6;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>scattering phase function</p>
</def>
</def-item>
<def-item>
<term id="G35-fther.2022.882941">
<inline-formula id="inf136">
<mml:math id="m163">
<mml:mi>&#x3c9;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>single scattering albedo</p>
</def>
</def-item>
</def-list>
</sec>
<sec id="s14">
<title>Subscripts and Superscripts</title>
<def-list>
<def-item>
<term id="G36-fther.2022.882941">0</term>
<def>
<p>initial value</p>
</def>
</def-item>
<def-item>
<term id="G37-fther.2022.882941">a</term>
<def>
<p>radius of ice grain, &#xb5;m</p>
</def>
<def>
<p>absorption</p>
</def>
</def-item>
<def-item>
<term id="G38-fther.2022.882941">air</term>
<def>
<p>air</p>
</def>
</def-item>
<def-item>
<term id="G39-fther.2022.882941">b</term>
<def>
<p>blackbody</p>
</def>
</def-item>
<def-item>
<term id="G40-fther.2022.882941">c</term>
<def>
<p>critical</p>
</def>
</def-item>
<def-item>
<term id="G41-fther.2022.882941">nir</term>
<def>
<p>near-infrared</p>
</def>
</def-item>
<def-item>
<term id="G42-fther.2022.882941">s</term>
<def>
<p>scattering</p>
</def>
</def-item>
<def-item>
<term id="G43-fther.2022.882941">sky</term>
<def>
<p>sky</p>
</def>
</def-item>
<def-item>
<term id="G44-fther.2022.882941">sol</term>
<def>
<p>solar</p>
</def>
</def-item>
<def-item>
<term id="G45-fther.2022.882941">surf</term>
<def>
<p>surface</p>
</def>
</def-item>
<def-item>
<term id="G46-fther.2022.882941">th</term>
<def>
<p>thermal</p>
</def>
</def-item>
<def-item>
<term id="G47-fther.2022.882941">tr</term>
<def>
<p>transport</p>
</def>
</def-item>
<def-item>
<term id="G48-fther.2022.882941">vis</term>
<def>
<p>visible range</p>
</def>
</def-item>
<def-item>
<term id="G49-fther.2022.882941">w</term>
<def>
<p>spectral window</p>
</def>
</def-item>
<def-item>
<term id="G50-fther.2022.882941">&#x3bb;</term>
<def>
<p>spectral</p>
</def>
</def-item>
</def-list>
</sec>
</back>
</article>