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<journal-id journal-id-type="publisher-id">Front. Mater.</journal-id>
<journal-title>Frontiers in Materials</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Mater.</abbrev-journal-title>
<issn pub-type="epub">2296-8016</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
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<article-meta>
<article-id pub-id-type="publisher-id">1614951</article-id>
<article-id pub-id-type="doi">10.3389/fmats.2025.1614951</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Materials</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Impact of GGBS on the rheology and mechanical behavior of pumpable concrete</article-title>
<alt-title alt-title-type="left-running-head">Akhlaq et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/fmats.2025.1614951">10.3389/fmats.2025.1614951</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Akhlaq</surname>
<given-names>Hanzlah</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
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</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Peng</surname>
<given-names>Tianbo</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
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<contrib contrib-type="author" corresp="yes">
<name>
<surname>Ajmal</surname>
<given-names>Muhammad Mubashir</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2972780/overview"/>
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<contrib contrib-type="author">
<name>
<surname>Khan</surname>
<given-names>Muhammad Salman</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
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<contrib contrib-type="author">
<name>
<surname>Riaz</surname>
<given-names>Mamoon</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
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<aff id="aff1">
<sup>1</sup>
<institution>College of Civil Engineering</institution>, <institution>Tongji University</institution>, <addr-line>Shanghai</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>College of Engineering and Technology</institution>, <institution>University of Sargodha</institution>, <addr-line>Sargodha</addr-line>, <country>Pakistan</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>State Key Laboratory of Disaster Reduction in Civil Engineering</institution>, <institution>Tongji University</institution>, <addr-line>Shanghai</addr-line>, <country>China</country>
</aff>
<aff id="aff4">
<sup>4</sup>
<institution>Department of Civil Engineering</institution>, <institution>International Islamic University</institution>, <addr-line>Islamabad</addr-line>, <country>Pakistan</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/101261/overview">John L. Provis</ext-link>, Paul Scherrer Institut (PSI), Switzerland</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/996572/overview">Lucio Nobile</ext-link>, University of Bologna, Italy</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/2529179/overview">Congjie Wei</ext-link>, Texas A and M University, United States</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Tianbo Peng, <email>ptb@tongji.edu.cn</email>; Muhammad Mubashir Ajmal, <email>mubashir.ajmal@uos.edu.pk</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>30</day>
<month>07</month>
<year>2025</year>
</pub-date>
<pub-date pub-type="collection">
<year>2025</year>
</pub-date>
<volume>12</volume>
<elocation-id>1614951</elocation-id>
<history>
<date date-type="received">
<day>20</day>
<month>04</month>
<year>2025</year>
</date>
<date date-type="accepted">
<day>18</day>
<month>07</month>
<year>2025</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2025 Akhlaq, Peng, Ajmal, Khan and Riaz.</copyright-statement>
<copyright-year>2025</copyright-year>
<copyright-holder>Akhlaq, Peng, Ajmal, Khan and Riaz</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The increasing demand for high-performance pumpable concrete in large-scale infrastructure projects necessitates optimizing workability and strength while reducing environmental impact. This research explores the rheological, workability, and mechanical behavior of pumpable concrete with fractional substitution of cement by Ground Granulated Blast Furnace Slag (GGBS), aiming to enhance sustainability and performance. A total of 30 mix designs with GGBS replacements ranging from 0% to 90% were prepared, systematically optimizing the water-binder ratio (W/B) and superplasticizer dosage to maintain constant workability (i.e., 130 &#xb1; 15 mm slump value) to achieve the required pumpability. A total of 810 samples were prepared and tested to evaluate compressive strength (450 specimens at 7, 14, 21, 28, and 56 days), splitting tensile strength (180 specimens at 28 and 56 days), and flexural strength (180 specimens at 28 and 56 days). The findings show that GGBS enhances the rheological behavior of fresh concrete by lowering both plastic viscosity and yield stress, which in turn improves its flowability and pumpability. The optimal GGBS replacement level was found to be in the range of 30%&#x2013;50%, where the best balance between workability and strength development was achieved. Compressive strength tests showed that while higher GGBS levels resulted in delayed early-age strength gain, long-term strength development was significantly enhanced due to pozzolanic reactions. The splitting tensile and flexural strength results followed similar trends, demonstrating optimal performance at 40% GGBS replacement. This study confirms that the controlled use of GGBS in pumpable concrete enhances both fresh and hardened properties while promoting sustainability by reducing OPC consumption and associated carbon emissions. The findings provide valuable insights for optimizing mix designs to achieve high-performance, eco-friendly pumpable concrete suitable for modern construction applications.</p>
</abstract>
<kwd-group>
<kwd>GGBS</kwd>
<kwd>pumpable concrete</kwd>
<kwd>constant slump concrete</kwd>
<kwd>environmental protection</kwd>
<kwd>sustainability</kwd>
<kwd>Rheological properties</kwd>
</kwd-group>
<contract-num rid="cn001">51278372</contract-num>
<contract-sponsor id="cn001">National Natural Science Foundation of China<named-content content-type="fundref-id">10.13039/501100001809</named-content>
</contract-sponsor>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Structural Materials</meta-value>
</custom-meta>
</custom-meta-wrap>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Modern construction techniques demand materials that can meet the challenges of large-scale and complex projects, such as high-rise buildings, long-span bridges, deep tunnels, etc. (<xref ref-type="bibr" rid="B25">Basit et al., 2024</xref>; <xref ref-type="bibr" rid="B5">Akhlaq et al., 2022</xref>; <xref ref-type="bibr" rid="B7">Akhlaq et al., 2025a</xref>). Among these, pumpable concrete has become indispensable due to its ability to flow smoothly through pipelines to reach otherwise inaccessible locations. Its ease of placement, reduced labor requirements, and enhanced construction speed make it a preferred choice for many structural applications (<xref ref-type="bibr" rid="B78">Yuan et al., 2022</xref>).</p>
<p>Pumpability in concrete technology refers to the ability of a concrete mixture to flow through a pipeline without significant loss of quality. It is not an inherent property of concrete but rather the outcome of optimizing the concrete mix design, pipeline geometry, and pumping equipment (<xref ref-type="bibr" rid="B41">Kaplan et al., 2005</xref>). The pumpability of concrete is highly dependent on its rheological characteristics, particularly plastic viscosity and yield stress, which govern flow behavior. Plastic viscosity describes the resistance of a material to continued flow after movement has commenced, whereas yield stress refers to the minimum stress needed to start the flow (<xref ref-type="bibr" rid="B24">Banfill, 1990</xref>). For effective pumping, concrete must exhibit low yield stress to start flowing easily and moderate plastic viscosity to maintain steady flow without segregation (<xref ref-type="bibr" rid="B31">Feys et al., 2016</xref>). Achieving optimal rheological behavior involves more than just mix design. The use of chemical admixtures, such as superplasticizers, enhances flowability and reduces water demand without compromising cohesion (<xref ref-type="bibr" rid="B56">Paritala et al., 2023</xref>). Proper rheological control ensures that the concrete flows smoothly through pipelines, preventing issues like segregation, bleeding, or blockages during extended pumping operations (<xref ref-type="bibr" rid="B26">Binns, 2003</xref>).</p>
<p>Despite the practical benefits of pumpable concrete, its environmental implications remain a concern. Ordinary Portland Cement (OPC) manufacturing is a major source of worldwide CO<sub>2</sub> emissions, contributing roughly 5%&#x2013;8% to the total (<xref ref-type="bibr" rid="B4">Ajmal et al., 2023</xref>; <xref ref-type="bibr" rid="B43">Khan et al., 2025</xref>). This environmental burden is largely due to the energy-intensive nature of cement manufacturing and the release of carbon dioxide during limestone calcination (<xref ref-type="bibr" rid="B70">Stanmore and Gilot, 2005</xref>). To alleviate the environmental bearing of cement manufacturing, the incorporation of supplementary cementitious materials (SCMs) has become increasingly popular (<xref ref-type="bibr" rid="B59">Riaz et al., 2022</xref>). These materials not only contribute to a reduction in CO<sub>2</sub> emissions but also increase the strength and durability of concrete (<xref ref-type="bibr" rid="B47">Malhotra, 2000</xref>). Commonly used SCMs include industrial waste such as fly ash, silica fume, and ground granulated blast furnace slag (GGBS). Among them, GGBS is particularly notable for its effectiveness in enhancing performance characteristics of concrete while substantially lowering its environmental footprint (<xref ref-type="bibr" rid="B72">Suresh and Nagaraju, 2015</xref>). GGBS is a secondary material derived as a waste by-product from the iron-making process in blast furnaces. If not reused, GGBS disposal poses significant environmental challenges, including landfill use and potential soil and water contamination. By incorporating GGBS in concrete, its disposal issue as industrial waste can be addressed, contributing to a circular economy and sustainable construction practices.</p>
<p>
<xref ref-type="bibr" rid="B34">Gee (1979)</xref>, <xref ref-type="bibr" rid="B62">Roy (1982)</xref>, <xref ref-type="bibr" rid="B76">Wan et al. (2004)</xref> indicate that the incorporation of GGBS markedly improves the compressive strength of concrete. This increase is essentially attributed to its pozzolanic behavior and the consequent densification of the cementitious matrix. Incorporating GGBS into concrete reduces the heat of hydration, enhances resistance to chloride and sulfate attacks, and decreases permeability, making it ideal for aggressive environments (<xref ref-type="bibr" rid="B51">Nadir and Ahmed, 2022</xref>). In addition to its durability benefits, GGBS improves the workability and cohesiveness of fresh concrete, making it particularly advantageous for pumpable applications (<xref ref-type="bibr" rid="B6">Akhlaq et al., 2025b</xref>; <xref ref-type="bibr" rid="B8">Alkuhly, 2021</xref>).</p>
<p>Although numerous studies have explored the benefits of GGBS in conventional concrete, its application in pumpable concrete, particularly at high replacement levels, remains under-researched. The collective impact of GGBS and superplasticizers on the rheological and mechanical behavior of pumpable concrete has yet to be comprehensively analyzed. Furthermore, there is a lack of clear guidelines for optimizing mix designs to achieve pumpable concrete. This research seeks to bridge these gaps by investigating the influence of partial substitution of cement with GGBS on the performance of pumpable concrete. The primary objective is to assess the rheological behavior of fresh concrete, specifically yield stress and plastic viscosity, as well as the mechanical behavior of hardened concrete, including compressive, splitting tensile, and flexural strengths. Moreover, the study investigates the mix design of pumpable concrete by adjusting GGBS replacement levels and superplasticizer dosages to optimize the balance between workability and strength.</p>
</sec>
<sec id="s2">
<title>2 Research significance</title>
<p>This research holds substantial promises for advancing both the technical and environmental dimensions of concrete production. By demonstrating the viability of GGBS-based pumpable concrete, the study not only addresses the pressing need to decrease Ordinary Portland Cement (OPC) consumption, a major contributor to global CO<sub>2</sub> emissions, but also provides a practical approach to repurposing an industrial by-product that would otherwise pose environmental disposal challenges. Focusing on rheological properties like yield stress and plastic viscosity, this work supplies much-needed insight into how GGBS and superplasticizers synergistically enhance pumpability and overall performance, especially under high-volume replacement conditions where current literature remains sparse. Moreover, the findings are expected to yield clear guidelines for mix design optimization, enabling practitioners to balance sustainability, cost-effectiveness, and structural performance. Ultimately, this study&#x2019;s integrated approach, spanning rheology, mechanical strength, and environmental impact, marks a step forward in fostering a more sustainable construction industry while extending the frontiers of knowledge on pumpable concrete systems.</p>
</sec>
<sec id="s3">
<title>3 Experimental program</title>
<sec id="s3-1">
<title>3.1 Materials</title>
<p>This study utilized several key materials to produce and evaluate pumpable concrete with varying levels of GGBS as a partial replacement for OPC. OPC conforming to ASTM C150 (<xref ref-type="bibr" rid="B1">A. ASTM C150, 2017</xref>) was used as the primary binder in all concrete mixtures. The setting times were evaluated as per ASTM C191 (<xref ref-type="bibr" rid="B16">ASTMC191-08, 2009</xref>), with an initial setting time of 82 min and a final setting time of 182 min, ensuring compliance with standards for pumpable concrete. The chemical analysis and physical characteristics of cement are given in <xref ref-type="table" rid="T1">Tables 1</xref>, <xref ref-type="table" rid="T2">2</xref>.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Chemical analysis of binding materials.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="center">Binder</th>
<th colspan="8" align="center">Chemical composition (%)</th>
<th rowspan="2" align="center">LOI<xref ref-type="table-fn" rid="Tfn1">
<sup>a</sup>
</xref>
</th>
</tr>
<tr>
<th align="center">SiO<sub>2</sub>
</th>
<th align="center">CaO</th>
<th align="center">MgO</th>
<th align="center">Al<sub>2</sub>O<sub>3</sub>
</th>
<th align="center">Fe<sub>2</sub>O<sub>3</sub>
</th>
<th align="center">K<sub>2</sub>O</th>
<th align="center">Na<sub>2</sub>O</th>
<th align="center">SO<sub>3</sub>
</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="center">Cement</td>
<td align="center">20.87</td>
<td align="center">61.11</td>
<td align="center">1.42</td>
<td align="center">5.04</td>
<td align="center">3.11</td>
<td align="center">0.54</td>
<td align="center">0.23</td>
<td align="center">2.44</td>
<td align="center">2.88</td>
</tr>
<tr>
<td align="center">GGBS</td>
<td align="center">38.19</td>
<td align="center">31.92</td>
<td align="center">8.75</td>
<td align="center">11.18</td>
<td align="center">1.88</td>
<td align="center">0.41</td>
<td align="center">1.26</td>
<td align="center">-</td>
<td align="center">1.1</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="Tfn1">
<label>
<sup>a</sup>
</label>
<p>Loss on ignition.</p>
</fn>
</table-wrap-foot>
</table-wrap>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Physical parameters of binders.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Physical properties</th>
<th align="left">Cement</th>
<th align="left">GGBS</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Specific Gravity (g/cm<sup>3</sup>)</td>
<td align="left">3.15</td>
<td align="left">2.9</td>
</tr>
<tr>
<td align="left">Specific Surface (cm<sup>2</sup>/g)</td>
<td align="left">3560</td>
<td align="left">4050</td>
</tr>
<tr>
<td align="left">Initial Setting Time (min)</td>
<td align="left">82</td>
<td align="left"/>
</tr>
<tr>
<td align="left">Final Setting Time (min)</td>
<td align="left">182</td>
<td align="left"/>
</tr>
</tbody>
</table>
</table-wrap>
<p>The GGBS complied with ASTM C989 (<xref ref-type="bibr" rid="B21">ASTM C989, 2004</xref>) and was classified as Grade 100, often used in high-strength or performance-oriented concrete. The Pozzolanic Activity Index and Strength Activity Index, measured as per ASTM C311 (<xref ref-type="bibr" rid="B17">ASTM-C311-11, 2019</xref>) and ASTM C989 (<xref ref-type="bibr" rid="B21">ASTM C989, 2004</xref>), were 75% and 85% at 28 days, respectively. These properties highlight the suitability of GGBS for producing durable and sustainable pumpable concrete. The chemical analysis and physical characteristics of GGBS are provided in <xref ref-type="table" rid="T1">Tables 1</xref>, <xref ref-type="table" rid="T2">2</xref>.</p>
<p>Locally available river sand was utilized as the fine aggregate in this research with a fineness modulus of 2.75. To ensure quality, the sand was washed and sieved to eliminate impurities and oversized particles, in accordance with ASTM C136 (<xref ref-type="bibr" rid="B22">ASTM International, 2019</xref>). Course aggregate from local crusher was utilized in the experimental work, with a particle size not exceeding 19 mm. Key physical properties, including a specific gravity of 2.70 (g/cm<sup>3</sup>) and a water absorption of 0.8%, were tested as per ASTM C127 (<xref ref-type="bibr" rid="B14">ASTM C127, 2001</xref>). Sieve analysis ensured proper gradation, essential for achieving pumpability and durability. To attain the required workability for pumpable concrete, a water-reducing admixture conforming to ASTM C494 (<xref ref-type="bibr" rid="B19">ASTM C494, 2005</xref>) Type F specifications was utilized.</p>
</sec>
<sec id="s3-2">
<title>3.2 Mix proportions</title>
<p>In total, 30 concrete mixtures were prepared, including three control mixes containing only OPC (A1, B1, &#x26; C1) and twenty-seven mixtures incorporating GGBS with varying replacement levels (10%, 20%, &#x2026;, 90%). These mixes were grouped into three series (A, B, and C) based on nominal ratio-based mix designs, a common practice in local construction (e.g., 1:1:2, 1:2:4, etc.). Specifically, Series A used a 1:1:2 ratio of coarse aggregate: fine aggregate: cement, Series B used a 1:2:4 ratio, and Series C used a 1:3:6 ratio. By selecting these three mixes, the study captures a representative range of paste contents, spanning from a relatively rich mix (Series A) to moderate (Series B) and lean (Series C), thereby reflecting typical local practice and ensuring broad applicability of the findings.</p>
<p>The pumpable concrete mixes were initially designed following ACI 211-1 (<xref ref-type="bibr" rid="B69">Standard, 1996</xref>). The final mix proportions were determined after multiple trials to achieve a consistent slump of 130 &#xb1; 15 mm (<xref ref-type="bibr" rid="B63">Rumman, 2018</xref>) for three mix series incorporating GGBS.</p>
<p>The initial mix design was developed with a fixed water-to-binder (w/b) ratio of 0.47 and a superplasticizer (SP) dosage of 1.5% by weight of the total binder. The SP was thoroughly mixed with the total design water volume. To adjust workability and meet the target slump (130 &#xb1; 15 mm), the SP-water solution was gradually introduced during mixing. The process began by adding 60% of the solution, with slump measured after each incremental addition. The point at which the desired slump was achieved marked the final quantity of solution added.</p>
<p>Based on the volume of solution actually used, the final w/b ratio and SP dosage (% of binder weight) were back-calculated for each mix. Although both values varied across mixes, the ratio of w/b to SP dosage was consistently maintained at 31.3 for all specimens. For instance, in Mix A5, the target slump was achieved at 61.7% solution addition, resulting in a w/b ratio of 0.29 and SP dosage of 0.926%. In contrast, Mix C1 required 100% of the solution, yielding a w/b ratio of 0.47 and SP dosage of 1.5%. In both cases, the w/b-to-SP dosage ratio remained constant at 31.3.</p>
<p>The slump test, conducted in accordance with ASTM C143 (<xref ref-type="bibr" rid="B15">ASTM C143/C143M, 2015</xref>), was used to assess the workability of fresh concrete, with the associated mix proportions provided in <xref ref-type="table" rid="T3">Table 3</xref>.</p>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Mix design of pumpable concrete.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="center">Mix ID</th>
<th align="center">% GGBS</th>
<th align="center">Adjusted W/B Ratio</th>
<th align="center">Adjusted SP Dosage (% of Binder)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="center">A1 (1:1:2)</td>
<td align="center">0</td>
<td align="center">0.40</td>
<td align="center">1.28%</td>
</tr>
<tr>
<td align="center">A2 (1:1:2)</td>
<td align="center">10</td>
<td align="center">0.35</td>
<td align="center">1.12%</td>
</tr>
<tr>
<td align="center">A3 (1:1:2)</td>
<td align="center">20</td>
<td align="center">0.34</td>
<td align="center">1.07%</td>
</tr>
<tr>
<td align="center">A4 (1:1:2)</td>
<td align="center">30</td>
<td align="center">0.30</td>
<td align="center">0.96%</td>
</tr>
<tr>
<td align="center">A5 (1:1:2)</td>
<td align="center">40</td>
<td align="center">0.29</td>
<td align="center">0.93%</td>
</tr>
<tr>
<td align="center">A6 (1:1:2)</td>
<td align="center">50</td>
<td align="center">0.32</td>
<td align="center">1.02%</td>
</tr>
<tr>
<td align="center">A7 (1:1:2)</td>
<td align="center">60</td>
<td align="center">0.34</td>
<td align="center">1.09%</td>
</tr>
<tr>
<td align="center">A8 (1:1:2)</td>
<td align="center">70</td>
<td align="center">0.36</td>
<td align="center">1.15%</td>
</tr>
<tr>
<td align="center">A9 (1:1:2)</td>
<td align="center">80</td>
<td align="center">0.37</td>
<td align="center">1.18%</td>
</tr>
<tr>
<td align="center">A10 (1:1:2)</td>
<td align="center">90</td>
<td align="center">0.38</td>
<td align="center">1.20%</td>
</tr>
<tr>
<td align="center">B1 (1:2:4)</td>
<td align="center">0</td>
<td align="center">0.42</td>
<td align="center">1.34%</td>
</tr>
<tr>
<td align="center">B2 (1:2:4)</td>
<td align="center">10</td>
<td align="center">0.40</td>
<td align="center">1.28%</td>
</tr>
<tr>
<td align="center">B3 (1:2:4)</td>
<td align="center">20</td>
<td align="center">0.37</td>
<td align="center">1.18%</td>
</tr>
<tr>
<td align="center">B4 (1:2:4)</td>
<td align="center">30</td>
<td align="center">0.34</td>
<td align="center">1.09%</td>
</tr>
<tr>
<td align="center">B5 (1:2:4)</td>
<td align="center">40</td>
<td align="center">0.33</td>
<td align="center">1.06%</td>
</tr>
<tr>
<td align="center">B6 (1:2:4)</td>
<td align="center">50</td>
<td align="center">0.31</td>
<td align="center">1.00%</td>
</tr>
<tr>
<td align="center">B7 (1:2:4)</td>
<td align="center">60</td>
<td align="center">0.33</td>
<td align="center">1.04%</td>
</tr>
<tr>
<td align="center">B8 (1:2:4)</td>
<td align="center">70</td>
<td align="center">0.35</td>
<td align="center">1.10%</td>
</tr>
<tr>
<td align="center">B9 (1:2:4)</td>
<td align="center">80</td>
<td align="center">0.35</td>
<td align="center">1.12%</td>
</tr>
<tr>
<td align="center">B10 (1:2:4)</td>
<td align="center">90</td>
<td align="center">0.36</td>
<td align="center">1.15%</td>
</tr>
<tr>
<td align="center">C1 (1:3:6)</td>
<td align="center">0</td>
<td align="center">0.47</td>
<td align="center">1.50%</td>
</tr>
<tr>
<td align="center">C2 (1:3:6)</td>
<td align="center">10</td>
<td align="center">0.43</td>
<td align="center">1.37%</td>
</tr>
<tr>
<td align="center">C3 (1:3:6)</td>
<td align="center">20</td>
<td align="center">0.41</td>
<td align="center">1.30%</td>
</tr>
<tr>
<td align="center">C4 (1:3:6)</td>
<td align="center">30</td>
<td align="center">0.39</td>
<td align="center">1.24%</td>
</tr>
<tr>
<td align="center">C5 (1:3:6)</td>
<td align="center">40</td>
<td align="center">0.36</td>
<td align="center">1.15%</td>
</tr>
<tr>
<td align="center">C6 (1:3:6)</td>
<td align="center">50</td>
<td align="center">0.34</td>
<td align="center">1.09%</td>
</tr>
<tr>
<td align="center">C7 (1:3:6)</td>
<td align="center">60</td>
<td align="center">0.35</td>
<td align="center">1.13%</td>
</tr>
<tr>
<td align="center">C8 (1:3:6)</td>
<td align="center">70</td>
<td align="center">0.37</td>
<td align="center">1.18%</td>
</tr>
<tr>
<td align="center">C9 (1:3:6)</td>
<td align="center">80</td>
<td align="center">0.38</td>
<td align="center">1.22%</td>
</tr>
<tr>
<td align="center">C10 (1:3:6)</td>
<td align="center">90</td>
<td align="center">0.39</td>
<td align="center">1.24%</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-3">
<title>3.3 Preparation of samples and tests carried out</title>
<p>The study involved the preparation of 810 specimens to assess mechanical properties. All specimens were prepared in accordance with standard procedures outlined in (<xref ref-type="bibr" rid="B28">Documents and Information, 2005</xref>). Immediately after casting, the molds were sealed with polythene sheets to minimize moisture evaporation and were kept in a laboratory environment maintained at 20&#xb0;C &#xb1; 1&#xb0;C. The specimens were demolded after 24 h and submersed in water, also maintained at 20&#xb0;C &#xb1; 1&#xb0;C, where they remained until their respective testing ages.</p>
<sec id="s3-3-1">
<title>3.3.1 Consistency</title>
<p>The standard consistency of cement paste was determined via Vicat apparatus in line with ASTM C187 (<xref ref-type="bibr" rid="B11">Astm, 2004</xref>) for different levels of GGBS replacement (0%&#x2013;90%).</p>
</sec>
<sec id="s3-3-2">
<title>3.3.2 Setting time</title>
<p>Initial and final setting times were determined following the procedures outlined in ASTM C191 (<xref ref-type="bibr" rid="B40">International, 2008</xref>). The initial setting time was assessed using a 1 mm square needle, with measurements taken until the penetration depth reached 5 &#xb1; 0.5 mm from the base of the mold. The final setting time was assessed with an annular attachment, taking measurements every 30 min until the paste surface showed no visible indentation.</p>
</sec>
<sec id="s3-3-3">
<title>3.3.3 Workability</title>
<p>Concrete workability was evaluated through the slump test, conducted immediately after mixing and in accordance with ASTM C143 (<xref ref-type="bibr" rid="B12">ASTM, 2014</xref>). The slump was maintained within the specified range to ensure pumpability.</p>
</sec>
<sec id="s3-3-4">
<title>3.3.4 Rheological properties</title>
<p>The rheological behavior of each concrete mix was assessed using a state-of-the-art rheometer equipped with a four-blade vane, measuring 50.1 mm in length and 15.3 mm in diameter. The sample volume was selected to approximate an infinite medium, ensuring reliable measurement conditions (<xref ref-type="bibr" rid="B54">Nguyen and V Boger, 1992</xref>). To maintain consistency, the concrete paste was manually remixed before testing to prevent particle settlement and ensure homogeneity. A 30-second resting period was followed to allow the dissipation of residual stresses induced during mixing.</p>
<p>All fresh concrete and mortar samples were tested at approximately 15 min after the mixing water was introduced. To minimize any thixotropic effects or early structural buildup, we began each test with a 30-second high-speed shearing phase (<xref ref-type="bibr" rid="B60">Roussel, 2006</xref>). Next, the rotational speed of the rheometer was decreased stepwise over 0.6 rev/s to 0.1 rev/s range, corresponding to a maximum shear rate of about 10 s<sup>-1</sup>. Each speed step included a 2-second transition followed by a 3-second measurement period to allow the system to reach near steady-state conditions. Following these measurements, the Bingham model was employed to analyze the data and extract values for yield stress and plastic viscosity (<xref ref-type="bibr" rid="B32">Feys et al., 2007</xref>).</p>
<p>To validate the applicability of the Bingham model for analyzing the rheological behavior of the concrete mixes, experimental shear stress versus shear rate data were plotted alongside model predictions. As shown in <xref ref-type="fig" rid="F1">Figure 1</xref>, the data for mixtures A6, B6, and C6 closely follow linear trends, indicating a strong fit with the Bingham model. This supports the model&#x2019;s assumption of a linear relationship between shear stress and shear rate for cementitious systems with varying GGBS contents. The consistency of the linear fits across mix types with different aggregate proportions (1:1:2, 1:2:4, and 1:3:6) further reinforces the appropriateness of using the Bingham model in this study (<xref ref-type="bibr" rid="B57">Park et al., 2005</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Rheological behavior of fresh concrete mixtures fitted with the bingham model.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g001.tif">
<alt-text content-type="machine-generated">Graph showing the relationship between shear stress (Pa) and shear rate (s&#x207B;&#xB9;). Three datasets are plotted: A6 Mix (red circles and dashed line), B6 Mix (blue squares and dashed line), and C6 Mix (green triangles and dashed line). Shear stress increases with shear rate for all mixtures.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s3-3-5">
<title>3.3.5 Mechanical properties</title>
<p>Compressive strength was evaluated by calculating the average crushing strength of three cylindrical specimens for each mix, tested at 7, 14, 21, 28, and 56 days. The splitting tensile and flexural strengths were determined using the mean values of three cylinders and prisms, tested at 28 and 56 days.</p>
<p>A summary of the different tests conducted on paste and fresh concrete is presented in <xref ref-type="table" rid="T4">Table 4</xref>, while the tests for hardened concrete specimens are detailed in <xref ref-type="table" rid="T5">Table 5</xref>.</p>
<table-wrap id="T4" position="float">
<label>TABLE 4</label>
<caption>
<p>Summary of tests for paste and fresh concrete properties.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="center">Test name</th>
<th align="center">ASTM standard</th>
<th align="center">Remarks</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="center">Consistency</td>
<td align="center">ASTM C187 (<xref ref-type="bibr" rid="B11">Astm, 2004</xref>)</td>
<td align="center">Cement-GGBS Paste</td>
</tr>
<tr>
<td align="center">Setting Time</td>
<td align="center">ASTM C191 (<xref ref-type="bibr" rid="B40">International, 2008</xref>)</td>
<td align="center">Cement-GGBS Paste</td>
</tr>
<tr>
<td align="center">Workability</td>
<td align="center">ASTM C143 (<xref ref-type="bibr" rid="B12">ASTM, 2014</xref>)</td>
<td align="center">Fresh Concrete</td>
</tr>
<tr>
<td align="center">Yield Stress</td>
<td rowspan="2" align="center">ASTM C1749 (<xref ref-type="bibr" rid="B13">ASTM International, 2025</xref>)</td>
<td align="center">Fresh Concrete</td>
</tr>
<tr>
<td align="center">Plastic Viscosity</td>
<td align="center">Fresh Concrete</td>
</tr>
</tbody>
</table>
</table-wrap>
<table-wrap id="T5" position="float">
<label>TABLE 5</label>
<caption>
<p>Summary of test methods for hardened concrete properties.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="center">Test name</th>
<th align="center">ASTM standard</th>
<th align="center">Specimen</th>
<th align="center">Specimen size</th>
<th align="center">Remarks</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td rowspan="5" align="center">Compressive Strength</td>
<td rowspan="5" align="center">ASTM C39 (<xref ref-type="bibr" rid="B18">ASTM: C39/C39M, 2003</xref>)</td>
<td rowspan="5" align="center">Cylinder</td>
<td rowspan="5" align="center">150 &#xd7; 300 mm</td>
<td align="center">7 Days</td>
</tr>
<tr>
<td align="center">14 Days</td>
</tr>
<tr>
<td align="center">21 Days</td>
</tr>
<tr>
<td align="center">28 Days</td>
</tr>
<tr>
<td align="center">56 Days</td>
</tr>
<tr>
<td rowspan="2" align="center">Splitting Tensile Strength</td>
<td rowspan="2" align="center">ASTM C496 (<xref ref-type="bibr" rid="B20">ASTM: C496/C496M &#x2212; 17, 2011</xref>)</td>
<td rowspan="2" align="center">Cylinder</td>
<td rowspan="2" align="center">150 &#xd7; 300 mm</td>
<td align="center">28 Days</td>
</tr>
<tr>
<td align="center">56 Days</td>
</tr>
<tr>
<td rowspan="2" align="center">Flexural Strength</td>
<td rowspan="2" align="center">ASTM C78 (<xref ref-type="bibr" rid="B68">ASTM International, 2009</xref>)</td>
<td rowspan="2" align="center">Prism</td>
<td rowspan="2" align="center">100 &#xd7; 100 &#xd7; 500 mm</td>
<td align="center">28 Days</td>
</tr>
<tr>
<td align="center">56 Days</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
</sec>
</sec>
<sec sec-type="results|discussion" id="s4">
<title>4 Results and discussion</title>
<sec id="s4-1">
<title>4.1 Properties of cement paste with GGBS</title>
<sec id="s4-1-1">
<title>4.1.1 Consistency</title>
<p>The normal consistency of cement paste was measured for different levels of GGBS replacement, ranging from 0% to 90%, with the results shown in <xref ref-type="fig" rid="F2">Figure 2</xref>. The values of water required for normal consistency exhibited an incremental trend as the percentage of GGBS replacement increased. For pure cement paste (0% GGBS), the consistency was measured as 23%, which increased gradually to 30.1% at 90% GGBS replacement. GGBS contributes to higher consistency values primarily due to its physical and chemical properties. The smoother and glassy texture and reduced friction of GGBS particles enhance the paste&#x2019;s cohesiveness, which requires more water to achieve the standard flow (<xref ref-type="bibr" rid="B67">Siddique and Bennacer, 2012</xref>). Furthermore, the higher fineness of GGBS contributes to an increased specific surface area, leading to greater water retention in the paste. The consistency values of 28% at 50% GGBS replacement and 31.1% at 90% GGBS replacement suggest that GGBS enhances the paste&#x2019;s plasticity while maintaining its stability. A linear regression of the data points yielded the best&#x2010;fit line y &#x3d; 0.080x&#x2b;23.38, as shown in <xref ref-type="fig" rid="F2">Figure 2</xref>, with a high coefficient of determination (R<sup>2</sup> &#x3d; 0.98). This strong correlation confirms a near&#x2010;linear relationship between the GGBS replacement level and the paste consistency.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Water required for normal consistency of cement paste partially replaced with GGBS.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g002.tif">
<alt-text content-type="machine-generated">Scatter plot showing the relationship between GGBS replacement percentage and consistency percentage. Blue data points increase along the x-axis, with a red dashed best fit line indicating a positive linear trend. The equation of the line is y &#x3d; 0.080x &#x2b; 23.38 with an R-squared value of 0.9724, suggesting a strong correlation.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s4-1-2">
<title>4.1.2 Initial and final setting time</title>
<p>The setting times of cement paste serve as key indicators of the hydration process and are notably affected by the partial substitution of cement with GGBS. The initial setting time indicates when the paste begins to lose its plasticity, whereas the final setting time signifies when it has hardened enough to withstand defined pressure levels. These parameters are particularly important in evaluating the suitability of GGBS-blended cement paste for practical construction applications, especially for pumpable concrete.</p>
<p>The results, presented in <xref ref-type="fig" rid="F3">Figure 3</xref>, show a progressive increase in both the initial and final setting times as the percentage of GGBS replacement increased (<xref ref-type="bibr" rid="B48">Mark et al., 2019</xref>). For 100% OPC (0% GGBS), the initial setting time was recorded at 82 min, and the final setting time at 182 min. As the GGBS replacement level increased to 90%, the initial and final setting times extended significantly to 192 min and 298 min, respectively.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Initial and final setting time of cement paste partially replaced with GGBS.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g003.tif">
<alt-text content-type="machine-generated">Graph showing the relationship between GGBS replacement percentage and setting time. The vertical axis represents setting time in minutes, and the horizontal axis represents GGBS replacement percentage. Orange triangles indicate final setting times with a linear fit: y &#x3d; 1.234x &#x2b; 170.67, R&#xB2; &#x3d; 0.9245. Teal squares indicate initial setting times with a linear fit: y &#x3d; 1.192x &#x2b; 75.18, R&#xB2; &#x3d; 0.9544. Dashed lines represent best fit for initial and final setting times.</alt-text>
</graphic>
</fig>
<p>This pattern aligns with the observations of Yu et al., who attributed the extended setting times to the slower hydration kinetics associated with GGBS (<xref ref-type="bibr" rid="B77">Yu et al., 2021</xref>). GGBS, being a latent hydraulic material, relies on the activation provided by OPC and water to contribute to hydration. As the OPC content decreases with higher GGBS replacement, the availability of active hydration compounds, such as tri-calcium silicate (C<sub>3</sub>S), diminishes, leading to slower setting (<xref ref-type="bibr" rid="B46">Liew et al., 2024</xref>).</p>
<p>Additionally, the fineness of GGBS, combined with its smoother surface texture, reduces its immediate reactivity compared to OPC. This delayed reaction is particularly evident in the slower initial hydration phase, which is critical for the development of early strength. However, the extended setting times also offer some practical advantages. The decrease in heat of hydration observed with increased GGBS content helps reduce the risk of thermal cracking in large-scale concrete elements, thereby making GGBS-based binders well-suited for mass concrete applications (<xref ref-type="bibr" rid="B44">Lawrence et al., 2012</xref>).</p>
<p>The findings also indicate a consistent rise in final setting time as the GGBS content increases. Specifically, the final setting time extended by around 63%, increasing from 182 min at 0% GGBS to 298 min at 90% replacement. However, at high GGBS levels, delayed setting may become a challenge for rapid construction schedules, particularly in cold climates where hydration is naturally slowed. Moreover, linear regressions of the data indicate a near&#x2010;linear trend: for the initial setting time, y &#x3d; 1.192x&#x2b;75.18 with R<sup>2</sup> &#x3d; 0.9544, and for the final setting time, y &#x3d; 1.234x&#x2b;170.67 with R<sup>2</sup> &#x3d; 0.9245. These high coefficients of determination confirm a strong correlation between GGBS replacement level and the corresponding increases in setting times.</p>
<p>While a linear regression was applied here to describe the trend between GGBS replacement level and setting time, it is recognized that this approach is empirical in nature. For a more mechanistic understanding of the setting process, models such as the Avrami hydration kinetics equation could be applied in future studies to better capture the nucleation and growth behavior of hydration products in cement-GGBS systems (<xref ref-type="bibr" rid="B71">Sun et al., 2022</xref>).</p>
</sec>
</sec>
<sec id="s4-2">
<title>4.2 Rheological properties of fresh concrete</title>
<sec id="s4-2-1">
<title>4.2.1 Yield stress</title>
<p>
<xref ref-type="fig" rid="F4">Figures 4a&#x2013;c</xref> illustrate the variation in yield stress for pumpable concrete across different GGBS replacement levels in all mix series. All mixes followed a general trend of increasing yield stress with time, an expected phenomenon reflecting ongoing hydration and structural build-up in the fresh cementitious system (<xref ref-type="bibr" rid="B10">Arularasi et al., 2021</xref>). During the early stages (first 30 min), the yield stress was comparatively low, promoting ease of flow and pumpability. As hydration products accumulated, intra-particle bonding became more pronounced, which raised the yield stress noticeably beyond the 30-minute mark.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Evolution of Yield Stress of <bold>(a)</bold> Mix Series A, <bold>(b)</bold> Mix Series B, and <bold>(c)</bold> Mix Series C vs. time, and <bold>(d)</bold> Effect of GGBS Replacement on Yield Stress of All Mix Series.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g004.tif">
<alt-text content-type="machine-generated">Four graphs depict yield stress trends over time and GGBS percentage. Graph (a) shows different mixes A1-A10; stress increases with time. Graph (b) shows mixes B1-B10; similar upward trend. Graph (c) represents mixes C1-C10; stress rises with time. Graph (d) displays yield stress versus percentage GGBS for Mixes A, B, and C, showing variation across mixes.</alt-text>
</graphic>
</fig>
<p>In Mix Series A, which contains a higher cement-to-aggregate ratio, the larger paste volume contributed to a milder early increase in yield stress, indicating the mix retained sufficient fluidity to support pumping operations during the initial period. In contrast, the leaner mixes (Series B and Series C) had less paste available to lubricate the aggregates, thus displaying steeper increases in yield stress after the 30-min mark. These variations highlight how both paste content and mix proportions can influence the kinetics of structural build-up, highlighting the need to balance early workability with the desired rate of stiffening.</p>
<p>
<xref ref-type="fig" rid="F4">Figure 4d</xref> further illustrates the effect of increasing levels of GGBS on the yield stress for all mixes. In general, partial replacements of cement with GGBS (e.g., 20%&#x2013;40%) consistently lowered the initial yield stress, fostering enhanced workability and more extended pumpability windows. This improvement is primarily linked to GGBS particles refining the paste matrix, reducing internal friction, and prolonging the induction period of hydration, particularly in the early minutes after mixing.</p>
<p>These observations align well with the findings of <xref ref-type="bibr" rid="B57">Park et al. (2005)</xref>, who studied the rheological behavior of cementitious systems incorporating GGBS using a cylindrical spindle rheometer. In their study, cement was partially replaced with GGBS at various levels. The results revealed that replacing cement with GGBS in the range of 15%&#x2013;45% led to a noticeable reduction in yield stress, indicating improved flowability and workability of the concrete mixtures.</p>
<p>However, as the GGBS content increases beyond 50%, a more pronounced rise in yield stress is observed after the initial low values. This behavior results from the diminished OPC content, which reduces the availability of tricalcium silicate (C<sub>3</sub>S), the main compound responsible for initiating early hydration. As a consequence, the dormant phase concludes more abruptly, and the activation of GGBS becomes the dominant source of hydration. Although this delayed activation initially promotes fluidity, it also leads to a steeper post-induction structuration due to the build-up of hydration products. The sudden stiffening effect, coupled with reduced OPC, can present challenges in pumping applications where extended flowability is needed. Therefore, while moderate GGBS levels optimize initial yield stress and enhance early workability, excessive replacement requires careful mix design control to avoid premature loss of flow during placement.</p>
<p>Past literature reports a similar trend in yield stress with increasing replacement of cement by GGBS. Several studies indicate that replacing cement with GGBS in the range of 15%&#x2013;30% results in the lowest (i.e., optimum) yield stress, enhancing workability (<xref ref-type="bibr" rid="B2">Adjoudj et al., 2014</xref>; <xref ref-type="bibr" rid="B9">Amran et al., 2021</xref>). However, beyond this level, further increases in GGBS content tend to increase the yield stress, likely due to changes in particle packing and reduced early reactivity at high replacement levels (<xref ref-type="bibr" rid="B50">Montes et al., 2012</xref>).</p>
<p>Furthermore, at higher GGBS levels, the reduced calcium silicate content shifts the hydration mechanism toward aluminate-dominant reactions, particularly involving phases such as C<sub>4</sub>AF and the alumina-rich components of GGBS. These aluminates can rapidly react with available sulfates, leading to early ettringite formation and localized flocculation, which contributes to the sudden yield stress increase observed after the dormant phase (<xref ref-type="bibr" rid="B52">Nedunuri and Muhammad, 2024</xref>). Additionally, chemical shrinkage from hydration reactions may enhance particle crowding in the paste, particularly under reduced OPC content, triggering early-age structuration and stiffening. These microstructural phenomena likely play a complementary role in the sharp rise in yield stress seen at GGBS levels exceeding 50%, and reinforce the importance of mix control when targeting extended pumpability.</p>
</sec>
<sec id="s4-2-2">
<title>4.2.2 Plastic viscosity</title>
<p>The plastic viscosity of all mix series was monitored over time to assess its evolution during the fresh state. <xref ref-type="fig" rid="F5">Figures 5a&#x2013;c</xref> illustrate the trends observed for each mix series. The results indicate that plastic viscosity generally increased with time, which can be attributed to the ongoing hydration of cementitious materials and the flocculation of particles in the fresh concrete. This phenomenon aligns with previous studies, which report that the time-dependent increase in plastic viscosity is primarily due to the progressive formation of hydration products and the reduction in free water available for lubrication (<xref ref-type="bibr" rid="B30">Ferraris, 2001</xref>; <xref ref-type="bibr" rid="B61">Roussel et al., 2010</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Evolution of Plastic Viscosity of <bold>(a)</bold> Mix Series A, <bold>(b)</bold> Mix Series B, and <bold>(c)</bold> Mix Series C vs. time, and <bold>(d)</bold> Effect of GGBS Replacement on Plastic Viscosity of All Mix Series at 0 min (freshly mixed state).</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g005.tif">
<alt-text content-type="machine-generated">Four line graphs (a, b, c, and d) show plastic viscosity changes over time and percentage of GGBS replacement. Graph (a) and (b) plot multiple series over time, with viscosities increasing. Graph (c) shows different viscosities for multiple series, with some increasing. Graph (d) tracks plastic viscosity decreasing as percentage of GGBS replacement increases, with Mix A, B, and C.</alt-text>
</graphic>
</fig>
<p>For Mix Series A, the plastic viscosity exhibited a steady increase over time, reflecting the gradual structuration of the cement paste. Similarly, Mix Series B showed a comparable trend, albeit with slightly higher initial plastic viscosity due to differences in mix design parameters. Interestingly, Mix Series C demonstrated a more pronounced increase in plastic viscosity over time, suggesting that specific mix proportions or admixture effects could be influencing the structuration rate.</p>
<p>The observed increase in plastic viscosity over time is a critical consideration in pumpability, as excessive stiffening of the mix during pumping could lead to blockages in pipelines. This highlights the importance of optimizing mix proportions and incorporating appropriate admixtures to regulate viscosity development.</p>
<p>The impact of GGBS replacement on plastic viscosity was analyzed for all mix series, as illustrated in <xref ref-type="fig" rid="F5">Figure 5d</xref>. The values plotted in <xref ref-type="fig" rid="F5">Figure 5d</xref> correspond to measurements taken at 0 min, i.e., immediately after mixing. The results indicate that increasing GGBS content generally led to a reduction in plastic viscosity. This decrease is primarily due to the finer particles and smooth surface texture of GGBS, which promote better particle packing and improve the dispersion of cementitious components. Consequently, the mix exhibits lower internal friction, resulting in reduced plastic viscosity.</p>
<p>Notably, the effect of GGBS replacement varied among the different mix series. In Mix Series A, incorporating GGBS resulted in a noticeable decline in plastic viscosity, particularly at higher replacement levels. The dilution effect and latent hydraulic activity of GGBS contribute to a less viscous paste. In Mix Series B, a similar trend was observed, albeit with a slightly less pronounced reduction in viscosity. This could be attributed to variations in mix proportions and water-to-binder ratios, which influence the overall rheological response.</p>
<p>Mix Series C exhibited a consistent reduction in plastic viscosity across all levels of GGBS replacement, reinforcing the idea that GGBS contributes positively to reducing the internal resistance to flow in fresh concrete. These findings align with previous studies, which highlight that GGBS reduces the overall viscosity of cement paste due to its lower water demand and enhanced dispersion characteristics (<xref ref-type="bibr" rid="B75">Vikan and Justnes, 2007</xref>).</p>
<p>While GGBS generally reduces plastic viscosity due to its spherical shape, high fineness, and lower water demand, this trend begins to plateau beyond 50% replacement. At such high levels, the dilution of OPC reduces the C-S-H framework formation in early hydration but increases alumina-based reactions, which can promote particle agglomeration and reduced fluid dispersion. Additionally, as superplasticizers are less effective in highly aluminate-rich environments, the dispersion efficiency may drop, leading to slight increases or stagnation in viscosity reduction. These effects, combined with increased paste volume and particle packing density, help explain the more complex plastic viscosity behavior observed at high GGBS levels.</p>
<p>The observed reduction in plastic viscosity with increasing GGBS content is consistent with the past studies (<xref ref-type="bibr" rid="B35">Grzeszczyk and Janowska-Renkas, 2012</xref>). For example, <xref ref-type="bibr" rid="B57">Park et al. (2005)</xref> explored the rheological behavior of cementitious systems containing mineral admixtures, including GGBS. They reported that partial replacement of cement with GGBS led to a notable decrease in plastic viscosity. This effect was attributed to the smoother particle morphology and lower early-age reactivity of GGBS, which helped reduce interparticle friction and enhance the dispersion of solid particles within the mix.</p>
</sec>
</sec>
<sec id="s4-3">
<title>4.3 Mechanical properties</title>
<sec id="s4-3-1">
<title>4.3.1 Compressive strength</title>
<p>Compressive strength is a key parameter for assessing the structural performance and load-bearing capacity of concrete. It directly governs the load-bearing capacity, durability, and serviceability of concrete in construction applications. In pumpable concrete, compressive strength is significantly influenced by concrete composition, water-to-cement ratio, admixture content, and the fractional substitution of cement with GGBS.</p>
<p>The incorporation of GGBS as an SCM enhances long-term strength development, but at the cost of lower early-age strength due to its slower pozzolanic reaction (<xref ref-type="bibr" rid="B49">Monteiro, 2006</xref>). This research investigated the compressive strength performance of 30 pumpable concrete mixes, comprising three series (A, B, and C), each with GGBS content varying from 0% to 90%. The compressive strength was measured at 7, 14, 21, 28, and 56 days, ensuring a comprehensive understanding of strength development trends. The experimental values are presented in <xref ref-type="fig" rid="F6">Figure 6</xref>, illustrating the result of curing (age) and GGBS content on compressive-strength performance.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Compressive strength of <bold>(a)</bold> mix series A, <bold>(b)</bold> mix series b, and <bold>(c)</bold> mix series C at 7, 14, 21, 28, and 56 days, and <bold>(d)</bold> effect of GGBS replacement on compressive strength at 28 and 56 Days.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g006.tif">
<alt-text content-type="machine-generated">Four graphs show compressive strength trends for different concrete mixes. Graphs (a), (b), and (c) plot compressive strength in megapascals against curing time in days for various mix series (A, B, C). Graph (d) plots compressive strength against percentage of GGBS replacement for mixes A, B, and C at twenty-eight and fifty-six days. All graphs display upward trends or specific curves, indicating the performance of different mixes.</alt-text>
</graphic>
</fig>
<p>At early ages (7&#x2013;21 days), the results indicate a decrease in compressive strength as the GGBS content increases. This is primarily due to the slower initial hydration reaction of GGBS compared to OPC, leading to delayed strength gain (Monteiro, 2006). The trends show that low GGBS content (0%&#x2013;20%) exhibits higher early-age strength, as OPC dominates the hydration process. With moderate GGBS content (30%&#x2013;50%), early-age strength is slightly reduced but remains sufficient for practical applications. However, a high GGBS content (exceeding 50%) leads to noticeably reduced early-age strength, primarily due to the slower pozzolanic activity of GGBS. These findings align with studies by <xref ref-type="bibr" rid="B55">Oh et al. (2024)</xref> and <xref ref-type="bibr" rid="B45">Li et al. (2014)</xref>, which reported delayed early-age strength development in GGBS-based concrete.</p>
<p>Notably, Series A (1:1:2), with richer cement content, shows comparatively higher early-age strengths across all GGBS replacement levels, while Series C (1:3:6), being the leanest mix, consistently yields lower strengths at these ages. Series B (1:2:4) lies between these two extremes. Despite these differences, the general trend of reduced early strength with higher GGBS replacement remains consistent across all three series.</p>
<p>Regarding later-age strength gain (28 and 56 days), the pozzolanic activity of GGBS accelerates, leading to continued strength development beyond 28 days. Most mixes containing GGBS catch up or surpass the control mix by 56 days. The enhancement in strength is primarily due to the increased formation of calcium silicate hydrate (C-S-H) gel, which strengthens the concrete&#x2019;s microstructure. Furthermore, improved matrix densification and lower porosity contribute to higher compressive strength at later curing stages, as supported by microstructural evidence in previous studies (<xref ref-type="bibr" rid="B37">He and Lu, 2024a</xref>; <xref ref-type="bibr" rid="B39">He et al., 2024</xref>). It is important to note that this explanation is based on indirect mechanical evidence and literature precedent. No direct microstructural validation (e.g., SEM, MIP) was performed in this study. Therefore, the interpretation of C-S-H densification remains speculative and should be confirmed through future microstructural analyses.</p>
<p>The results show that, at 28 days, the maximum compressive strength is typically achieved with a 40% GGBS replacement level across all three mix series (A, B, and C). By 56 days, mixes within the 30%-50% GGBS range show the highest strengths, often exceeding the strength of the control mix (0% GGBS). For instance, in Series A, the peak 56-day strength (49.5 MPa) is achieved at 40% GGBS content. Beyond 50% GGBS, strength continues to increase with curing time but remains lower compared to the 30%&#x2013;50% range. These findings align with previous research (<xref ref-type="bibr" rid="B27">Chen et al., 2024</xref>), where GGBS improved long-term strength but required extended curing durations to match or exceed OPC concrete strength.</p>
<p>An interesting observation is that even with high GGBS content (e.g., 90%), later-age strengths can still reach structurally viable strength under carefully managed laboratory conditions. For Series A, 90% GGBS and 10% OPC can yield a 56-day compressive strength of about 37.5 MPa, provided that the mix design includes a suitably low water-to-binder ratio, adequate superplasticizer dosage, and proper curing. Although early-age strength (7&#x2013;21 days) is significantly reduced at these high replacement levels, the slower pozzolanic reaction of GGBS can still lead to substantial long-term strength when given sufficient curing time and favorable conditions (<xref ref-type="bibr" rid="B49">Monteiro, 2006</xref>). Nevertheless, for practical purposes, such high&#x2010;volume GGBS mixes may not be ideal where early strength is critical.</p>
<p>The results confirm that low GGBS content (0%&#x2013;20%) maintains high early-age strength but does not offer the most significant long-term benefits. Conversely, moderate GGBS content (30%&#x2013;50%) achieves the best balance between early-age and later-age strength, making it ideal for structural applications requiring good workability, pumpability, and enhanced durability. High GGBS content (&#x3e;50%) excessively delays strength gain and reduces the 28-day strength, although continued curing can still improve the final strength somewhat. As illustrated in <xref ref-type="fig" rid="F6">Figure 6d</xref>, the maximum compressive strength at 28 and 56 days was specifically observed at 40% GGBS replacement. Although mixes with 30% and 50% GGBS also showed considerable long-term gains, exceeding 50% GGBS generally resulted in lower 28-day strength due to the dilution of OPC and slower hydration reactions. These findings are consistent with previous studies suggesting that an optimal GGBS replacement range for concrete lies between 30% and 50% (<xref ref-type="bibr" rid="B33">Ganesh and Murthy, 2019</xref>).</p>
<p>While the observed strength enhancement at moderate GGBS levels is likely associated with increased C-S-H formation and matrix densification, this explanation remains interpretative. Since the present study does not include microstructural validation techniques (e.g., SEM or MIP), the proposed mechanisms are based on indirect evidence from mechanical trends. Future studies incorporating such analyses could more definitively verify these observations.</p>
</sec>
<sec id="s4-3-2">
<title>4.3.2 Splitting tensile strength</title>
<p>Cracking in hardened concrete initiates when the locally induced tensile stress exceeds the concrete&#x2019;s intrinsic tensile capacity. The Splitting Tensile Strength, obtained in compliance with ASTM C496 (<xref ref-type="bibr" rid="B20">ASTM: C496/C496M &#x2212; 17, 2011</xref>), is therefore a direct indicator of the stress level at which first micro-cracks form under restraint loading. Likewise, the Flexural Strength or Modulus of Rupture (ASTM C78 (<xref ref-type="bibr" rid="B68">ASTM International, 2009</xref>)) governs crack initiation and propagation under bending; it is the parameter used in serviceability-limit calculations for pavements, slabs and beams. Mixtures that exhibit higher Splitting Tensile and Flexural Strength delay crack initiation, reduce crack spacing, and limit crack widths, thereby restricting the ingress of aggressive agents such as chlorides, sulfates and CO<sub>2</sub>. Numerous durability models (e.g., fib Model Code 2010 (<xref ref-type="bibr" rid="B73">Taerwe and Matthys, 2013</xref>), ACI 546) embed these parameters when predicting service-life or allowable crack width.</p>
<p>Since concrete is inherently poor in tension, its splitting tensile strength is significantly influenced by the mix proportions, aggregate interlocking, paste cohesion, and hydration reactions (<xref ref-type="bibr" rid="B53">Neville, 2011</xref>). The effect of GGBS replacement, w/c ratio, and superplasticizer dosage on splitting tensile strength was investigated at 28 and 56 days, with results illustrated in <xref ref-type="fig" rid="F7">Figure 7</xref>.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Splitting Tensile Strength of <bold>(a)</bold> Mix Series A, <bold>(b)</bold> Mix Series B, and <bold>(c)</bold> Mix series C at 28 and 56 Days.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g007.tif">
<alt-text content-type="machine-generated">Bar charts (a, b, c) display the splitting tensile strength of concrete mixes A, B, and C at various GGBS replacement levels over 28 and 56 days. Dashed lines indicate control strengths. Charts show varied strengths across mixes and times, highlighting performance changes with different GGBS levels.</alt-text>
</graphic>
</fig>
<p>The results confirm that splitting tensile strength increases with curing age, aligning with the findings of <xref ref-type="bibr" rid="B36">G&#xfc;neyisi et al. (2013)</xref>, who observed a similar gain in tensile resistance due to continued hydration and pozzolanic reactions. At 28 days, mixes with low GGBS content (0%&#x2013;30%) exhibit higher splitting tensile strength because of the early strength contribution of OPC hydration (<xref ref-type="bibr" rid="B58">Ramzi and Hajiloo, 2023</xref>).</p>
<p>The highest splitting tensile strength at 28 days was observed at 40% GGBS replacement, with Mix A5 achieving 4.6 MPa, Mix B5 reaching 3.7 MPa, and Mix C5 attaining 3.1 MPa. At 56 days, an increase in tensile strength is observed across all mixes, with the maximum tensile strength still recorded at 40% GGBS replacement. Mix A5 achieves 5.1 MPa, Mix B5 reaches 4.1 MPa, and Mix C5 records 3.5 MPa, confirming that 40% GGBS replacement provides the optimal balance for splitting tensile strength improvement. These results align with the pozzolanic reaction that enhances the binding properties of the paste over time, as also observed by Venkitasamy et al. (<xref ref-type="bibr" rid="B74">Venkitasamy et al., 2024</xref>).</p>
<p>Beyond 40% GGBS replacement, a decreasing trend is observed, suggesting that excessive GGBS incorporation leads to higher paste viscosity, poor aggregate bonding, and delayed hydration effects, leading to tensile strength reduction (<xref ref-type="bibr" rid="B66">Siddique, 2014</xref>). Mixes with high GGBS content exhibited the lowest tensile strengths at both 28 and 56 days, with Mix A10, B10, and C10 showing 2.9 MPa, 2.1 MPa, and 1.6 MPa at 28 days, respectively, and further reductions at 56 days.</p>
<p>A direct correlation between compressive and splitting tensile strength is observed, consistent with past research. The optimal replacement range (30%&#x2013;50% GGBS) ensures both compressive and tensile strength enhancement, making it ideal for structural applications requiring high durability. Excessive GGBS replacement (&#x3e;50%) adversely affects early-age compressive and tensile strength, suggesting that beyond this limit, GGBS inclusion leads to excessive cohesiveness and lower aggregate-paste bonding (<xref ref-type="bibr" rid="B65">Sankar and Ramadoss, 2022</xref>).</p>
<p>As illustrated in <xref ref-type="fig" rid="F7">Figure 7</xref>, horizontal reference lines indicate the control mix&#x2019;s 28-day and 56-day splitting tensile strengths, allowing a clear comparison of each GGBS-based mixture against the baseline. With respect to tensile strength, the results show that mixes incorporating 30%&#x2013;50% GGBS either match or outperform the control mix, while higher replacement levels generally lead to a decline in performance, reinforcing 40% GGBS as the optimal replacement level.</p>
<p>Splitting tensile strength, unlike compressive strength, is more directly influenced by the formation and propagation of internal microcracks and the quality of the paste&#x2013;aggregate bond. At moderate GGBS levels (30%&#x2013;40%), enhanced matrix packing and reduced porosity support better crack resistance. However, at higher GGBS levels, the slower pozzolanic activation can weaken early-age ITZ development, potentially leading to microstructural discontinuities that impair tensile resistance. These observations align with studies where tensile performance has been linked to early microcracking behavior and delayed matrix cohesion in GGBS-blended systems (<xref ref-type="bibr" rid="B39">He et al., 2024</xref>).</p>
</sec>
<sec id="s4-3-3">
<title>4.3.3 Flexural strength</title>
<p>Flexural strength is an essential mechanical property that evaluates the ability of concrete to resist bending stresses, particularly in beam and slab structures. The flexural performance of pumpable concrete is significantly influenced by the mix composition, w/c ratio, GGBS replacement level, and curing age. Partially replacing cement with GGBS modifies the hydration process, which in turn influences the flexural strength of concrete over time. The flexural strength results for all 30 mix designs were evaluated at 28 and 56 days. The age-dependent flexural strength development is presented in <xref ref-type="fig" rid="F8">Figures 8a&#x2013;c</xref>, which demonstrate the flexural strength variations for Mix A, Mix B, and Mix C, respectively. At 28 days, the results indicate a steady increase in flexural strength with increasing GGBS replacement up to 40%, beyond which a decline is observed. The maximum flexural strength at 28 days was recorded at 40% GGBS replacement, with Mix A5 achieving 5.8 MPa, Mix B5 reaching 5.0 MPa, and Mix C5 attaining 4.0 MPa. This trend aligns with previous studies (<xref ref-type="bibr" rid="B29">Dom et al., 2022</xref>) attributing the improvement at moderate GGBS levels to the pozzolanic activity of GGBS, which leads to the formation of secondary C-S-H gel, enhancing the matrix&#x2019;s load-bearing capacity.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Flexural Strength of <bold>(a)</bold> Mix Series A, <bold>(b)</bold> Mix Series B, and <bold>(c)</bold> Mix series C at 28 and 56 Days.</p>
</caption>
<graphic xlink:href="fmats-12-1614951-g008.tif">
<alt-text content-type="machine-generated">Bar charts showing flexural strength at different ground granulated blast-furnace slag (GGBS) replacement levels for concrete mixes. Mix A (a) and Mix B (b) compare 28-day and 56-day strengths, with control benchmarks. Mix B (c) shows similar data with a different color scheme, indicating changes in flexural strength over time against control values.</alt-text>
</graphic>
</fig>
<p>At 56 days, most of the mixes demonstrated continued strength gain, indicating the prolonged hydration process facilitated by GGBS reactivity at later ages. Similar to compressive and splitting tensile strength trends, Mixes with 40% GGBS consistently achieved the highest flexural strength at 56 days. The extended curing period allowed for increased pozzolanic reactions, forming additional C-S-H gel, which improved the tensile load distribution capacity (<xref ref-type="bibr" rid="B23">Ayub et al., 2014</xref>). However, for mixes exceeding 50% GGBS replacement, the continued strength gain was relatively lower due to the lack of sufficient OPC content, which is essential for initiating early hydration and strength development.</p>
<p>The relationship between flexural strength and GGBS replacement at 28 and 56 days is illustrated in <xref ref-type="fig" rid="F8">Figure 8d</xref>. The results indicate that low GGBS content (0%&#x2013;20%) results in lower flexural strength due to the lack of supplementary pozzolanic reactions, which are essential for improving the concrete matrix&#x2019;s tensile resistance. In contrast, moderate GGBS content (30%&#x2013;50%) provides optimum flexural performance, enhancing load transfer capability and minimizing microcracking under bending stresses. This is attributed to the increased formation of C-S-H gel, which strengthens the bond between the aggregates and the cementitious matrix. However, at high GGBS content (&#x3e;50%), a noticeable decline in flexural strength occurs, likely owing to the excessive dilution of OPC and increased porosity, which weakens the mix&#x2019;s ability to resist tensile stresses (<xref ref-type="bibr" rid="B64">Samad and Shah, 2017</xref>).</p>
<p>These findings align with past studies (<xref ref-type="bibr" rid="B42">Karri et al., 2015</xref>; <xref ref-type="bibr" rid="B3">Ahmad et al., 2022</xref>), which emphasize that an optimum range of 30%&#x2013;50% GGBS replacement maximizes mechanical properties without compromising early-age strength. The results further confirm that while GGBS enhances long-term mechanical properties, excessive replacement reduces early-age strength and negatively impacts flexural behavior. Therefore, careful optimization of GGBS content is essential to achieve a balance between workability, strength, and long-term performance, ensuring structural integrity in high-performance applications.</p>
<p>A comparative analysis of Mix A, B, and C shows that Mix A exhibited the highest flexural strength, followed by Mix B and then Mix C. This can be attributed to the lower w/c ratio in Mix A, leading to a denser and more compact concrete matrix. Mix C, having the highest w/c ratio, exhibited the lowest flexural strength due to increased porosity and reduced cohesion between cementitious particles. These patterns align with the results observed in compressive and splitting tensile strength, highlighting the interconnected nature of concrete strength properties.</p>
<p>Flexural strength is particularly governed by how well tensile stresses are redistributed across the cross-section and how effectively cracks are bridged at the bottom fiber. In this context, the bond between coarse aggregates and paste plays a dominant role. Moderate GGBS content improves ITZ characteristics, resulting in higher energy absorption and delayed crack widening under flexural loading. However, at GGBS levels above 50%, reduced early hydration limits the formation of a dense bond network, which can initiate premature cracking and more brittle behavior&#x2014;especially in leaner mixes like Series C. Prior microstructural research has linked such flexural failure modes to insufficient ITZ formation during early curing (<xref ref-type="bibr" rid="B38">He and Lu, 2024b</xref>).</p>
<p>In this study the mixes containing 30%&#x2013;50% GGBS achieved the highest Splitting Tensile and Flexural Strength, which implies a lower risk of early micro-cracking and, consequently, enhanced long-term durability through improved resistance to deleterious ion penetration and freeze&#x2013;thaw damage. These observations are consistent with the crack-resistance mechanisms reported by <xref ref-type="bibr" rid="B53">Neville (2011)</xref> and <xref ref-type="bibr" rid="B74">Venkitasamy et al. (2024)</xref> for tensile behaviour, and by <xref ref-type="bibr" rid="B29">Dom et al. (2022)</xref> for flexural performance, reinforcing the durability benefits of moderate GGBS replacement.</p>
</sec>
</sec>
</sec>
<sec sec-type="conclusion" id="s5">
<title>5 Conclusion</title>
<p>This study investigated the effects of GGBS as a partial replacement for OPC on the rheological and mechanical characteristics of pumpable concrete. From the experimental observations, the following conclusions are evident:<list list-type="simple">
<list-item>
<p>1. The consistency of cement paste increased with higher GGBS replacement levels, primarily due to the finer particle size and higher specific surface area of GGBS, which led to greater water retention.</p>
</list-item>
<list-item>
<p>2. Both the initial and final setting times of the cement paste showed a gradual increase as the GGBS content was raised. At 90% GGBS replacement, the initial setting time was extended to 192 min, while the final setting time reached 298 min. The delay in setting time is attributed to the lower availability of tricalcium silicate (C<sub>3</sub>S) in GGBS, which slows down the early hydration process. While this delay can be beneficial for mass concrete applications, it may present challenges in rapid construction projects requiring early strength development.</p>
</list-item>
<list-item>
<p>3. The incorporation of GGBS significantly improved the flowability and pumpability of fresh concrete by reducing both yield stress and plastic viscosity, with an optimal replacement range of 30%&#x2013;50%, ensuring workability and stability without segregation. Over time, yield stress and plastic viscosity increased due to progressive hydration and structuration of the cement paste, affecting the pumpability of concrete. The use of 30%&#x2013;50% GGBS effectively delayed early stiffening, maintaining a longer pumpability window. However, at higher GGBS levels (&#x3e;50%), excessive viscosity reduction increased the risk of bleeding and segregation, while yield stress showed a sharper rise after the dormant phase, requiring careful mix optimization to prevent sudden stiffening during extended pumping.</p>
</list-item>
<list-item>
<p>4. Early-age (7&#x2013;21 days) compressive strength decreased with increasing GGBS content due to its slower pozzolanic reaction. At 28 days, concrete with 30%&#x2013;50% GGBS replacement achieved compressive strengths comparable to or higher than the control mix. By 56 days, GGBS-incorporated mixes exhibited superior strength performance, with 40% GGBS replacement yielding the highest compressive strength.</p>
</list-item>
<list-item>
<p>5. Splitting tensile and flexural strength results followed trends similar to compressive strength, with peak values observed at 40% GGBS replacement. At lower GGBS levels (10%&#x2013;20%), minimal improvement in tensile strength was observed compared to the control mix. Higher replacement levels (&#x3e;50%) led to a decline in tensile and flexural strength due to reduced early-age cement hydration and matrix cohesion.</p>
</list-item>
</list>
</p>
<p>While this study identifies 30%&#x2013;40% GGBS as the optimal replacement range for balancing strength and workability, this conclusion is specific to the materials, water-to-binder ratio, superplasticizer type, mix proportions, and curing conditions adopted in our experiments. The optimal level of GGBS replacement may vary in other contexts, especially under different ambient temperatures, binder chemistries, admixture systems, or curing regimes. Therefore, while these findings provide useful design guidance, they should be applied with caution beyond the boundaries of the present study.</p>
<sec id="s5-1">
<title>5.1 Limitations and future works</title>
<p>Although this study provides detailed insights into the mechanical and rheological performance of pumpable concrete with GGBS, a key limitation is the absence of microstructural analysis such as SEM or MIP to directly validate the proposed mechanisms of C-S-H densification and pore refinement. Future research should incorporate such techniques to provide more definitive evidence supporting the strength development and durability trends observed in this work.</p>
</sec>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s6">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/supplementary material, further inquiries can be directed to the corresponding authors.</p>
</sec>
<sec sec-type="author-contributions" id="s7">
<title>Author contributions</title>
<p>HA: Formal Analysis, Methodology, Writing &#x2013; review and editing, Investigation, Conceptualization, Writing &#x2013; original draft. TP: Writing &#x2013; review and editing, Funding acquisition, Supervision, Validation. MA: Formal Analysis, Investigation, Data curation, Writing &#x2013; original draft, Methodology. MK: Software, Resources, Writing &#x2013; review and editing, Methodology. MR: Software, Formal Analysis, Writing &#x2013; review and editing, Conceptualization, Data curation.</p>
</sec>
<sec sec-type="funding-information" id="s8">
<title>Funding</title>
<p>The author(s) declare that financial support was received for the research and/or publication of this article. This research was supported by the National Natural Science Foundation of China under Grant Nos. 51278372 and 51878489.</p>
</sec>
<sec sec-type="COI-statement" id="s9">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="ai-statement" id="s10">
<title>Generative AI statement</title>
<p>The author(s) declare that Generative AI was used in the creation of this manuscript. Artificial intelligence tools, specifically OpenAI&#x2019;s ChatGPT 4.0, were used to improve the grammar, clarity, and structure of the manuscript. The authors confirm that all core ideas, data analysis, experimental design, interpretation of results, and conclusions were developed by the authors. The use of AI was limited to editorial assistance and did not influence the scientific content or integrity of the work.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
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