The research was conducted in the Western Yakutia in the territory of the Daldyn-Alakit diamond-bearing region 66°24′N, 112°17′E of the Yakut diamondiferous province (Figure 1).

The Daldyn-Alakit diamond-bearing region is a unique geological object, located in the central part of the Yakut diamondiferous province at the junction of the northeastern margin of the Tunguska syneclise with the Anabar anteclise (Afanasiev et al., 2010; Kargin et al., 2011). In this area, kimberlite bodies form a discontinuous strip about 150 km long, extending in a north-eastern direction. More than 130 pipes and dikes are known, unevenly distributed (Kharkiv et al., 1998). They are concentrated within two areas: the Daldyn kimberlite field (DKF) is in the northeast, where the Udachninsky Mining and Processing Plant (UMPP) has been developing the Udachnaya kimberlite pipe since 1971, and since 2000 – the Zarnitsa pipe. The Alakit-Markha kimberlite field (AMKF) is located in the central and southwestern parts of the region, where the Aikhal Mining and Processing Plant (AMPP) put five kimberlite pipes into operation from 1961 to 2023 – Yubileinaya, Aikhal, Sytykanskaya, Zarya and Komsomolskaya. Currently, underground mining is underway at the Udachnaya and Aikhal pipe quarries, and the Sytykanskaya and Komsomolskaya pipes have been completely exhausted and their quarries have been mothballed.

The research area is drained by three large watercourses: Markha, Daldyn and Alakit. In the Daldyn river basin in the northeast of the region, carbonate rocks of the Lower Ordovician and Upper Cambrian are widespread, represented by limestones, dolomites, claystones and marls. In the southwestern part, in the upper reaches of the Alakit and Markha rivers, variegated clay-carbonate deposits of the Middle Ordovician and limestones of the Lower Silurian predominate. In addition, the Upper Paleozoic terrigenous rocks are widely developed in this area. They include clay shales, siltstones and sandstones of the Middle-Upper Carboniferous and Lower and Upper Permian. All these Lower Paleozoic formations are intruded by numerous kimberlite pipes of the Middle Paleozoic age (Kharkiv et al., 1998).

The region is characterized by a sharply continental cryoarid climate, with negative average annual temperatures of −12 °С and continuous distribution of permafrost rocks (Shadrinova, 2024).

The combination of geological conditions and climatic factors determines the specificity of the soil-forming rocks of the region, which are distinguished by a complex composition with a significant influence of magmatic processes on the geochemistry of modern landscapes. Natural geochemical anomalies related to kimberlites, traps and deep faults, form the geochemical habit of the territory with the dominance of the Cr-Ni-Co component in the microelement composition of the soils (Legostaeva et al., 2023). Modern man-made landscapes (quarries, waste rock dumps, tailings storages, etc.), consisting of a mixture of rubble-block material and sandy-loam fractions, are sources of impact on the components of the natural landscape and, above all, on the soil cover, with the formation of man-made anomalies in the soil cover, which are distinguished by high-contrast variations of elements coherent with kimberlites with admixture of Zn, Mn, Pb, Cd and As.

The study focuses on soils from natural undisturbed landscapes and anthropogenic substrates from mining waste dumps at the industrial sites of the Daldyn-Alakit diamond-bearing region. Man-made massifs or formations are represented by dumps around quarries of developed diamond deposits and preserved “tails” of kimberlite enrichment - tailings storage facilities. The dumps are composed of rubble-block material from deposits hosting and overlying kimberlites with an admixture of argillo-arenaceous filler. Tailings–by sandy-loam fraction of kimberlites. Man-made formations overlap the Quaternary formations of various genesis and age. The area of distribution and thickness of man-made deposits directly depend on the size and depth of the quarries being developed (Legostaeva et al., 2017). For example, in the area of the Aikhal deposit, the thickness of man-made deposits on waste rock dumps reaches 40 m (Figure 2). And on the right slope of the Daldyn River valley, where the Udachnaya pipe quarry is located, there are dumps of rocks containing kimberlites: Severny (occupies an area of 238 ha and has a height of 125 m), Zapadny (272 ha, height 125 m) and Yuzhny (70 ha, height 85 m). Their absolute marks are 420 m, 455 m and 425 m respectively.

In general, waste rock dumps and tailings storages are man-made deposits, which, on the one hand, may be potential mineral deposits, or deposits with a high content of a wide range of elements, on the other hand, it is a permanent and long-term source of secondary pollution of adjacent territories. We have considered the assessment of the degree of impact of man-made massifs on ecosystem components based on the analysis of the ecological and geochemical state of the soil cover of industrial sites themselves with an assessment of the geoecological state of the territories, and the development of soil salinization processes in technogenically transformed landscapes is considered as an indicator of the manifestation of technogenic impact.

The selection and sample preparation of soils were carried out in accordance with ISO 18400-8 (2018), the main oxides (SiO₂, Al₂O₃, Fe₂O₃, etc.) were determined using classical methods of silicate analysis, including gravimetric, spectrophotometric, and titrimetric techniques following established handbooks (Arinushkina, 1970; Vozbutskaya, 1968; PND F 16.1.42-04, 2016). The content of the main anions and cations was determined in an water extract with a soil to water ratio of 1:5 according to GOST 26423-85 (1985); carbonate and bicarbonate anions (CO₃ ^2–, HCO^3–) were determined by titration with hydrochloric acid (HCl) using a potentiometric endpoint (GOST 26423-85, 1985); sulfate anions (SO₄ ^2–) were analyzed turbidimetrically by precipitation with barium chloride (BaCl₂); chloride anions (Cl⁻) were quantified by argentometric titration (Mohr’s method) in accordance with GOST 26425-85 (1985); water-soluble calcium (Ca²⁺) and magnesium (Mg2⁺) cations were measured by complexometric titration with Trilon B (EDTA) (GOST 26428-85, 1985); water-soluble sodium Na⁺ and potassium K⁺ cations were calculated from the difference between the total sum of anions and the sum of measured cations, a standard ion balance method (GOST 26426-85, 1985). The assessment of the chemistry and degree of salinity of soils and grounds was carried out based on the sum of toxic salts based on the results of water extract (Bazilevich and Pankova, 1968; 1972; GOST R 59540, 2021). The mineralogical composition was studied by petrographic (on a polarizing microscope–МТ9430L, MEIJI TECHNO CO., LTD., Japan) and X-ray phase (on a diffractometer D2 PHASER) methods of analysis. Semi-quantitative mineralogical composition was calculated using peak intensity comparison with reference data using the RIR method (Reference Intensity Ratio) taking into account the elemental composition to adjust the proportions of minerals. The elemental composition of gallstones was analyzed using semi-quantitative atomic emission spectroscopy (MAES, “VMK-Optoelectronics,” Russia). Powdered samples were atomized using an electrothermal sprayer with a graphite rod, and the resulting spectral lines were evaluated visually. Among 32 analyzed elements (Au, Ta, Sb, Ga, W, Cr, Ge, Ba, Be, Nb, Sn, V, Mo, Li, La, In, Sc, Yb, Y, Ag, Co, Sr), concentrations were below the detection limit The map-schemes of the areal distribution of soil salinity were constructed in the Surfer-13 software package using the “kriging” interpolation method.

The data were processed using descriptive statistics. The results are presented as the arithmetic mean (Mean), minimum and maximum values (Min, Max), standard deviation (Std. Dev.), and coefficient of variation (CV, %) to characterize the central tendency and variability of the obtained datasets.

Our integrated analysis reveals a clear disconnect between the geogenic salinization potential and the actual technogenic factors controlling its expression, as unequivocally demonstrated by petrological data from sedimentary and igneous rocks.

Man-made massifs on the industrial sites of the Udachninsky and Aikhal mining and processing plants are composed of sedimentary rock fragments, mainly limestone, dolomite and gypsum. The Udachninskaya site is dominated by brown and grey limestones with a massive structure, as well as milky-white varieties with inclusions of plant remains, probably algae. The algae are composed of dark grey pelitomorphic carbonate against a background of light fine-grained calcite (Figure 3a). Dolomites are mostly marbled, have a banded texture and fine-grained structure, less often–a massive structure (Figures 3b,c). Their color range varies from gray and brownish-gray to green with yellowish-brown lenses. There are also yellowish-gray fine-grained sandstones with a banded texture.

At the Aikhal site, brownish and grayish limestones are also characterized by a massive structure, and dolomites are brownish-gray. The composition of the dolomites at both sites includes carbonates and insoluble mineral residue (quartz, mica, feldspars, clinochlore – 2%). The petrographic study was confirmed by the results of semi-quantitative X-ray phase analysis (Table 1). The vast majority of samples are represented by carbonate rocks: limestones, dolomites and calcareous sandstones. The phase-mineral composition of limestones and dolomites includes carbonates and insoluble mineral residue. X-ray phase analysis revealed that limestones contain small admixtures of dolomite, and dolomites contain small admixtures of calcite. The exception is three samples (numbers P1, P3 and P4), where the insoluble mineral residue is represented by quartz, feldspars and mica. Clinochlore was found in four samples (numbers P1, P4, P5 and P9) (between 2.27% and 9.06%).

The chemical composition of rocks clearly reflects the mineral composition of carbonates and insoluble mineral residues. Oxides of silicon, titanium, aluminum, iron, potassium and sodium characterize the insoluble mineral residue, and oxides of calcium, magnesium, manganese and iron oxide characterize the carbonate component.

Samples from the empty dumps of the Udachninsky mining and processing plant are predominantly represented by clayey carbonate rocks, in particular calcite-bearing clayey dolomite and dolomite-bearing clayey limestone. Samples from the dumps of the Aikhal mining and processing plant are, as a rule, marls described as calcite-bearing dolomite, calcite dolomite, calcareous dolomite. The clay rocks record dolomite-bearing clayey limestone (sample number 3371) and dolomite clayey limestone (samples numbers 3346, 3348), and the marls record calcareous dolomite (sample P-19-4), calcite dolomite (samples P-19-1-7 and P-19-1-8), low-magnesite dolomite (sample 3-1/1-5) and magnesite-bearing dolomite (sample 3-1/1-1) marls. In some samples, clinochlore was detected, which, as a phyllosilicate, is a mineral of metamorphic processes, and its presence in marls explains their marbling.

The identified types of carbonate rocks differ petrochemically (Table 2). Marls in both the quarry dumps of the Aikhal mining and processing plant and the quarry dumps of the Udachninsky mining and processing plant are distinguished by an increased content of silica (between 23.88% and 34.24%) and alumina (between 3.26% and 8.28%), which in general defines the difference from clayey carbonate rocks. The content of potassium oxide in marls (between 1.54% and 1.74%) significantly exceeds the content of this oxide in clayey carbonate rocks, where it does not reach even one percent.

Gypsum, found mainly in the dumps of the Komsomolskaya, Yubileynaya and Sytykanskaya pipes on the territory of the Aikhal site, differs from marls and clayey carbonate rocks by its increased sulfur content (50.33%), and the content of calcium oxide (30.14%) and magnesium oxide (3.05%) allows us to conclude that calcareous dolomite marls were the host rocks.

It is found in layers where the dolomite, inundation part is composed of gray, inequigranular dolomites with interlayers of stromatolitic, clayey and calcareous dolomites and dolomite marls with gypsum and anhydrite.

It should be noted that the change in the calcite content is inversely proportional to the dolomite content–with an increase in the first, the amount of the second decreases. The following common factor is observed for feldspars: potassium feldspar is present in limestones, the amount of sodium-calcium feldspars (plagioclases) is very insignificant or is below the sensitivity limit of the analysis method; plagioclase is present in dolomites, at the same time, on the contrary, the amount of potassium feldspar is very insignificant, or is below the sensitivity limit of the analysis method.

Fragments of igneous rocks in the dumps are represented by dolerites and kimberlites (Figure 4). Dolerites have a massive and ophitic structure, composed of plagioclase (40%), pyroxene (25%), olivine (25%) and ore minerals (10%) (Figures 4b,f). Kimberlites have a massive, porphyry structure, contain up to 15% xenogenic material (carbonates) and 85% of the main mass (carbonate, phlogopite, serpentine, ore minerals) (Figures 4d,h).

Chemical analysis of two samples (3340 and 3347) of kimberlites in the dumps of the Komsomolskaya pipe quarry of the Aikhal mining and processing plant revealed characteristic features of the chemical composition (Table 3), reflecting the processes of secondary rock changes. The predominant components in all studied samples are silicon dioxide (between 48.32% and 48.63%) and aluminum oxide (between 15.24% and 16.33%), which is typical for silicate rocks. The significant content of iron oxide (between 11.20% and 12.21%) in the complete absence of iron oxide indicates the predominance of oxidized forms of iron, which is typical for weathered kimberlites. Variations in calcium oxide content between 11.37% and 14.18% may be due to uneven distribution of carbonate material in the dumps. Low magnesium oxide content (between 7.45% and 8.49%) and the presence of volatile components also indicate the influence of weathering processes in kimberlite rocks. Alkaline components are present in small quantities: sodium oxide (between 1.46% and 1.48%) and potassium oxide (between 0.22% and 0.26%), that corresponds to the typical geochemistry of kimberlites. The obtained data are consistent with the literature data on the composition of altered kimberlites and indicate a significant degree of their secondary transformation (Zinchuk, 2021). It should be noted that the high content of iron oxide and calcium oxide in the soils and rocks of the Aikhal mining and processing plant dumps may affect the salt balance of adjacent soils, which in turn is not found in the rocks of the Udachninsky mining and processing plant waste dumps.

The conclusions obtained during the petrographic study are confirmed by the results of semi-quantitative X-ray phase analysis (Table 4). The variation in the amount of minerals in the composition of dolerites is as follows: plagioclase between 47% and 69%, pyroxene between 23% and 33%, ilmenite between 7% and 12%, montmorillonite group minerals between 1% and 5%, quartz between 1% and 3%, chlorite group minerals about 3%, mica about 7%, olivine, amphibole and talc are present in minor quantities.

A set of methods used in the analysis of the structural and material composition of man-made formations allows us to conclude that dumps are composed of rubble and block material of rocks containing and overlying kimberlite pipes), consisting mainly of limestones and dolomites, with wide variation in quartz content, while the amount of feldspars and layered silicates varies within only 10%.

The dumps are composed of limestone and dolomite on the surface, but gypsum is present in the dumps of the Komsomolskaya, Yubileynaya and Sytykanskaya pipes of the Aikhal industrial site. The predominance of serpentine and carbonates in kimberlites is noted, which probably indicates that the kimberlite grounmass is substantially altered, namely, serpentinized and carbonated.

Average characteristics of geochemical features of rocks in dumps can be the basis for assessment when identifying any differences (Table 5). The prevalence of elements is adopted according to Vinogradov (1988).

Based on the clarkes, the rocks in the dumps are distinguished by the uniqueness of their trace element spectra:

• DKF - Nb _4,02→ Sc _3,03 →Ni _1,5 →Cr _1,25→ Mn _1,09,

The given geochemical assessment is somewhat conditional, but it is quite acceptable for a general characterization. The composition of the trace element spectra shows the dominance of dolerites on the surface of the dumps.

The discovery of gypsum in the waste dumps of the Aikhal site (Komsomolskaya, Yubileynaya pipes) identifies them as a definitive potential source for sulfate-type salinization. In contrast, the kimberlites themselves, while enriched in a range of trace elements (Table 5), are dominated by silicate and carbonate minerals (e.g., serpentine, calcite) with low solubility in the cold Arctic climate. As our data on water-soluble salts confirm, their weathering alone is unlikely to cause significant soil salinization under natural conditions but contributes strongly to the trace metal load (e.g., Ni, Cr).

In the soil cover, cryosols (hereinafter: Cryosols according to the WRB classification) occupy 40.7%. Permafrost alluvial soils (Fluvisols) are an intrazonal type and are located on 19.4% of the area within the territory. Coarse-humic leptosols (Leptosols Skeletic (Humic)) and coarse-humic carbo-leptosols (Rendzin Leptosols (Humic)) - mountain primitive soils occupy a subordinate position in the structure of the soil cover and are formed in the upper parts of gentle slopes. All diagnosed soils belong to the postlithogenic group (Shishov et al., 2004; Dokuchaev Soil Science Inst, 2008). The soils are characterized by shallow profile, high rubble content, heavy granulometric composition, weak differentiation of the soil profile, which thickness on average reaches 30 cm with signs of thixotropy and cryoturbation mixing. For zonal loamy soils of watersheds, the average temperature for three summer months (June-August) at a depth of 20 cm varies between 0.1 and 3.6 °C–3.9 °C (Fedorov-Davydov et al., 2018). The lower soil horizons are usually frozen even in the summer months.

The lower horizons of C or CRM soils are usually frozen even during the summer months. The content of hygroscopic moisture varies from zero point ninety-eight hundredths to three-point fifteen hundredths percent depending on the depth of the horizons and the content of coarse-humic organic matter. The pH values in the studied soils varied from acidic to alkaline–from four point three to eight point seven (Table 6). Most soil samples are characterized by an alkaline pH reaction, their share is seventy percent, about fifteen percent of soil samples are characterized by a neutral pH reaction. The organic matter content is quite high, which is typical for soils in the northern regions and is associated with poor decomposition of organic matter.

Soils are usually characterized by a heavy granulometric composition with a predominance of finely dispersed fractions. Clay fractions have the highest sorption capacity and can accumulate the groundmass of micro- and macroelements.

Table 7 presents the results of the chemical composition analysis of the studied soils. The main parameters include the content of major oxides (SiO₂, Al₂O₃, Fe₂O₃, CaO, MgO, Na₂O, K₂O, TiO₂, MnO), volatile components (H₂O⁻, P₂O₅, CO₂), trace elements (Li₂O, Rb₂O) and total sulfur. The relatively low average SiO₂ values (40%–55%) reflect the medium loamy composition of the studied soils. Overall, there is a noticeable decrease in Si, Al, and Fe oxides upward through the soil profile, indicating the predominance of the organogenic fraction. Similarly, the total content of calcium and magnesium oxides consistently decreases in the upper soil layers compared to the parent material.

The mineralogical composition of soils is given in general for zonal soil types, formed within the conventional boundaries of the Daldyn and Alakit-Markha kimberlite fields. The mineral composition of the studied soil types is almost identical.

The mineralogical composition of the soils is generally characteristic of zonal soil types formed within the conventional boundaries of the Daldyn and Alakit-Markha kimberlite fields. The mineral composition of the studied soil types is virtually identical.

It is natural that the mineralogical composition of the soil is mainly inherited from the parent rock. The main minerals of all soils are quartz, feldspars and dolomite; calcite was identified only in Rendzic Leptosols. Next aluminosilicates come, their composition is quite uniform and is represented by minerals from the group of micas, chlorites and minerals with a labile lattice. Pyroxene is present in leptosols. The content of dolomite, feldspars and minerals of the chlorite and mica group decreases from bottom to top along the profile (Table 8), which indicates heritability from rocks and weak transformation in the soil profile. This mechanism is typical for cryogenic landscapes, where low temperatures and a short growing season slow down the processes of chemical weathering and clay formation.

Trace element characteristics of soils of the Daldyn and Alakit-Markha kimberlite fields are given in Table 9. The average concentrations of trace elements in the soils of the Daldyn kimberlite field decrease in the following order: Ni > Mn > Cr > Li > Zn > V > P > Ti, etc. Among them, the contents of Ni, Cr, Co, As, Mn exceeded background values by 4.93, 2.09, 1.72, 1.69 and 1.65 times, respectively. The coefficient of variation (CV) reflects the average variation of element concentrations, while CV > 35% reflects a high level of oscillations, 15% < CV < 35% is a moderate level of variation, and CV ≤ 15% – low variability (Wang et al., 2019; Abliz et al., 2023). In this study, the CV of Ni, Cr and P accounted for more than 35%, which indicates high fluctuations in values. 42% of the values are characterized by low variation, and Li, V, Mn and Zn have more uniform values.

The results of the study of the trace element composition of soils at the industrial site of the Udachninsky mining and processing plant revealed significant differences in the distribution of heavy metals compared to regional and local background values (Table 9). Data analysis demonstrates a pronounced man-made transformation of the soil cover, manifested in changes in both the gross content and mobility of trace elements. The most significant changes are noticeable for chromium, which content in industrial soils (107 mg/kg) exceeds both regional background values (80.6 mg/kg) and the indicators of undisturbed areas (63 mg/kg). At the same time, the mobility of chromium remains extremely low (1.1%–5.0%), which is typical for its stable forms in the soil environment. A similar trend is observed for nickel, which concentration at the industrial site (63 mg/kg) is significantly higher than the regional background (38 mg/kg), however, its mobility rate has been reduced to 6.2% against the regional average of 23.6%. The behavior of lead deserves special attention, demonstrating not only an increase in the gross content in industrial soils (10 mg/kg versus 5.6 mg/kg in the local background), but also abnormally high mobility rates (100.7% in regional data), which requires additional verification of the results obtained. Zinc also shows an increase in content in the zone of technogenic impact (70.3 mg/kg) relative to the regional background (54 mg/kg) with some decrease in mobility (13.0% versus 18.4%). Copper is characterized by relative stability of gross content (27.1–32 mg/kg) while maintaining a high degree of mobility at the level of 25%–25.5%, which is due to its ability to form complex compounds with soil organic matter. Manganese, despite the decrease in its total content in industrial soils (560 mg/kg) compared to the regional background (1030 mg/kg), retains high mobility (34.7%–34.9%), which is explained by its active participation in redox processes. The obtained results indicate a significant man-made impact on the soil cover in the area of the industrial site of the Udachninsky mining and processing plant, expressed in the accumulation of a number of heavy metals (Cr, Ni, Pb, Zn) with a change in their migration capacity.

Thus, the soils of the Daldyn and Alakit-Markha kimberlite fields reflect the characteristics of the soil-forming rocks and climatic conditions of the region, which is confirmed by their mineralogical composition. The mineralogical composition of soils represented mainly by silicate and carbonate associations, plays a key role in soil formation processes. In cryolithozone conditions these mineral groups, having limited solubility at low temperatures, do not contribute to the development of salinization processes. As is known, in extreme northern conditions, physical weathering of the mineral matrix prevails over chemical weathering. In this regard, a geoecological assessment of the state of the territories of industrial sites of mining and processing plants of the Daldyn-Alakit diamond-bearing region was carried out on the technogenically transformed territory of industrial sites of mining and processing plants. This assessment was based on the interpretation of the results of the water-soluble salt dynamics analysis as an indicator of technogenic impact on soil cover and soil-like formations.

The surface cover of technogenically transformed landscapes of industrial sites is a motley pedonic complex with disturbed internal relationships of natural mechanisms of intra-profile distribution of matter. In addition to the remaining small areas with natural soil and vegetation cover with undisturbed soil profile morphology, anthropogenically modified soils have been formed–these are soils “preserved” by man-made embankments, dumps or a layer of spilled pulp, covering a completely preserved natural appearance of the soil profile. Most of the territory of industrial sites is occupied by man-made surface formations (MSF), represented by the lithostrats–waste dump soils with signs of primary soil formation, and toxilithostrats–soils on the beaches of tailings storage facilities, consisting of fine- and medium-grained material from waste pulp, often with the beginnings of ruderal vegetation development along the periphery of the sites (or the beach of tailings).

In the natural landscapes of the Daldyn-Alakit diamond-bearing region outside the zone of technogenic impact, the cation-anion composition of soils is characterized by the following series: Ca²⁺, Cl⁻ > HCO₃ ⁻ > Mg²⁺ > Na⁺,K⁺ > SO₄ ²⁻ and a complete absence of salinization processes. The background soils contain non-toxic salts such as Ca(HCO₃)₂ and CaSO₄, toxic salts are absent or are present in concentrations below the toxicity limit values (Figure 5A).

At the same time, the development of area soil salinization can be observed at the industrial sites of both mining and processing plants, which is especially evident in the area of impact of man-made storage facilities.

In the soils of the industrial site of the Udachninsky mining and processing plant with occurrence of salinization processes from weak to moderate degree, a uniform increase of all ions is noticeable, and in soils with a strong and very strong degree, a sharp increase of Cl⁻ and Na⁺ and K⁺is recorded. The soils of the industrial site of the Udachnaya pipe are distinguished by a large range of toxic salts. In 2012, a highly mineralized water discharge was discovered on the territory of the “Kiengsky” injection site (Legostaeva et al., 2018). According to the analysis results, high values of chlorides and sodium, and, accordingly, the degree of salinization, are observed at the points of their outcrop. In addition, high salt contents are recorded in soils near tailings storage facilities and waste dumps both at the AMPP and UMPP sites (Figures 5B,C).

The qualitative composition of toxic salts is characterized by the presence of toxic salts MgCl₂ and NaCl in all saline samples and CaCl₂ in more than half of the samples. Their concentration in highly and very highly saline soils in relation to slightly saline samples increases by more than 11, 44 and 25 times, respectively (Table 10). The entire area is characterized by a predominantly chloride type of salinization.

In the soils of the industrial site of the AMPP with the occurrence of halogenesis processes, an increase in the content of almost all water-soluble ions except hydrocarbonates is recorded. In soils with a low degree of salinity, a sharp increase in sulfates and sodium is visible, chloride values remain virtually unchanged, soils are characterized mainly by chloride-sulphate, sulphate, less often - sulphate-chloride type. In soils with an average degree of salinity, a sharp increase in chloride content is recorded and they are characterized by a chloride, sulfate-chloride type. One point with a high degree of chloride type salinity was identified on the territory of the AMPP–on the territory of the Komsomolskaya pipe, where an emergency spill of the reinjection water pipeline occurred (Figure 6).

Na₂SO₄ and MgCl₂ are commonly present in toxic salts (Table 10). As the degree of salinity increases, the NaCl content increases. The maximum values of the sum of toxic salts reach 0.8%.

In general, in the territory of the Daldyn-Alakit diamond-bearing region, the development of technogenic salinization processes has acquired an area character (Figure 7). On the territory of the UMPP, a more intensive process of development of salinization of the predominantly chloride type is observed. The qualitative composition is dominated by toxic chloride salts: MgCl₂, NaCl and CaCl₂. Salts dominate in the soils and grounds on the territory of the AMPP: Na₂SO₄ and MgCl₂ and NaCl. Increased concentrations of chlorides are observed in the impact zone of tailings storage facilities, where, according to (Yannikov et al., 2022), chloride brines with a concentration of up to 60 g/L are buried.

The development of kimberlite pipes in the Yakutian diamond province is complicated by the presence of highly mineralized brines. As the quarry depth increases, the volume of brines flowing into it also increases. These highly mineralized waters are pumped to the surface and stored in both underground and surface technogenic storage facilities, which have a direct impact on the adjacent territory.

Currently, the natural brine inflow is 300–350 m³/day at the Udachnaya pipe, 120–150 m³/day at the Aikhal mine, and 10–20 m³/day at the Yubileynaya pipe. Further mining operations plan to increase the depth of the pipes: Aikhal - up to 1,100 m, Yubileynaya - up to 900 or 1,500 m, and Udachnaya - to a depth of 1,830 m (Yannikov et al., 2024). This will undoubtedly lead to an increase in the inflow of highly mineralized brines (Yannikov et al., 2021) and the volume of waste. Consequently, an activation of surface salinization processes can be expected in areas within the impact zone of tailings storage facilities and waste rock dumps.

The territory of the Daldyn kimberlite field is characterized by larger volumes of brines compared to the Alakit-Markha kimberlite field. In general, the predominance of the chloride type of salinization in the soils at the Udachninsky MPP site is due to a complex hydrogeological situation and the indirect influence of highly mineralized brines. In contrast, the territory of the Aikhal MPP exhibits predominantly sulfate and chloride-sulfate types of soil salinization, which is caused primarily by the impact of waste dumps characterized by a diverse composition.

This latent geogenic potential is activated almost exclusively by external technogenic factors. The data presented in Figures X and Y provide compelling evidence that the primary activator for chloride-type salinization is the infiltration and surface runoff of highly mineralized brines from drainage water injection sites and tailings storage facilities. This explains the stark contrast between the two sites: the predominance of chloride salinity at the Udachninsky site is linked to its complex hydrogeology and brine management practices, while the sulfate-chloride types at the Aikhal site are triggered by the combined impact of brine discharge and the active weathering of gypsum-bearing dumps.

Thus, the spatial patterns of salinization are not a simple function of the waste rock composition but a complex interplay between this inherent potential and the specific mining-induced pathways of solute transport.