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<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title-group>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
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<issn pub-type="epub">2296-6463</issn>
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<article-id pub-id-type="publisher-id">1774169</article-id>
<article-id pub-id-type="doi">10.3389/feart.2026.1774169</article-id>
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<subj-group subj-group-type="heading">
<subject>Original Research</subject>
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<title-group>
<article-title>Petrogenesis of Huichizi granite and hosted amphibolite lens: implications for early Paleozoic evolution of the North Qinling orogenic belt</article-title>
<alt-title alt-title-type="left-running-head">Cui et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2026.1774169">10.3389/feart.2026.1774169</ext-link>
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<contrib contrib-type="author">
<name>
<surname>Cui</surname>
<given-names>Zhenhua</given-names>
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<contrib contrib-type="author" corresp="yes">
<name>
<surname>Chen</surname>
<given-names>Danling</given-names>
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<name>
<surname>Ren</surname>
<given-names>Yunfei</given-names>
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<surname>Bai</surname>
<given-names>Bowen</given-names>
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<contrib contrib-type="author">
<name>
<surname>Tang</surname>
<given-names>Yuan</given-names>
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<contrib contrib-type="author">
<name>
<surname>Ma</surname>
<given-names>Long</given-names>
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<name>
<surname>Liu</surname>
<given-names>Minglei</given-names>
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<aff id="aff1">
<institution>State Key Laboratory of Continental Evolution and Early Life, Department of Geology, Northwest University</institution>, <city>Xi&#x2019;an</city>, <country country="CN">China</country>
</aff>
<author-notes>
<corresp id="c001">
<label>&#x2a;</label>Correspondence: Danling Chen, <email xlink:href="mailto:dlchen@nwu.edu.cn">dlchen@nwu.edu.cn</email>; Yunfei Ren, <email xlink:href="mailto:yfren@nwu.edu.cn">yfren@nwu.edu.cn</email>
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<pub-date publication-format="electronic" date-type="pub" iso-8601-date="2026-02-18">
<day>18</day>
<month>02</month>
<year>2026</year>
</pub-date>
<pub-date publication-format="electronic" date-type="collection">
<year>2026</year>
</pub-date>
<volume>14</volume>
<elocation-id>1774169</elocation-id>
<history>
<date date-type="received">
<day>23</day>
<month>12</month>
<year>2025</year>
</date>
<date date-type="rev-recd">
<day>23</day>
<month>01</month>
<year>2026</year>
</date>
<date date-type="accepted">
<day>26</day>
<month>01</month>
<year>2026</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2026 Cui, Chen, Ren, Bai, Tang, Ma and Liu.</copyright-statement>
<copyright-year>2026</copyright-year>
<copyright-holder>Cui, Chen, Ren, Bai, Tang, Ma and Liu</copyright-holder>
<license>
<ali:license_ref start_date="2026-02-18">https://creativecommons.org/licenses/by/4.0/</ali:license_ref>
<license-p>This is an open-access article distributed under the terms of the <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">Creative Commons Attribution License (CC BY)</ext-link>. The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</license-p>
</license>
</permissions>
<abstract>
<p>The genesis of Early Paleozoic granite and its relationship with multi-stage metamorphism in the North Qinling Tectonic Belt (NQTB) are heavily debated and limit our understanding on the evolution of the Qinling Orogenic Belt. In this paper, we conducted systematic studies of petrology, geochemistry and zircon chronology on the Huichizi granite and a hosted composite lenticle (composed of amphibolite and felsic gneiss) in the NQTB. The results show that the composite lenticle recorded three metamorphic ages at 496&#x2013;492 Ma, 452 Ma and 404&#x2013;400 Ma, and metamorphic zircons from the amphibolite display flat heavy rare earth elements (REE) patterns without visible Eu anomalies. Both the metamorphic ages framework and zircon REE patterns are consistent with those from ultrahigh-pressure (UHP) metamorphic rocks in the NQTB. The Huichizi granite shows adakitic signatures with high Sr (391&#x2013;741 ppm), low Y (3.99&#x2013;6.87 ppm) contents and high Sr/Y ratios (60.6&#x2013;173). It is enriched in light REE and large-ion lithophile elements (Rb, Sr, Ba, Pb), and depleted in high-field-strength elements (Nb, Ta, Ti). The high Th (7.47&#x2013;12.9 ppm) content and Th/Ta (8.10&#x2013;31.5) ratios, but low Ce/Pb (1.67&#x2013;3.24) and Nb/La (0.14&#x2013;0.35) ratios are consistent with those of island arc granitoids. The granite is further characterized by low MgO, Cr, Ni contents, low K<sub>2</sub>O/Na<sub>2</sub>O ratios, and slightly depleted Sr-Nd isotopic compositions that resemble those of eclogites in the NQTB, indicating derivation from partial melting of Neoproterozoic mafic rocks during crustal thickening. The granite has a protolith age of 438 &#xb1; 5 Ma, at least 50 Ma later than the peak UHP metamorphism and underwent granulite-facies metamorphism/anatexis at ca. 400 Ma. Integrating the above results with existing studies, we propose that the northward subduction of the Shangdan Oceanic crust triggered partial melting of Neoproterozoic mafic rocks that had accumulated beneath the North Qinling Terrane. The ascending magma entrapped the exhumed UHP rocks of the Qinling Complex and emplaced at 438Ma. At ca. 400Ma, during the regional tectonic regime transition from compression to extension, the Huichizi granite and entrapped composite lenticle underwent medium-pressure granulite-facies metamorphism and anatexis together.</p>
</abstract>
<kwd-group>
<kwd>amphibolite and felsic gneiss composite lenticle</kwd>
<kwd>geochemistry</kwd>
<kwd>Huichizi granite</kwd>
<kwd>North Qinling Tectonic Belt</kwd>
<kwd>zircon U-Pb-Hf isotopes</kwd>
</kwd-group>
<funding-group>
<award-group id="gs1">
<funding-source id="sp1">
<institution-wrap>
<institution>National Natural Science Foundation of China</institution>
<institution-id institution-id-type="doi" vocab="open-funder-registry" vocab-identifier="10.13039/open_funder_registry">10.13039/501100001809</institution-id>
</institution-wrap>
</funding-source>
<award-id rid="sp1">42372074</award-id>
<award-id rid="sp1">42030307</award-id>
</award-group>
<funding-statement>The author(s) declared that financial support was received for this work and/or its publication. This work was supported by funds from National Natural Science Foundation of China (Grants Nos. 42372074 and 42030307).</funding-statement>
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<fig-count count="11"/>
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<ref-count count="112"/>
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<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Petrology</meta-value>
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</front>
<body>
<sec sec-type="intro" id="s1">
<label>1</label>
<title>Introduction</title>
<p>Although granitoids vary significantly in composition and scale across different orogenic stages (oceanic subduction, continental subduction/collision, exhumation, and orogenic collapse), their geochemical characteristics are controlled not only by tectonic setting but also by source composition and melting conditions. This leads to ambiguity in determining their formation environment solely based on discrimination diagrams (<xref ref-type="bibr" rid="B111">Zheng, 2012</xref>; <xref ref-type="bibr" rid="B50">Li et al., 2013</xref>; <xref ref-type="bibr" rid="B14">Chen et al., 2014</xref>). Therefore, discussions on formation mechanism of granite in orogenic belts must be based on the tectonic framework of orogenic belt evolution. For collisional orogens that experienced ultrahigh-pressure (UHP) metamorphism, the timing of UHP metamorphism can serve as an effective marker for distinguishing between syn-collision and post-collision granitic magmatism (<xref ref-type="bibr" rid="B78">Song et al., 2015</xref>). This criterion works well for orogenic belts that involve a single orogenic cycle, such as the Caledonian Orogen Belt in Europe and the North Qaidam Orogen Belt in northwest China. However, for composite orogenic belts with polycyclic orogenic history, the relationship between granitic magmatism and orogenic evolution is a complex challenge, which requires a comprehensive analysis that integrates multiple lines of evidence, including regional metamorphism, sedimentation, and stratigraphic unconformities.</p>
<p>The Qinling Orogenic Belt (QOB), located in central China, is a typical composite orogenic belt that has undergone multiple tectonic cycles. As a major component of the QOB, the North Qinling Tectonic Belt (NQTB) was formed during Early Paleozoic orogeny, thus serving as a key area for investigating the Early Paleozoic evolution of the QOB. Early Paleozoic magmatism in the NQTB was extremely intense and can be roughly divided into three episodes: 507&#x2013;470 Ma, 460&#x2013;422 Ma, and 415&#x2013;400 Ma. For a long time, this magmatism has long been regarded as Andean-type arc magmatism, which formed in response to the long-lived northward subduction of the Shangdan Ocean (branch of the Proto-Tethys ocean between the North China and South China Blocks) beneath the North Qinling Terrane (NQT) (<xref ref-type="bibr" rid="B27">Dong et al., 2011b</xref>; <xref ref-type="bibr" rid="B25">Dong and Santosh, 2016</xref> and references therein). However, since the discovery of UHP metamorphism at ca. 500 Ma in the NQTB, the genesis of the Early Paleozoic magmatism and tectonic evolution of the NQTB have been the subject of intense debate. Given that the UHP eclogites in the NQTB have similar protolith ages (<xref ref-type="bibr" rid="B87">Wang et al., 2011</xref>; <xref ref-type="bibr" rid="B12">Chen et al., 2012</xref>; <xref ref-type="bibr" rid="B15">2015</xref>; <xref ref-type="bibr" rid="B60">Liu et al., 2013</xref>; <xref ref-type="bibr" rid="B91">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B33">Gong, 2017</xref>) and geochemical signatures (<xref ref-type="bibr" rid="B88">Wang et al., 2013</xref>; <xref ref-type="bibr" rid="B61">Liu et al., 2016</xref>) with Neoproterozoic basaltic rocks in the South Qinling. <xref ref-type="bibr" rid="B95">Wu and Zheng (2013)</xref> proposed that the NQT, a continental sliver rifted from the South Qinling, subducted beneath the Erlangping arc terrane at ca.500 Ma, leading to the formation of the UHP metamorphic rocks. Subsequent subduction of the Shangdan Ocean beneath the exhumed NQT and followed arc-continent collision gave rise to granulite-facies metamorphism and extensive magmatism (450&#x2013;420 Ma) in the NQTB. In contrast, <xref ref-type="bibr" rid="B61">Liu et al. (2016)</xref> argued that UHP metamorphism resulted from deep subduction of South Qinling continental crust after the closure of the Shangdan Ocean at ca. 500 Ma and the ca. 470&#x2013;420 Ma metamorphism and magmatism were related to the exhumation and anatexis of the deep subducted continental crust. Recently, based on a detailed study on granulites with &#x201c;red-eye socket&#x201d; textures, <xref ref-type="bibr" rid="B5">Bai et al. (2025)</xref> proposed that the UHP rocks in the NQTB exhumed to crust level rapidly after the 500 Ma peak metamorphism and later overprinted by two granulite-facies events (465&#x2013;455 Ma and 423 Ma) relating to the subduction and final closure of the Shangdan Ocean, respectively.</p>
<p>The second episode of Early Paleozoic magmatism (460&#x2013;422 Ma) is the most extensively developed in the NQTB (<xref ref-type="bibr" rid="B86">Wang et al., 2009</xref>; <xref ref-type="bibr" rid="B90">Wang et al., 2015</xref>). Its genesis and link to regional metamorphism are crucial for addressing the debates outlined above. As the largest pluton among the second episode magmatic rocks, the Huichizi granite was formed at approximately 440&#x2013;420 Ma (<xref ref-type="bibr" rid="B49">Li et al., 2001</xref>; <xref ref-type="bibr" rid="B72">Qin et al., 2015</xref>; <xref ref-type="bibr" rid="B16">Chen et al., 2018</xref>; <xref ref-type="bibr" rid="B18">Chen et al., 2024</xref>). Currently, multiple interpretations regarding its petrogenesis have been proposed. Most scholars attribute its formation to partial melting of thickened juvenile mafic lower crust, either during subduction of the Shangdan Ocean (<xref ref-type="bibr" rid="B49">Li et al., 2001</xref>; <xref ref-type="bibr" rid="B72">Qin et al., 2015</xref>; <xref ref-type="bibr" rid="B18">Chen et al., 2024</xref>) or post-collisional setting after the ocean&#x2019;s closure (<xref ref-type="bibr" rid="B86">Wang et al., 2009</xref>; <xref ref-type="bibr" rid="B16">Chen et al., 2018</xref>). In contrast, some scholars suggest that it originated from partial melting of the UHP metamorphic rocks during their exhumation (<xref ref-type="bibr" rid="B61">Liu et al., 2016</xref>; <xref ref-type="bibr" rid="B65">Luo et al., 2018</xref>; <xref ref-type="bibr" rid="B17">Chen et al., 2019</xref>).</p>
<p>In this paper, an integrated petrology, geochemistry and geochronology study was conducted on the Huichizi granite, as well as a newly discovered composite lenticle consisting of amphibolite and felsic gneiss within it. We aim to provide constraints on relationship between magmatism and multiple metamorphism and the tectonic evolution of the NQTB during the Early Paleozoic.</p>
</sec>
<sec id="s2">
<label>2</label>
<title>Geological setting</title>
<p>The QOB is mainly composed of four parts, which are, from north to south, the Southern margin of North China Block (S-NCB), the NQTB, the South Qinling Tectonic Belt (SQTB), and the Northern margin of the South China Block (N-SCB), and records the subduction and collision process of different plates along the Shangdan Suture Zone in the Early Paleozoic and along the Mianlue Suture Zone in the Early Mesozoic (<xref ref-type="bibr" rid="B105">Zhang et al., 2001</xref>). The NQTB, bounded by the Shangdan Fault to the south and the Luonan-Luanchuan Fault to the north, is composed of four tectonic lithologic units, including the Kuangping Complex, the Erlangping Complex, the Qinling Complex, and the Danfeng Complex from north to south (<xref ref-type="fig" rid="F1">Figure 1b</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(a)</bold> Simplified tectonic subdivisions of China. <bold>(b)</bold> Simplified tectonic map of the Qinling Tectonic Belt (modified after <xref ref-type="bibr" rid="B26">Dong et al., 2011a</xref>). <bold>(c)</bold> Geological map of Huichizi pluton in the NQTB and sample locations (modified after <xref ref-type="bibr" rid="B18">Chen et al., 2024</xref>).</p>
</caption>
<graphic xlink:href="feart-14-1774169-g001.tif">
<alt-text content-type="machine-generated">Three-panel geological map comprises (a) Simplified tectonic subdivisions of China, (b) a regional tectonic overview with labeled faults and sutures, and (c) a detailed geological map near Huichizi displaying sample locations, fault lines, and rock units. Legend explains symbols for rock types, faults, and sampling sites.</alt-text>
</graphic>
</fig>
<p>The Kuangping Complex comprises greenschist to lower amphibolite facies metamorphosed metabasalt, terrigenous clastic rocks, and marble. The metabasalts have Mid-Ocean Ridge Basalt (MORB) affinity and protolith ages of 1,445&#x2013;943 Ma (<xref ref-type="bibr" rid="B23">Diwu et al., 2010</xref>; <xref ref-type="bibr" rid="B28">Dong et al., 2014</xref>), while the youngest detrital zircon ages in clastic rocks are 550&#x2013;500 Ma (<xref ref-type="bibr" rid="B24">Diwu et al., 2014</xref>; <xref ref-type="bibr" rid="B112">Zhu et al., 2011</xref>; <xref ref-type="bibr" rid="B77">Shi et al., 2013</xref>; <xref ref-type="bibr" rid="B32">Gao et al., 2015</xref>; <xref ref-type="bibr" rid="B93">Wang et al., 2021</xref>; <xref ref-type="bibr" rid="B82">Tang et al., 2024</xref>). The metamorphic ages of these rocks are constrained at 440&#x2013;400 Ma (<xref ref-type="bibr" rid="B103">Zhai et al., 1998</xref>; <xref ref-type="bibr" rid="B82">Tang et al., 2024</xref>).</p>
<p>The Erlangping Complex is mainly composed of upper greenschist to amphibolite-facies metavolcanic and clastic rocks (<xref ref-type="bibr" rid="B58">Liu et al., 1993</xref>; <xref ref-type="bibr" rid="B48">Li et al., 1998</xref>). The metavolcanics show the geochemical characteristics of back-arc basin-type ophiolites, with formation ages ranging from 475 to 463 Ma (<xref ref-type="bibr" rid="B26">Dong et al., 2011a</xref>; <xref ref-type="bibr" rid="B109">Zhao et al., 2012</xref>). The youngest detrital zircon ages of ca. 500 Ma for the clasticrocks (<xref ref-type="bibr" rid="B100">Yang et al., 2016</xref>).</p>
<p>The Qinling Complex is the oldest unit in the NQTB, characterized by the most extensive metamorphism, deformation and magmatic activity. It is mainly composed of felsic gneiss, schist, marble, and minor amphibolite that occurs as lenses, layers, or dikes within gneiss. The amphibolites exhibit geochemical characteristics of Within-Plate Basalt (WPB), with protolith ages of ca. 800 Ma (<xref ref-type="bibr" rid="B87">Wang et al., 2011</xref>; <xref ref-type="bibr" rid="B60">Liu et al., 2013</xref>; <xref ref-type="bibr" rid="B11">Chen and Liu, 2011</xref>; <xref ref-type="bibr" rid="B15">Chen et al., 2015</xref>; <xref ref-type="bibr" rid="B91">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B33">Gong, 2017</xref>). The protoliths of the felsic gneisses are terrigenous clastic rocks, deposited during the Meso-to Neoproterozoic (<xref ref-type="bibr" rid="B63">Lu et al., 2006</xref>). The Qinling Complex was early interpreted as an arc terrane related to the northward subduction of the Shangdan Ocean, which underwent regional amphibolite-facies but locally granulite-to eclogite-facies metamorphism (<xref ref-type="bibr" rid="B105">Zhang et al., 2001</xref> and references therein; <xref ref-type="bibr" rid="B27">Dong et al., 2011b</xref>). Over the past 2 decades, various high-pressure (HP)-UHP metamorphic rocks have been discovered in the Qinling Complex in the Guanpo, Qingyouhe, and Danfeng areas. Zircon U-Pb dating reveals that the peak HP-UHP metamorphism occurred at ca.500&#x2013;490 Ma, followed by granulite-facies and amphibolite-facies metamorphism and anatexis at ca. 470&#x2013;450 Ma and 420&#x2013;400 Ma, respectively (<xref ref-type="bibr" rid="B60">Liu et al., 2013</xref>; <xref ref-type="bibr" rid="B56">Liao et al., 2016</xref>; <xref ref-type="bibr" rid="B61">Liu et al., 2016</xref>; <xref ref-type="bibr" rid="B65">Luo et al., 2018</xref>).</p>
<p>The Danfeng Complex is primarily composed of greenschist to lower amphibolite-facies meta-ophiolites, subduction-related volcanic rocks, and sedimentary rocks (<xref ref-type="bibr" rid="B105">Zhang et al., 2001</xref>). The metabasic rocks exhibit geochemical characteristics of Normal Mid-Ocean Ridge Basalt (N-MORB), Enriched Mid-Ocean Ridge Basalt (E-MORB), and Island Arc Basalt (IAB), and formed at ca.534&#x2013;420 Ma (<xref ref-type="bibr" rid="B26">Dong et al., 2011a</xref>; <xref ref-type="bibr" rid="B52">Li et al., 2015</xref>).</p>
</sec>
<sec id="s3">
<label>3</label>
<title>Field occurrence and petrography</title>
<p>As the largest I-type granite pluton in the NQTB, the Huichizi granite has an outcrop area of 340 km<sup>2</sup> (<xref ref-type="bibr" rid="B49">Li et al., 2001</xref>). Our samples were collected from its southern segment (<xref ref-type="fig" rid="F1">Figure 1c</xref>). Intense ductile deformation of the granite is clear in the outcrop, with well-developed gneissic foliation that is consistent with regional structure (<xref ref-type="fig" rid="F2">Figure 2b</xref>). A composite lenticle (3 m &#xd7; 1 m in size) was identified within the granite. In this lenticle, amphibolite is enveloped by felsic gneiss, with leucosome developed inside the amphibolite (<xref ref-type="fig" rid="F2">Figure 2a</xref>). In this study, the Huichizi granite as well as amphibolite, felsic gneiss, and leucosome in the composite lenticle are systematically collected.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Field occurrence <bold>(a,b)</bold> and microphotographs <bold>(c&#x2013;f)</bold> of the Huichizi biotite monzogranite and the hosted composite lenticle <bold>(b)</bold> was taken approximately 500 m north of <bold>(a)</bold>. Mineral abbreviations: Q, quartz; Bt, biotite; Kfs, K-feldspar; Amp, amphibole; Pl, plagioclase; Ttn, titanite; Ilm, ilmenite.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g002.tif">
<alt-text content-type="machine-generated">Field photograph and micrographs illustrating rock relationships and mineral compositions in a geological outcrop. Panel a shows biotite monzogranite, felsic gneiss, amphibolite, and leucosome exposures with labeled contact zones. Panel b displays deformed granite with visible flow banding. Panels c-f present thin section micrographs of biotite monzogranite, leucosome, felsic gneiss, and another biotite monzogranite, highlighting minerals such as quartz, plagioclase, biotite, K-feldspar, ilmenite, and amphibole, each labeled with mineral abbreviations and scale bars for reference.</alt-text>
</graphic>
</fig>
<p>The Huichizi biotite monzogranite (22QYH-9) is greyish-white in color, with a granitic texture and weak gneissic structure. It is composed of plagioclase (35%&#x2013;40%), quartz (25%&#x2013;35%), K-feldspar (20%&#x2013;25%), biotite (&#x223c;5%), and minor amounts of apatite and zircon (<xref ref-type="fig" rid="F2">Figure 2f</xref>).</p>
<p>The amphibolite (22QYH-6) in the composite lenticle is dark green in color, and shows a granoblastic texture and gneissic structure. It is composed of amphibole (55%&#x2013;60%), plagioclase (25%&#x2013;30%), quartz (5%&#x2013;10%), and minor amounts of ilmenite and titanite (<xref ref-type="fig" rid="F2">Figure 2c</xref>).</p>
<p>The leucosome within the amphibolite (22QYH-7) is white in color and exhibits medium-to fine-grained, subhedral to anhedral granular texture, with a massive structure. It consists of plagioclase (65%&#x2013;70%), quartz (25%&#x2013;30%), and minor amounts of zircon and apatite (<xref ref-type="fig" rid="F2">Figure 2d</xref>).</p>
<p>The felsic gneiss (22QYH-8) is greyish-white in color and displays lepidoblastic texture and gneissic structure. It is mainly composed of plagioclase (45%&#x2013;50%), quartz (30%&#x2013;35%), K-feldspar (10%&#x2013;15%), biotite (5%&#x2013;10%), and minor amounts of ilmenite (<xref ref-type="fig" rid="F2">Figure 2e</xref>).</p>
</sec>
<sec id="s4">
<label>4</label>
<title>Analytical methods</title>
<p>Except for whole-rock Sr-Nd isotope analysis, which was conducted at Wuhan Sample Solution Analytical Technology Co., Ltd, other analyses were performed at the State Key Laboratory of Continental Evolution and Early Life, Northwest University, Xi&#x2019;an.</p>
<sec id="s4-1">
<label>4.1</label>
<title>Whole-rock major and trace element analyses</title>
<p>Whole-rock major elements were analyzed by using a RIKEN RIX2000 spectrometer with Li-borate glass discs. BCR-2 and GBW07105 were used as external standards, and analytical precision was better than 2%. Trace elements were determined by using an Agilent 7500a inductively coupled plasma mass spectrometry (ICP-MS). Blanks, duplicate samples, and international reference materials (BHVO-2, AGV-2, BCR-2, GSP-2) were routinely analyzed for quality control, and precision generally better than 5%. The results are listed in <xref ref-type="sec" rid="s14">Supplementary Table S1</xref>.</p>
</sec>
<sec id="s4-2">
<label>4.2</label>
<title>LA-ICP-MS zircon U-Pb analyses</title>
<p>Zircon U-Pb dating and trace elements analyses were performed using an Agilent 7500a ICP-MS coupled with a 193 nm ArF laser ablation system. The laser spot is 24 &#x3bc;m or 32 &#x3bc;m in diameter. Zircon 91,500 was used as an external age standard and GJ-1 as an unknown sample to monitor data quality. NIST 610 was used as an external reference material and <sup>29</sup>Si as an internal standard to calibrate trace element concentrations. Raw data reduction was performed using the Glitter (Ver 4.0) program, and concordia diagrams were made using the Isoplot (ver. 4.15; <xref ref-type="bibr" rid="B64">Ludwig, 2012</xref>). Detailed results for the zircon U-Pb dating are presented in <xref ref-type="sec" rid="s14">Supplementary Table S2</xref>, and the zircon trace element data are provided in <xref ref-type="sec" rid="s14">Supplementary Table S3</xref>.</p>
</sec>
<sec id="s4-3">
<label>4.3</label>
<title>Zircon Hf isotope analyses</title>
<p>Zircon Lu-Hf isotope analysis was performed using a Nu Plasma II multi-collector ICP-MS coupled with a 193 nm ArF excimer laser ablation. Zircon GJ-1 and Mud Tank were used as quality control monitors. Detailed analytical methods and instrument parameters are described in <xref ref-type="bibr" rid="B101">Yuan et al. (2008)</xref> and <xref ref-type="bibr" rid="B6">Bao et al. (2023)</xref>. The recommended <sup>176</sup>Lu/<sup>175</sup>Lu ratio of 0.02669 and <sup>176</sup>Yb/<sup>172</sup>Yb ratio of 0.5886 were used to correct <sup>176</sup>Lu and <sup>176</sup>Yb isobaric interferences, respectively (<xref ref-type="bibr" rid="B20">Chu et al., 2002</xref>). Standard zircons 91,500 and GJ-1 were used to monitor the instrument condition. A decay constant for <sup>176</sup>Lu of 1.867 &#xd7; 10<sup>&#x2212;11</sup>yr<sup>&#x2212;1</sup> (<xref ref-type="bibr" rid="B1">Albar&#xe8;de et al., 2006</xref>), and present-day chondritic ratios of <sup>176</sup>Hf/<sup>177</sup>Hf &#x3d; 0.282772 and <sup>176</sup>Lu/<sup>177</sup>Hf &#x3d; 0.0332 (<xref ref-type="bibr" rid="B8">Blichert-Toft and Albarede, 1997</xref>) were adopted to calculate &#x3b5;<sub>Hf</sub>(t) values. For the calculation of single-stage Hf model ages (T<sub>DM1</sub>), the present-day <sup>176</sup>Hf/<sup>177</sup>Hf ratio of 0.28325 and <sup>176</sup>Lu/<sup>177</sup>Hf of 0.0384 of the depleted mantle (<xref ref-type="bibr" rid="B36">Griffin et al., 2000</xref>) were utilized. Two-stage Hf model ages (T<sub>DM2</sub>) were calculated by adopting the average composition of the continental crust, with a mean <sup>176</sup>Lu/<sup>177</sup>Hf value of 0.015 as <xref ref-type="bibr" rid="B37">Griffin et al. (2002)</xref>. The results are presented in <xref ref-type="sec" rid="s14">Supplementary Table S4</xref>.</p>
</sec>
<sec id="s4-4">
<label>4.4</label>
<title>Whole-rock Sr-Nd isotope analyses</title>
<p>Whole-rock Sr-Nd isotope analysis was performed using the MC-ICP-MS (Neptune Plus) from Thermo Fisher Scientific, Germany. Detailed analytical procedures are described in <xref ref-type="bibr" rid="B46">Li C. F. et al. (2012)</xref>. Standard NBS SRM 987 (<sup>87</sup>Sr/<sup>86</sup>Sr &#x3d; 0.71025) and Shin Etsu JNdi-1 (<sup>143</sup>Nd/<sup>144</sup>Nd &#x3d; 0.512115) for calibration. The present-day chondritic uniform reservoir (CHUR) ratios of (<sup>143</sup>Nd/<sup>144</sup>Nd)<sub>CHUR</sub> &#x3d; 0.512638 and (<sup>147</sup>Sm/<sup>144</sup>Nd)<sub>CHUR</sub> &#x3d; 0.1967 (<xref ref-type="bibr" rid="B44">Jacobsen and Wasserburg, 1980</xref>) were adopted to calculate &#x3b5;<sub>Nd</sub>(t) values. Single-stage Nd model ages (T<sub>DM</sub>) were calculated with the depleted mantle (DM) evolution model, adopting the present-day values of (<sup>143</sup>Nd/<sup>144</sup>Nd)<sub>DM</sub> &#x3d; 0.51315 and (<sup>147</sup>Sm/<sup>144</sup>Nd)<sub>DM</sub> &#x3d; 0.2137 (<xref ref-type="bibr" rid="B22">DePaolo, 1981</xref>). Analytical results are presented in <xref ref-type="sec" rid="s14">Supplementary Table S5</xref>.</p>
</sec>
</sec>
<sec sec-type="results" id="s5">
<label>5</label>
<title>Results</title>
<sec id="s5-1">
<label>5.1</label>
<title>Whole-rock major and trace element compositions</title>
<p>The Huichizi biotite monzogranite samples have high SiO<sub>2</sub> (68.7&#x2013;72.0 wt%), Al<sub>2</sub>O<sub>3</sub> (15.1&#x2013;16.8 wt%) and Na<sub>2</sub>O (4.64&#x2013;5.29 wt%), but low K<sub>2</sub>O (1.73&#x2013;2.76 wt%) and MgO (0.58&#x2013;0.86 wt%) and TiO<sub>2</sub> (0.25&#x2013;0.33 wt%) contents. They are weakly peraluminous (A/CNK &#x3d; 1.02&#x2013;1.07) and belong to calc-alkaline series with high alkali (Na<sub>2</sub>O&#x2b; K<sub>2</sub>O) content (6.62&#x2013;7.61 wt%) and medium K<sub>2</sub>O/Na<sub>2</sub>O ratio (0.35&#x2013;0.57). They plot in the tonalite field on the An&#x2013;Ab&#x2013;Or diagram and I-type granite field on Na<sub>2</sub>O&#x2013;K<sub>2</sub>O diagram (<xref ref-type="fig" rid="F3">Figures 3a,c</xref>). The granite is relatively enriched in light rare earth elements (LREE) and depleted in heavy rare earth elements (HREE), and displays LREE enrichment patterns (La<sub>N</sub>/Yb<sub>N</sub> &#x3d; 29.1&#x2013;66.0) without obvious Eu anomalies (&#x3b4;Eu &#x3d; 0.90&#x2013;1.17, <xref ref-type="fig" rid="F4">Figure 4a</xref>). On the primitive mantle-normalized spider diagram (<xref ref-type="fig" rid="F4">Figure 4b</xref>), the granite is rich in large-ion lithophile elements (LILE, Rb, Ba, Sr, K, Pb), but depleted in high-field-strength elements (HFSE, Nb, Ta, Ti). Additionally, the granite has high Sr (391&#x2013;741 ppm), but low Y (3.99&#x2013;6.87 ppm) and Yb (0.29&#x2013;0.52 ppm) contents, resulting in high Sr/Y (60.6&#x2013;173) and La/Yb (40.5&#x2013;91.9) ratios.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Discrimination diagrams for the Huichizi biotite monzogranite. <bold>(a)</bold> An-Qb-Or normative diagram (<xref ref-type="bibr" rid="B7">Barker, 1979</xref>); <bold>(b)</bold> K<sub>2</sub>O vs. Si<sub>2</sub>O diagram (<xref ref-type="bibr" rid="B74">Rickwood, 1989</xref>); <bold>(c)</bold> Na<sub>2</sub>O vs. K<sub>2</sub>O diagram (<xref ref-type="bibr" rid="B73">Qiu and Lin, 1991</xref>).</p>
</caption>
<graphic xlink:href="feart-14-1774169-g003.tif">
<alt-text content-type="machine-generated">Panel (a) contains a ternary diagram showing red squares clustered in the trondhjemite field, among tonalite, granite, and quartz-monzonite fields. Panel (b) is a K2O versus SiO2 scatter plot with red squares located within the high-K calc-alkaline and calc-alkaline series. Panel (c) is a Na2O versus K2O scatter plot with red squares grouped in the I-type field, away from the A-type and S-type fields.</alt-text>
</graphic>
</fig>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Chondrite-normalized REE diagrams and primitive mantle-normalized spidergrams for the Huichizi biotite monzogranite <bold>(a,b)</bold>, and amphibolite <bold>(c,d)</bold>. OIB: Oceanic Island Basalt; N-MORB: Normal Mid-Ocean Ridge Basalt; E-MORB: Enriched Mid-Ocean Ridge Basalt. The Chondrite, primitive mantle, OIB, N-MORB and E-MORB values are from <xref ref-type="bibr" rid="B79">Sun and McDonough (1989)</xref>. Data of (retrograde) eclogites in the NQTB are from <xref ref-type="bibr" rid="B11">Chen and Liu (2011)</xref>, <xref ref-type="bibr" rid="B88">Wang et al. (2013)</xref>, <xref ref-type="bibr" rid="B84">Wang (2015)</xref>, and <xref ref-type="bibr" rid="B33">Gong (2017)</xref>.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g004.tif">
<alt-text content-type="machine-generated">Four-panel scientific figure with line graphs. Panel (a) shows rare earth element patterns normalized to chondrite, panel (b) displays trace elements normalized to the primitive mantle, both with red lines representing sample data. Panel (c) compares amphibolite lenticle samples (red lines) and North Qinling HP-UHP eclogites (gray lines) with OIB, E-MORB, and N-MORB reference curves, rock/chondrite normalized. Panel (d) presents multi-element patterns with the same reference curves, rock/primitive mantle normalized. Axes use logarithmic scales and element abbreviations.</alt-text>
</graphic>
</fig>
<p>The amphibolite samples have low SiO<sub>2</sub> (47.8&#x2013;49.1 wt%), Na<sub>2</sub>O (1.27&#x2013;1.43 wt%), K<sub>2</sub>O (1.16&#x2013;1.27 wt%), P<sub>2</sub>O<sub>5</sub> (0.15&#x2013;0.22 wt%) but high MgO (6.46&#x2013;6.72 wt%), Fe<sub>2</sub>O<sub>3</sub>&#x1d40; (14.9&#x2013;16.0 wt%), and TiO<sub>2</sub> (2.40&#x2013;2.72 wt%) concentrations, with Mg&#x23; values of 44&#x2013;46 and K<sub>2</sub>O/Na<sub>2</sub>O ratios of 0.81&#x2013;0.94. They display slightly right-slopping REE patterns (La<sub>N</sub>/Yb<sub>N</sub> &#x3d; 1.96&#x2013;2.51) without obvious Eu anomalies (&#x3b4;Eu &#x3d; 0.95&#x2013;1.06) (<xref ref-type="fig" rid="F4">Figure 4c</xref>). On the primitive mantle-normalized spider diagram, they are relatively rich in Rb, K, U, Ti, and Pb, but depleted in Ba, Th, Sr, Nb, and Ta (<xref ref-type="fig" rid="F4">Figure 4d</xref>), all fall in the fields of Enriched E-MORB and WPB on different trace element discrimination diagrams (<xref ref-type="fig" rid="F5">Figure 5</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Tectonic discrimination diagrams for amphibolite in the composite lenticle. <bold>(a)</bold> Zr/Y vs. Zr diagram (<xref ref-type="bibr" rid="B68">Pearce, 1982</xref>). <bold>(b)</bold> Th/Yb vs. Ta/Yb diagram (<xref ref-type="bibr" rid="B68">Pearce, 1982</xref>). <bold>(c)</bold> Hf/3-Th-Ta diagram (<xref ref-type="bibr" rid="B94">Wood, 1980</xref>). WPB: Within-Plate Basalt; MORB: Mid-Ocean Ridge Basalt; IAB: Island Arc Basalt; SHO: Shoshonite; ICA: Island Calc-Alkaline; OAB: Oceanic Arc Basalt; CAB: Calc-Alkaline Basalt; IAT: Island Arc Tholeiite; ALK: Alkaline; TR: Transitional; TH: Tholeiitic; WPT: Within-Plate Tholeiite; WPAB: Within-Plate Alkaline Basalt; N-MORB: Normal Mid-Ocean Ridge Basalt; E-MORB: Enriched Mid-Ocean Ridge Basalt. Data for HP-UHP eclogites in the North Qinling are from <xref ref-type="bibr" rid="B11">Chen and Liu (2011)</xref>, <xref ref-type="bibr" rid="B88">Wang et al. (2013)</xref>, <xref ref-type="bibr" rid="B84">Wang (2015)</xref>, and <xref ref-type="bibr" rid="B33">Gong (2017)</xref>.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g005.tif">
<alt-text content-type="machine-generated">Three geochemical discrimination diagrams compare amphibolite lenticle samples from this study (red diamonds) and North Qinling HP-UHP eclogites from literature (white diamonds), with field boundaries for tectonic settings labeled IAB, MORB, WPB, OAB, CAB, IAT, and others. Panel (a) is a Zr/Y versus Zr plot with logarithmic axes and setting fields. Panel (b) displays Th/Yb versus Ta/Yb with several tectonic setting fields. Panel (c) presents a ternary plot of Th, Ta, and Hf/3, showing distribution within geochemical fields.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s5-2">
<label>5.2</label>
<title>Zircon U-Pb dating</title>
<p>Zircons from the Huichizi biotite monzogranite (22QYH-9) are colorless, prismatic grains of 50&#x2013;200 &#x3bc;m in length and aspect ratios of 2:1 to 3:1. In cathodoluminescence (CL) images, a few zircons are homogeneous, but most grains consist of a light-grey core with clear oscillatory zoning and a dark-grey homogeneous rim that is similar to the homogeneous grains. Some zircons additionally have bright remnants with oscillatory zoning (<xref ref-type="fig" rid="F6">Figure 6j</xref>). Analyses on oscillatory-zoned cores yield <sup>206</sup>Pb/<sup>238</sup>U ages of 435&#x2013;440 Ma (<xref ref-type="sec" rid="s14">Supplementary Table S2</xref>), with a weighted mean <sup>206</sup>Pb/<sup>238</sup>U age of 438 &#xb1; 5 Ma (MSWD &#x3d; 0.042, n &#x3d; 11), interpreted as the formation age of the granite. 10 analyses on zircon rims and homogeneous grains yield a weighted mean age of 401 &#xb1; 5 Ma (MSWD &#x3d; 0.17). These spots all have low Th/U ratios (mostly &#x3c;0.1), supporting a metamorphic/anatectic origin. Analyses on remanent domains yield scattered ages ranging from 805 to 2005 Ma.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Representative CL images <bold>(a,d,g,j)</bold>, concordia diagrams <bold>(b,e,h,k)</bold>, and chondrite-normalized REE patterns <bold>(c,f,i,l)</bold> for zircons from different samples. Colored solid circles on CL images denote U-Pb spots, white dashed circles denote Lu-Hf spots. Chondrite values are from <xref ref-type="bibr" rid="B79">Sun and McDonough (1989)</xref>.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g006.tif">
<alt-text content-type="machine-generated">Multi-panel scientific figure showing analysis of four rock samples labeled 22QYH-6 amphibolite, 22QYH-7 leucosome, 22QYH-8 felsic gneiss, and 22QYH-9 biotitemonzogranite. For each sample, the left panels display annotated microscopic images of mineral grains with age measurements; the middle panels present isotopic concordia diagrams with plotted age data and mean age calculations; the right panels show multi-line geochemical graphs of rare earth element concentrations normalized to chondrite, comparing rock samples across different measured ages. All panels include legends, axis labels, and age color coding.</alt-text>
</graphic>
</fig>
<p>Zircons from the amphibolite (22QYH-6) are colorless and prismatic, with lengths of 100&#x2013;300 &#x3bc;m and aspect ratios of 2:1. Most zircons show core-rim structures in CL images. The cores are grey-black and show mottled or fir-tree structures, whereas the rims are grey-black to grey-white and homogeneous. Some grains additionally have a grey-white, narrow outer rim at the outermost part and inherited domains with oscillatory zoning are also observed in a few grains (<xref ref-type="fig" rid="F6">Figure 6a</xref>). The inherited zircons have high rare earth elements (REE) content (200&#x2013;1,577 ppm; <xref ref-type="sec" rid="s14">Supplementary Table S3</xref>) and Th/U ratios (0.05&#x2013;0.53, mostly &#x3e;0.1). They display heavy REE (HREE)-enriched (Lu<sub>N</sub>/Gd<sub>N</sub> &#x3d; 6.68&#x2013;41.9) REE patterns with remarkable Eu anomalies (&#x3b4;Eu &#x3d; 0.06&#x2013;0.33), similar to typical magmatic zircons (<xref ref-type="fig" rid="F6">Figure 6c</xref>). 19 analyses on inherited zircons yield <sup>206</sup>Pb/<sup>238</sup>U ages of 601&#x2013;855 Ma (<xref ref-type="sec" rid="s14">Supplementary Table S2</xref>) and eight of them form a cluster on the concordia diagram, yielding a weighted mean <sup>206</sup>Pb/<sup>238</sup>U age of 810 &#xb1; 21 Ma (MSWD &#x3d; 2.0, n &#x3d; 8, <xref ref-type="fig" rid="F6">Figure 6b</xref>), representing the protolith age of the amphibolite. In contrast, 34 analyses domains without oscillatory zoning have low Th/U ratios (mostly &#x3c;0.1, except three of 0.16&#x2013;0.19) and display flat HREE patterns (Lu<sub>N</sub>/Gd<sub>N</sub> &#x3d; 1.31&#x2013;12.3) without obvious negative Eu anomalies (&#x3b4;Eu &#x3d; 0.91&#x2013;1.40, <xref ref-type="fig" rid="F6">Figure 6c</xref>), indicating their metamorphic origin. They yield <sup>206</sup>Pb/<sup>238</sup>U ages of 402&#x2013;498 Ma and form three clusters on the concordia diagram (<xref ref-type="fig" rid="F6">Figure 6b</xref>), with weighted mean ages of 492 &#xb1; 8 Ma (MSWD &#x3d; 0.19, n &#x3d; 9), 452 &#xb1; 4 Ma (MSWD &#x3d; 0.36, n &#x3d; 22) and 404 &#xb1; 10 Ma (MSWD &#x3d; 0.054, n &#x3d; 3). The age of 492 Ma comes from grey-black mottled cores and has the lowest &#x3a3;HREE (16.9&#x2013;47.9 ppm). The 452 Ma ages were obtained from grey-black overgrowth rims around older cores or from fir-tree sector-zoned cores, and show higher &#x3a3;HREE (22.1&#x2013;55.0 ppm). The age of 404 Ma is from grey-white rims or separate grey-white grains, its &#x3a3;HREE (37.5&#x2013;56.3 ppm) resembles the 452 Ma group and is slightly higher than the 492 Ma group (<xref ref-type="fig" rid="F6">Figure 6c</xref>).</p>
<p>Zircons from the leucosome (22QYH-7) are colorless, prismatic grains (50&#x2013;150 &#x3bc;m in length; aspect ratios 2:1 to 3:1). They are homogeneous and greyish black in CL images with scarce bright cores (<xref ref-type="fig" rid="F6">Figure 6d</xref>). Analyses on homogeneous grains show that they have extremely high U (1,529&#x2013;4,367 ppm) and REE (738&#x2013;1,341 ppm) contents, but low Th (28.0&#x2013;156 ppm) contents, resulting low Th/U ratios of 0.01&#x2013;0.05. They exhibit HREE-enriched (Lu<sub>N</sub>/Gd<sub>N</sub> &#x3d; 54.4&#x2013;132) REE patterns with obvious negative Eu anomalies (&#x3b4;Eu &#x3d; 0.20&#x2013;0.88, except one shows a positive Eu anomaly, probably contaminated by plagioclase inclusions), similar to typical anatectic zircons (<xref ref-type="bibr" rid="B13">Chen et al., 2013</xref>; <xref ref-type="fig" rid="F6">Figure 6f</xref>). Zircon U-Pb dating yields <sup>206</sup>Pb/<sup>238</sup>U ages of 398&#x2013;408 Ma (<xref ref-type="sec" rid="s14">Supplementary Table S2</xref>), giving a weighted mean <sup>206</sup>Pb/<sup>238</sup>U age of 402 &#xb1; 4 Ma (MSWD &#x3d; 0.12, n &#x3d; 14; <xref ref-type="fig" rid="F6">Figure 6e</xref>), interpreted as the leucosome formation age. Two analyses on bright-luminescent cores show that they have obviously lower U (58.0&#x2013;472 ppm) and Th (7.00&#x2013;298 ppm) contents, but higher Th/U ratios (0.63 and 0.13), and <sup>206</sup>Pb/<sup>238</sup>U ages of 605 Ma and 712 Ma were yielded, indicating an inherited origin.</p>
<p>Zircons from the felsic gneiss (22QYH-8) are colorless and prismatic grains with lengths of 50&#x2013;200 &#x3bc;m. Most of them consist of a grey core with oscillatory zoning and a black homogeneous rim (<xref ref-type="fig" rid="F6">Figure 6g</xref>). The cores have high Th/U ratios (0.09&#x2013;0.69) and exhibit left-slopping REE patterns with remarkable Eu anomalies, typical of magmatic origin. 16 analyses form a cluster on concordia diagram, giving a weighted mean <sup>206</sup>Pb/<sup>238</sup>U age of 866 &#xb1; 8 Ma (MSWD &#x3d; 0.41). The rims have low Th/U ratios of 0.02&#x2013;0.08, indicative of metamorphic origin. 16 analyses on rims form three clusters on concordia diagram (<xref ref-type="fig" rid="F6">Figure 6h</xref>), yielding weighted mean <sup>206</sup>Pb/<sup>238</sup>U ages of 496 &#xb1; 9 Ma (MSWD &#x3d; 0.069, n &#x3d; 5), 452 &#xb1; 8 Ma (MSWD &#x3d; 0.2, n &#x3d; 6), and 400 &#xb1; 7 Ma (MSWD &#x3d; 0.16, n &#x3d; 5), interpreted as three distinct metamorphic events in the felsic gneiss.</p>
</sec>
<sec id="s5-3">
<label>5.3</label>
<title>Zircon Hf isotope composition</title>
<p>Seven analyses were conducted on core domains with clear oscillatory zoning of zircons from the Huichizi granites. They have <sup>176</sup>Lu/<sup>177</sup>Hf ratios of 0.000657&#x2013;0.001416 and <sup>176</sup>Hf/<sup>177</sup>Hf ratios of 0.282340&#x2013;0.28708 (<xref ref-type="sec" rid="s14">Supplementary Table S4</xref>), corresponding to &#x3b5;<sub>Hf</sub>(t) values of (&#x2212;6.01 to &#x2b;7.38, most are positive) and two-stage Hf model ages (T<sub>DM2</sub>) of 949&#x2013;1795 Ma, when calculating at t &#x3d; 438 Ma (<xref ref-type="fig" rid="F7">Figure 7a</xref>).</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Zircon age-&#x3b5;<sub>Hf</sub>(t) diagram <bold>(a)</bold> and whole-rock (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub>-&#x3b5;<sub>Nd</sub>(t) diagram <bold>(b)</bold> for the Huichizi biotite monzogranite. Zircon Hf isotope sources: Huichizi biotite monzogranite&#x2013;<xref ref-type="bibr" rid="B86">Wang et al. (2009)</xref>, <xref ref-type="bibr" rid="B72">Qin et al. (2015)</xref>, <xref ref-type="bibr" rid="B16">Chen et al. (2018)</xref>, <xref ref-type="bibr" rid="B101">Yuan et al. (2008)</xref>; North Qinling HP-UHP eclogites&#x2013;<xref ref-type="bibr" rid="B87">Wang et al. (2011)</xref>, <xref ref-type="bibr" rid="B88">Wang et al. (2013)</xref>, <xref ref-type="bibr" rid="B70">Qian et al. (2013)</xref>, <xref ref-type="bibr" rid="B90">Wang et al. (2015)</xref>. Whole-rock Sr-Nd isotope sources: Huichizi biotite monzogranite&#x2013;<xref ref-type="bibr" rid="B49">Li et al. (2001)</xref>, <xref ref-type="bibr" rid="B57">Liu (2014)</xref>, <xref ref-type="bibr" rid="B72">Qin et al. (2015)</xref>, <xref ref-type="bibr" rid="B16">Chen et al. (2018)</xref>; North Qinling HP-UHP eclogites&#x2013;<xref ref-type="bibr" rid="B88">Wang et al. (2013)</xref>, <xref ref-type="bibr" rid="B90">Wang et al. (2015)</xref>, <xref ref-type="bibr" rid="B33">Gong (2017)</xref>.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g007.tif">
<alt-text content-type="machine-generated">Two scientific scatter plots compare geochemical data of Huichizi biotite monzogranite and North Qinling HP-UHP eclogites. Panel (a) plots &#x3B5;Hf(t) versus Age in million years, showing groupings for depleted mantle and chondrite, with three sample types indicated using red squares, white squares, and diamonds. Panel (b) plots &#x3B5;Nd(t) versus initial strontium isotope ratio (^87Sr/^86Sr), using red squares, white squares, and crosses for different datasets, with a light shaded region outlining most data.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s5-4">
<label>5.4</label>
<title>Whole-rock Sr-Nd isotope composition</title>
<p>Five granite samples were selected for whole-rock Sr&#x2013;Nd isotope analyses. The result shows that this granite is relatively homogeneous and has initial <sup>87</sup>Sr/<sup>86</sup>Sr ratios [(<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub>] of 0.705160&#x2013;0.706258 and &#x3b5;<sub>Nd</sub>(t) values ranging from &#x2b;0.05 to &#x2b;1.13, which correspond to Nd model ages of 953&#x2013;1,020 Ma, when calculating at t &#x3d; 438 Ma (<xref ref-type="fig" rid="F7">Figure 7b</xref>).</p>
</sec>
</sec>
<sec sec-type="discussion" id="s6">
<label>6</label>
<title>Discussion</title>
<sec id="s6-1">
<label>6.1</label>
<title>Genesis of the composite lenticle and their relationship with HP-UHP rocks in the NQTB</title>
<p>As a dating mineral with extremely high stability, zircon can provide reliable genetic constraints on dating results through its internal textures and trace element characteristics, even when the host rock has undergone intense retrogression and the peak-stage mineral assemblages have been completely erased. It has played a critical role in the identification and in-depth study of the UHP metamorphic rocks in the NQTB (<xref ref-type="bibr" rid="B89">Wang et al., 2014</xref>; <xref ref-type="bibr" rid="B34">Gong et al., 2016</xref>; <xref ref-type="bibr" rid="B17">Chen et al., 2019</xref>). In this study, zircon dating yield three metamorphic ages (496&#x2013;492 Ma, ca. 452 Ma, 404&#x2013;400 Ma) for both amphibolite and felsic gneiss in the composite lenticle hosted in Huichizi biotite monzogranite (<xref ref-type="fig" rid="F6">Figures 6b,h</xref>). The first metamorphic age (496&#x2013;492 Ma) is predominantly obtained from the core domains of metamorphic zircons, while the latter two ages (ca.452 Ma and 404&#x2013;400 Ma) are from the two overgrowth rims (<xref ref-type="fig" rid="F6">Figure 6a</xref>). Notably, metamorphic zircon domains from the amphibolite exhibit flat HREE patterns without visible Eu anomalies, typical of eclogite-facies metamorphic zircon (<xref ref-type="bibr" rid="B75">Rubatto, 2002</xref>; <xref ref-type="bibr" rid="B76">2017</xref>). The three metamorphic ages and the corresponding zircon REE patterns from the amphibolite in the composite lenticle are fully consistent with the UHP peak metamorphic age (ca. 500 Ma), the two stages of overprinting metamorphic ages (ca. 470&#x2013;450 Ma and 420&#x2013;400 Ma) of the Qinling Complex in the NQTB, and their corresponding zircon REE signatures (<xref ref-type="bibr" rid="B34">Gong et al., 2016</xref>; <xref ref-type="bibr" rid="B56">Liao et al., 2016</xref>; <xref ref-type="bibr" rid="B91">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B81">Tang et al., 2022</xref>; <xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>). Additionally, considering the following two lines of evidence: (1) the amphibolite and felsic gneiss in the composite lenticle exhibit an occurrence similar to that in Qinling Complex; and (2) the amphibolite in the composite lenticle has a comparable protolith age (810 Ma) and geochemical signatures (WPB affinity) with (retrograde) eclogites in the Qinling Complex, we infer that the rocks in the composite lenticle in the Huichizi biotite monzogranite are retrograde eclogite-facies metamorphic rocks of the Qinling Complex.</p>
<p>Zircon dating yielded a crystallization age of 438 &#xb1; 5 Ma and a metamorphic age of 401 &#xb1; 5 Ma for the Huichizi granite (<xref ref-type="fig" rid="F6">Figure 6j</xref>). This crystallization age is younger than the first two metamorphic ages (ca. 496&#x2013;492 Ma and 452 Ma) of amphibolite and felsic gneiss in the composite lenticle. But the metamorphic age of the granite is consistent within errors with the third metamorphic ages (404 &#xb1; 10 Ma and 400 &#xb1; 7 Ma, respectively) of amphibolite and felsic gneiss and the anatectic ages (402 &#xb1; 4 Ma) recorded by the leucosome within the amphibolite. These results indicate that the composite lenticle was trapped by the Huichizi granite after two episodes of metamorphism at ca. 496&#x2013;492 Ma and 452 Ma; subsequently, both the composite lenticle and the granite underwent metamorphism and anatexis at ca. 400 Ma.</p>
</sec>
<sec id="s6-2">
<label>6.2</label>
<title>Formation mechanism of the huichizi granite</title>
<p>Geochemical data show that the Huichizi granite is an I-type granite (<xref ref-type="fig" rid="F3">Figure 3c</xref>) and exhibits adakitic signatures of high Sr (391&#x2013;741 ppm), low Y (3.99&#x2013;6.87 ppm) and Yb (0.29&#x2013;0.52 ppm) contents and high Sr/Y (60.6&#x2013;173) and La/Yb (40.5&#x2013;91.9) ratios (<xref ref-type="fig" rid="F8">Figure 8</xref>).</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Sr/Y vs. Y <bold>(a)</bold> and (La/Yb)<sub>N</sub> vs. Yb<sub>N</sub> <bold>(b)</bold> diagrams (<xref ref-type="bibr" rid="B21">Defant and Drummond, 1990</xref>).</p>
</caption>
<graphic xlink:href="feart-14-1774169-g008.tif">
<alt-text content-type="machine-generated">Two scientific graphs compare geochemical ratios for rocks: (a) plots Sr/Y versus Y with labeled fields for adakite, eclogite, and island arc magmatic rock; (b) plots (La/Yb)N versus YbN with similar fields. Red squares show sample data clustering within the adakite fields. Dashed lines indicate compositional trends for varying proportions of garnet amphibolite and eclogite.</alt-text>
</graphic>
</fig>
<p>Adakitic rocks generally can form through partial melting of subducted oceanic crust under eclogite-facies conditions (<xref ref-type="bibr" rid="B21">Defant and Drummond, 1990</xref>), partial melting of thickened lower crust (<xref ref-type="bibr" rid="B2">Atherton and Petford, 1993</xref>) or delaminated lower crust (<xref ref-type="bibr" rid="B85">Wang et al., 2006</xref>), assimilation-fractional crystallization (AFC) of basaltic magmas (<xref ref-type="bibr" rid="B10">Castillo et al., 1999</xref>), and crust-mantle magma mixing (<xref ref-type="bibr" rid="B71">Qin et al., 2010</xref>). Neither mafic microgranular enclave, nor disequilibrium textures or microstructural signatures of magma mixing (e.g., acicular apatite) have been observed in the Huichizi granite. And most samples exhibit magmatic evolution characteristics dominated by partial melting in the La/Sm-La and La/Yb-La diagrams (<xref ref-type="fig" rid="F9">Figure 9</xref>). These lines of evidence rule out the genetic mechanisms of crust-mantle magma mixing and AFC of basaltic magmas. In addition, the Huichizi granite has low MgO (0.58&#x2013;0.86 wt%), Cr (4.19&#x2013;12.3 ppm), and Ni (3.83&#x2013;6.84 ppm) contents, and low Mg&#x23; values (41&#x2013;44) (<xref ref-type="fig" rid="F10">Figure 10</xref>). These geochemical features indicate that the granitic magma did not undergo material exchange with mantle, thereby ruling out its formation via partial melting of a subducted slab or delaminated lower crust. Therefore, the Huichizi granite is more likely derived from partial melting of thickened lower continental crust.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>La/Sm vs. La <bold>(a)</bold> and La/Yb vs. La <bold>(b)</bold> diagrams for the Huichizi biotite monzogranite.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g009.tif">
<alt-text content-type="machine-generated">Two scientific scatter plots compare La/Sm and La/Yb ratios against La concentration, both with labeled trends for partial melting and assimilation-fractional crystallization. Panel a shows La/Sm versus La, panel b shows La/Yb versus La, both using red square data points.</alt-text>
</graphic>
</fig>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Diagrams of <bold>(a)</bold> MgO vs. SiO<sub>2</sub> (<xref ref-type="bibr" rid="B85">Wang et al., 2006</xref>). <bold>(b)</bold> Cr vs. SiO<sub>2</sub> (<xref ref-type="bibr" rid="B85">Wang et al., 2006</xref>). <bold>(c)</bold> Ni vs. SiO<sub>2</sub>(<xref ref-type="bibr" rid="B43">Huang et al., 2009</xref>). <bold>(d)</bold> Mg&#x23; vs. SiO<sub>2</sub> (<xref ref-type="bibr" rid="B43">Huang et al., 2009</xref>) for the Huichizi biotite monzogranite.</p>
</caption>
<graphic xlink:href="feart-14-1774169-g010.tif">
<alt-text content-type="machine-generated">Four geochemical scatter plots labeled a to d compare SiO2 content with MgO (wt%), Cr (ppm), Ni (ppm), and Mg# for adakites from various origins, with fields outlined for different formation scenarios and red squares representing sample data.</alt-text>
</graphic>
</fig>
<p>Experimental studies show that partial melting of both mafic and pelitic rocks under high-pressure conditions (&#x3e;1.0 GPa, <xref ref-type="bibr" rid="B67">Moyen, 2009</xref>) can form adakitic rocks. However, the low K<sub>2</sub>O/Na<sub>2</sub>O (0.35&#x2013;0.57) and Rb/Sr (0.07&#x2013;0.23) ratios of the Huichizi granite clearly differ from melts derived from metapelite (<xref ref-type="bibr" rid="B39">Harris and Inger, 1992</xref>; <xref ref-type="bibr" rid="B102">Zeng et al., 2011</xref>), indicating a metabasalt partial melting origin. The Huichizi granite is characterized by high Sr, low Y and Yb contents, significant depletion in HREE, Nb, Ta and Ti, with negligible Eu anomalies (<xref ref-type="fig" rid="F5">Figures 5a,b</xref>). These features indicate the source residue contains garnet and rutile but almost no plagioclase, suggesting that the Huichizi granite was derived from partial melting of either thickened mafic lower crust (&#x3e;1.5 GPa, &#x3e;50 km, constrained by rutile stability field; <xref ref-type="bibr" rid="B97">Xiong et al., 2005</xref>) or eclogite (<xref ref-type="fig" rid="F8">Figures 8</xref>, <xref ref-type="fig" rid="F10">10a</xref>).</p>
<p>Although the Huichizi granite hosts retrograde eclogite (represented by amphibolite in the composite lenticle), and it has similar zircon Hf and whole-rock Sr-Nd isotopic compositions to those of the HP-UHP eclogites in the NQTB (<xref ref-type="fig" rid="F7">Figure 7</xref>), the following lines of evidence suggest that the Huichizi granite was not formed by decompressional melting of HP-UHP rocks in the NQTB during their exhumation. First, extensive studies demonstrated that decompression melting of deeply subducted crust generally occurs nearly synchronously or within 20&#x2013;30 Ma after UHP metamorphism, generating tonalites and peraluminous granites with negligible mantle input (<xref ref-type="bibr" rid="B78">Song et al., 2015</xref>). In the NQTB, only the Piaochi S-type granite is consistent with syn-collisional magmatism formed either synchronously with UHP metamorphism or during the exhumation, in terms of both formation age (473 Ma; <xref ref-type="bibr" rid="B72">Qin et al., 2014</xref>) and geochemical characteristics. However, the Huichizi granite (440&#x2013;420 Ma) formed at least 50 Ma later than the UHP metamorphism. Second, the Huichizi granite is the largest granite pluton (&#x3e;300 km<sup>2</sup> area) in the NQTB and its formation requires a huge volume of mafic rocks, however, the HP-UHP rocks in the NQTB are mainly felsic rocks with only a low proportion of amphibolites/eclogites. Third, the leucosomes and granite veins formed by decompression melting of HP-UHP rocks in the NQTB are potassium-rich and sodium-poor, with negative zircon &#x3b5;<sub>Hf</sub>(t) values (<xref ref-type="bibr" rid="B65">Luo et al., 2018</xref>). In contrast, the Huizhizi granite has high Na<sub>2</sub>O/K<sub>2</sub>O ratios and mainly positive &#x3b5;<sub>Hf</sub>(t) values. Therefore, the Huichizi granite should be derived from partial melting of Neoproterozoic mafic volcanic rocks, which were accumulated beneath the North Qinling terrane (<xref ref-type="bibr" rid="B72">Qin et al., 2015</xref>) and similar to protolith of the UHP eclogites (<xref ref-type="fig" rid="F7">Figure 7</xref>).</p>
<p>The granulite-facies metamorphism in Qinling Complex is synchronous with the second episode of granitic magmatism (440&#x2013;420 Ma) in the NQTB. However, its metamorphic conditions (700 &#xb0;C&#x2013;850 &#xb0;C and 0.8&#x2013;1.2 GPa; <xref ref-type="bibr" rid="B106">Zhang et al., 2011</xref>; <xref ref-type="bibr" rid="B96">Xiang et al., 2012</xref>; <xref ref-type="bibr" rid="B61">Liu et al., 2016</xref>; <xref ref-type="bibr" rid="B55">Liao, 2018</xref>; <xref ref-type="bibr" rid="B104">Zhai et al., 2019</xref>; <xref ref-type="bibr" rid="B53">Li et al., 2023</xref>; <xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>) are significantly lower than the P-T conditions required for the generation of adakites via partial melting of mafic rocks (800 &#xb0;C&#x2013;1,000 &#xb0;C and 1.2&#x2013;3.0 GPa; <xref ref-type="bibr" rid="B92">Wang et al., 2020</xref>). Furthermore, the presence of numerous anatectic leucosomes with formation ages of 490&#x2013;470Ma (<xref ref-type="bibr" rid="B19">Cheng et al., 2011</xref>; <xref ref-type="bibr" rid="B40">He et al., 2018</xref>; <xref ref-type="bibr" rid="B41">2023</xref>) and eclogites with amphibolite-facies retrograde ages of 485&#x2013;475Ma (<xref ref-type="bibr" rid="B87">Wang et al., 2011</xref>; <xref ref-type="bibr" rid="B95">Wu and Zheng, 2013</xref>; <xref ref-type="bibr" rid="B51">Li et al., 2014</xref>; <xref ref-type="bibr" rid="B42">Hu et al., 2020</xref>) in the Qinling Complexindicates that the North Qinling UHP Terrane experienced rapid exhumation after peak metamorphism (<xref ref-type="bibr" rid="B87">Wang et al., 2011</xref>; <xref ref-type="bibr" rid="B54">Li Y et al., 2012</xref>; <xref ref-type="bibr" rid="B51">2014</xref>; <xref ref-type="bibr" rid="B3">Bader et al., 2013</xref>; <xref ref-type="bibr" rid="B95">Wu and Zheng, 2013</xref>; <xref ref-type="bibr" rid="B40">He et al., 2018</xref>; <xref ref-type="bibr" rid="B41">2023</xref>; <xref ref-type="bibr" rid="B42">Hu et al., 2020</xref>; <xref ref-type="bibr" rid="B29">Dong et al., 2022</xref>; <xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>), and reached the middle-shallow crust (<xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>) by at least ca.470 Ma. This depth is significantly shallower than the melting depth of the source region of Huichizi granite (&#x3e;1.5 GPa, &#x3e;50 km). Therefore, the composite lenticle hosted in the granite should be captured by the ascending magma after eclogite-facies metamorphism at ca. 500 Ma and granulite-facies metamorphism at ca. 450 Ma. This is also consistent with the phenomenon that the first two metamorphic ages recorded by the composite lenticle predate the formation age of the Huichizi granite (438 Ma). All these lines of evidence indicate that the ca. 450 Ma granitic magmatism and granulite-facies metamorphism in the NQTB were likely a tectonic event independent of the earlier (ca. 500 Ma) UHP metamorphism.</p>
<p>Rencently, studies on mafic and felsic granulites with &#x201c;red-eye socket&#x201d; textures in the eastern segment of the NQTB have shown that, after undergoing HP-UHP at ca. 500 Ma, the Qinling Complex experience two episodes of granulite-facies metamorphism at ca. 460&#x2013;448 Ma and ca. 422&#x2013;421 Ma, respectively (<xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>). Based on the recorded prograde metamorphic history by garnet zoning for the first episode granulite-facies metamorphism, as well as the occurrence of amphibole reverse zoning in the Songshugou garnet amphibolites (<xref ref-type="bibr" rid="B46">Li C. F. et al., 2012</xref>; <xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>) argued that the two episodes of granulite-facies metamorphism are not retrograde metamorphic events associated with exhumation of UHP rocks. Instead, they are more likely related to the subduction of the Shangdan Ocean beneath the exhumed NQT and the subsequent collision following the ocean&#x2019;s closure. These findings and understandings, combined with our results, indicate that the widely developed 460&#x2013;420 Ma granulite-facies metamorphism and magmatism in the Qinling Complex represent a tectono-magmatic event associated with the subduction and collision of the Shangdan Ocean.</p>
<p>The Huichizi granite is enriched in LILE (Rb, Ba, Sr, K, and Pb) and depleted in HFSE (Nb, Ta, and Ti), exhibiting characteristics of arc granites. It has high Th/Ta ratios (8.10&#x2013;31.5), which is similar to igneous rocks formed in active continental margin (Th/Ta &#x3d; 6&#x2013;20; <xref ref-type="bibr" rid="B35">Gorton and Schandl, 2000</xref>) and oceanic island arc settings (Th/Ta &#x3e;20&#x2013;90; <xref ref-type="bibr" rid="B35">Gorton and Schandl, 2000</xref>). Its low Ce/Pb (1.67&#x2013;3.24, 2.23 in average) and Nb/La (0.14&#x2013;0.35, 0.22 in average) ratios are close to the average values of arc magmatic rocks (Ce/Pb &#x3d; 3, Nb/La &#x2264;1; <xref ref-type="bibr" rid="B9">Candies, 1989</xref>). In the tectonic discrimination diagrams, the Huichizi granite plots into the field of volcanic arc granite (<xref ref-type="fig" rid="F11">Figure 11</xref>). Considering the Sifangtai, Lajimiao, and Fushui complexes with arc basalt geochemical signatures emplaced along the Shangdan Suture Zone during ca.500&#x2013;420 Ma (<xref ref-type="bibr" rid="B47">Li et al., 1993</xref>; <xref ref-type="bibr" rid="B59">Liu et al., 2008</xref>; <xref ref-type="bibr" rid="B108">Zhang et al., 2015</xref>), the continuous marine sedimentation from the Cambrian to the Silurian, as well as the unconformity between the Middle Devonian and Silurian strata in the SQTB (<xref ref-type="bibr" rid="B25">Dong and Santosh, 2016</xref>; <xref ref-type="bibr" rid="B45">Jiang et al., 2019</xref>), the Shangdan Ocean did not close until the Early Devonian (<xref ref-type="bibr" rid="B95">Wu and Zheng, 2013</xref>; <xref ref-type="bibr" rid="B25">Dong and Santosh, 2016</xref> and references therein; <xref ref-type="bibr" rid="B5">Bai et al., 2025</xref>). Therefore, the Huichizi granite should have formed during the subduction of the Shangdan Ocean.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Tectonic setting discrimination diagrams for the Huichizi biotite monzogranite (<xref ref-type="bibr" rid="B69">Pearce et al., 1984</xref>).</p>
</caption>
<graphic xlink:href="feart-14-1774169-g011.tif">
<alt-text content-type="machine-generated">Two geochemical discrimination diagrams are shown. Both are scatter plots with Rb in parts per million on the vertical logarithmic axis from one to ten thousand. The left plot has Yb plus Ta in parts per million on the horizontal logarithmic axis, while the right plot has Y plus Nb. Each plot is divided into fields labeled syn-collisional granites, within-plate granites, volcanic arc granites, and ocean ridge granite. Multiple red squares are clustered in the volcanic arc granites field in both diagrams.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s6-3">
<label>6.3</label>
<title>Metamorphism of the huichizi granite and its tectonic significance</title>
<p>A metamorphic age of ca. 400 Ma was obtained from both the Huichizi granite (401 &#xb1; 5 Ma, <xref ref-type="fig" rid="F6">Figure 6k</xref>) and its hosted composite lenticle, including amphibolite (404 &#xb1; 10 Ma, <xref ref-type="fig" rid="F6">Figure 6b</xref>) and felsic gneisses (400 &#xb1; 7 Ma, <xref ref-type="fig" rid="F6">Figure 6h</xref>). A similar anatexis age of 402 &#xb1; 4 Ma was also yielded from leucosomes within the amphibolite. This leucosome, composed predominantly of plagioclase (65%&#x2013;70%) and quartz (25%&#x2013;30%), is restricted to the interior of the amphibolite, which rules out the possibility of melt injection from the surrounding felsic gneisses or granites. These results demonstrate that the Huichizi granite and the composite lenticle underwent a metamorphism and anatexis event at ca. 400 Ma together. This metamorphism is also observed in the Liangchahe granitic gneiss (<xref ref-type="bibr" rid="B4">Bai, 2024</xref>), a small metamorphosed granite located adjacent to the southern side of the Huichizi Granite. Garnet porphyroblasts and garnet megacrysts-bearing leucosome can be observed in the Liangchahe granitic gneiss. Zircon dating yields a protolith age of 441 &#xb1; 11 Ma and a metamorphic age of 402 &#xb1; 5 Ma for the granitic gneiss, as well as a formation age of 401 &#xb1; 5 Ma for the garnet megacryst-bearing leucosome (<xref ref-type="bibr" rid="B4">Bai, 2024</xref>). P-T conditions of the Liangchahe granitic gneiss were constrained to 3.8&#x2013;5.0 kbar and 736 &#xb0;C&#x2013;748 &#xb0;C by phase equilibrium modelling, corresponding to medium-pressure granulite-facies. Ti-in-zircon thermometer (assuming activities of SiO<sub>2</sub> and TiO<sub>2</sub> as one and 0.5, respectively; <xref ref-type="bibr" rid="B31">Ferry and Watson, 2007</xref>) yields formation temperatures of 648 &#xb0;C&#x2013;733 &#xb0;C for metamorphic zircons from the Huichizi granite, and 620 &#xb0;C&#x2013;768 &#xb0;C for the anatectic zircons from the leucosome within amphibolite (<xref ref-type="sec" rid="s14">Supplementary Table S3</xref>). These temperatures are consistent with those of the Liangchahe granitic gneiss. All these results, combined with the intense deformation features (<xref ref-type="fig" rid="F2">Figure 2b</xref>) of the Huichizi granite, indicate that the Huichizi granite indeed experienced a medium-pressure granulite-facies metamorphic-anatectic event at ca. 400 Ma. Notably, the ca. 400 Ma metamorphic and anatectic events recorded in the Paleozoic granitoids of the NQTB are reported here for the first time, whereas such events in the Qinling Complex have been extensively documented in recent years (<xref ref-type="bibr" rid="B30">Faure et al., 2008</xref>; <xref ref-type="bibr" rid="B3">Bader et al., 2013</xref>; <xref ref-type="bibr" rid="B80">Sun et al., 2019</xref>; <xref ref-type="bibr" rid="B110">Zhao et al., 2020</xref>; <xref ref-type="bibr" rid="B38">Guo et al., 2023</xref>; <xref ref-type="bibr" rid="B62">Liu et al., 2024</xref>). For instance, <xref ref-type="bibr" rid="B110">Zhao et al. (2020)</xref> and <xref ref-type="bibr" rid="B62">Liu et al. (2024)</xref> have both identified a medium-pressure high-temperature (MP-HT) granulite-facies metamorphic event at ca.400 Ma (8.5&#x2013;9.7 kbar and 745 &#xb0;C&#x2013;820 &#xb0;C, 409&#x2013;395 Ma, <xref ref-type="bibr" rid="B110">Zhao et al., 2020</xref>; 790 &#xb0;C&#x2013;862 &#xb0;C and 9.9&#x2013;11.9 kbar, 410&#x2013;390 Ma; <xref ref-type="bibr" rid="B62">Liu et al., 2024</xref>) in migmatized felsic gneisses of the Qinling Complex in the Weiziping area, and attributed it to thermal relaxation following crustal thickening. <xref ref-type="bibr" rid="B38">Guo et al. (2023)</xref> reported a garnet amphibolite of the Qinling Complex in Tianshui area, which experienced high-temperature granulite-facies metamorphism (8.4&#x2013;9.9 kbar, 869 &#xb0;C&#x2013;886 &#xb0;C) at ca. 410 Ma related to thinning of thickened orogenic crust. Further considered the presence of 415&#x2013;400Ma undeformed, highly fractionated, K-rich granite (<xref ref-type="bibr" rid="B107">Zhang et al., 2013</xref>; <xref ref-type="bibr" rid="B90">Wang et al., 2015</xref>), and A<sub>2</sub>-type granites in NQTB (<xref ref-type="bibr" rid="B98">Xu et al., 2017</xref>), the tectonic regime in the NQTB switched from collisional compression to extension at ca. 400 Ma.</p>
</sec>
<sec id="s6-4">
<label>6.4</label>
<title>Implications on the early paleozoic evolution of the NQTB</title>
<p>Based on the results of this study and existing research, we summarize the Early Paleozoic tectonic evolution process of the NQTB as follows: The North Qinling Terrane rifted from the northern margin of the Yangtze Block during the breakup of the Rodinia supercontinent and drifted northward. It underwent continental deep subduction and ultrahigh-pressure metamorphism at 500 Ma, followed by rapid exhumation to the middle-shallow crust. Subsequently, continuous northward subduction of the Shangdan Oceanic crust triggered partial melting of Neoproterozoic mafic rocks accumulated beneath the NQT and led to the formation of the Paleozoic granitoids (including Huichizi granite), and also resuted in the contemporaneous granulite-facies metamorphism. The granite trapped a few exhumed retrograde HP-UHP metamorphic rocks of Qinling Complex during magma ascending. At ca. 400 Ma, as the tectonic regime of the NQTB switched from contraction to extension, the Huichizi granite and the composite lenticle, as well as the Qinling Complex experienced medium-pressure granulite-facies metamorphism and anatexis.</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s7">
<label>7</label>
<title>Conclusion</title>
<p>
<list list-type="order">
<list-item>
<p>The Huichizi granite, formed at 438 &#xb1; 5 Ma, was derived from partial melting of a thickened juvenile mafic lower crust during the subduction of the Shangdan Ocean.</p>
</list-item>
<list-item>
<p>The composite lenticle composed of amphibolite and felsic gneiss in the Huichizi granite are retrograded eclogite-facies metamorphic rocks of the Qinling Complex. They were captured by the ascending Huichizi granite after exhumation to the crust level and underwent granulite-facies metamorphism together with the host Huizhici granite at ca. 400 Ma.</p>
</list-item>
<list-item>
<p>The tectonic regime of the North Qinling Tectonic Belt switched from compression to extension at ca. 400 Ma.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s8">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s14">Supplementary Material</xref>, further inquiries can be directed to the corresponding authors.</p>
</sec>
<sec sec-type="author-contributions" id="s9">
<title>Author contributions</title>
<p>ZC: Conceptualization, Data curation, Formal Analysis, Investigation, Methodology, Writing &#x2013; original draft. DC: Conceptualization, Data curation, Formal Analysis, Funding acquisition, Investigation, Methodology, Writing &#x2013; review and editing. YR: Conceptualization, Data curation, Formal Analysis, Investigation, Methodology, Writing &#x2013; review and editing. BB: Conceptualization, Data curation, Formal Analysis, Investigation, Writing &#x2013; review and editing. YT: Conceptualization, Data curation, Investigation, Writing &#x2013; review and editing. LM: Data curation, Investigation, Writing &#x2013; review and editing. ML: Investigation, Writing &#x2013; review and editing.</p>
</sec>
<ack>
<title>Acknowledgements</title>
<p>We thank Zhian Bao for zircon Hf isotope analytical assistance, and thank Haijie Wang for field work.</p>
</ack>
<sec sec-type="COI-statement" id="s11">
<title>Conflict of interest</title>
<p>The author(s) declared that this work was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="ai-statement" id="s12">
<title>Generative AI statement</title>
<p>The author(s) declared that generative AI was not used in the creation of this manuscript.</p>
<p>Any alternative text (alt text) provided alongside figures in this article has been generated by Frontiers with the support of artificial intelligence and reasonable efforts have been made to ensure accuracy, including review by the authors wherever possible. If you identify any issues, please contact us.</p>
</sec>
<sec sec-type="disclaimer" id="s13">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec sec-type="supplementary-material" id="s14">
<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2026.1774169/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2026.1774169/full&#x23;supplementary-material</ext-link>
</p>
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<fn fn-type="custom" custom-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/144151/overview">Yi Chen</ext-link>, Chinese Academy of Sciences (CAS), China</p>
</fn>
<fn fn-type="custom" custom-type="reviewed-by">
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<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/926473/overview">Wei-Qiang Ji</ext-link>, Chinese Academy of Sciences (CAS), China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/3328323/overview">Qing-Hua Zhang</ext-link>, Anhui University of Science and Technology, China</p>
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</article>