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<article article-type="research-article" dtd-version="2.3" xml:lang="EN" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">
<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Mech. Eng</journal-id>
<journal-title>Frontiers in Mechanical Engineering</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Mech. Eng</abbrev-journal-title>
<issn pub-type="epub">2297-3079</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">887657</article-id>
<article-id pub-id-type="doi">10.3389/fmech.2022.887657</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Mechanical Engineering</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Non-Reacting Spray Characteristics of Gasoline and Diesel With a Heavy-Duty Single-Hole Injector</article-title>
<alt-title alt-title-type="left-running-head">Tzanetakis et al.</alt-title>
<alt-title alt-title-type="right-running-head">High-Pressure Non-Reacting Gasoline Spray Characteristics</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Tzanetakis</surname>
<given-names>Tom</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1290376/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Johnson</surname>
<given-names>Jaclyn</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1702033/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Schmidt</surname>
<given-names>Henry</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Atkinson</surname>
<given-names>William</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1710190/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Naber</surname>
<given-names>Jeffrey</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/233073/overview"/>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>Aramco Americas: Aramco Research Center - Detroit</institution>, <addr-line>Detroit</addr-line>, <addr-line>MI</addr-line>, <country>United States</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Advanced Power Systems Research Center</institution>, <institution>Department of Mechanical Engineering-Engineering Mechanics</institution>, <institution>Michigan Technological University</institution>, <addr-line>Houghton</addr-line>, <addr-line>MI</addr-line>, <country>United States</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1288555/overview">Cinzia Tornatore</ext-link>, CNR&#x2014;Istituto di Scienze e Tecnologie per l&#x2019;Energia e la Mobilit&#xe0; Sostenibili (STEMS), Italy</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1706897/overview">Isaac Ekoto</ext-link>, Sandia National Laboratories (SNL), United States</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/986175/overview">Haifeng Liu</ext-link>, Tianjin University, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Tom Tzanetakis, <email>tom.tzanetakis@aramcoamericas.com</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Engine and Automotive Engineering, a section of the journal Frontiers in Mechanical Engineering</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>19</day>
<month>05</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>8</volume>
<elocation-id>887657</elocation-id>
<history>
<date date-type="received">
<day>01</day>
<month>03</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>28</day>
<month>03</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Tzanetakis, Johnson, Schmidt, Atkinson and Naber.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Tzanetakis, Johnson, Schmidt, Atkinson and Naber</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>Gasoline compression ignition (GCI) is a promising combustion technology that could help alleviate the projected demand for diesel in commercial transport while providing a pathway to achieve upcoming CO<sub>2</sub> and criteria pollutant regulations for heavy-duty engines. However, relatively high (i.e., diesel-like) injection pressures are needed to enable GCI across the entire load range while maintaining soot emissions benefits and managing heat release rates. There have only been a limited number of previous studies investigating the spray characteristics of light distillates with high-pressure direct-injection hardware under charge gas conditions relevant to heavy-duty applications. The current work aims to address this issue while providing experimental data needed for calibrating spray models used in simulation-led design activities. The non-reacting spray characteristics of two gasoline-like fuels relevant to GCI were studied and compared to ultra-low-sulfur diesel (ULSD). These fuels shared similar physical properties and were thus differentiated based on their research octane number (RON). Although RON60 and RON92 had different reactivities, it was hypothesized that they would exhibit similar non-reacting spray characteristics due to their physical similarities. Experiments were conducted in an optically accessible, constant volume combustion chamber using a single-hole injector representing high-pressure, common-rail fuel systems. Shadowgraph and Mie-scattering techniques were employed to measure the spray dispersion angles and penetration lengths under both non-vaporizing and vaporizing conditions. Gasoline-like fuels exhibited similar or larger non-vaporizing dispersion angle compared to ULSD. All fuels followed a typical correlation based on air-to-fuel density ratio indicating that liquid density is the main governing fuel parameter. Injection pressure had a negligible effect on the dispersion angle. Gasoline-like fuels had slower non-vaporizing penetration rates compared to ULSD, primarily due to their larger dispersion angles. As evidenced by the collapse of data onto a non-dimensional penetration correlation over a wide range of test conditions, all fuels conformed to the expected physical theory governing non-vaporizing sprays. There was no significant trend in the vaporizing dispersion angle with respect to fuel type which remained relatively constant across the entire charge gas temperature range of 800&#x2013;1200&#xa0;K. There was also no discernable difference in vapor penetration among the fuels or across charge temperature. The liquid length of gasoline-like fuels was much shorter than ULSD and exhibited no dependence on charge temperature at a given charge gas pressure. This behavior was attributed to gasoline being limited by interphase transport as opposed to mixing or air entrainment rates during its evaporation process. RON92 had a larger non-vaporizing dispersion angle but similar penetration compared to RON60. Although this seems to violate the original similarity hypothesis for these fuels, the analysis was made difficult due to the use of different injector builds for the experiments. However, RON92 did show a slightly larger vapor dispersion angle than RON60 and ULSD. This observation was attributed to nuanced volatility differences between the gasoline-like fuels and indicates that vapor dispersion angle likely relies on a more complex correlation beyond that of only air-to-fuel density ratio. Finally, RON92 showed the same quantitative liquid length and insensitivity to charge gas temperature as RON60.</p>
</abstract>
<kwd-group>
<kwd>gasoline</kwd>
<kwd>high pressure</kwd>
<kwd>common rail (CR)</kwd>
<kwd>fuel injection</kwd>
<kwd>sprays</kwd>
<kwd>non-reacting</kwd>
</kwd-group>
<contract-sponsor id="cn001">Aramco Americas<named-content content-type="fundref-id">10.13039/100016861</named-content>
</contract-sponsor>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Liquid petroleum is projected to continue providing a large share of transportation sector energy over the next 30&#xa0;years (<xref ref-type="bibr" rid="B36">U.S. Energy Information Administration, 2021</xref>; <xref ref-type="bibr" rid="B13">International Energy Agency, 2021</xref>). This is primarily due to its high energy density and ease of distribution. Demand for middle distillates like diesel and kerosene is also expected to rise within the commercial transport sector (<xref ref-type="bibr" rid="B8">ExxonMobil, 2021</xref>). These fuels are needed to support the increased economic activity associated with large, continuously developing nations. At the same time, demand for light distillates like gasoline is expected to decrease due to efficiency gains in the passenger vehicle sector (i.e., hybridization, electrification, etc.) (<xref ref-type="bibr" rid="B8">ExxonMobil, 2021</xref>). This scenario will create a demand disparity which could have negative economic impacts on commercial freight operators that rely solely on medium distillates. Furthermore, greenhouse gas and criteria pollutant emissions regulations for the on-road commercial transport sector are becoming far more stringent and difficult to meet with conventional diesel powertrains.</p>
<p>Gasoline compression ignition (GCI) is one technology that could help address the projected demand shift by using light distillates in the heavy-duty transportation sector. Recent research has shown that compared to diesel combustion, GCI can drastically reduce soot emissions while maintaining relatively low engine-out NOx (<xref ref-type="bibr" rid="B42">Zhang et al., 2016</xref>; <xref ref-type="bibr" rid="B41">Zhang et al., 2018</xref>). This is due to the higher volatility, lower viscosity, longer ignition delay, and better fuel-air mixing achieved with gasoline-like fuels. The improved soot-NOx tradeoff could also help alleviate the tremendous operational and durability demands placed on modern lean aftertreatment systems for meeting upcoming emissions regulations (<xref ref-type="bibr" rid="B18">Lee et al., 2017</xref>; <xref ref-type="bibr" rid="B17">Lee et al., 2019</xref>; <xref ref-type="bibr" rid="B27">Sharp et al., 2021</xref>). Optimizing the combustion system for GCI (i.e., piston bowl shape, injector, and air system configurations) also has the potential to improve fuel economy compared to the most efficient internal combustion engines today (<xref ref-type="bibr" rid="B15">Kumar et al., 2019</xref>; <xref ref-type="bibr" rid="B24">Pei et al., 2019</xref>; <xref ref-type="bibr" rid="B26">Sellnau et al., 2019</xref>). However, relatively high injection pressures (&#x3e;1,000 bar) are needed to simultaneously manage soot emissions and heat release rates over the entire operating range of the engine, especially at high loads. Therefore, it is important to consider the use of high-pressure common rail injection systems as a key enabler for GCI.</p>
<p>There are only a few prior studies that have investigated the spray behavior of gasoline at high, diesel-like injection pressures (<xref ref-type="bibr" rid="B23">Payri et al., 2012a</xref>; <xref ref-type="bibr" rid="B22">Payri et al., 2012b</xref>; <xref ref-type="bibr" rid="B12">Han et al., 2014</xref>; <xref ref-type="bibr" rid="B11">Feng et al., 2016</xref>; <xref ref-type="bibr" rid="B6">Engine Combustion Network (ECN), 2022a</xref>). Even fewer have considered charge gas conditions and injector hardware relevant to heavy-duty compression ignition applications (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>; <xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>; <xref ref-type="bibr" rid="B32">Tang et al., 2017b</xref>; <xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). The current study aims to address these gaps by investigating the spray characteristics of a heavy-duty, high-pressure common rail injector operating with real gasoline-like fuels. This work is an extension of three preceding studies which used optical diagnostics to measure the spray behavior of a unique light distillate under similar boundary conditions using a heavy-duty injector (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>; <xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>; <xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). Non-reacting test results for this and market gasoline will be presented and compared to ultra-low-sulfur diesel (ULSD) at operating conditions relevant to heavy-duty GCI. The data is intended to shed light on the governing physics of high-pressure gasoline sprays and provide calibration data for high-fidelity models used in the simulation-led design of GCI combustion systems.</p>
</sec>
<sec id="s2">
<title>2 Materials and Methods</title>
<sec id="s2-1">
<title>2.1 Fuel Specifications</title>
<p>
<xref ref-type="table" rid="T1">Table 1</xref> lists the fuel properties of ULSD and two light distillates that can be used in GCI applications. The RON60 is named as such because it has a research octane number (RON) of about 60. It exhibits similar reactivity to diesel but represents a drastic change in physical properties like density, viscosity, and volatility. The RON92 has an octane rating equivalent to that of regular market gasoline but contains no ethanol. Oxygenated compounds were avoided for this initial study to reduce the complexity in comparative analysis between RON92 gasoline and the other pure hydrocarbon fuels.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Fuel properties.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Property</th>
<th align="center">Units</th>
<th align="center">Method</th>
<th align="center">ULSD</th>
<th align="center">RON60</th>
<th align="center">RON92</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Density</td>
<td align="left">kg/m<sup>3</sup>
</td>
<td align="left">ASTM D4052</td>
<td align="char" char=".">848.0</td>
<td align="char" char=".">707.4</td>
<td align="char" char=".">733.1</td>
</tr>
<tr>
<td align="left">Viscosity<sup>1</sup>
</td>
<td align="left">cSt</td>
<td align="left">ASTM D445</td>
<td align="char" char=".">2.6</td>
<td align="char" char=".">0.572</td>
<td align="char" char=".">0.550</td>
</tr>
<tr>
<td align="left">IBP</td>
<td align="left">&#xb0;C</td>
<td align="left">ASTM D86</td>
<td align="char" char=".">173.3</td>
<td align="char" char=".">35.7</td>
<td align="char" char=".">35.7</td>
</tr>
<tr>
<td align="left">T10</td>
<td align="left">&#xb0;C</td>
<td align="left">ASTM D86</td>
<td align="char" char=".">214.4</td>
<td align="char" char=".">61.3</td>
<td align="char" char=".">52.2</td>
</tr>
<tr>
<td align="left">T50</td>
<td align="left">&#xb0;C</td>
<td align="left">ASTM D86</td>
<td align="char" char=".">267.8</td>
<td align="char" char=".">95.2</td>
<td align="char" char=".">81.0</td>
</tr>
<tr>
<td align="left">T90</td>
<td align="left">&#xb0;C</td>
<td align="left">ASTM D86</td>
<td align="char" char=".">315.0</td>
<td align="char" char=".">123.7</td>
<td align="char" char=".">148.7</td>
</tr>
<tr>
<td align="left">FBP</td>
<td align="left">&#xb0;C</td>
<td align="left">ASTM D86</td>
<td align="center">347.0</td>
<td align="char" char=".">135.2</td>
<td align="char" char=".">198.1</td>
</tr>
<tr>
<td align="left">RVP<sup>2</sup>
</td>
<td align="left">kPa</td>
<td align="left">ASTM D5191</td>
<td align="center">n/a</td>
<td align="char" char=".">48.8</td>
<td align="char" char=".">57.1</td>
</tr>
<tr>
<td align="left">WSD<sup>3</sup>
</td>
<td align="left">&#x3bc;m</td>
<td align="left">ASTM D6079</td>
<td align="center">570</td>
<td align="char" char=".">400</td>
<td align="char" char=".">290</td>
</tr>
<tr>
<td align="left">Saturates</td>
<td align="left">% Vol</td>
<td align="left">ASTM D1319</td>
<td align="center">71.0</td>
<td align="char" char=".">88.4</td>
<td align="char" char=".">65.7</td>
</tr>
<tr>
<td align="left">Olefins</td>
<td align="left">% Vol</td>
<td align="left">ASTM D1319</td>
<td align="center">1.0</td>
<td align="char" char=".">4.3</td>
<td align="char" char=".">8.8</td>
</tr>
<tr>
<td align="left">Aromatics</td>
<td align="left">% Vol</td>
<td align="left">ASTM D1319</td>
<td align="center">28.0</td>
<td align="char" char=".">7.3</td>
<td align="char" char=".">25.5</td>
</tr>
<tr>
<td align="left">Oxygen</td>
<td align="left">% Wt</td>
<td align="left">ASTM D5622</td>
<td align="center">n/a</td>
<td align="char" char=".">0.11</td>
<td align="char" char=".">&#x3c;0.05</td>
</tr>
<tr>
<td align="left">Sulfur</td>
<td align="left">ppm (m)</td>
<td align="left">ASTM D5453</td>
<td align="center">8</td>
<td align="char" char=".">10.5</td>
<td align="char" char=".">4</td>
</tr>
<tr>
<td align="left">H/C Ratio</td>
<td align="left">mol/mol</td>
<td align="left">ASTM D5291</td>
<td align="center">1.82</td>
<td align="char" char=".">2.14</td>
<td align="char" char=".">1.89</td>
</tr>
<tr>
<td align="left">LHV</td>
<td align="left">MJ/kg</td>
<td align="left">ASTM D240</td>
<td align="center">42.83</td>
<td align="char" char=".">44.25</td>
<td align="char" char=".">43.45</td>
</tr>
<tr>
<td align="left">RON</td>
<td align="left">--</td>
<td align="left">ASTM D2699</td>
<td align="center">n/a</td>
<td align="char" char=".">57.7</td>
<td align="char" char=".">92.0</td>
</tr>
<tr>
<td align="left">MON</td>
<td align="left">--</td>
<td align="left">ASTM D2700</td>
<td align="center">n/a</td>
<td align="char" char=".">58.0</td>
<td align="char" char=".">84.0</td>
</tr>
<tr>
<td align="left">(D)CN<sup>4</sup>
</td>
<td align="left">--</td>
<td align="left">ASTM D613</td>
<td align="center">44.2</td>
<td align="char" char=".">37.3</td>
<td align="char" char=".">20.5</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn>
<p>Notes: (1) Measured at 40&#xb0;C for diesel, 20&#xb0;C for gasoline, (2) Reid vapor pressure of diesel is below detection limit of method (i.e., 7&#xa0;kPa), (3) Measured at 60&#xb0;C for diesel, 25&#xb0;C for gasoline, (4) Derived cetane number (DCN) measured <italic>via</italic> ASTM D6890 for gasoline only.</p>
</fn>
</table-wrap-foot>
</table-wrap>
<p>The rationale for selecting RON60 and RON92 is elucidated in <xref ref-type="fig" rid="F1">Figure 1</xref>. Viscosity is used as a singular metric for physical properties because it strongly correlates with volatility and density for petroleum distillates (<xref ref-type="bibr" rid="B1">Aleme et al., 2012</xref>). Existing within a similar reactivity range as diesel, RON60 allows the impact of gasoline physical properties on spray behavior to be somewhat isolated and studied. Then, with similar physical properties to RON60 but much lower cetane number, RON92 allows the impact of reactivity differences among gasoline range fuel sprays to be investigated. Excluding the ethanol content, RON92 also closely matches the properties of market gasoline, which is the ultimate target fuel for near-term GCI applications. ULSD provides an established baseline to compare gasoline-like fuels with in high-pressure, direct injection hardware. Since RON60 and RON92 share similar physical properties, it is expected that non-reacting spray characteristics like penetration and dispersion angle should also be similar. This hypothesis has been previously verified with gasoline direct injection (GDI) hardware up to fuel pressures of 450 bar (<xref ref-type="bibr" rid="B39">Zhang et al., 2020</xref>). The aim of the current work is to extend this validation to higher fuel pressures with common rail hardware at charge conditions relevant to heavy-duty engines. Although only non-reacting conditions are considered, the fuels are distinguished according to their research octane number to be consistent with other GCI combustion studies which focus on reacting spray characteristics or engine performance and emissions (<xref ref-type="bibr" rid="B32">Tang et al., 2017b</xref>; <xref ref-type="bibr" rid="B41">Zhang et al., 2018</xref>). Some nuanced differences in non-reacting spray behavior are expected between the gasolines driven primarily by their distinctive density and distillation characteristics (i.e., final boiling points). However, these will be further elaborated upon in the results section.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Middle and light distillate fuel property ranges.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g001.tif"/>
</fig>
<p>One additional note should be mentioned regarding fuel lubricity. The neat wear scar diameter (WSD) of gasoline-like fuels typically ranges between 700 and 1000&#xa0;&#x3bc;m (<xref ref-type="bibr" rid="B2">Arkoudeas et al., 2014</xref>). The WSDs of RON60 and RON92 were brought below the maximum value recommended for high-pressure injection equipment by dosing them with 200&#xa0;ppm of a lubricity-improving additive (<xref ref-type="bibr" rid="B16">Lacey and Mason, 2000</xref>; <xref ref-type="bibr" rid="B37">Voice et al., 2017</xref>).</p>
</sec>
<sec id="s2-2">
<title>2.2 Experimental Setup</title>
<p>A constant-volume, optically accessible combustion chamber was used to generate the charge gas conditions pertaining to heavy-duty compression ignition applications (<xref ref-type="bibr" rid="B42">Zhang et al., 2016</xref>; <xref ref-type="bibr" rid="B41">Zhang et al., 2018</xref>). The 1&#xa0;L vessel was rated to a maximum pressure and temperature of 345 bar and 2000&#xa0;K, respectively.</p>
<p>For non-vaporizing tests, fuel and charge temperatures were kept at 40&#xb0;C (313&#xa0;K) to minimize phase change within the spray. Pure N<sub>2</sub> gas was used to backfill the vessel and provide the desired charge density. <xref ref-type="fig" rid="F2">Figure 2</xref> compares fuel distillation curves to the vessel temperature and indicates that significant evaporation was not expected. <xref ref-type="fig" rid="F3">Figure 3</xref> shows the Z-type shadowgraph image setup used to measure liquid spray penetration and dispersion angle under non-vaporizing conditions (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>; <xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). A FASTCAM SA 1.1 high-speed camera with an 85&#xa0;mm Nikon lens and a lens aperture setting of f/1.4 was employed to capture the spray evolution at 30,000 frames per second (FPS).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Fuel distillation curves (ASTM D86) compared to non-evaporating ambient vessel temperature.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g002.tif"/>
</fig>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Optical setup for non-reacting, non-vaporizing tests, reproduced with permission from <xref ref-type="bibr" rid="B30">Tang et al. (2018)</xref>, &#x00A9; SAE International.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g003.tif"/>
</fig>
<p>High temperature vaporizing conditions were achieved by using a lean-dilute, acetylene-hydrogen fueled pre-burn process in the vessel. The initial fuel-air mixture composition was designed so that the thermodynamic end state of the pre-burn combustion process simulated the desired charge gas conditions to be studied without any excess oxygen. Prior to ignition of the pre-burn mixture by a spark discharge, two small fans spinning in opposite directions stirred the gaseous contents to obtain a uniform temperature profile within the chamber. Liquid fuel injection was triggered only when the desired charge pressure and temperature were reached during the cool-down phase of the gas. This occurred after the pre-burn process was completed and heat was lost through the relatively cool vessel walls which were pre-conditioned to 180&#xb0;C with electrical heating. A separate cooling circuit was also employed around the injector tip to keep fuel temperature at 85&#xb0;C regardless of the gas conditions. This was required due to heat transfer from the electrically heated vessel and pre-burn product gases to the injector tip. Additional details about the constant-volume chamber and pre-burn process may be found elsewhere (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>; <xref ref-type="bibr" rid="B25">Pickett et al., 2005</xref>; <xref ref-type="bibr" rid="B14">Johnson et al., 2009</xref>; <xref ref-type="bibr" rid="B5">Engine Combustion Network (ECN), 2022b</xref>).</p>
<p>
<xref ref-type="fig" rid="F4">Figure 4</xref> shows the near-simultaneous Z-type shadowgraph/Mie-scattering layout designed to capture the time evolution of liquid length, vapor penetration, and vapor dispersion angle under evaporating conditions (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>; <xref ref-type="bibr" rid="B39">Zhang et al., 2020</xref>). The same high-speed camera previously described was also used for this optical setup but with two Lightspeed Technologies HPLS-36AD3500 light emitting diodes (LEDs). One LED provided the light source for a Mie-scattering image to capture liquid length, while the other produced a shadowgraph image to determine the vapor penetration and dispersion angle. <xref ref-type="fig" rid="F4">Figure 4</xref> also shows how each LED was synchronized to flash separately in time with the camera shutter at 30,000 FPS (i.e., every 33.3&#xa0;&#x3bc;s).</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Optical setup and synchronized LED signals for non-reacting, vaporizing tests, reproduced with permission from <xref ref-type="bibr" rid="B39">Zhang et al. (2020)</xref>, &#x00A9; SAE International.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g004.tif"/>
</fig>
</sec>
<sec id="s2-3">
<title>2.3 Injector</title>
<p>
<xref ref-type="table" rid="T2">Table 2</xref> describes the single-hole injector used in this study. The design was based on a production heavy-duty Cummins XPI injector used in current ISX15 engines. Like most high-pressure diesel hardware, it consisted of a solenoid driven, hydraulically lifted main needle. However, the hole was placed along the central axis of the nozzle tip, as in the Engine Combustion Network (ECN) &#x201c;Spray-D&#x201d; configuration (<xref ref-type="bibr" rid="B7">Engine Combustion Network (ECN), 2022c</xref>; <xref ref-type="bibr" rid="B38">Yasutomi et al., 2019</xref>). The exit diameter, internal taper (K-factor), and peak flow capacity of the single-hole nozzle were targeted to match those of one hole from the production part as closely as possible (<xref ref-type="bibr" rid="B33">Torelli et al., 2018</xref>). Due to internal nozzle flow differences which impact the fuel injection rate shape profile and issuing spray behavior, this single-hole design may not be completely representative of the real multi-hole application (<xref ref-type="bibr" rid="B34">Torelli et al., 2021</xref>). However, it does enable high-fidelity optical interrogation of a single plume for detailed modeling and analysis studies.</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Single-hole injector specifications.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Parameter</th>
<th align="center">Value</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Nozzle exit hole diameter (&#x3bc;m)</td>
<td align="char" char=".">176</td>
</tr>
<tr>
<td align="left">Orifice taper (K-factor)</td>
<td align="char" char=".">1.8</td>
</tr>
<tr>
<td align="left">Discharge coefficient (<italic>C</italic>
<sub>
<italic>d</italic>
</sub>)</td>
<td align="char" char=".">0.94</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s2-4">
<title>2.4 Image and Data Processing</title>
<p>
<xref ref-type="fig" rid="F5">Figure 5</xref> shows the methodology used to extract penetration and dispersion angle from shadowgraph images under non-vaporizing conditions (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>; <xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>):<list list-type="simple">
<list-item>
<p>(1) Read in grayscale data from an uncompressed, 8-bit image file</p>
</list-item>
<list-item>
<p>(2) Perform background subtraction</p>
</list-item>
<list-item>
<p>(3) Apply threshold to grayscale and obtain a binary, black/white image</p>
</list-item>
<list-item>
<p>(4) Identify the spray boundary and extract penetration length based on a specific definition</p>
</list-item>
<list-item>
<p>(5) Extract the dispersion angle based on a specific definition</p>
</list-item>
</list>
</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Non-vaporizing image processing methodology, reproduced with permission from <xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>, <xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>, &#x00A9; SAE International.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g005.tif"/>
</fig>
<p>Non-vaporizing penetration length was defined as the distance downstream of the injector tip which captured 99% of the total spray area. Two separate methods were considered for determining the spray dispersion angle. The first definition was to perform a linear fit on both sides of the spray plume boundary between the injector tip and 60% of its penetration (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>). The second definition employed the same linear fit technique but only within 45 exit hole diameters (<inline-formula id="inf1">
<mml:math id="m1">
<mml:mrow>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>) downstream of the nozzle tip (<xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). A threshold corresponding to 5% of the upper limit of pixel intensity was used to define the spray boundary. Prior work showed that changing the threshold value by &#xb1; 20% had a negligible impact on spray penetration and dispersion angle measurements (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>). Therefore, the image processing methodology was insensitive to the choice of threshold.</p>
<p>
<xref ref-type="fig" rid="F6">Figure 6</xref> shows the post-processing methodology applied to shadowgraph images under vaporizing conditions (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>). Steps 1&#x2013;4 were essentially the same as those applied to the corresponding Mie-scattering images and previously to non-vaporizing images with only minor differences. Mie-scattering background subtraction was performed in the standard way due to the high contrast between the liquid spray and charge gas. However, vaporizing shadowgraph background subtraction was performed using the previous frame image due to the lack of contrast between fuel vapor and background gas. Instead of using a 5% max intensity threshold to determine the spray boundary, Otsu&#x2019;s method was applied to extract a global threshold from the vaporizing shadowgraph images and create a binary image (<xref ref-type="bibr" rid="B20">Otsu, 1979</xref>). The definitions for liquid penetration, vapor penetration, and vapor dispersion angle were consistent with those used in the non-vaporizing tests. Varying the threshold values by &#xb1; 50% resulted in less than 3% difference among the measured parameters, indicating that the vaporizing post-processing technique was also insensitive to the choice of threshold (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>). <xref ref-type="fig" rid="F7">Figure 7</xref> shows an example of shadowgraph and Mie-scattered image boundaries under vaporizing conditions 0.8&#xa0;ms after the start of injection (ASOI) (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>).</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Vaporizing shadowgraph image processing methodology (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>).</p>
</caption>
<graphic xlink:href="fmech-08-887657-g006.tif"/>
</fig>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Example of vaporizing shadowgraph and Mie scattering image spray boundary tracking (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>).</p>
</caption>
<graphic xlink:href="fmech-08-887657-g007.tif"/>
</fig>
<p>Due to the finite capture rate of the camera (i.e., time between frames), it was not possible to know the exact start of injection (SOI). However, the procedure shown in <xref ref-type="fig" rid="F8">Figure 8</xref> was used to estimate SOI and align subsequently measured data points with the origin (<italic>t</italic>, <italic>y</italic>) &#x3d; (0, 0) (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>; <xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>). This process was needed to properly compare penetration data across different fuels and test conditions. A square-root function was fit against the first three measurements in the penetration curve and extrapolated to the point of zero penetration (<italic>y</italic> &#x3d; 0). This mathematical dependence for early spray penetration has been firmly established in prior studies of similar injector hardware (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>). The corresponding time value at zero penetration represents the estimated SOI and time-shift needed to pass the curve through the origin.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>SOI estimation and time origin alignment procedure for penetration curves.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g008.tif"/>
</fig>
<p>To compare spray dispersion angle across different fuels and conditions, a quasi-steady-state (QSS) average was extracted from the time-dependent data. <xref ref-type="fig" rid="F9">Figure 9</xref> shows that an averaging window between 0.4&#xa0;ms ASOI and 0.2&#xa0;ms before the end of injection (BEOI) was used for the 60% penetration angle criterion. To extract a QSS angle based on the <inline-formula id="inf2">
<mml:math id="m2">
<mml:mrow>
<mml:mn>45</mml:mn>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> criterion, a hybrid approach was implemented (<xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). Prior to reaching a finite spray penetration of 45 equivalent exit hole diameters, the 60% penetration criterion was used. Afterwards, the <inline-formula id="inf3">
<mml:math id="m3">
<mml:mrow>
<mml:mn>45</mml:mn>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> criterion could be applied for the remaining injection period. With this hybrid approach, the QSS averaging window was set between 20% and 80% of the total injection duration. A QSS liquid length was also determined under vaporizing conditions based on the 0.4&#xa0;ms ASOI to 0.2&#xa0;ms BEOI averaging window. These approaches were developed to ensure that a single definition for each measurement could be applied across all the experimental data.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Averaging windows used for determining quasi-steady-state dispersion angle.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g009.tif"/>
</fig>
<p>Finally, all measurements were repeated between 2&#x2013;3 times for each test condition to create an ensemble-averaged data set. <xref ref-type="fig" rid="F10">Figure 10</xref> shows that up to 5 repeats were conducted at one condition and did not show a reduced uncertainty compared to the lower number of realizations. Error bars reported on graphs in the results section correspond to the standard deviation across test repeats.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Standard deviation of RON92 measurements for <bold>(A)</bold> vapor dispersion angle and <bold>(B)</bold> liquid length at &#x3c1;<sub>a</sub> &#x3d; 22.3&#xa0;kg/m<sup>3</sup> using different numbers of test repeats.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g010.tif"/>
</fig>
</sec>
<sec id="s2-5">
<title>2.5 Test Conditions</title>
<p>
<xref ref-type="table" rid="T3">Table 3</xref> summarizes the test conditions explored in this study. Spray characteristics were not determined across every single condition or fuel. However, measurements at a charge gas temperature of 900&#xa0;K, density of 23&#xa0;kg/m<sup>3</sup>, and injection pressure of 1,500&#xa0;bar were conducted across all operating conditions, fuels, and optical methods. This was done to provide consistency with ECN Spray-D data which shares a similar hardware configuration and has also been extensively studied (<xref ref-type="bibr" rid="B7">Engine Combustion Network (ECN), 2022c</xref>; <xref ref-type="bibr" rid="B38">Yasutomi et al., 2019</xref>). The high charge gas densities and temperatures correspond to in-cylinder environments for boosted, high compression ratio diesel engines. These conditions are also relevant to medium-high load GCI which leverages a mixing-controlled combustion strategy for managing soot emissions and heat release rate (<xref ref-type="bibr" rid="B44">Zhang et al., 2017b</xref>). The lower temperatures are relevant to low-medium load GCI which leverages a partially premixed compression ignition (PPCI) combustion strategy to simultaneously control NOx and soot (<xref ref-type="bibr" rid="B4">Cho et al., 2018</xref>).</p>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Experimental test conditions.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Parameter</th>
<th align="center">Range</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Fuels</td>
<td align="left">ULSD, RON60, RON92</td>
</tr>
<tr>
<td rowspan="2" align="left">Charge Temperature (<italic>T</italic>
<sub>
<italic>a</italic>
</sub>)</td>
<td align="left">313&#xa0;K (non-vaporizing)</td>
</tr>
<tr>
<td align="left">800&#x2013;1200&#xa0;K (vaporizing)</td>
</tr>
<tr>
<td align="left">Charge Pressure (<italic>P</italic>
<sub>
<italic>a</italic>
</sub>)</td>
<td align="left">10&#x2013;160&#xa0;bar</td>
</tr>
<tr>
<td align="left">Charge Density (<italic>&#x3c1;</italic>
<sub>
<italic>a</italic>
</sub>)</td>
<td align="left">10.3&#x2013;166.5&#xa0;kg/m<sup>3</sup>
</td>
</tr>
<tr>
<td align="left">Injection Pressure (<italic>P</italic>
<sub>
<italic>inj</italic>
</sub>)</td>
<td align="left">1,000&#x2013;2,500&#xa0;bar</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
</sec>
<sec sec-type="results|discussion" id="s3">
<title>3 Results and Discussion</title>
<sec id="s3-1">
<title>3.1 Non-Vaporizing Sprays</title>
<sec id="s3-1-1">
<title>3.1.1 Dispersion Angle</title>
<p>
<xref ref-type="fig" rid="F11">Figure 11</xref> shows the dispersion angles (<italic>&#x3b8;</italic>) at different injection pressures and charge densities using the 60% penetration criterion. The angles increase with a higher charge gas density because of larger air mass entrainment into the spray. Results from <xref ref-type="fig" rid="F11">Figure 11</xref> also indicate that gasoline-like fuels exhibit similar or greater dispersion compared to ULSD. Although the physical properties for both gasolines are very similar, RON92 has an appreciably larger angle than RON60. Based on previous work, the non-vaporizing dispersion angle is expected to correlate as follows (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>; <xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>):<disp-formula id="e1">
<mml:math id="m4">
<mml:mrow>
<mml:mi>t</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>n</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mi>&#x3b8;</mml:mi>
<mml:mn>2</mml:mn>
</mml:mfrac>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mi>A</mml:mi>
<mml:msup>
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mi>B</mml:mi>
</mml:msup>
</mml:mrow>
</mml:math>
<label>(1)</label>
</disp-formula>
</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Non-vaporizing dispersion angle vs. charge gas density using 60% penetration criterion at <bold>(A)</bold> P<sub>inj</sub> &#x003D; 1,000 bar, <bold>(B)</bold> P<sub>inj</sub> &#x003D; 1,500 bar, and <bold>(C)</bold> P<sub>inj</sub> &#x003D; 2,500 bar.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g011.tif"/>
</fig>
<p>Given that constants <italic>A</italic> and <italic>B</italic> are typically fixed for a given injector design, and <inline-formula id="inf4">
<mml:math id="m5">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the fuel density, one would expect the dispersion angle to scale in the following order from smallest to largest: ULSD-RON92-RON60. <xref ref-type="fig" rid="F12">Figure 12</xref> shows that the unexpected order for RON92 dispersion angle is maintained even when using the alternative <inline-formula id="inf5">
<mml:math id="m6">
<mml:mrow>
<mml:mn>45</mml:mn>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> definition. The differences become more pronounced with this criterion because it focuses on the near-nozzle region, whereas the 60% penetration definition captures more of the far-field spray phenomena as well (<xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>). Evaporation could also impact the dispersion angle measurements. However, <xref ref-type="fig" rid="F2">Figure 2</xref> indicates that no significant vaporization is expected for either gasoline at an ambient vessel temperature of 40&#xb0;C (313&#xa0;K). Furthermore, <xref ref-type="table" rid="T1">Table 1</xref> shows that RON60 and RON92 have the same IBP and would likely be equally impacted by evaporation effects at this condition.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Non-vaporizing dispersion angle vs. charge gas density using 45d<sub>o</sub> criterion.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g012.tif"/>
</fig>
<p>One possible explanation for the discrepancy could be related to injector hardware. The measurements for ULSD and RON60 were performed with one injector, while the experiments for RON92 were conducted with another. Although the nozzle geometry targets were the same for both, there is always some level of manufacturing tolerance that could lead to variation in the rate of injection and subsequent spray behavior. To investigate this further, the dispersion angles for each fuel were separately correlated using <xref ref-type="disp-formula" rid="e1">Eq. 1</xref> and plotted in <xref ref-type="fig" rid="F13">Figure 13</xref>. The RON92 results fall on a different fit line which indicates distinctive injector behavior. This is also clearly shown in <xref ref-type="table" rid="T4">Table 4</xref> which summarizes the fit line coefficients for each fuel. ULSD and RON60 have very similar coefficients, while the <italic>B</italic>-coefficient for RON92 is distinctly different.</p>
<fig id="F13" position="float">
<label>FIGURE 13</label>
<caption>
<p>Tangent of non-vaporizing dispersion half-angle vs. density ratio.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g013.tif"/>
</fig>
<table-wrap id="T4" position="float">
<label>TABLE 4</label>
<caption>
<p>Fit coefficients and <italic>R</italic>
<sup>2</sup> values for non-vaporizing dispersion angle correlation in <xref ref-type="disp-formula" rid="e1">Eq. 1</xref> and <xref ref-type="fig" rid="F13">Figure 13</xref>.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Coefficients</th>
<th align="center">ULSD</th>
<th align="center">RON60</th>
<th align="center">RON92</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">
<italic>A</italic>
</td>
<td align="char" char=".">0.280</td>
<td align="char" char=".">0.282</td>
<td align="char" char=".">0.282</td>
</tr>
<tr>
<td align="left">
<italic>B</italic>
</td>
<td align="char" char=".">0.172</td>
<td align="char" char=".">0.176</td>
<td align="char" char=".">0.140</td>
</tr>
<tr>
<td align="left">
<italic>R</italic>
<sup>2</sup>
</td>
<td align="char" char=".">0.98</td>
<td align="char" char=".">0.94</td>
<td align="char" char=".">0.85</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>Finally, <xref ref-type="fig" rid="F14">Figure 14</xref> shows that injection pressure does not have a significant impact on the spray dispersion angle for all fuels. This further validates that density ratio (<italic>&#x3c1;<sub>a</sub>/&#x3c1;<sub>f</sub>
</italic>) is the main parameter describing non-vaporizing dispersion for high-pressure sprays. However, there may be some more complex, secondary fuel effects that are not completely captured by the simple correlation in <xref ref-type="disp-formula" rid="e1">Eq. 1</xref>. Evidence for this is provided by the difference in data spread observed for ULSD versus RON60 and RON92 across different injection pressures using the 45<italic>d<sub>o</sub>
</italic> criterion (see <xref ref-type="fig" rid="F12">Figure 12</xref>) (<xref ref-type="bibr" rid="B30">Tang et al., 2018</xref>).</p>
<fig id="F14" position="float">
<label>FIGURE 14</label>
<caption>
<p>Non-vaporizing dispersion angle vs. injection pressure at different charge gas densities.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g014.tif"/>
</fig>
</sec>
<sec id="s3-1-2">
<title>3.1.2 Penetration</title>
<p>
<xref ref-type="fig" rid="F15">Figure 15</xref> compares the non-vaporizing spray penetration among fuels at a charge gas density of 23&#xa0;kg/m<sup>3</sup>. Below an injection pressure of 2,500&#xa0;bar, both gasoline-like fuels show a slower penetration rate than ULSD. This is an expected result given their dispersion angles are larger than diesel. <xref ref-type="disp-formula" rid="e2">Eq. 2</xref> was developed in prior work to describe the penetration (<italic>S</italic>) of high-pressure, single-hole diesel sprays and can be used to explain this behavior (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>):<disp-formula id="e2">
<mml:math id="m7">
<mml:mrow>
<mml:mi>S</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:msqrt>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>C</mml:mi>
<mml:mi>v</mml:mi>
</mml:msub>
<mml:mo>&#x22c5;</mml:mo>
<mml:msqrt>
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:msub>
<mml:mi>C</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
</mml:msqrt>
</mml:mrow>
<mml:mrow>
<mml:mi>a</mml:mi>
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<italic>C</italic>
<sub>
<italic>v</italic>
</sub> and <italic>C</italic>
<sub>
<italic>a</italic>
</sub> are the velocity and area coefficients of the orifice, respectively, and are related to the discharge coefficient (i.e., <inline-formula id="inf6">
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</inline-formula>). The <italic>a</italic>-term is assigned a constant value of 0.66 while <italic>t</italic> represents elapsed time. Although there has been some recent evidence that discharge coefficients may change slightly when using gasoline instead of diesel (<xref ref-type="bibr" rid="B35">Tzanetakis et al., 2021</xref>), the current analysis assumes no dependence on fuel type for simplicity. Therefore, it is clear from this expression that sprays with a larger dispersion angle should exhibit slower penetration rates. Essentially, a greater degree of spray dispersion or radial spreading should be accompanied by a slower rate of axial penetration.</p>
<fig id="F15" position="float">
<label>FIGURE 15</label>
<caption>
<p>Fuel effect on non-vaporizing penetration at a charge gas density of 23&#xa0;kg/m.<sup>3</sup>.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g015.tif"/>
</fig>
<p>Another result from <xref ref-type="fig" rid="F15">Figure 15</xref> is that RON60 and RON92 exhibit very similar penetration rates. This seemingly conforms to the original hypothesis that both gasolines should have similar non-reacting spray characteristics due to their similar physical properties. However, this is not an expected outcome given the difference observed in their dispersion angles (see <xref ref-type="fig" rid="F11">Figures 11</xref>, <xref ref-type="fig" rid="F12">12</xref>). Based on <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>, RON92 is expected to have a slower penetration rate compared to RON60 at a given operating condition. As previously discussed, this inconsistency could be due to the use of a different injector build for RON92 experiments.</p>
<p>
<xref ref-type="disp-formula" rid="e2">Equation 2</xref> also indicates that spray penetration rate should increase with higher injection pressure. This is due to the higher initial velocity that gets imparted to the liquid fuel at the nozzle exit <italic>via</italic> Bernoulli&#x2019;s principle. <xref ref-type="fig" rid="F16">Figure 16</xref> confirms that this is indeed the case for RON92 gasoline, while previous work also observed the expected trend for RON60 and ULSD using the same injector configuration (<xref ref-type="bibr" rid="B31">Tang et al., 2017a</xref>).</p>
<fig id="F16" position="float">
<label>FIGURE 16</label>
<caption>
<p>Injection pressure effect on non-vaporizing penetration for RON92 gasoline.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g016.tif"/>
</fig>
<p>
<xref ref-type="fig" rid="F17">Figure 17</xref> shows the impact of charge gas density on non-vaporizing spray penetration at an injection pressure of 1,500&#xa0;bar. As predicted by <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>, a higher charge gas density (&#x3c1;<sub>a</sub>) should result in a slower penetration rate. This is due to larger rates of air mass entrainment with higher charge density. The results in <xref ref-type="fig" rid="F17">Figure 17</xref> are consistent across all fuels and highlight the slower penetration of RON60 compared to ULSD due to dispersion angle effects. Although the RON92 data is self-consistent (i.e., conditions with higher charge density penetrate more slowly), there is an unexpected ordering of curves against RON60 and ULSD results due to a combination of dispersion angle effects and potentially, injector hardware effects (see previous section).</p>
<fig id="F17" position="float">
<label>FIGURE 17</label>
<caption>
<p>Charge gas density effect on non-vaporizing penetration at an injection pressure of 1,500 bar.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g017.tif"/>
</fig>
<p>The spray penetration can be normalized to a non-dimensional form using the following transformations based on <xref ref-type="disp-formula" rid="e2">Eq. 2</xref> (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>):<disp-formula id="e3">
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</disp-formula>
</p>
<p>When the actual penetration (<italic>x</italic>) and time (<italic>t</italic>) are normalized against their respective length and time scales (<italic>x</italic>
<sup>&#x2b;</sup>, <italic>t</italic>
<sup>&#x2b;</sup>), the data across different operating conditions, fuel types, and nozzle geometries should all collapse onto a single curve. The scaling calculations in <xref ref-type="disp-formula" rid="e3">Eqs 3</xref>, <xref ref-type="disp-formula" rid="e4">4</xref> were performed using specifications from <xref ref-type="table" rid="T2">Table 2</xref>, estimating the <italic>C</italic>
<sub>
<italic>v</italic>
</sub> based on its relationship to discharge coefficient (<inline-formula id="inf7">
<mml:math id="m12">
<mml:mrow>
<mml:msub>
<mml:mi>C</mml:mi>
<mml:mi>v</mml:mi>
</mml:msub>
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</mml:msub>
<mml:mo>/</mml:mo>
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<mml:mi>C</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>), and assuming an average value of <italic>C</italic>
<sub>
<italic>a</italic>
</sub> &#x3d; 0.95 taken from similar single-hole nozzles characterized in prior work (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>). The <italic>a</italic>-term was also set to 0.66 as prescribed in this previous study. If experimental results adhere to the established physical theory of non-vaporizing sprays, then the normalized penetration data should collapse onto the correlation described in <xref ref-type="disp-formula" rid="e5">Eq. 5</xref>. <xref ref-type="fig" rid="F18">Figure 18</xref> shows that this is indeed the case for all three fuels over a wide range of injection pressures and charge gas densities.</p>
<fig id="F18" position="float">
<label>FIGURE 18</label>
<caption>
<p>Normalized spray penetration curves for non-vaporizing data set.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g018.tif"/>
</fig>
</sec>
</sec>
<sec id="s3-2">
<title>3.2 Vaporizing Sprays</title>
<sec id="s3-2-1">
<title>3.2.1 Dispersion Angle</title>
<p>
<xref ref-type="fig" rid="F19">Figure 19</xref> shows a scatter plot of dispersion angle versus charge gas density under vaporizing conditions. Angles were determined using the 60% penetration criterion and only represent dispersion of the fuel vapor envelope, not the liquid portion of the spray. As predicted by <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>, the angle generally increases with charge density due to a greater rate of air mass entrainment into the spray. Interestingly however, there does not seem to be any discernable trend with respect to fuel type.</p>
<fig id="F19" position="float">
<label>FIGURE 19</label>
<caption>
<p>Vaporizing spray dispersion angle vs. charge gas density at different injection pressures.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g019.tif"/>
</fig>
<p>To investigate this further, <xref ref-type="fig" rid="F20">Figure 20</xref> shows the unique power-law fit for each fuel&#x2019;s dispersion angle according to <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>. The RON60 and ULSD data were acquired on the same injector, so differences between the two correlations are most likely the result of evaporation effects caused by their vastly different volatility. Based on the original hypothesis of RON92 and RON60 gasoline having similar non-reacting spray characteristics, it is expected they would share similar vaporizing dispersion angles. Although the power law fit for RON92 does not support this claim, additional data at density ratios beyond 0.02 and 0.04 would be needed to make a fair comparison with the other fuels.</p>
<fig id="F20" position="float">
<label>FIGURE 20</label>
<caption>
<p>Tangent of vaporizing dispersion half-angle vs. density ratio.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g020.tif"/>
</fig>
<p>
<xref ref-type="table" rid="T5">Table 5</xref> summarizes the power law coefficients for the half-angle correlation in <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>. Much more variation is observed across fuels with a generally lower <italic>R</italic>
<sup>2</sup> value compared to the non-vaporizing data in <xref ref-type="table" rid="T4">Table 4</xref>. Since these angle measurements were based on the fuel vapor envelope, the correlation between dispersion angle and liquid fuel density may not likely be as strong under these conditions.</p>
<table-wrap id="T5" position="float">
<label>TABLE 5</label>
<caption>
<p>Fit coefficients and <italic>R</italic>
<sup>2</sup> values for vaporizing dispersion angle correlation in <xref ref-type="disp-formula" rid="e1">Eq. 1</xref> and <xref ref-type="fig" rid="F20">Figure 20</xref>.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Coefficients</th>
<th align="center">ULSD</th>
<th align="center">RON60</th>
<th align="center">RON92</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">
<italic>A</italic>
</td>
<td align="char" char=".">0.422</td>
<td align="char" char=".">0.299</td>
<td align="char" char=".">0.687</td>
</tr>
<tr>
<td align="left">
<italic>B</italic>
</td>
<td align="char" char=".">0.277</td>
<td align="char" char=".">0.184</td>
<td align="char" char=".">0.421</td>
</tr>
<tr>
<td align="left">
<italic>R</italic>
<sup>2</sup>
</td>
<td align="char" char=".">0.82</td>
<td align="char" char=".">0.77</td>
<td align="char" char=".">0.77</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>The vapor dispersion angle for all three fuels is plotted against charge temperature in <xref ref-type="fig" rid="F21">Figure 21</xref>. Unlike the other results reported in this section, this data was collected with the same nozzle and thus free from any potential injector build impacts on RON92 dispersion angle. As previously observed in <xref ref-type="fig" rid="F19">Figure 19</xref>, there is no statistically significant trend with respect to fuel type for RON60 and ULSD. Within the uncertainty of measurements, the dispersion angle also remains relatively flat with respect to charge temperature. However, RON92 exhibits a larger angle than the other two fuels below 1100&#xa0;K. Scaling of the dispersion angle also does not follow the order expected due to liquid density (see <xref ref-type="table" rid="T1">Table 1</xref> and <xref ref-type="disp-formula" rid="e1">Eq. 1</xref>). These results indicate that a more complex physical model including volatility parameters may be needed to better describe vapor dispersion. For example, RON92 is more volatile than RON60 for 60% of the distillation curve and has a higher RVP (see <xref ref-type="table" rid="T1">Table 1</xref> and <xref ref-type="fig" rid="F2">Figure 2</xref>). These differences may have an influence on vapor dispersion angle, especially at the lower end of charge gas temperatures.</p>
<fig id="F21" position="float">
<label>FIGURE 21</label>
<caption>
<p>Vaporizing dispersion angle vs. charge gas temperature at &#x3c1;<sub>a</sub> &#x3d; 23&#xa0;kg/m<sup>3</sup> and P<sub>inj</sub> &#x3d; 1,500&#xa0;bar.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g021.tif"/>
</fig>
</sec>
<sec id="s3-2-2">
<title>3.2.2 Vapor Penetration</title>
<p>
<xref ref-type="fig" rid="F22">Figure 22</xref> shows a plot of vapor penetration for all three fuels over a charge gas temperature range of 800&#x2013;1200&#xa0;K. Results indicate that there is no discernable trend with respect to fuel type. This was also observed in previous work which showed a maximum difference of only 5% between the vapor penetration curves of RON60 gasoline and ULSD (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>). Since all the data in <xref ref-type="fig" rid="F22">Figure 22</xref> was obtained using the same nozzle, there were no potential injector build effects on the RON92 measurements. Hence, it can be confidently said that RON92 exhibits a similar vapor penetration to the other two fuels. The absence of any significant trend with respect to charge gas temperature is consistent with the relatively flat dispersion angles observed over 800&#x2013;1200&#xa0;K in <xref ref-type="fig" rid="F21">Figure 21</xref>. However, the differences between RON92 and the other fuels below 1100&#xa0;K does not seem to impact the penetration. As discussed previously, this may be due to more complex volatility effects that influence the evaporating spray beyond those accounted for in <xref ref-type="disp-formula" rid="e1">Eqs 1</xref>, <xref ref-type="disp-formula" rid="e2">2</xref>. To better understand these nuanced effects, mixing field measurements using planar laser induced fluorescence (PLIF) or laser induced exciplex fluorescence (LIEF) are planned as part of future work (<xref ref-type="bibr" rid="B21">Parrish and Zink, 2012</xref>; <xref ref-type="bibr" rid="B9">Fansler and Parrish, 2014</xref>; <xref ref-type="bibr" rid="B3">Chen et al., 2019</xref>; <xref ref-type="bibr" rid="B10">Feng et al., 2021</xref>).</p>
<fig id="F22" position="float">
<label>FIGURE 22</label>
<caption>
<p>Vapor penetration across T<sub>a</sub> &#x3d; 800&#x2013;1200&#xa0;K at &#x3c1;<sub>a</sub> &#x3d; 23&#xa0;kg/m<sup>3</sup> and P<sub>inj</sub> &#x3d; 1,500&#xa0;bar.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g022.tif"/>
</fig>
</sec>
<sec id="s3-2-3">
<title>3.2.3 Liquid Length</title>
<p>Under vaporizing conditions, the liquid penetration of the spray reaches a quasi-steady-state length. This occurs at a location downstream of the nozzle orifice where the mass flow rate of fuel exactly matches the evaporation rate (<xref ref-type="bibr" rid="B28">Siebers, 1998</xref>; <xref ref-type="bibr" rid="B29">Siebers, 1999</xref>). <xref ref-type="fig" rid="F23">Figure 23</xref> plots the liquid length versus charge temperature at different charge gas densities. For ULSD, the liquid length decreases with increasing charge pressure due to higher gas density and rates of hot air entrainment (i.e., enthalpy) into the spray. This supports higher evaporation rates and shortens penetration. Intuitively, the liquid length of diesel also decreases with charge gas temperature because there is more enthalpy available for evaporation.</p>
<fig id="F23" position="float">
<label>FIGURE 23</label>
<caption>
<p>Quasi-steady-state liquid length vs. charge gas temperature at P<sub>inj</sub> &#x3d; 1,500 bar and different charge gas pressures.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g023.tif"/>
</fig>
<p>As observed in previous work however, RON60 exhibits a strikingly flat liquid length characteristic versus charge temperature (<xref ref-type="bibr" rid="B40">Zhang et al., 2017a</xref>). RON92 behaves similarly and seems to validate the original hypothesis regarding similarity of non-reacting spray characteristics among gasoline-like fuels. The results reported in <xref ref-type="fig" rid="F24">Figure 24</xref> at a constant charge gas density were taken with the same injector and further substantiate the gasoline similarity hypothesis due to the alignment between RON60 and RON92.</p>
<fig id="F24" position="float">
<label>FIGURE 24</label>
<caption>
<p>Quasi-steady-state liquid length vs. charge gas temperature at &#x3c1;<sub>a</sub> &#x3d; 23&#xa0;kg/m<sup>3</sup> and P<sub>inj</sub> &#x3d; 1,500&#xa0;bar.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g024.tif"/>
</fig>
<p>To explain why gasoline exhibits a relatively flat penetration curve compared to diesel, the liquid lengths were normalized according to <xref ref-type="disp-formula" rid="e3">Eq. 3</xref> through <xref ref-type="disp-formula" rid="e5">Eq. 5</xref> and plotted in <xref ref-type="fig" rid="F25">Figure 25</xref>. The normalized penetrations of RON92 and RON60 fall much closer to the transition regime defined by a normalized time of <inline-formula id="inf8">
<mml:math id="m13">
<mml:mrow>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>t</mml:mi>
<mml:mo>&#x2dc;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>. This point in the correlation curve represents a transition between the short and long timescale limits describing spray behavior. At shorter timescales, interphase transport processes like mass diffusion and heat conduction become the limiting factor in evaporation of the fuel (<xref ref-type="bibr" rid="B19">Naber and Siebers, 1996</xref>; <xref ref-type="bibr" rid="B28">Siebers, 1998</xref>; <xref ref-type="bibr" rid="B29">Siebers, 1999</xref>). Under these conditions, evaporation is largely a function of physical fuel properties like heat capacity, saturation temperature, thermal conductivity, etc. Thus, it is expected that gasoline-like fuels approaching this regime and sharing similar fuel properties should exhibit similar spray behavior that is also independent of air entrainment rates.</p>
<fig id="F25" position="float">
<label>FIGURE 25</label>
<caption>
<p>Normalized liquid penetration data under vaporizing conditions.</p>
</caption>
<graphic xlink:href="fmech-08-887657-g025.tif"/>
</fig>
<p>Conversely, <xref ref-type="fig" rid="F25">Figure 25</xref> shows that ULSD liquid lengths are better described by the longer timescales of the correlation. Interphase transport processes are relatively fast compared to the mixing and air entrainment rates that ultimately limit fuel evaporation in this regime. Under these conditions, the available charge gas enthalpy and entrainment rate of air into the spray directly impact the evaporation rate of fuel. Thus, it is expected that diesel liquid length would be more strongly governed by spray momentum and charge gas properties like density and temperature.</p>
<p>The much lower liquid length exhibited by gasoline-like fuels compared to diesel is of practical significance and can be used to optimize combustion system designs for GCI. In previous work for heavy-duty engine applications, this behavior was leveraged to develop a unique, low-NOx combustion system (<xref ref-type="bibr" rid="B43">Zhang et al., 2019</xref>). Using simulation-led design tools, a wide and shallow piston shape was combined with low swirl ratio and a 14-hole injector to produce significantly lower in-cylinder heat transfer losses compared to a conventional geometry-guided (i.e., step-lip), mixing shape, especially at low to medium engine loads. The improved fuel efficiency for this design was determined to be the result of increased air utilization (i.e., faster burning rate) and reduced spray flame interaction with the internal heat transfer surfaces of the combustion chamber.</p>
</sec>
</sec>
</sec>
<sec id="s4">
<title>4 Conclusion</title>
<p>The non-reacting spray characteristics of RON60 and RON92 gasoline were studied and compared to ULSD. Experiments were performed in an optically accessible, constant-volume combustion chamber using a single-hole injector representative of heavy-duty common rail fuel systems. The intent of this work was to elucidate the physics of light distillate fuel sprays needed to enable high injection pressure GCI applications for heavy-duty engines. The hypothesis that gasoline-like fuels should exhibit similar non-reacting spray behavior due to their similar physical properties was tested. The major findings are summarized as follows:<list list-type="simple">
<list-item>
<p>&#x2022; Gasoline-like fuels exhibited a similar or larger non-vaporizing dispersion angle compared to ULSD. All angles closely follow a correlation depending on the air-to-fuel density ratio (i.e., <inline-formula id="inf9">
<mml:math id="m14">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mo>/</mml:mo>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>) which indicates that liquid density is the main fuel property influencing dispersion. RON92 showed a larger angle than RON60, but this was likely due to having used different injector builds for the experiments. Injection pressure had a negligible effect on the spray dispersion angle for all fuels.</p>
</list-item>
<list-item>
<p>&#x2022; Gasoline-like fuels exhibited slower non-vaporizing penetration rates compared to ULSD due to their larger dispersion angles. All fuels followed the expected trends of decreased penetration rates for increasing charge gas density and decreasing injection pressure. RON92 showed a similar penetration rate to RON60 despite their appreciable difference in dispersion angle. Once again, this was likely due to injector build impacts rather than lack of conformance to the physical theory governing non-vaporizing sprays. Further evidence for this was given by the collapse of all fuel data onto a non-dimensional penetration correlation over a wide range of test conditions.</p>
</list-item>
<list-item>
<p>&#x2022; The vaporizing dispersion angle had no significant trend with respect to fuel which generally increased along with charge density. Each fuel exhibited a distinctive fit to the standard air-fuel density ratio correlation, likely because of evaporation effects. The lack of similarity between RON92 and RON60 may be due to nuanced differences in their volatility characteristics (i.e., vapor pressures and distillation curves). RON60 and ULSD did not have any statistically significant difference in their relatively constant angles between charge temperatures of 800&#x2013;1200&#xa0;K, whereas RON92 had a slightly larger, increasing angle below 1100&#xa0;K.</p>
</list-item>
<list-item>
<p>&#x2022; There were no discernable differences in vapor penetration across fuel type or the entire charge gas temperature range of 800&#x2013;1200&#xa0;K. This result correlates well with prior work and the relatively flat dispersion angles measured across charge temperature for each fuel.</p>
</list-item>
<list-item>
<p>&#x2022; Gasoline-like fuels exhibit a much shorter liquid length compared to diesel under vaporizing conditions. At constant charge pressure, the liquid lengths of RON92 and RON60 were similar and independent of charge temperature, which was not the case for ULSD. This behavior was attributed to gasoline-like fuels being interphase transport limited in their evaporation process as opposed to mixing or air entrainment limited. The shorter, less temperature sensitive liquid length of gasoline-like fuels can be leveraged to design unique combustion systems (i.e., injector configurations and piston bowl shapes) that are optimized for GCI.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec id="s5">
<title>Data Availability Statement</title>
<p>The datasets presented in this article are not readily available because approval from all author affiliations is needed on a case-by-case basis before access can be granted. Requests to access the datasets should be directed to <ext-link ext-link-type="uri" xlink:href="jnaber@mtu.edu">jnaber@mtu.edu</ext-link>.</p>
</sec>
<sec id="s6">
<title>Author Contributions</title>
<p>TT coordinated the study, provided the fuels, analyzed the data, and wrote the manuscript; JJ performed all the image post-processing; HS and WA performed all of the experiments; JN supervised the experiments, image processing, and final data analysis.</p>
</sec>
<sec sec-type="COI-statement" id="s7">
<title>Conflict of Interest</title>
<p>Author TT was employed by the company Aramco Americas.</p>
<p>The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s8">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
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<sec id="s9">
<title>
<bold>Glossary</bold>
</title>
<def-list>
<def-item>
<term id="G1-fmech.2022.887657">
<italic>
<bold>A</bold>
</italic>, <italic>
<bold>a</bold>
</italic>
</term>
<def>
<p>Equation constants</p>
</def>
</def-item>
<def-item>
<term id="G2-fmech.2022.887657">
<bold>ASOI</bold>
</term>
<def>
<p>After start of injection</p>
</def>
</def-item>
<def-item>
<term id="G3-fmech.2022.887657">
<bold>ASTM</bold>
</term>
<def>
<p>American Society for Testing and Materials</p>
</def>
</def-item>
<def-item>
<term id="G4-fmech.2022.887657">
<bold>
<italic>B</italic>, <italic>b</italic>
</bold>
</term>
<def>
<p>Equation constants</p>
</def>
</def-item>
<def-item>
<term id="G5-fmech.2022.887657">
<bold>BEOI</bold>
</term>
<def>
<p>Before end of injection</p>
</def>
</def-item>
<def-item>
<term id="G6-fmech.2022.887657">
<bold>
<italic>C</italic>
<sub>
<italic>a</italic>
</sub>
</bold>
</term>
<def>
<p>Area coefficient</p>
</def>
</def-item>
<def-item>
<term id="G7-fmech.2022.887657">
<bold>
<italic>C</italic>
<sub>
<italic>d</italic>
</sub>
</bold>
</term>
<def>
<p>Discharge coefficient</p>
</def>
</def-item>
<def-item>
<term id="G8-fmech.2022.887657">
<bold>
<italic>C</italic>
<sub>
<italic>v</italic>
</sub>
</bold>
</term>
<def>
<p>Velocity coefficient</p>
</def>
</def-item>
<def-item>
<term id="G9-fmech.2022.887657">
<bold>CN</bold>
</term>
<def>
<p>Cetane number</p>
</def>
</def-item>
<def-item>
<term id="G10-fmech.2022.887657">
<inline-formula id="inf10">
<mml:math id="m15">
<mml:mrow>
<mml:msub>
<mml:mi>d</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, <inline-formula id="inf11">
<mml:math id="m16">
<mml:mrow>
<mml:msub>
<mml:mi>D</mml:mi>
<mml:mi>o</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>Nozzle exit hole diameter</p>
</def>
</def-item>
<def-item>
<term id="G11-fmech.2022.887657">
<bold>DCN</bold>
</term>
<def>
<p>Derived cetane number</p>
</def>
</def-item>
<def-item>
<term id="G12-fmech.2022.887657">
<bold>ECN</bold>
</term>
<def>
<p>Engine Combustion Network</p>
</def>
</def-item>
<def-item>
<term id="G13-fmech.2022.887657">
<bold>FPS</bold>
</term>
<def>
<p>Frames per second</p>
</def>
</def-item>
<def-item>
<term id="G14-fmech.2022.887657">
<bold>GCI</bold>
</term>
<def>
<p>Gasoline compression ignition</p>
</def>
</def-item>
<def-item>
<term id="G15-fmech.2022.887657">
<bold>IBP</bold>
</term>
<def>
<p>Initial boiling point</p>
</def>
</def-item>
<def-item>
<term id="G16-fmech.2022.887657">
<bold>LED</bold>
</term>
<def>
<p>Light emitting diode</p>
</def>
</def-item>
<def-item>
<term id="G17-fmech.2022.887657">
<bold>LIEF</bold>
</term>
<def>
<p>Laser induced exciplex fluorescence</p>
</def>
</def-item>
<def-item>
<term id="G18-fmech.2022.887657">
<bold>LHV</bold>
</term>
<def>
<p>Lower heating value</p>
</def>
</def-item>
<def-item>
<term id="G19-fmech.2022.887657">
<bold>MON</bold>
</term>
<def>
<p>Motor octane number</p>
</def>
</def-item>
<def-item>
<term id="G20-fmech.2022.887657">
<bold>NOx</bold>
</term>
<def>
<p>Oxides of nitrogen (NO, NO<sub>2</sub>)</p>
</def>
</def-item>
<def-item>
<term id="G21-fmech.2022.887657">
<bold>
<italic>P</italic>
<sub>
<italic>a</italic>
</sub>
</bold>
</term>
<def>
<p>Charge gas pressure</p>
</def>
</def-item>
<def-item>
<term id="G22-fmech.2022.887657">
<bold>
<italic>P</italic>
<sub>
<italic>inj</italic>
</sub>
</bold>
</term>
<def>
<p>Injection pressure</p>
</def>
</def-item>
<def-item>
<term id="G23-fmech.2022.887657">
<bold>PLIF</bold>
</term>
<def>
<p>Planar laser induced fluorescence</p>
</def>
</def-item>
<def-item>
<term id="G24-fmech.2022.887657">
<bold>PPCI</bold>
</term>
<def>
<p>Partially premixed compression ignition</p>
</def>
</def-item>
<def-item>
<term id="G25-fmech.2022.887657">
<bold>QSS</bold>
</term>
<def>
<p>Quasi-steady-state</p>
</def>
</def-item>
<def-item>
<term id="G26-fmech.2022.887657">
<bold>RON</bold>
</term>
<def>
<p>Research octane number</p>
</def>
</def-item>
<def-item>
<term id="G27-fmech.2022.887657">
<bold>RVP</bold>
</term>
<def>
<p>Reid vapor pressure</p>
</def>
</def-item>
<def-item>
<term id="G28-fmech.2022.887657">
<italic>
<bold>S</bold>
</italic>
</term>
<def>
<p>Spray penetration</p>
</def>
</def-item>
<def-item>
<term id="G29-fmech.2022.887657">
<inline-formula id="inf12">
<mml:math id="m17">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>S</mml:mi>
<mml:mo>&#x2dc;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>Normalized penetration</p>
</def>
</def-item>
<def-item>
<term id="G30-fmech.2022.887657">
<bold>SOI</bold>
</term>
<def>
<p>Start of injection</p>
</def>
</def-item>
<def-item>
<term id="G31-fmech.2022.887657">
<bold>
<italic>T</italic>
<sub>
<italic>a</italic>
</sub>
</bold>
</term>
<def>
<p>Charge gas temperature</p>
</def>
</def-item>
<def-item>
<term id="G32-fmech.2022.887657">
<italic>
<bold>t</bold>
</italic>
</term>
<def>
<p>Time</p>
</def>
</def-item>
<def-item>
<term id="G33-fmech.2022.887657">
<inline-formula id="inf13">
<mml:math id="m18">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>t</mml:mi>
<mml:mo>&#x2dc;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>Normalized time</p>
</def>
</def-item>
<def-item>
<term id="G34-fmech.2022.887657">
<italic>
<bold>t</bold>
</italic>
<sup>&#x2b;</sup>
</term>
<def>
<p>Penetration time scale</p>
</def>
</def-item>
<def-item>
<term id="G35-fmech.2022.887657">
<bold>
<italic>t</italic>
<sub>
<italic>shift</italic>
</sub>
</bold>
</term>
<def>
<p>Time shift applied to penetration data</p>
</def>
</def-item>
<def-item>
<term id="G36-fmech.2022.887657">
<bold>ULSD</bold>
</term>
<def>
<p>Ultra-low-sulfur diesel</p>
</def>
</def-item>
<def-item>
<term id="G37-fmech.2022.887657">
<bold>WSD</bold>
</term>
<def>
<p>Wear scar diameter</p>
</def>
</def-item>
<def-item>
<term id="G38-fmech.2022.887657">
<bold>
<italic>x</italic>, <italic>y</italic>
</bold>
</term>
<def>
<p>Axial spray penetration</p>
</def>
</def-item>
<def-item>
<term id="G39-fmech.2022.887657">
<italic>
<bold>x</bold>
</italic>
<sup>&#x2b;</sup>
</term>
<def>
<p>Penetration length scale</p>
</def>
</def-item>
<def-item>
<term id="G40-fmech.2022.887657">
<italic>
<bold>&#x3b8;</bold>
</italic>
</term>
<def>
<p>Dispersion angle</p>
</def>
</def-item>
<def-item>
<term id="G41-fmech.2022.887657">
<inline-formula id="inf14">
<mml:math id="m19">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>Charge gas density</p>
</def>
</def-item>
<def-item>
<term id="G42-fmech.2022.887657">
<inline-formula id="inf15">
<mml:math id="m20">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>Fuel density</p>
</def>
</def-item>
</def-list>
</sec>
</back>
</article>