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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Mater.</journal-id>
<journal-title>Frontiers in Materials</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Mater.</abbrev-journal-title>
<issn pub-type="epub">2296-8016</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">764338</article-id>
<article-id pub-id-type="doi">10.3389/fmats.2021.764338</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Materials</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Ultra-Thin Metasurface-Based Absorber of Low-Frequency Sound With Bandwidth Optimization</article-title>
<alt-title alt-title-type="left-running-head">Guan et&#x20;al.</alt-title>
<alt-title alt-title-type="right-running-head">Ultrathin Low-Frequency Sound Absorber</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Guan</surname>
<given-names>Yi-jun</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1485226/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Ge</surname>
<given-names>Yong</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Sun</surname>
<given-names>Hong-xiang</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1352006/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Yuan</surname>
<given-names>Shou-qi</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Lai</surname>
<given-names>Yun</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Liu</surname>
<given-names>Xiao-jun</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>Research Center of Fluid Machinery Engineering and Technology, School of Physics and Electronic Engineering, Jiangsu University, <addr-line>Zhenjiang</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>Key Laboratory of Modern Acoustics, National Laboratory of Solid State Microstructures, Department of Physics and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, <addr-line>Nanjing</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>State Key Laboratory of Acoustics, Institute of Acoustics, Chinese Academy of Sciences, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1267729/overview">Fuyin Ma</ext-link>, Xi&#x2019;an Jiaotong University, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1116419/overview">Nansha Gao</ext-link>, Northwestern Polytechnical University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1442910/overview">Hui Zhang</ext-link>, Southeast University, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Hong-xiang Sun, <email>jsdxshx@ujs.edu.cn</email>; Shou-qi Yuan, <email>shouqiy@ujs.edu.cn</email>; Yun Lai, <email>laiyun@nju.edu.cn</email>; Xiao-jun Liu, <email>liuxiaojun@nju.edu.cn</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Metamaterials, a section of the journal Frontiers in Materials</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>30</day>
<month>09</month>
<year>2021</year>
</pub-date>
<pub-date pub-type="collection">
<year>2021</year>
</pub-date>
<volume>8</volume>
<elocation-id>764338</elocation-id>
<history>
<date date-type="received">
<day>25</day>
<month>08</month>
<year>2021</year>
</date>
<date date-type="accepted">
<day>20</day>
<month>09</month>
<year>2021</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2021 Guan, Ge, Sun, Yuan, Lai and Liu.</copyright-statement>
<copyright-year>2021</copyright-year>
<copyright-holder>Guan, Ge, Sun, Yuan, Lai and Liu</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these&#x20;terms.</p>
</license>
</permissions>
<abstract>
<p>We report, both theoretically and experimentally, a type of ultra-thin metasurface-based low-frequency sound absorber with bandwidth optimization. Such a metasurface unit consists of an ultrathin resonator (thickness&#x223c;1/90 wavelength) with a circular hole on the upper panel and four narrow slits inside a multiple-cavity structure. Eigenmode simulations of the unit show rich artificial Mie resonances, in which a type of monopolar Mie resonance mode can be obtained at 238.4&#xa0;Hz. Based on the excitation of the monopolar mode, we can realize the near-perfect low-frequency sound absorption with the maximum absorption coefficient and fractional bandwidth of 0.97 and 12.9%, respectively, which mainly arises from the high thermal-viscous loss around the circular hole and four narrow slits of the unit. More interestingly, by combining 4 units with different diameters of the circular hole, we further enhance the fractional bandwidth of the compound unit to 18.7%. Our work provides a route to design ultra-thin broadband sound absorbers by artificial Mie resonances, showing great potential in practical applications of low-frequency noise control and architectural acoustics.</p>
</abstract>
<kwd-group>
<kwd>acoustics</kwd>
<kwd>absorber</kwd>
<kwd>low-frequency sound</kwd>
<kwd>metasurface</kwd>
<kwd>bandwidth optimization</kwd>
</kwd-group>
<contract-num rid="cn001">11774137 51779107&#x20;11834008 61671314&#x20;11974176 12174159</contract-num>
<contract-sponsor id="cn001">National Natural Science Foundation of China<named-content content-type="fundref-id">10.13039/501100001809</named-content>
</contract-sponsor>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Studies on low-frequency sound absorption have attracted great scientific and engineering fascination due to its extensive practical applications in noise control, architectural acoustics, and environmental protection. Traditionally, the realization of sound absorption is mainly based on porous and fibrous materials (<xref ref-type="bibr" rid="B3">Biot, 1956</xref>; <xref ref-type="bibr" rid="B52">Zarek, 1978</xref>) and micro-perforated plate structures with cavities at the back (<xref ref-type="bibr" rid="B33">Maa, 1998</xref>; <xref ref-type="bibr" rid="B1">Arenas and Crocker, 2010</xref>). However, these absorbing structures usually have imperfect impedance matching with free space and relatively large sizes comparable to working wavelengths.</p>
<p>In the past few years, rapid development of metamaterials (<xref ref-type="bibr" rid="B27">Liu et&#x20;al., 2000</xref>; <xref ref-type="bibr" rid="B11">Fang et&#x20;al., 2006</xref>; <xref ref-type="bibr" rid="B22">Li et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B43">Toyoda et&#x20;al., 2011</xref>; <xref ref-type="bibr" rid="B7">Christensen and de Abajo, 2012</xref>; <xref ref-type="bibr" rid="B26">Liang and Li, 2012</xref>; <xref ref-type="bibr" rid="B36">Quan et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B8">Cummer et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B5">Cheng et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B13">Gao et&#x20;al., 2021</xref>) and metasurfaces (<xref ref-type="bibr" rid="B25">Li et&#x20;al., 2013</xref>; <xref ref-type="bibr" rid="B41">Tang et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B48">Xie et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B47">Xie et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B2">Assouar et&#x20;al., 2018</xref>; <xref ref-type="bibr" rid="B17">Holloway et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B35">Quan et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B56">Zhu and Assouar, 2019</xref>; <xref ref-type="bibr" rid="B12">Gao et&#x20;al., 2020</xref>; <xref ref-type="bibr" rid="B37">Nikkhah et&#x20;al., 2020</xref>) provides an unprecedented way to overcome the limits of conventional absorption materials and realize high absorption performance. These absorbing structures usually contain subwavelength resonant units to enhance energy density and dissipate sound energy inside. The previously demonstrated resonant units mainly include Helmholtz resonators (<xref ref-type="bibr" rid="B18">Jimenez et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B23">Li et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B38">Romero-Garcia et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B20">Jimenez et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B28">Long et&#x20;al., 2017</xref>), sound membranes (<xref ref-type="bibr" rid="B34">Mei et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B32">Ma et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B50">Yang et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B51">Yang et&#x20;al., 2015</xref>), coiled Fabry-Perot resonators (<xref ref-type="bibr" rid="B53">Zhang and Hu, 2016</xref>; <xref ref-type="bibr" rid="B19">Jimenez et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B49">Yang et&#x20;al., 2017</xref>), split-ring-resonators (<xref ref-type="bibr" rid="B45">Wu et&#x20;al., 2016</xref>), acoustic metasurfaces (<xref ref-type="bibr" rid="B4">Cai et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B24">Li and Assouar, 2016</xref>; <xref ref-type="bibr" rid="B42">Tang et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B9">Donda et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B16">Ge et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B30">Long et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B14">Gao et&#x20;al., 2021</xref>), etc. The above designs exhibit high efficiency for low-frequency sound absorption. However, due to their resonant nature, the design of sound absorption structures with both broad bandwidth and deep subwavelength thickness remains a challenging task. Theoretical analysis shows that broadband absorption can be achieved by dispersive dissipative meta-films (<xref ref-type="bibr" rid="B10">Duan et&#x20;al., 2015</xref>). Meanwhile, sound absorption can also be theoretically obtained by coherent perfect absorbers based on interference cancellation (<xref ref-type="bibr" rid="B39">Song et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B44">Wei et&#x20;al., 2014</xref>).</p>
<p>Recently, a type of maze-like unit consisting of eight zigzag channels has become a hot topic due to its rich artificial Mie resonances and subwavelength size (<xref ref-type="bibr" rid="B6">Cheng et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B21">Landi et&#x20;al., 2018</xref>). Based on different types of Mie resonance modes created by the maze-like units, a variety of application designs of low-frequency sound have been realized, including rainbow trapping (<xref ref-type="bibr" rid="B55">Zhou et&#x20;al., 2016</xref>), extraordinary transmission (<xref ref-type="bibr" rid="B46">Xia et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B54">Zhang et&#x20;al., 2017</xref>), sound filtering (<xref ref-type="bibr" rid="B40">Sun et&#x20;al., 2019</xref>), energy harvesting (<xref ref-type="bibr" rid="B15">Gao et&#x20;al., 2019</xref>) and directional propagation (<xref ref-type="bibr" rid="B31">Lu et&#x20;al., 2017</xref>). Additionally, a multi-band near-perfect sound absorber based on the multi-orders monopolar and dipolar Mie resonances has been designed (<xref ref-type="bibr" rid="B29">Long et&#x20;al., 2018</xref>). However, this system is composed of a Mie resonator array backed by a rigid wall, and broadband sound absorbers designed by a single layer of Mie resonator array with deep subwavelength thickness still pose a challenge.</p>
<p>In this work, we propose a metasurface unit which consists of an upper surface panel with a central circular hole and a multiple-cavity structure. By applying eigenmode simulations to the unit, a series of artificial Mie resonance modes can be observed, such as a monopolar Mie resonance (MMR) mode at 238.4&#xa0;Hz and a second MMR mode at 1,145.4&#xa0;Hz. Based on the thermal-viscous loss created by the circular hole and four narrow slits of the unit under the excitation of the MMR mode, the near-perfect low-frequency sound absorption is observed at 239&#xa0;Hz, and the maximum absorption coefficient and fractional bandwidth can reach about 0.97 and 12.9%, respectively. Additionally, we discuss the influences of structure parameters on the sound absorption performance, and design two types of broadband compound units by combining 4 units with different central circular holes. The fractional bandwidth of the compound unit can be further enhanced to 18.7%. The measured sound absorption spectra agree well with the simulated&#x20;ones.</p>
</sec>
<sec id="s2">
<title>Design and Performances of Sound Absorber</title>
<sec id="s2-1">
<title>Design of Unit</title>
<p>As schematically shown in <xref ref-type="fig" rid="F1">Figure&#x20;1A</xref>, we propose an acoustic metasurface-based absorber consisting of periodic square units with a length <italic>a</italic> and a thickness <italic>h</italic>. A central circular hole with a diameter <italic>d</italic> is located at the upper surface of the unit. Each unit is composed of an upper surface panel (with a thickness <italic>t</italic>
<sub>3</sub>) and a multiple-cavity structure (with a thickness <italic>t</italic>
<sub>4</sub>) on the bottom (<xref ref-type="fig" rid="F1">Figure&#x20;1B</xref>). As shown in <xref ref-type="fig" rid="F1">Figure&#x20;1C</xref>, the multiple-cavity structure consists of a central square cavity (with a length <italic>b</italic>) surrounded by four interconnected identical cavities which are divided by four narrow slits (with a width <italic>t</italic>
<sub>1</sub>), showing a high structure symmetry. The distance between the slits and the outer frame is <italic>t</italic>
<sub>2</sub>, and the frames (with a thickness <italic>t</italic>) are made of epoxy resin based on 3D-printing technology. Here, the COMSOL Multiphysics software is used to numerically simulate sound absorption characteristics, and the structure parameters are selected as <italic>a</italic>&#x20;&#x3d; 100&#xa0;mm, <italic>b</italic>&#x20;&#x3d; 42&#xa0;mm, <italic>d</italic>&#x20;&#x3d; 5&#xa0;mm, <italic>t</italic>&#x20;&#x3d; <italic>t</italic>
<sub>1</sub> &#x3d; 2&#xa0;mm, <italic>t</italic>
<sub>2</sub> &#x3d; 10&#xa0;mm, <italic>t</italic>
<sub>3</sub> &#x3d; 1&#xa0;mm, and <italic>t</italic>
<sub>4</sub>&#x20;&#x3d; 15&#xa0;mm. In our work, the sound absorption is created by the thermoviscous loss of the unit structure, and we use the module of Thermoviscous Acoustic-Solid Interaction inside the unit, and the module of Acoustic Pressure outside the unit due to the huge computation load. In the simulations, the thermoviscous acoustic boundary is used for all the surfaces inside the unit (include the inner surface of the hole), and the acoustic-thermoviscous acoustic boundary is adopted for the interface between the hole and the external space. The parameters of epoxy resin are the density <italic>&#x3c1;</italic>
<sub>e</sub> &#x3d; 1,180&#xa0;kg/m<sup>3</sup>, the longitudinal wave velocity <italic>c</italic>
<sub>
<italic>l</italic>
</sub> &#x3d; 2,720&#xa0;m/s, and the transversal wave velocity <italic>c</italic>
<sub>
<italic>t</italic>
</sub> &#x3d; 1,460&#xa0;m/s, and those of air are calculated as<inline-formula id="inf1">
<mml:math id="m1">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>p</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mi>M</mml:mi>
</mml:mrow>
<mml:mo>/</mml:mo>
<mml:mrow>
<mml:mi>R</mml:mi>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf2">
<mml:math id="m2">
<mml:mrow>
<mml:msub>
<mml:mi>c</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msqrt>
<mml:mrow>
<mml:mrow>
<mml:mrow>
<mml:mi>&#x3b3;</mml:mi>
<mml:mi>R</mml:mi>
<mml:mi>T</mml:mi>
</mml:mrow>
<mml:mo>/</mml:mo>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:mrow>
</mml:msqrt>
</mml:mrow>
</mml:math>
</inline-formula>, in which the ratio of the molar heat capacities <italic>&#x3b3;</italic>, the molar mass <italic>M</italic>, and the temperature of air are 1.4, 28.97 &#xd7; 10<sup>&#x2013;3</sup>&#xa0;kg/mol, and 293&#xa0;K, respectively, the molar gas constant <italic>R</italic>&#x20;&#x3d; 8.31&#xa0;J/(mol/K), and <italic>p</italic>
<sub>0</sub>&#x20;&#x3d; 101.325&#xa0;kPa. The paragraph of the unit is shown in <xref ref-type="fig" rid="F1">Figure&#x20;1D</xref>.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(A)</bold> Structure of acoustic metasurface-based absorber composed of periodic square units. <bold>(B)</bold> 3D structure of the unit constructed by an upper surface panel with a central circular hole and a multiple-cavity structure on the bottom. <bold>(C)</bold> 2D structure of the multiple-cavity structure. <bold>(D)</bold> Top view of paragraph of the&#x20;unit.</p>
</caption>
<graphic xlink:href="fmats-08-764338-g001.tif"/>
</fig>
</sec>
<sec id="s2-2">
<title>Characteristics of Two Types of MMR Modes</title>
<p>
<xref ref-type="fig" rid="F2">Figure&#x20;2</xref> shows the simulated pressure amplitude and phase eigenfunctions of the proposed unit. We can see that two types of eigenmodes present typical characteristics of the MMR, which are denoted as the monopole and second monopole. Additionally, due to high symmetry of the multiple-cavity structure, the Mie resonance of the dipole and quadrupole can also be observed (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>), showing rich Mie resonant modes of the unit. As shown in <xref ref-type="fig" rid="F2">Figure&#x20;2A</xref>, for the MMR mode at 238.4 Hz, the sound energy is mainly concentrated into the surrounding four cavities, and the whole structure exhibits a collective in-phase characteristic (<xref ref-type="fig" rid="F2">Figure&#x20;2B</xref>). But for the second MMR mode at 1,145.4&#xa0;Hz, the sound energy is mainly in the central square cavity (<xref ref-type="fig" rid="F2">Figure&#x20;2C</xref>), and an out-of-phase feature (<xref ref-type="fig" rid="F2">Figure&#x20;2D</xref>) is observed between the internal and external cavities. Here, to further demonstrate the mechanism of both MMR modes, we simulate the pressure amplitude and phase eigenfunctions of the units with different number of surrounding cavities (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>). The results show that the eigenfrequencies of both MMR modes change greatly with different number of cavities, but their mode characteristics are almost the&#x20;same.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Simulated pressure amplitude and phase eigenfunctions of Mie resonance modes of the unit for <bold>(A)</bold>, <bold>(B)</bold> monopole at 238.4&#xa0;Hz and <bold>(C)</bold>, <bold>(D)</bold> second monopole at 1,145.4&#xa0;Hz.</p>
</caption>
<graphic xlink:href="fmats-08-764338-g002.tif"/>
</fig>
</sec>
<sec id="s2-3">
<title>Low-Frequency Sound Absorption Created by the MMR Mode</title>
<p>Next, we experimentally measure the absorption performance of low-frequency sound created by the MMR mode in <xref ref-type="fig" rid="F2">Figure&#x20;2A</xref>. As shown in <xref ref-type="fig" rid="F3">Figure&#x20;3A</xref>, in the experiment, the sample (shown in <xref ref-type="fig" rid="F1">Figure&#x20;1D</xref>) is placed at the right side in the straight waveguide which is made of acrylic plates to satisfy sound hard boundary condition. The experimental set-up is presented in the <xref ref-type="sec" rid="s10">Supplementary Material</xref>. <xref ref-type="fig" rid="F3">Figure&#x20;3B</xref> shows the measured and simulated sound absorption spectra created by the unit. We find that there exists a sound absorption peak at 239&#xa0;Hz for both results, and the absorption coefficient can reach about 0.97, showing a near-perfect low-frequency sound absorption. Moreover, the bandwidth of sound absorption (black shaded region) is about 31&#xa0;Hz, and its corresponding fractional bandwidth (the ratio of the bandwidth to the center frequency) can reach about 12.9%. The measured and simulated sound absorption spectra match well with each other. Beyond that, the thickness <italic>h</italic> of the unit is only 16&#xa0;mm, which is equal to &#x3bb;/90, exhibiting a deep subwavelength thickness of the proposed low-frequency sound absorber.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>
<bold>(A)</bold> Experiment set-up of sound absorption. <bold>(B)</bold> Simulated (blue solid line) and measured (red open circles) sound absorption spectra of the unit. <bold>(C)</bold> Real and imaginary parts of relative acoustic impedance <italic>Z</italic>
<sub>r</sub> of the unit. Distributions of <bold>(D)</bold> the pressure amplitude and <bold>(E)</bold> total thermal viscous power loss density in the unit excited by a normal incident wave (blue solid arrows) at 239&#xa0;Hz.</p>
</caption>
<graphic xlink:href="fmats-08-764338-g003.tif"/>
</fig>
<p>To explain the existence of the sound absorption peak, we introduce the relative acoustic impedance of the unit defined as <inline-formula id="inf3">
<mml:math id="m3">
<mml:mrow>
<mml:msub>
<mml:mi>Z</mml:mi>
<mml:mi>r</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mrow>
<mml:mo>&#x2329;</mml:mo>
<mml:mi>p</mml:mi>
<mml:mo>&#x232a;</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>Z</mml:mi>
<mml:mi>a</mml:mi>
</mml:msub>
<mml:mrow>
<mml:mo>&#x2329;</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>v</mml:mi>
<mml:mo>&#x22a5;</mml:mo>
</mml:msub>
</mml:mrow>
<mml:mo>&#x232a;</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:math>
</inline-formula>(<xref ref-type="bibr" rid="B23">Li et&#x20;al., 2016</xref>), where <italic>Z</italic>
<sub>a</sub> &#x3d; <italic>&#x3c1;</italic>
<sub>a</sub>
<italic>c</italic>
<sub>a</sub> is the acoustic impedance of air, <italic>p</italic> and <italic>v</italic>
<sub>&#x22a5;</sub>are the total acoustic pressure and the sound velocity normal to the surface, respectively, and <inline-formula id="inf4">
<mml:math id="m4">
<mml:mrow>
<mml:mrow>
<mml:mo>&#x2329;</mml:mo>
<mml:mo>.</mml:mo>
<mml:mo>&#x232a;</mml:mo>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> represents averaging over the surface of the unit. The simulated real and imaginary parts of <italic>Z</italic>
<sub>r</sub> are shown in <xref ref-type="fig" rid="F3">Figure&#x20;3C</xref>. We observe that, at the frequency of absorption peak, the real and imaginary parts of <italic>Z</italic>
<sub>r</sub> are about 1.35 and 0, respectively, indicating better impedance match between the proposed structure and air at 239&#xa0;Hz. Therefore, the near-perfect sound absorption can be created by the unit structure.</p>
<p>Furthermore, we find that the frequency of sound absorption peak is almost the same as that of the MMR mode, and thus the sound absorption may arise from the MMR mode of the unit. To make a further insight into it, we simulate the distributions of the pressure amplitude and total thermal-viscous power loss density in the unit created by a normal incidence of sound at 239&#xa0;Hz, which are shown in <xref ref-type="fig" rid="F3">Figures 3D,E</xref>, respectively. Note that the excited pressure amplitude distribution of the unit (<xref ref-type="fig" rid="F3">Figure&#x20;3D</xref>) agrees well with that of the MMR mode (<xref ref-type="fig" rid="F2">Figure&#x20;2A</xref>), indicating that the low-frequency sound absorption is created by the MMR mode of the unit. Moreover, as shown in <xref ref-type="fig" rid="F3">Figure&#x20;3E</xref>, there exist an obvious thermal-viscous sound loss around the central circular hole and four narrow slits, especially the central circular hole. Therefore, we deduce that the sound absorption of the unit arises from the thermoviscous loss around the central circular hole and four narrow slits under the excitation of the MMR mode. Beyond that, we also simulate the sound absorption spectra created by the MMR mode of the unit with different incident angles (<italic>&#x3b8;</italic>), and the absorption spectra are relatively stable below <italic>&#x3b8; &#x3d;</italic> 60&#xb0;. (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>).</p>
<p>Besides the sound absorption created by the MMR mode, we simulate the performances of sound absorption created by the second MMR mode of the unit. The results show that the sound absorption can also be created by the second MMR mode, but its absorption performance is reduced greatly due to the sound reflection created by the impedance mismatch (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>). Furthermore, we simulate the sound absorption spectra of the units with different number of surrounding cavities (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>), in which the results further demonstrates that the sound absorption of the unit arises from the excitation of both MMR&#x20;modes.</p>
</sec>
</sec>
<sec id="s3">
<title>Bandwidth Optimization of Sound Absorber</title>
<p>Finally, we discuss the influences of the parameters <italic>b</italic> and <italic>d</italic> on the sound absorption and further optimize the working bandwidth of the sound absorber. <xref ref-type="fig" rid="F4">Figures 4A,B</xref> show the simulated sound absorption spectra created by the MMR mode as a function of the parameters <italic>b</italic> and <italic>d</italic>, respectively, in which other parameters remain unchanged. It is found that, with the decrease of both parameters, the working bandwidth moves to the low-frequency region with a high sound absorption coefficient. The corresponding measured results for the parameters <italic>b</italic> and <italic>d</italic> are displayed in <xref ref-type="fig" rid="F4">Figures 4C,D</xref>, which agree well with the simulation ones. Thus, we can reduce the working frequency of the sound absorption by simply decreasing the values of <italic>b</italic> and&#x20;<italic>d</italic>.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Simulated sound absorption spectra as a function of parameters <bold>(A)</bold> <italic>b</italic> and <bold>(B)</bold> <italic>d</italic>, and the corresponding measured sound absorption spectra for the parameters <bold>(C)</bold> <italic>b</italic> and <bold>(D)</bold> <italic>d</italic>, in which the other parameters remain unchanged.</p>
</caption>
<graphic xlink:href="fmats-08-764338-g004.tif"/>
</fig>
<p>To further optimize the working bandwidth, we design two types of compound units A and B consisting of 4 units (2 &#xd7; 2 array) with different values of <italic>d</italic> (<italic>d</italic>&#x20;&#x3d; 8, 10, and 12&#xa0;mm for the units I, II and III), and experimentally measure sound absorption of both compound units. The experiment set-up is shown in <xref ref-type="fig" rid="F5">Figure&#x20;5A</xref>, in which the width and height of the waveguide double those in <xref ref-type="fig" rid="F3">Figure&#x20;3A</xref>, and the other parameters are the same. As shown in <xref ref-type="fig" rid="F5">Figure&#x20;5B</xref>, the compound unit A consists of two types of units (I and II), and the arrangement of 4 units is shown in the sample photograph (shown in bottom inset). Note that, by combining the units I and II, the fractional bandwidth of the compound unit A can reach about 16.4%, in which the working frequency range (266&#x2013;313.5&#xa0;Hz, black shaded region) can cover those of a single unit I or II. Compared with the result in <xref ref-type="fig" rid="F3">Figure&#x20;3B</xref>, the maximum sound absorption coefficient decreases slightly, but the absorption peak becomes wide and flat due to their coupling effect of both types of units. Additionally, as shown in <xref ref-type="fig" rid="F5">Figure&#x20;5C</xref>, the compound unit B is composed of three types of units (I, II and III). By introducing the unit III, the working band (266&#x2013;321&#xa0;Hz, black shaded region) of the compound unit B is further improved, and its fractional bandwidth can be enhanced to 18.7%, showing a broadband feature of the sound absorption. The measured sound absorption spectra for both compound units agree with the simulations. Therefore, by combining the units with different values of <italic>d</italic>, we can further enhance the working bandwidth of the proposed sound absorber. Furthermore, we simulate the sound absorption spectra of another two types of compound units C and D with different configurations (see <xref ref-type="sec" rid="s10">Supplementary Material</xref>). Compared with the absorption performance of the compound units A and B, we demonstrate that the absorption performance of the compound unit is closely related to its configuration.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>
<bold>(A)</bold> Experiment set-up of sound absorption for the compound unit. Simulated (blue solid lines) and measured (red open circles) sound absorption spectra of the compound units <bold>(B)</bold> A and <bold>(C)</bold> B. The arrangement of 4 units with different values of <italic>d</italic> (<italic>d</italic>&#x20;&#x3d; 8, 10, and 12&#xa0;mm for the units I, II, and III) are shown in the paragraphs of the compound units A and B (shown as two insets on the bottom).</p>
</caption>
<graphic xlink:href="fmats-08-764338-g005.tif"/>
</fig>
</sec>
<sec sec-type="conclusion" id="s4">
<title>Conclusion</title>
<p>In conclusions, we have demonstrated a metasurface-based unit with near-perfect low-frequency sound absorption based on artificial Mie resonances. The results show that a series of artificial Mie resonance modes can be observed in the unit, including the MMR mode at 238.4&#xa0;Hz and the second MMR mode at 1,145.4&#xa0;Hz. Based on the excited MMR mode and the thermal-viscous loss around the circular hole and four narrow slits of the unit, the near-perfect low-frequency sound absorption is achieved at 239&#xa0;Hz, the maximum absorption coefficient and fractional bandwidth of the proposed unit can reach 0.97 and 12.9%. It is noted that the thickness of the unit is only about &#x3bb;/90, showing a deep subwavelength thickness of the proposed metasurface-based sound absorber. In addition, we discuss the influences of structure parameters <italic>b</italic> and <italic>d</italic> on the sound absorption in detail, and find that the working bandwidth moves to the low-frequency region with a high absorption coefficient by decreasing both parameters. Finally, we improve the working bandwidth of the sound absorption by combining 4 units with different values of <italic>b</italic>, and the fractional bandwidth of the compound unit B can be further enhanced to 18.7%. The measured and simulated sound absorption spectra match well with each other. The proposed multiple-cavity units with the near-perfect sound absorption and broadband feature provide diverse routes to design advanced sound absorption structures with great potential applications in low-frequency noise control, architectural acoustics and environmental protection.</p>
</sec>
</body>
<back>
<sec id="s5">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s10">Supplementary Material</xref>, further inquiries can be directed to the corresponding authors.</p>
</sec>
<sec id="s6">
<title>Author Contributions</title>
<p>Y-JG and YG contributed equally to this&#x20;work.</p>
</sec>
<sec id="s7">
<title>Funding</title>
<p>This work was supported by the National Natural Science Foundation of China (11774137, 51779107, 11834008, 61671314, 11974176, and 12174159).</p>
</sec>
<sec sec-type="COI-statement" id="s8">
<title>Conflict of Interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s9">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec id="s10">
<title>Supplementary Material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/fmats.2021.764338/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/fmats.2021.764338/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="DataSheet1.DOC" id="SM1" mimetype="application/DOC" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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