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<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
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<publisher-name>Frontiers Media S.A.</publisher-name>
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<article-meta>
<article-id pub-id-type="publisher-id">1601135</article-id>
<article-id pub-id-type="doi">10.3389/feart.2025.1601135</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Magma mixing in the Karamaili granite belt of Eastern Junggar: evidence from A2-type granites and their mafic microgranular enclaves</article-title>
<alt-title alt-title-type="left-running-head">Sun et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2025.1601135">10.3389/feart.2025.1601135</ext-link>
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<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Sun</surname>
<given-names>Yafei</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<xref ref-type="aff" rid="aff2">
<sup>2</sup>
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<name>
<surname>Zhang</surname>
<given-names>Bowen</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
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<contrib contrib-type="author">
<name>
<surname>Yao</surname>
<given-names>Yuan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<xref ref-type="aff" rid="aff2">
<sup>2</sup>
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<contrib contrib-type="author">
<name>
<surname>Zhan</surname>
<given-names>Xinzhong</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
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<contrib contrib-type="author">
<name>
<surname>Yalikun</surname>
<given-names>Yaxiaer</given-names>
</name>
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<sup>3</sup>
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<contrib contrib-type="author">
<name>
<surname>Wang</surname>
<given-names>Yacong</given-names>
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<sup>3</sup>
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<aff id="aff1">
<sup>1</sup>
<institution>Xinjiang Pamir Intracontinental Subduction National Observation and Research Station</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Urumqi Institute of Central Asia Earthquake, China Earthquake Administration</institution>, <addr-line>Urumqi</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>Xinjiang Key Laboratory for Geodynamic Processes and Metallogenic Prognosis of the Central Asian Orogenic Belt, College of Geology and Mining Engineering, Xinjiang University</institution>, <addr-line>Urumqi</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> J. Gregory Shellnutt, National Taiwan Normal University, Taiwan</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/92855/overview">Basilios Tsikouras</ext-link>, Universiti Brunei Darussalam, Brunei</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1794187/overview">Muhammad Saleem Mughal</ext-link>, University of Azad Jammu and Kashmir, Pakistan</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Bowen Zhang, <email>54392171@qq.com</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>11</day>
<month>09</month>
<year>2025</year>
</pub-date>
<pub-date pub-type="collection">
<year>2025</year>
</pub-date>
<volume>13</volume>
<elocation-id>1601135</elocation-id>
<history>
<date date-type="received">
<day>27</day>
<month>03</month>
<year>2025</year>
</date>
<date date-type="accepted">
<day>18</day>
<month>08</month>
<year>2025</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2025 Sun, Zhang, Yao, Zhan, Yalikun and Wang.</copyright-statement>
<copyright-year>2025</copyright-year>
<copyright-holder>Sun, Zhang, Yao, Zhan, Yalikun and Wang</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The Karamaili Orogenic Belt forms an essential part of the southernmost margin of the Eastern Junggar Orogenic Belt. The Late Carboniferous granitic belt of the Karamaili belt provides a valuable natural setting for studying the evolution of silicic magmas. In this study the petrology, rock geochemistry, and chronology of granite and mafic microgranular enclaves (MMEs) in the Sabei, Huangyangshan, and Sujiquan plutons are investigated. The results show similar zircon U-Pb ages of 315.9 &#xb1; 2.4 Ma, 316.1 &#xb1; 2.2 Ma, 319.4 &#xb1; 2.0 Ma, and 313.9 &#xb1; 3.5 Ma for the granite and Sabei MMEs. The granites are high silica, alkali-rich, weakly alkaline to sub-aluminous A<sub>2</sub>-type, and are strongly depleted in Eu. They are enriched in Ta, Th, U, Rb, K, and Pb, and formed in a post-collisional extensional environment. In contrast, the Sabei MMEs are sub-aluminous, calc-alkaline to high-K calc-alkaline gabbroic enclaves that exhibit typical magmatic structures and evidence of mixing and evolution. They represent residual dioritic enclaves derived from underplated, rising mafic magma that underwent mixing. Whole-rock &#x3b5;Nd(t) values of &#x2b;4.0 to &#x2b;4.5 for the Sabei, Huangyangshan, and Sujiquan plutons, and &#x3b5;Nd(t) values of &#x2b;5.5 to &#x2b;5.7 for the Sabei MMEs, indicate the involvement of juvenile mantle-derived magmas, suggesting significant juvenile crustal growth in the region. The results reveal intense mafic magmatism associated with the Karamaili granites. It included mafic magma input that generated highly differentiated granites, such as the Kamusite granite and mafic magmatic components contributing to eastern plutons and forming alkaline granites rich in dioritic enclaves like the Sabei and Huangyangshan granites. This study provides petrogenetic constraints on the formation of plutons in the Karamaili Granite Belt and the evolution of siliceous magmas in the region.</p>
</abstract>
<kwd-group>
<kwd>Eastern Junggar</kwd>
<kwd>Karamaili granitic belt</kwd>
<kwd>A-type granite</kwd>
<kwd>mafic microgranular enclaves</kwd>
<kwd>magma mixing</kwd>
</kwd-group>
<contract-num rid="cn001">2022YFC3003700</contract-num>
<contract-sponsor id="cn001">National Key Research and Development Program of China<named-content content-type="fundref-id">10.13039/501100012166</named-content>
</contract-sponsor>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Petrology</meta-value>
</custom-meta>
</custom-meta-wrap>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Magma mixing, a key intrusion mechanism in igneous rock-forming systems, is crucial in understanding petrogenetic processes and analyzing magma evolution, crust-mantle interactions, and magmatic dynamics. (<xref ref-type="bibr" rid="B42">Hoskin and Ireland, 2000</xref>; <xref ref-type="bibr" rid="B54">Li, 2002</xref>; <xref ref-type="bibr" rid="B6">Barbarin, 2005</xref>; <xref ref-type="bibr" rid="B50">Kumar and Rino, 2006</xref>; <xref ref-type="bibr" rid="B84">S&#x142;aby and Martin, 2008</xref>). Granitic rocks that host mafic microgranular enclaves (MMEs) provide valuable insights into crust-mantle interactions by acting as a &#x201c;lithoprobe&#x201d; and &#x201c;window&#x201d; from which direct evidence of magma mixing can be obtained and a pathway to investigate the deep lithosphere (<xref ref-type="bibr" rid="B7">Barbarin and Didier, 1992</xref>). <xref ref-type="bibr" rid="B5">Barbarin (1988)</xref> introduced the term MMEs to describe mafic rocks enclosed within other magmatic rocks. MMEs typically have a darker color than surrounding rocks (<xref ref-type="bibr" rid="B6">Barbarin, 2005</xref>), such as calc-alkaline granites. Magmatic mixing is ubiquitous and occurs not only in I-type granites but also in S-type and A-type granites (<xref ref-type="bibr" rid="B93">Wang, 2000</xref>; <xref ref-type="bibr" rid="B13">Bonin, 2007</xref>; <xref ref-type="bibr" rid="B82">Shellnutt et al., 2010</xref>; <xref ref-type="bibr" rid="B17">Champion and Bultitude, 2013</xref>).</p>
<p>The Central Asian Orogenic Belt (CAOB) is the largest accretionary orogenic belt and continental crust growth zone that has formed since the Phanerozoic era. The complete process of the ancient Asian Ocean generation, subduction, closure, and collision-related development is preserved within its rocks (<xref ref-type="bibr" rid="B80">Seng&#xf6;r and Natal&#x2019;in, 1996</xref>; <xref ref-type="bibr" rid="B109">Xiao et al., 2008</xref>; <xref ref-type="bibr" rid="B108">Xiao and Santosh, 2014</xref>). The Junggar structural belt is typically divided into three main components: the Western Junggar Orogenic Belt, the Junggar Basin, and the Eastern Junggar Orogenic Belt (EJOB) (<xref ref-type="fig" rid="F1">Figure 1b</xref>). The latter is located in the southwestern part of the CAOB (<xref ref-type="fig" rid="F1">Figure 1a</xref>) and consists of a series of Paleozoic magmatic arcs and accretionary complexes that have recorded the formation and evolution of the ancient Asian Ocean (<xref ref-type="bibr" rid="B110">Xiao et al., 2010</xref>; <xref ref-type="bibr" rid="B108">Xiao and Santosh, 2014</xref>). Intense crust-mantle interactions occur in this area during the continental margin accretionary orogeny and post-collisional vertical crustal growth (<xref ref-type="bibr" rid="B109">Xiao et al., 2008</xref>). The Paleozoic tectonic evolution in this region was critical to the growth of continental crust and the evolution of the ancient Asian Ocean. Establishing and refining the complete magmatic evolution in this area thus plays a vital role in reconstructing the ancient tectonic framework of northern Xinjiang and understanding the evolutionary history of the CAOB (<xref ref-type="bibr" rid="B112">Xiao et al., 2019b</xref>). The Karamaili tectonic belt is located in the EJOB north of the Karamaili Fault (<xref ref-type="fig" rid="F1">Figure 1c</xref>), and represents the inferred termination point of the Paleozoic oceanic basin in the Junggar region (<xref ref-type="bibr" rid="B55">Li et al., 2012</xref>). However, the magmatic source region, tectonic setting, and evolutionary history of this area have consistently been points of contention in basic geological research of the Karamaili region (<xref ref-type="bibr" rid="B87">Su et al., 2007</xref>; <xref ref-type="bibr" rid="B90">Tang et al., 2007</xref>; <xref ref-type="bibr" rid="B88">Su et al., 2008</xref>; <xref ref-type="bibr" rid="B117">Yang et al., 2008</xref>; <xref ref-type="bibr" rid="B121">Zhang et al., 2013</xref>; <xref ref-type="bibr" rid="B63">Liu et al., 2017</xref>; <xref ref-type="bibr" rid="B122">Zhang et al., 2018</xref>; <xref ref-type="bibr" rid="B123">Zhang et al., 2020</xref>; <xref ref-type="bibr" rid="B98">Wang et al., 2021</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(a)</bold> Simplified geologic map of the Central Asian Orogenic Belt, modified from <xref ref-type="bibr" rid="B111">Xiao et al. (2019a)</xref>; <bold>(b)</bold> Regional tectonic map of northern Xinjiang, modified from <xref ref-type="bibr" rid="B22">Chen and Jahn (2004)</xref>; <bold>(c)</bold> Geological map of the Karamaili belt.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g001.tif">
<alt-text content-type="machine-generated">Three-panel geological map detailing regions in Central Asia:a) Overview map showing Siberian and Central Asian orogenic belts, with a red outline indicating the detailed area in sub-map b.b) Regional map showing orogenic belts and faults, including the Wulungu and Karamaili Faults, with the detailed area for sub-map c outlined in red.c) Detailed geological map highlighting various plutoons and rock types, such as granitoids, ultrabasic, and basic rocks. Key features include the Karamaili Fault, Kamusite and Yemaquan Plutons, and sample locations marked with stars. A legend identifies rock types and structures.</alt-text>
</graphic>
</fig>
<p>The Karamaili Granite Belt (KGB) comprises A-type granites, as evidenced by positive &#x3b5;Nd(t) and &#x3b5;Hf(t) values. These granite types are corroborated by the presence of mafic-ultramafic plutons, including active late-stage vein plutons, which indicate Late Paleozoic magmatic activity (<xref ref-type="bibr" rid="B41">Hong et al., 1995</xref>; <xref ref-type="bibr" rid="B37">Han et al., 1997</xref>). Nevertheless, significant spatial disparities have emerged concerning the petrography, degree of magmatic fractionation, mafic magma supply, and magma mixing in the area. A study of the late Silurian to early Devonian Karamaili serpentinite belt (<xref ref-type="bibr" rid="B115">Xu et al., 2014</xref>) proposed the development of a local extensional tectonic setting during the late stages of ancient oceanic plate subduction in the region, which led to substantial silicic magma activity. Mantle-derived material was the reason for the growth of the ancient lithospheric crust and the formation of the juvenile crust. Although this model is widely accepted (<xref ref-type="bibr" rid="B95">Wang and Hou, 2018</xref>), uncertainties regarding the diversity of granites due to crust-mantle magma mixing remain, and a comprehensive analysis of the evolution of magma mixing in a crystal mush state is lacking (<xref ref-type="bibr" rid="B71">Mo, 2011</xref>; <xref ref-type="bibr" rid="B49">Kr&#xf6;ner et al., 2017</xref>; <xref ref-type="bibr" rid="B94">Wang, 2017</xref>). Thus, this study focuses on the eastern segment of the KGB, in which numerous MMEs have been observed in the Sabei, Huangyangshan, and Sujiquan plutons. This study is based on previous investigations and utilizes additional petrography and geochemical data, zircon U-Pb dating, and whole-rock Nd isotope analysis of the granites and their MMEs to determine the origin of magma mixing and magma evolution to provide insights into different evolutionary processes during the Late Carboniferous in this granitic belt and the transition from compressional to extensional stress environments in the late subduction stages.</p>
</sec>
<sec id="s2">
<title>2 Geological background</title>
<p>The Karamaili tectonic belt is located on the eastern edge of the Junggar Block in Xinjiang, with its tectonic structure lying at the junction between the Siberian Plate and the Kazakhstan-Junggar Block. The eastern margin of the Junggar Block has undergone long-term and complex tectonic evolution since the Paleozoic era, accompanied by intense magmatic activity, forming of the WNW-oriented Karamaili ophiolite belt and the parallel KGB in the southeastern part of the block. The Karamaili structural belt is currently primarily controlled by the Karamaili, Ulungu, and Erqisi deep faults. The region is also affected by a series of WNW-striking strike-slip faults associated with tectonic activity and the occurrence of A-type granites.</p>
<p>The Karamaili tectonic belt is an important part of the Paleozoic orogenic belt in Eastern Junggar. A northwest-striking ophiolite belt, potentially containing Early Devonian oceanic crust, occurs discontinuously along the northern flank of the Karamaili deep fault (<xref ref-type="bibr" rid="B53">Li, 1995</xref>). The exposed strata in the area are mainly Devonian and Carboniferous tuffaceous siltstone and pyroclastic rocks, with a small fraction of Silurian strata scattered to the south. The NW-trending Late Carboniferous KGB developed in this area, with rock types predominantly plagiogranite, granodiorite, biotite granite, hornblende granite and alkaline granite. Calc-alkaline granites associated with gold and copper metallogenic series and alkali-rich or highly differentiated granites related to the tin metallogenic series are the most significant (<xref ref-type="bibr" rid="B118">Yang et al., 2009</xref>; <xref ref-type="bibr" rid="B35">Gu et al., 2020</xref>). The KGB outcrop is a roughly NW-oriented, banded, massive batholith extending approximately 110 km in length and covering an area of approximately 1,068 km<sup>2</sup>. Previous authors have divided the belt into the Kamusite, Laoyaquan, Belekuduke, Sabei, Huangyangshan, and Sujiquan plutons from west to east. The plutons are generally considered an A-type granite series with a magmatic age of approximately 330&#x2013;310 Ma (<xref ref-type="bibr" rid="B88">Su et al., 2008</xref>; <xref ref-type="bibr" rid="B117">Yang et al., 2008</xref>; <xref ref-type="bibr" rid="B122">Zhang et al., 2018</xref>) indicating that the KGB entered a post-collision extensional tectonic environment in the Late Carboniferous.</p>
<p>This study focuses on the Sabei, Huangyangshan, and Sujiquan plutons in the eastern KGB, which are rich in MMEs and exhibit significant spatial variations in terms of petrology, the degree of magma differentiation, mafic magma input, and magma mixing effects (<xref ref-type="fig" rid="F1">Figure 1c</xref>). The Sabei pluton comprises coarse- to medium-grained biotite granite and medium- to fine-grained potassic granite; it is in contact with the overlying Middle Devonian and Quaternary strata. A change in lithology occurs to the north of this pluton, and granodiorite is present (<xref ref-type="fig" rid="F1">Figure 1c</xref>). The Huangyangshan pluton is located on the northeastern side of the fracture zone (<xref ref-type="fig" rid="F1">Figure 1c</xref>). It is a spherical weathered outcrop with an exposure area of approximately 230 km<sup>2</sup>. It has intrusive relations with the tuffaceous siltstone of the Carboniferous Heishantou Formation. Thermal metamorphism occurs at the contact with the wall rock to varying degrees. The local grain size becomes finer close to the contact area. Graphite mineralization developed simultaneously in both plutons and occurred as a series of NE-trending granite porphyry veins, diorite veins, and a small number of diabase veins. The Sujiquan pluton is mainly composed of plagioclase granite, granodiorite, biotite granite, and alkali feldspar granite. The biotite granite is closely related to tin mineralization. Mesothermal graphite deposits are commonly found in the rock bodies, and the overlying strata are primarily Devonian and Carboniferous siltstone and pyroclastic rock (<xref ref-type="bibr" rid="B61">Liu et al., 1997</xref>; <xref ref-type="bibr" rid="B57">Lin et al., 2007</xref>; <xref ref-type="bibr" rid="B58">Lin et al., 2008</xref>).</p>
</sec>
<sec id="s3">
<title>3 Petrography</title>
<p>According to field observations and thin-section microscopic analysis, the lithology of the sample includes monzogranite, biotite syenogranite, biotite granite, and MMEs, which are shown in <xref ref-type="fig" rid="F2">Figure 2a</xref>.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Field photographs and micrographs of <bold>(a)</bold> the Sabei granites and mafic microgranular enclaves (MMEs); <bold>(b,c)</bold> Sabei alkaline feldspar granite; <bold>(d,e)</bold> Huangyangshan biotite potassium feldspar granite; <bold>(f,g)</bold> Sujiquan biotite granite; <bold>(h)</bold> Sabei MMEs. <bold>(i)</bold> Needle-like apatite in Sabei MMEs (Pl, Plagioclase; Pth, Perthite; Bt, Biotite; Qtz, Quartz; Ap, Apatite; Px, Pyroxene.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g002.tif">
<alt-text content-type="machine-generated">a) Geological field showing Sabel Pluton with labeled enclaves. b) Image highlighting contact cementation boundary and mineral accumulation. c) Microscopic view with minerals labeled as Qtz, Bt, and Pl. d) Granite rock with a coin for scale. e) Thin section showing minerals labeled Pl, Pth, Bt, and Qtz. f) Another granite rock sample with a coin for scale. g) Thin section with minerals Qtz, Bt, and Pl. h) Image with minerals labeled Ap and Px. i) Thin section with labeled Ap.</alt-text>
</graphic>
</fig>
<p>The monzogranite is mainly distributed in the Sabei pluton, with fresh surfaces generally appearing gray-white and having blocky structures. The pluton comprises medium- to coarse-grained monzogranite (<xref ref-type="fig" rid="F2">Figure 2b</xref>) composed of alkali feldspar (35%&#x2013;40%), plagioclase (30%&#x2013;35%), quartz (25%&#x2013;30%), and accessory biotite (3%&#x2013;5%). The alkali feldspar is heterogeneous with a grain size of 0.2&#x2013;4 mm, and striped feldspar is predominant (<xref ref-type="fig" rid="F2">Figure 2c</xref>), with the stripes fusiform in the exsolution direction and displaying weak kaolinization. Plagioclase occurs as subhedral grains displaying polysynthetic twinning (Albite law) and pervasive sericitization with argillic alteration. Quartz is anhedral with a grain size ranging from 0.5 to 5.5 mm, but generally greater than 3 mm.</p>
<p>The biotite syenogranite is primarily distributed in the Huangyangshan pluton, with a medium to fine-grained, subhedral, and massive structure. The main minerals are potassium feldspar (60%&#x2013;65%), quartz (20%&#x2013;25%), biotite (5%&#x2013;10%) and plagioclase (&#x3c;5%) (<xref ref-type="fig" rid="F2">Figure 2d</xref>). The alkali feldspar is well-formed and has a grain size of 0.4&#x2013;4 mm; it is generally about 2 mm. Potassium feldspar has undergone kaolinization. Quartz is anhedral (0.5&#x2013;3.5 mm), displaying homogeneous extinction and no evidence of secondary alteration (e.g., sericitization or chloritization) along the grain margins (<xref ref-type="fig" rid="F2">Figure 2e</xref>). Plagioclase exsolution lamellae are evident comprising mainly albite; these grains are subhedral and exhibit polysynthetic twinning (Albite law) and weak sericitization. Biotite occurs as subhedral flakes (grain size 0.2&#x2013;1 mm), exhibiting light brown pleochroism. It has been partially altered to chlorite and iron oxides along cleavage planes.</p>
<p>The biotite granite is mainly distributed in the Sujiquan plutons, with a gray-white fresh surface, a medium- and coarse-grained texture and blocky structures (<xref ref-type="fig" rid="F2">Figure 2f</xref>). It is composed of potassium feldspar (40%&#x2013;45%), plagioclase (30%&#x2013;35%), quartz (20%&#x2013;25%), and a small amount of biotite (8%&#x2013;10%). Alkali feldspar is euhedral to subhedral (grain size 0.2&#x2013;4.5 mm) predominantly orthoclase with minor kaolinization (<xref ref-type="fig" rid="F2">Figure 2g</xref>). Plagioclase (albite) displays Carlsbad twin law with sharp twin boundaries, suggesting magmatic crystallization, while biotite occurs as brown subhedral flakes (0.4&#x2013;2 mm) associated with accessory zircon and apatite.</p>
<p>The MMEs in the granite of the Sabei and Huangyangshan plutons are spherical, ellipsoidal, spindle-shaped, and lenticular, although the majority are ellipsoidal. The size of the long axis in the enclaves varies significantly, ranging from a few meters to a few millimeters. The MMEs are grey-black, contrasting sharply with the host rocks&#x2019; color. The MMEs exhibits a fine-grained, subhedral granular massive texture, marked by chilled margins and concentrations of fine-grained mafic minerals (<xref ref-type="fig" rid="F2">Figure 2b</xref>). Its main minerals are plagioclase (30%&#x2013;35%), biotite (25%&#x2013;30%), alkali feldspar (10%&#x2013;15%), pyroxene (10%&#x2013;15%), hornblende (5%&#x2013;10%), quartz (5%&#x2013;10%), and more typical needle-like apatite (<xref ref-type="fig" rid="F2">Figures 2h,i</xref>). Plagioclase occurs predominantly as euhedral tabular crystals exhibiting oscillatory zoning, indicating it resulted from magma mixing (<xref ref-type="bibr" rid="B113">Xie et al., 2004</xref>).</p>
</sec>
<sec id="s4">
<title>4 Analytical methods</title>
<p>Fourteen fresh granite samples were collected from undeformed and unaltered bedrock outcrops without late vein penetration in the Sabei, Huangyangshan, and Sujiquan plutons. The samples&#x2019; whole-rock geochemical composition was determined. Zircon U-Pb dating was performed on samples SB-1, HYS-1, SJQ-1, and SBMMEs-1, whereas whole-rock Nd isotope analysis was conducted on samples SB-1, SB-3, SBMME-1, SBMME-3, HYS-1, and SJQ-2. The samples comprised four pieces of medium-grained monzogranite from the Sabei pluton (SBMME-1 to SBMME-3), three pieces of MMEs from the medium-grained monzogranite in Sabei (SBMME-1 to SBMME-3), four pieces of biotite syenogranite from Huangyangshan (HYS-1 to HYS-4), and four pieces of biotite granite from the Sujiquan pluton (SJQ-1 to SJQ-4).</p>
<sec id="s4-1">
<title>4.1 Zircon U-Pb geochronology</title>
<p>Zircon crushing, single mineral selection, target development, and U-Pb and cathodoluminescence (CL) image acquisition were performed at Beijing Yanduzhongshi Geological Analysis Laboratories, Ltd. Zircon U-Pb dating was performed using a laser ablation system with a UP-213 deep ultraviolet laser (213 nm), and a MicroLas optical system. Inductively coupled plasma mass spectrometry (ICP-MS) was performed using a Jena M90, with the international zircon standard 91500. The ordinary Pb calibration method was used to calibrate the measurement results. ICP-MS DataCal software was used for data processing (<xref ref-type="bibr" rid="B62">Liu et al., 2010</xref>). Zircon U-Pb concordia diagrams and the mean squared weighted deviation (MSWD) were obtained using Isoplot. The age value error of 1&#x3c3; was used in determining the <sup>206</sup>Pb/<sup>238</sup>U age, and a 95% confidence interval was utilized (<xref ref-type="bibr" rid="B64">Ludwig, 2003</xref>).</p>
</sec>
<sec id="s4-2">
<title>4.2 Whole-rock geochemistry</title>
<p>Whole-rock geochemical analysis was performed at the Beijing Yanduzhongshi Geological Analysis Laboratories, Ltd. Fourteen fresh samples (none of the materials showed were altered) were ultrasonically cleaned with deionized water, oven-dried at 60 &#xb0;C for 24 h, and pulverized to &#x3c;75 &#x3bc;m using an agate mortar prior to geochemical analysis. For the whole rock major element testing, the sample powder was weighed and mixed with lithium tetraborate (Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>) as a flux in a ratio of 1:8. Ammonium nitrate (NH<sub>4</sub>NO<sub>3</sub>) was added as an oxidant, and lithium bromide (LiBr) was added as a flux. The sample was heated to 1,050 &#xb0;C for 15 min using a fusion furnace to form a uniform glass sheet in a platinum crucible. Testing was conducted using wavelength dispersive X-ray fluorescence (XRF) (Zetium, Malvern PANalytical, Malvern, United Kingdom), with a relative standard deviation (RSD) of less than 2%. The sample powder was weighed, placed in a polytetrafluoroethylene dissolution tank, and HF &#x2b; HNO<sub>3</sub> was added prior to whole-rock trace element analysis. The material was placed in a high-pressure digestion tank in a drying oven at 190 &#xb0;C for 72 h, after which it was removed for acid flushing. The solution was diluted to a constant volume for machine testing. Testing was completed using the Agilent 7700 ICP-MS, and a testing accuracy of better than 10% was achieved.</p>
</sec>
<sec id="s4-3">
<title>4.3 Whole-rock Nd isotopic composition analyses</title>
<p>Nd isotope analysis was performed using six sets of whole-rock samples at Beijing Yanduzhongshi Geological Analysis Laboratories Ltd. First, 0.25 g of the sample was accurately weighed and placed into a Teflon stew tank. HNO<sub>3</sub> and HF were added, and the sample was heated for 48 h digestion under closed conditions at 190 &#xb0;C. The temperature was reduced to 160 &#xb0;C under closed conditions to remove any HF. The HNO<sub>3</sub> solution was added, and the mixture was dissolved at a temperature of 150 &#xb0;C over 6 h under sealed conditions until a constant volume of 25 g was achieved. An appropriate amount of the Nd solution was centrifuged. The obtained suspension supernatant was evaporated to dryness, and the solution was adjusted to a suitable pH. A special LN resin was used to separate the pure Nd and obtain a sample solution. Finally, multi-collector ICP-MS (MC-ICP-MS) (Neptune Plus, Thermo Fisher Scientific) was performed to determine the <sup>143</sup>Nd/<sup>144</sup>Nd value for the sample solution. According to the exponential law for <sup>143</sup>Nd/<sup>144</sup>Nd (0.7218), online mass fractionation correction was performed on the measured <sup>143</sup>Nd/<sup>144</sup>Nd values with an error of 2&#x3c3; (uncertainty in the mass spectrometry measurement).</p>
</sec>
</sec>
<sec sec-type="results" id="s5">
<title>5 Results</title>
<sec id="s5-1">
<title>5.1 Zircon geochronology</title>
<p>Laser ablation-ICP-MS (LA-ICP-MS) zircon U-Pb dating was performed on three granite samples and one enclave sample from the Sabei, Huangyangshan, and Sujiquan plutons in the eastern KGB. Rectangular zircons with a complete crystal structure were selected under transmitted and reflected light, and CL images were obtained to perform zircon U-Pb dating (<xref ref-type="fig" rid="F3">Figure 3</xref>). The data used for zircon U-Pb dating are presented in <xref ref-type="table" rid="T1">Table 1</xref>.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Zircon U&#x2013;Pb Concordia diagrams, weighted average age map, and zircon CL image of the <bold>(a)</bold> Sabei granites, <bold>(b)</bold> Huangyangshan granites, <bold>(c)</bold> Sujiquan granite, and <bold>(d)</bold> Sabei MMEs.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g003.tif">
<alt-text content-type="machine-generated">Four radiogenic isotope ratio diagrams compare different granites and MME samples. Each panel shows scatter plots with red error ellipses and a concordia line, with inset zircon images and age data. Panels are labeled: (a) Sabei granites, (b) Huangyangshan granites, (c) Sujiquan granites, (d) Sabei MMEs. Each has specific mean ages and Mean Square Weighted Deviation (MSWD) values.</alt-text>
</graphic>
</fig>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Zircon U-Pb results for plagiogranite from Sabei, Huangyangshan, Sujiquan plutons.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Point</th>
<th colspan="3" align="left">Content (&#xd7;10<sup>&#x2013;6</sup>)</th>
<th align="left"/>
<th colspan="6" align="left">Isotoperatio</th>
<th colspan="6" align="left">Isotopicage (Ma)</th>
</tr>
<tr>
<th align="left">
<sup>208</sup>Pb</th>
<th align="left">
<sup>232</sup>Th</th>
<th align="left">
<sup>238</sup>U</th>
<th align="left">Th/U</th>
<th align="left">
<sup>207</sup>Pb/<sup>206</sup>Pb</th>
<th align="left">&#x3c3;</th>
<th align="left">
<sup>207</sup>Pb/<sup>235</sup>U</th>
<th align="left">&#x3c3;</th>
<th align="left">
<sup>206</sup>Pb/<sup>238</sup>U</th>
<th align="left">&#x3c3;</th>
<th align="center">
<sup>207</sup>Pb/<sup>206</sup>Pb</th>
<th align="center">&#x3c3;</th>
<th align="center">
<sup>207</sup>Pb/<sup>235</sup>U</th>
<th align="center">&#x3c3;</th>
<th align="center">
<sup>206</sup>Pb/<sup>238</sup>U</th>
<th align="left">&#x3c3;</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">SB1-01</td>
<td align="left">2.21</td>
<td align="left">141.03</td>
<td align="left">315.96</td>
<td align="left">0.45</td>
<td align="left">0.053330</td>
<td align="left">0.001430</td>
<td align="left">0.377770</td>
<td align="left">0.013160</td>
<td align="left">0.051270</td>
<td align="left">0.001120</td>
<td align="center">343</td>
<td align="center">41</td>
<td align="center">325</td>
<td align="center">10</td>
<td align="center">322</td>
<td align="left">7</td>
</tr>
<tr>
<td align="left">SB1-02</td>
<td align="left">3.49</td>
<td align="left">201.99</td>
<td align="left">340.71</td>
<td align="left">0.59</td>
<td align="left">0.051770</td>
<td align="left">0.001070</td>
<td align="left">0.362990</td>
<td align="left">0.008310</td>
<td align="left">0.050680</td>
<td align="left">0.000730</td>
<td align="center">275</td>
<td align="center">28</td>
<td align="center">314</td>
<td align="center">6</td>
<td align="center">319</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-03</td>
<td align="left">2.40</td>
<td align="left">147.89</td>
<td align="left">354.18</td>
<td align="left">0.42</td>
<td align="left">0.053800</td>
<td align="left">0.001120</td>
<td align="left">0.366610</td>
<td align="left">0.008200</td>
<td align="left">0.049340</td>
<td align="left">0.000680</td>
<td align="center">363</td>
<td align="center">27</td>
<td align="center">317</td>
<td align="center">6</td>
<td align="center">310</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-04</td>
<td align="left">2.94</td>
<td align="left">181.88</td>
<td align="left">400.28</td>
<td align="left">0.45</td>
<td align="left">0.053310</td>
<td align="left">0.000940</td>
<td align="left">0.368080</td>
<td align="left">0.006890</td>
<td align="left">0.049930</td>
<td align="left">0.000530</td>
<td align="center">342</td>
<td align="center">24</td>
<td align="center">318</td>
<td align="center">5</td>
<td align="center">314</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SB1-05</td>
<td align="left">2.49</td>
<td align="left">142.53</td>
<td align="left">365.26</td>
<td align="left">0.39</td>
<td align="left">0.052030</td>
<td align="left">0.002380</td>
<td align="left">0.367590</td>
<td align="left">0.015590</td>
<td align="left">0.051240</td>
<td align="left">0.000890</td>
<td align="center">287</td>
<td align="center">107</td>
<td align="center">318</td>
<td align="center">12</td>
<td align="center">322</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SB1-06</td>
<td align="left">1.38</td>
<td align="left">79.26</td>
<td align="left">206.64</td>
<td align="left">0.38</td>
<td align="left">0.055220</td>
<td align="left">0.002030</td>
<td align="left">0.386980</td>
<td align="left">0.013550</td>
<td align="left">0.050830</td>
<td align="left">0.000560</td>
<td align="center">421</td>
<td align="center">84</td>
<td align="center">332</td>
<td align="center">10</td>
<td align="center">320</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SB1-07</td>
<td align="left">2.96</td>
<td align="left">184.96</td>
<td align="left">426.89</td>
<td align="left">0.43</td>
<td align="left">0.053400</td>
<td align="left">0.000870</td>
<td align="left">0.358870</td>
<td align="left">0.005880</td>
<td align="left">0.048740</td>
<td align="left">0.000590</td>
<td align="center">346</td>
<td align="center">18</td>
<td align="center">311</td>
<td align="center">4</td>
<td align="center">307</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-08</td>
<td align="left">2.67</td>
<td align="left">163.79</td>
<td align="left">394.02</td>
<td align="left">0.42</td>
<td align="left">0.053680</td>
<td align="left">0.000870</td>
<td align="left">0.370280</td>
<td align="left">0.006330</td>
<td align="left">0.049970</td>
<td align="left">0.000600</td>
<td align="center">358</td>
<td align="center">19</td>
<td align="center">320</td>
<td align="center">5</td>
<td align="center">314</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-09</td>
<td align="left">3.54</td>
<td align="left">223.79</td>
<td align="left">455.42</td>
<td align="left">0.49</td>
<td align="left">0.053500</td>
<td align="left">0.000890</td>
<td align="left">0.361180</td>
<td align="left">0.006370</td>
<td align="left">0.048870</td>
<td align="left">0.000630</td>
<td align="center">350</td>
<td align="center">19</td>
<td align="center">313</td>
<td align="center">5</td>
<td align="center">308</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-10</td>
<td align="left">1.37</td>
<td align="left">88.13</td>
<td align="left">225.98</td>
<td align="left">0.39</td>
<td align="left">0.054100</td>
<td align="left">0.001640</td>
<td align="left">0.379880</td>
<td align="left">0.012050</td>
<td align="left">0.050900</td>
<td align="left">0.001180</td>
<td align="center">375</td>
<td align="center">34</td>
<td align="center">327</td>
<td align="center">9</td>
<td align="center">320</td>
<td align="left">7</td>
</tr>
<tr>
<td align="left">SB1-11</td>
<td align="left">3.74</td>
<td align="left">241.32</td>
<td align="left">495.61</td>
<td align="left">0.49</td>
<td align="left">0.052760</td>
<td align="left">0.001020</td>
<td align="left">0.360930</td>
<td align="left">0.007800</td>
<td align="left">0.049360</td>
<td align="left">0.000910</td>
<td align="center">318</td>
<td align="center">22</td>
<td align="center">313</td>
<td align="center">6</td>
<td align="center">311</td>
<td align="left">6</td>
</tr>
<tr>
<td align="left">SB1-12</td>
<td align="left">2.98</td>
<td align="left">178.67</td>
<td align="left">403.69</td>
<td align="left">0.44</td>
<td align="left">0.053400</td>
<td align="left">0.001450</td>
<td align="left">0.364560</td>
<td align="left">0.009650</td>
<td align="left">0.049360</td>
<td align="left">0.000530</td>
<td align="center">346</td>
<td align="center">40</td>
<td align="center">316</td>
<td align="center">7</td>
<td align="center">311</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SB1-13</td>
<td align="left">2.62</td>
<td align="left">172.38</td>
<td align="left">357.72</td>
<td align="left">0.48</td>
<td align="left">0.053460</td>
<td align="left">0.001300</td>
<td align="left">0.379370</td>
<td align="left">0.010410</td>
<td align="left">0.051090</td>
<td align="left">0.000830</td>
<td align="center">348</td>
<td align="center">34</td>
<td align="center">327</td>
<td align="center">8</td>
<td align="center">321</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SB1-14</td>
<td align="left">1.30</td>
<td align="left">83.20</td>
<td align="left">177.27</td>
<td align="left">0.47</td>
<td align="left">0.053150</td>
<td align="left">0.001280</td>
<td align="left">0.374040</td>
<td align="left">0.009700</td>
<td align="left">0.050990</td>
<td align="left">0.000740</td>
<td align="center">335</td>
<td align="center">33</td>
<td align="center">323</td>
<td align="center">7</td>
<td align="center">321</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SB1-15</td>
<td align="left">5.37</td>
<td align="left">318.50</td>
<td align="left">734.71</td>
<td align="left">0.43</td>
<td align="left">0.055300</td>
<td align="left">0.002020</td>
<td align="left">0.386460</td>
<td align="left">0.013080</td>
<td align="left">0.050680</td>
<td align="left">0.000690</td>
<td align="center">424</td>
<td align="center">83</td>
<td align="center">332</td>
<td align="center">10</td>
<td align="center">319</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-16</td>
<td align="left">3.17</td>
<td align="left">202.84</td>
<td align="left">436.44</td>
<td align="left">0.46</td>
<td align="left">0.052940</td>
<td align="left">0.000820</td>
<td align="left">0.369970</td>
<td align="left">0.006710</td>
<td align="left">0.050540</td>
<td align="left">0.000590</td>
<td align="center">326</td>
<td align="center">21</td>
<td align="center">320</td>
<td align="center">5</td>
<td align="center">318</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-17</td>
<td align="left">3.07</td>
<td align="left">163.06</td>
<td align="left">421.18</td>
<td align="left">0.39</td>
<td align="left">0.053220</td>
<td align="left">0.003770</td>
<td align="left">0.370910</td>
<td align="left">0.025170</td>
<td align="left">0.050550</td>
<td align="left">0.001020</td>
<td align="center">338</td>
<td align="center">163</td>
<td align="center">320</td>
<td align="center">19</td>
<td align="center">318</td>
<td align="left">6</td>
</tr>
<tr>
<td align="left">SB1-18</td>
<td align="left">3.29</td>
<td align="left">199.57</td>
<td align="left">429.15</td>
<td align="left">0.47</td>
<td align="left">0.053230</td>
<td align="left">0.000820</td>
<td align="left">0.377220</td>
<td align="left">0.005680</td>
<td align="left">0.051420</td>
<td align="left">0.000610</td>
<td align="center">338</td>
<td align="center">16</td>
<td align="center">325</td>
<td align="center">4</td>
<td align="center">323</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SB1-19</td>
<td align="left">2.59</td>
<td align="left">167.79</td>
<td align="left">375.95</td>
<td align="left">0.45</td>
<td align="left">0.051230</td>
<td align="left">0.000900</td>
<td align="left">0.356770</td>
<td align="left">0.007200</td>
<td align="left">0.050460</td>
<td align="left">0.000620</td>
<td align="center">251</td>
<td align="center">25</td>
<td align="center">310</td>
<td align="center">5</td>
<td align="center">317</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-01</td>
<td align="left">4.54</td>
<td align="left">267.75</td>
<td align="left">436.23</td>
<td align="left">0.61</td>
<td align="left">0.052120</td>
<td align="left">0.000960</td>
<td align="left">0.356170</td>
<td align="left">0.006490</td>
<td align="left">0.049540</td>
<td align="left">0.000540</td>
<td align="center">291</td>
<td align="center">23</td>
<td align="center">309</td>
<td align="center">5</td>
<td align="center">312</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">HYS1-02</td>
<td align="left">8.60</td>
<td align="left">481.34</td>
<td align="left">620.90</td>
<td align="left">0.78</td>
<td align="left">0.052030</td>
<td align="left">0.002820</td>
<td align="left">0.364150</td>
<td align="left">0.018800</td>
<td align="left">0.050770</td>
<td align="left">0.000820</td>
<td align="center">287</td>
<td align="center">127</td>
<td align="center">315</td>
<td align="center">14</td>
<td align="center">319</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">HYS1-03</td>
<td align="left">2.12</td>
<td align="left">128.83</td>
<td align="left">331.83</td>
<td align="left">0.39</td>
<td align="left">0.052410</td>
<td align="left">0.000840</td>
<td align="left">0.358030</td>
<td align="left">0.005930</td>
<td align="left">0.049500</td>
<td align="left">0.000600</td>
<td align="center">303</td>
<td align="center">18</td>
<td align="center">311</td>
<td align="center">4</td>
<td align="center">311</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-04</td>
<td align="left">1.88</td>
<td align="left">99.77</td>
<td align="left">258.50</td>
<td align="left">0.39</td>
<td align="left">0.055970</td>
<td align="left">0.003230</td>
<td align="left">0.393090</td>
<td align="left">0.021780</td>
<td align="left">0.050940</td>
<td align="left">0.000820</td>
<td align="center">451</td>
<td align="center">132</td>
<td align="center">337</td>
<td align="center">16</td>
<td align="center">320</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">HYS1-05</td>
<td align="left">4.94</td>
<td align="left">297.63</td>
<td align="left">590.77</td>
<td align="left">0.50</td>
<td align="left">0.051890</td>
<td align="left">0.000810</td>
<td align="left">0.365670</td>
<td align="left">0.006140</td>
<td align="left">0.050970</td>
<td align="left">0.000610</td>
<td align="center">281</td>
<td align="center">19</td>
<td align="center">316</td>
<td align="center">5</td>
<td align="center">320</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-06</td>
<td align="left">1.90</td>
<td align="left">100.78</td>
<td align="left">304.29</td>
<td align="left">0.33</td>
<td align="left">0.054880</td>
<td align="left">0.002540</td>
<td align="left">0.382640</td>
<td align="left">0.016570</td>
<td align="left">0.050570</td>
<td align="left">0.000830</td>
<td align="center">407</td>
<td align="center">106</td>
<td align="center">329</td>
<td align="center">12</td>
<td align="center">318</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">HYS1-07</td>
<td align="left">2.59</td>
<td align="left">153.97</td>
<td align="left">310.42</td>
<td align="left">0.50</td>
<td align="left">0.052350</td>
<td align="left">0.000900</td>
<td align="left">0.368500</td>
<td align="left">0.006280</td>
<td align="left">0.051000</td>
<td align="left">0.000550</td>
<td align="center">301</td>
<td align="center">20</td>
<td align="center">319</td>
<td align="center">5</td>
<td align="center">321</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">HYS1-08</td>
<td align="left">6.04</td>
<td align="left">368.07</td>
<td align="left">531.53</td>
<td align="left">0.69</td>
<td align="left">0.052390</td>
<td align="left">0.001160</td>
<td align="left">0.364670</td>
<td align="left">0.007410</td>
<td align="left">0.050600</td>
<td align="left">0.000690</td>
<td align="center">302</td>
<td align="center">23</td>
<td align="center">316</td>
<td align="center">6</td>
<td align="center">318</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-09</td>
<td align="left">4.16</td>
<td align="left">253.68</td>
<td align="left">398.62</td>
<td align="left">0.64</td>
<td align="left">0.052230</td>
<td align="left">0.000880</td>
<td align="left">0.367140</td>
<td align="left">0.005940</td>
<td align="left">0.051010</td>
<td align="left">0.000540</td>
<td align="center">295</td>
<td align="center">19</td>
<td align="center">318</td>
<td align="center">4</td>
<td align="center">321</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">HYS1-10</td>
<td align="left">2.59</td>
<td align="left">159.41</td>
<td align="left">302.49</td>
<td align="left">0.53</td>
<td align="left">0.053160</td>
<td align="left">0.000900</td>
<td align="left">0.367520</td>
<td align="left">0.006600</td>
<td align="left">0.050150</td>
<td align="left">0.000600</td>
<td align="center">336</td>
<td align="center">21</td>
<td align="center">318</td>
<td align="center">5</td>
<td align="center">315</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-11</td>
<td align="left">1.36</td>
<td align="left">77.78</td>
<td align="left">179.80</td>
<td align="left">0.43</td>
<td align="left">0.053130</td>
<td align="left">0.001210</td>
<td align="left">0.377880</td>
<td align="left">0.008540</td>
<td align="left">0.051700</td>
<td align="left">0.000770</td>
<td align="center">334</td>
<td align="center">26</td>
<td align="center">325</td>
<td align="center">6</td>
<td align="center">325</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">HYS1-12</td>
<td align="left">0.72</td>
<td align="left">42.59</td>
<td align="left">117.92</td>
<td align="left">0.36</td>
<td align="left">0.053130</td>
<td align="left">0.001520</td>
<td align="left">0.367620</td>
<td align="left">0.010340</td>
<td align="left">0.050490</td>
<td align="left">0.000730</td>
<td align="center">334</td>
<td align="center">38</td>
<td align="center">318</td>
<td align="center">8</td>
<td align="center">318</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-13</td>
<td align="left">2.12</td>
<td align="left">130.94</td>
<td align="left">308.80</td>
<td align="left">0.42</td>
<td align="left">0.052950</td>
<td align="left">0.001160</td>
<td align="left">0.360810</td>
<td align="left">0.007390</td>
<td align="left">0.049570</td>
<td align="left">0.000640</td>
<td align="center">327</td>
<td align="center">24</td>
<td align="center">313</td>
<td align="center">6</td>
<td align="center">312</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-14</td>
<td align="left">2.26</td>
<td align="left">140.13</td>
<td align="left">274.71</td>
<td align="left">0.51</td>
<td align="left">0.052780</td>
<td align="left">0.000970</td>
<td align="left">0.359320</td>
<td align="left">0.006710</td>
<td align="left">0.049290</td>
<td align="left">0.000500</td>
<td align="center">320</td>
<td align="center">24</td>
<td align="center">312</td>
<td align="center">5</td>
<td align="center">310</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">HYS1-15</td>
<td align="left">12.47</td>
<td align="left">766.04</td>
<td align="left">850.62</td>
<td align="left">0.90</td>
<td align="left">0.052060</td>
<td align="left">0.000570</td>
<td align="left">0.362260</td>
<td align="left">0.005070</td>
<td align="left">0.050290</td>
<td align="left">0.000550</td>
<td align="center">288</td>
<td align="center">15</td>
<td align="center">314</td>
<td align="center">4</td>
<td align="center">316</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">HYS1-16</td>
<td align="left">1.22</td>
<td align="left">78.07</td>
<td align="left">235.61</td>
<td align="left">0.33</td>
<td align="left">0.053480</td>
<td align="left">0.001090</td>
<td align="left">0.365080</td>
<td align="left">0.007590</td>
<td align="left">0.049550</td>
<td align="left">0.000630</td>
<td align="center">349</td>
<td align="center">25</td>
<td align="center">316</td>
<td align="center">6</td>
<td align="center">312</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">HYS1-17</td>
<td align="left">3.45</td>
<td align="left">206.05</td>
<td align="left">370.41</td>
<td align="left">0.56</td>
<td align="left">0.051420</td>
<td align="left">0.000870</td>
<td align="left">0.354760</td>
<td align="left">0.006160</td>
<td align="left">0.049980</td>
<td align="left">0.000520</td>
<td align="center">260</td>
<td align="center">22</td>
<td align="center">308</td>
<td align="center">5</td>
<td align="center">314</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SJQ1-01</td>
<td align="left">3.14</td>
<td align="left">194.50</td>
<td align="left">440.06</td>
<td align="left">0.44</td>
<td align="left">0.053730</td>
<td align="left">0.001210</td>
<td align="left">0.367200</td>
<td align="left">0.008610</td>
<td align="left">0.049880</td>
<td align="left">0.000960</td>
<td align="center">360</td>
<td align="center">24</td>
<td align="center">318</td>
<td align="center">6</td>
<td align="center">314</td>
<td align="left">6</td>
</tr>
<tr>
<td align="left">SJQ1-02</td>
<td align="left">5.47</td>
<td align="left">336.01</td>
<td align="left">881.45</td>
<td align="left">0.38</td>
<td align="left">0.053620</td>
<td align="left">0.000840</td>
<td align="left">0.379880</td>
<td align="left">0.007880</td>
<td align="left">0.051510</td>
<td align="left">0.000810</td>
<td align="center">355</td>
<td align="center">22</td>
<td align="center">327</td>
<td align="center">6</td>
<td align="center">324</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SJQ1-03</td>
<td align="left">4.84</td>
<td align="left">315.23</td>
<td align="left">760.23</td>
<td align="left">0.41</td>
<td align="left">0.053370</td>
<td align="left">0.000880</td>
<td align="left">0.378660</td>
<td align="left">0.009860</td>
<td align="left">0.051410</td>
<td align="left">0.000880</td>
<td align="center">344</td>
<td align="center">30</td>
<td align="center">326</td>
<td align="center">7</td>
<td align="center">323</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SJQ1-04</td>
<td align="left">4.27</td>
<td align="left">262.06</td>
<td align="left">561.53</td>
<td align="left">0.47</td>
<td align="left">0.053700</td>
<td align="left">0.001250</td>
<td align="left">0.371230</td>
<td align="left">0.008050</td>
<td align="left">0.050140</td>
<td align="left">0.000760</td>
<td align="center">359</td>
<td align="center">24</td>
<td align="center">321</td>
<td align="center">6</td>
<td align="center">315</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SJQ1-05</td>
<td align="left">3.23</td>
<td align="left">201.63</td>
<td align="left">496.38</td>
<td align="left">0.41</td>
<td align="left">0.054110</td>
<td align="left">0.001060</td>
<td align="left">0.374700</td>
<td align="left">0.009280</td>
<td align="left">0.050370</td>
<td align="left">0.000880</td>
<td align="center">376</td>
<td align="center">27</td>
<td align="center">323</td>
<td align="center">7</td>
<td align="center">317</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SJQ1-06</td>
<td align="left">1.21</td>
<td align="left">77.62</td>
<td align="left">174.31</td>
<td align="left">0.45</td>
<td align="left">0.053240</td>
<td align="left">0.001410</td>
<td align="left">0.376060</td>
<td align="left">0.012020</td>
<td align="left">0.051320</td>
<td align="left">0.000940</td>
<td align="center">339</td>
<td align="center">40</td>
<td align="center">324</td>
<td align="center">9</td>
<td align="center">323</td>
<td align="left">6</td>
</tr>
<tr>
<td align="left">SJQ1-07</td>
<td align="left">8.44</td>
<td align="left">531.26</td>
<td align="left">1239.19</td>
<td align="left">0.43</td>
<td align="left">0.053930</td>
<td align="left">0.000600</td>
<td align="left">0.376990</td>
<td align="left">0.004800</td>
<td align="left">0.050780</td>
<td align="left">0.000510</td>
<td align="center">368</td>
<td align="center">13</td>
<td align="center">325</td>
<td align="center">4</td>
<td align="center">319</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SJQ1-08</td>
<td align="left">1.31</td>
<td align="left">82.69</td>
<td align="left">170.20</td>
<td align="left">0.49</td>
<td align="left">0.053520</td>
<td align="left">0.001210</td>
<td align="left">0.370540</td>
<td align="left">0.008650</td>
<td align="left">0.050470</td>
<td align="left">0.000640</td>
<td align="center">351</td>
<td align="center">30</td>
<td align="center">320</td>
<td align="center">6</td>
<td align="center">317</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SJQ1-09</td>
<td align="left">2.34</td>
<td align="left">144.33</td>
<td align="left">356.43</td>
<td align="left">0.40</td>
<td align="left">0.053110</td>
<td align="left">0.001000</td>
<td align="left">0.378180</td>
<td align="left">0.007760</td>
<td align="left">0.051540</td>
<td align="left">0.000600</td>
<td align="center">334</td>
<td align="center">26</td>
<td align="center">326</td>
<td align="center">6</td>
<td align="center">324</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SJQ1-10</td>
<td align="left">8.67</td>
<td align="left">554.01</td>
<td align="left">1095.79</td>
<td align="left">0.51</td>
<td align="left">0.052800</td>
<td align="left">0.000850</td>
<td align="left">0.372820</td>
<td align="left">0.007520</td>
<td align="left">0.051260</td>
<td align="left">0.000810</td>
<td align="center">320</td>
<td align="center">21</td>
<td align="center">322</td>
<td align="center">6</td>
<td align="center">322</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SJQ1-11</td>
<td align="left">4.36</td>
<td align="left">290.66</td>
<td align="left">846.67</td>
<td align="left">0.34</td>
<td align="left">0.052980</td>
<td align="left">0.000740</td>
<td align="left">0.373900</td>
<td align="left">0.005420</td>
<td align="left">0.051120</td>
<td align="left">0.000460</td>
<td align="center">328</td>
<td align="center">17</td>
<td align="center">323</td>
<td align="center">4</td>
<td align="center">321</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SJQ1-12</td>
<td align="left">2.94</td>
<td align="left">191.66</td>
<td align="left">453.04</td>
<td align="left">0.42</td>
<td align="left">0.052700</td>
<td align="left">0.001060</td>
<td align="left">0.368570</td>
<td align="left">0.008200</td>
<td align="left">0.050680</td>
<td align="left">0.000630</td>
<td align="center">316</td>
<td align="center">29</td>
<td align="center">319</td>
<td align="center">6</td>
<td align="center">319</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SJQ1-13</td>
<td align="left">4.31</td>
<td align="left">275.08</td>
<td align="left">603.99</td>
<td align="left">0.46</td>
<td align="left">0.053740</td>
<td align="left">0.000930</td>
<td align="left">0.374870</td>
<td align="left">0.007830</td>
<td align="left">0.050400</td>
<td align="left">0.000700</td>
<td align="center">360</td>
<td align="center">24</td>
<td align="center">323</td>
<td align="center">6</td>
<td align="center">317</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SJQ1-14</td>
<td align="left">2.22</td>
<td align="left">136.02</td>
<td align="left">320.21</td>
<td align="left">0.42</td>
<td align="left">0.052890</td>
<td align="left">0.001050</td>
<td align="left">0.380300</td>
<td align="left">0.009380</td>
<td align="left">0.051750</td>
<td align="left">0.000680</td>
<td align="center">324</td>
<td align="center">33</td>
<td align="center">327</td>
<td align="center">7</td>
<td align="center">325</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SJQ1-15</td>
<td align="left">2.39</td>
<td align="left">152.18</td>
<td align="left">345.27</td>
<td align="left">0.44</td>
<td align="left">0.053090</td>
<td align="left">0.000970</td>
<td align="left">0.369160</td>
<td align="left">0.006950</td>
<td align="left">0.050370</td>
<td align="left">0.000550</td>
<td align="center">333</td>
<td align="center">24</td>
<td align="center">319</td>
<td align="center">5</td>
<td align="center">317</td>
<td align="left">3</td>
</tr>
<tr>
<td align="left">SJQ1-16</td>
<td align="left">0.50</td>
<td align="left">30.80</td>
<td align="left">77.59</td>
<td align="left">0.40</td>
<td align="left">0.053520</td>
<td align="left">0.002010</td>
<td align="left">0.363460</td>
<td align="left">0.012620</td>
<td align="left">0.049640</td>
<td align="left">0.000760</td>
<td align="center">351</td>
<td align="center">51</td>
<td align="center">315</td>
<td align="center">9</td>
<td align="center">312</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-01</td>
<td align="left">5.30</td>
<td align="left">335.55</td>
<td align="left">669.28</td>
<td align="left">0.50</td>
<td align="left">0.053080</td>
<td align="left">0.000740</td>
<td align="left">0.374290</td>
<td align="left">0.007570</td>
<td align="left">0.051190</td>
<td align="left">0.000840</td>
<td align="center">332.0</td>
<td align="center">21</td>
<td align="center">323</td>
<td align="center">6</td>
<td align="center">322</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-02</td>
<td align="left">2.29</td>
<td align="left">135.40</td>
<td align="left">312.47</td>
<td align="left">0.43</td>
<td align="left">0.054510</td>
<td align="left">0.001240</td>
<td align="left">0.363610</td>
<td align="left">0.009330</td>
<td align="left">0.048500</td>
<td align="left">0.000780</td>
<td align="center">392.0</td>
<td align="center">30</td>
<td align="center">315</td>
<td align="center">7</td>
<td align="center">305</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-03</td>
<td align="left">2.22</td>
<td align="left">134.07</td>
<td align="left">310.89</td>
<td align="left">0.43</td>
<td align="left">0.054160</td>
<td align="left">0.000850</td>
<td align="left">0.380450</td>
<td align="left">0.008250</td>
<td align="left">0.051060</td>
<td align="left">0.000880</td>
<td align="center">378.0</td>
<td align="center">22</td>
<td align="center">327</td>
<td align="center">6</td>
<td align="center">321</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-04</td>
<td align="left">4.59</td>
<td align="left">271.00</td>
<td align="left">586.89</td>
<td align="left">0.46</td>
<td align="left">0.054280</td>
<td align="left">0.000790</td>
<td align="left">0.383040</td>
<td align="left">0.007090</td>
<td align="left">0.051370</td>
<td align="left">0.000790</td>
<td align="center">383.0</td>
<td align="center">19</td>
<td align="center">329</td>
<td align="center">5</td>
<td align="center">323</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-05</td>
<td align="left">4.16</td>
<td align="left">223.42</td>
<td align="left">510.96</td>
<td align="left">0.44</td>
<td align="left">0.054940</td>
<td align="left">0.002960</td>
<td align="left">0.390150</td>
<td align="left">0.019770</td>
<td align="left">0.051500</td>
<td align="left">0.000950</td>
<td align="center">410.0</td>
<td align="center">124</td>
<td align="center">334</td>
<td align="center">14</td>
<td align="center">324</td>
<td align="left">6</td>
</tr>
<tr>
<td align="left">SBMME1-06</td>
<td align="left">2.35</td>
<td align="left">149.63</td>
<td align="left">341.51</td>
<td align="left">0.44</td>
<td align="left">0.054250</td>
<td align="left">0.001070</td>
<td align="left">0.372810</td>
<td align="left">0.008900</td>
<td align="left">0.049800</td>
<td align="left">0.000740</td>
<td align="center">382.0</td>
<td align="center">28</td>
<td align="center">322</td>
<td align="center">7</td>
<td align="center">313</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-07</td>
<td align="left">4.47</td>
<td align="left">265.49</td>
<td align="left">544.60</td>
<td align="left">0.49</td>
<td align="left">0.054370</td>
<td align="left">0.001080</td>
<td align="left">0.371630</td>
<td align="left">0.007750</td>
<td align="left">0.049660</td>
<td align="left">0.000720</td>
<td align="center">386.0</td>
<td align="center">23</td>
<td align="center">321</td>
<td align="center">6</td>
<td align="center">312</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SBMME1-08</td>
<td align="left">1.63</td>
<td align="left">102.70</td>
<td align="left">247.05</td>
<td align="left">0.42</td>
<td align="left">0.054310</td>
<td align="left">0.001500</td>
<td align="left">0.368720</td>
<td align="left">0.010110</td>
<td align="left">0.049510</td>
<td align="left">0.000760</td>
<td align="center">384.0</td>
<td align="center">35</td>
<td align="center">319</td>
<td align="center">7</td>
<td align="center">311</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-09</td>
<td align="left">5.56</td>
<td align="left">349.52</td>
<td align="left">656.72</td>
<td align="left">0.53</td>
<td align="left">0.053730</td>
<td align="left">0.000870</td>
<td align="left">0.361480</td>
<td align="left">0.007240</td>
<td align="left">0.048800</td>
<td align="left">0.000690</td>
<td align="center">360.0</td>
<td align="center">22</td>
<td align="center">313</td>
<td align="center">5</td>
<td align="center">307</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SBMME1-10</td>
<td align="left">2.57</td>
<td align="left">153.23</td>
<td align="left">349.44</td>
<td align="left">0.44</td>
<td align="left">0.054040</td>
<td align="left">0.003540</td>
<td align="left">0.369540</td>
<td align="left">0.023490</td>
<td align="left">0.049600</td>
<td align="left">0.000780</td>
<td align="center">373.0</td>
<td align="center">151</td>
<td align="center">319</td>
<td align="center">17</td>
<td align="center">312</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">SBMME1-11</td>
<td align="left">2.74</td>
<td align="left">171.18</td>
<td align="left">334.60</td>
<td align="left">0.51</td>
<td align="left">0.053220</td>
<td align="left">0.001020</td>
<td align="left">0.368330</td>
<td align="left">0.007930</td>
<td align="left">0.050210</td>
<td align="left">0.000660</td>
<td align="center">338.0</td>
<td align="center">26</td>
<td align="center">318</td>
<td align="center">6</td>
<td align="center">316</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SBMME1-12</td>
<td align="left">5.90</td>
<td align="left">388.32</td>
<td align="left">663.16</td>
<td align="left">0.59</td>
<td align="left">0.053440</td>
<td align="left">0.001000</td>
<td align="left">0.361310</td>
<td align="left">0.007990</td>
<td align="left">0.049050</td>
<td align="left">0.000670</td>
<td align="center">348.0</td>
<td align="center">27</td>
<td align="center">313</td>
<td align="center">6</td>
<td align="center">309</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SBMME1-13</td>
<td align="left">1.73</td>
<td align="left">107.69</td>
<td align="left">278.19</td>
<td align="left">0.39</td>
<td align="left">0.052960</td>
<td align="left">0.001120</td>
<td align="left">0.361380</td>
<td align="left">0.008740</td>
<td align="left">0.049440</td>
<td align="left">0.000700</td>
<td align="center">327.0</td>
<td align="center">30</td>
<td align="center">313</td>
<td align="center">7</td>
<td align="center">311</td>
<td align="left">4</td>
</tr>
<tr>
<td align="left">SBMME1-14</td>
<td align="left">3.31</td>
<td align="left">210.17</td>
<td align="left">401.74</td>
<td align="left">0.52</td>
<td align="left">0.052370</td>
<td align="left">0.001000</td>
<td align="left">0.372110</td>
<td align="left">0.009890</td>
<td align="left">0.051340</td>
<td align="left">0.000910</td>
<td align="center">302.0</td>
<td align="center">31</td>
<td align="center">321</td>
<td align="center">7</td>
<td align="center">323</td>
<td align="left">6</td>
</tr>
</tbody>
</table>
</table-wrap>
<sec id="s5-1-1">
<title>5.1.1 Zircon geochronology of granites</title>
<p>The zircons in the monzogranite, biotite syenogranite, and biotite granite samples are subhedral to euhedral, predominantly showing elongated prismatic morphology with well-developed bipyramidal terminations (120&#x2013;230 &#x3bc;m), with aspect ratios ranging from 1.5:1 to 3:1. Clear oscillatory bands and nucleation rims are observed in the CL images of the zircons (<xref ref-type="fig" rid="F3">Figures 3a&#x2013;c</xref>); these zones have Th/U values higher than 0.1 indicating distinct magmatic characteristics (<xref ref-type="bibr" rid="B42">Hoskin and Ireland, 2000</xref>; <xref ref-type="bibr" rid="B10">Belousova et al., 2002</xref>). The dates obtained from the zircons of the plutons are less than 1,000 Ma, therefore, the <sup>206</sup>Pb/<sup>238</sup>U dates are adopted.</p>
<p>Analysis of 19 spots in sample SB1 from the Sabei pluton shows Th and U contents of zircons ranging from 79.26&#x2013;318.50 ppm to 177.27&#x2013;734.71 ppm, respectively. The Th/U ratio of the zircons ranges from 0.38 to 0.59 indicating a magmatic origin of the zircon. The test points on the samples fall predominantly on or near the Concordia, with the degree of concordance greater than 95%. The weighted average <sup>206</sup>Pb/<sup>238</sup>U age of 315.9 &#xb1; 2.4 Ma (MSWD &#x3d; 1.3, <italic>n</italic> &#x3d; 17) (<xref ref-type="fig" rid="F3">Figure 3a</xref>) indicates a Late Carboniferous crystallization age for the monzogranite.</p>
<p>Analysis of 17 spots from zircons in sample HYS1 from the Huangyangshan pluton shows significant variation in the Th and U contents of the zircons, with values of 42.59&#x2013;766.04 ppm and 117.92&#x2013;850.62 ppm, respectively, and a Th/U ratio ranging from 0.33 to 0.90, suggesting a magmatic origin of the zircons. The age concordance of the 17 test points is within the 95% confidence interval, and the weighted average <sup>206</sup>Pb/<sup>238</sup>U age is 316.1 &#xb1; 2.2 Ma (MSWD &#x3d; 1.3, <italic>n</italic> &#x3d; 17) (<xref ref-type="fig" rid="F3">Figure 3b</xref>), indicating a Late Carboniferous crystallization age for the biotite syenogranite.</p>
<p>Analysis of 16 target points in sample SJQ1 from the Sujiquan rock mass shows Th and U contents of 30.80&#x2013;554.01 ppm and 77.59&#x2013;1095.79 ppm, respectively, with Th/U ratios of 0.34&#x2013;0.51, indicating a magmatic origin of the zircon. The analysis point has a consistent concordant age, and its <sup>206</sup>Pb/<sup>238</sup>U weighted average age is 319.4 &#xb1; 2.0 Ma (MSWD &#x3d; 0.73, <italic>n</italic> &#x3d; 16) (<xref ref-type="fig" rid="F3">Figure 3c</xref>), also indicating a Late Carboniferous crystallization age for the biotite granite.</p>
</sec>
<sec id="s5-1-2">
<title>5.1.2 Zircon geochronology of MMEs</title>
<p>The zircons in the MMEs of the Sabei pluton are subhedral prismatic crystals. They are colorless and transparent, with bipyramidal terminations. Individual zircons are rounded, with grain widths and lengths ranging from 50 to 110 &#x3bc;m &#xd7; 90 to 240 &#x3bc;m. The internal morphology of the zircons does not vary significantly in the CL images, with clear oscillatory zones and core-rim structures. The characteristics of the gaps in some zircons indicate that they may have been affected by dissolution at some point. Th and U contents of 102.70&#x2013;388.32 ppm and 247.05&#x2013;669.28 ppm are obtained, respectively, with Th/U ratios of 0.39&#x2013;0.59. The morphology, structure, and Th/U ratio of the zircons indicate a magmatic origin for this group of zircons. The weighted average <sup>206</sup>Pb/<sup>238</sup>U age of 313.9 &#xb1; 3.5 Ma (MSWD &#x3d; 1.7, <italic>n</italic> &#x3d; 14) (<xref ref-type="fig" rid="F3">Figure 3d</xref>) likely represents the crystallization age of the MMEs, i.e., the Late Carboniferous, which is similar to that of the host monzogranite.</p>
</sec>
</sec>
<sec id="s5-2">
<title>5.2 Whole-rock major elements</title>
<p>The results for the whole-rock major, trace, and rare earth elements (REEs) in the Sabei, Huangyangshan, and Sujiquan plutons and the MMEs are listed in <xref ref-type="table" rid="T2">Table 2</xref>. The three plutons have high contents of silicon (76.30&#x2013;77.41 wt%), potassium (4.04&#x2013;4.67 wt%), alkali (Na<sub>2</sub>O &#x2b; K<sub>2</sub>O &#x3d; 8.18&#x2013;8.80 wt%), and Na<sub>2</sub>O (3.98&#x2013;4.40 wt%); the total alkali mass fraction exceeds 8%, indicating the rock is subalkaline. The Mg&#x23; value ranges from 8.6 to 35.3. The aluminum saturation index (A/CNK) is 0.94&#x2013;0.99, and A/NK is 0.97&#x2013;1.06.</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Major (%), trace (&#xd7;10<sup>&#x2013;6</sup>), and rare earth elemental (&#xd7;10<sup>&#x2013;6</sup>) compositions of rocks from the Sabei, Huangyangshan, and Sujiquan plutons.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Pluton</th>
<th colspan="4" align="left">Sabei Pluton</th>
<th colspan="4" align="left">Huangyangshan Pluton</th>
<th colspan="4" align="left">Sujiquan Pluton</th>
<th colspan="3" align="left">MMEs</th>
</tr>
<tr>
<th align="left">Sample</th>
<th align="left">SB1</th>
<th align="left">SB2</th>
<th align="left">SB3</th>
<th align="left">SB4</th>
<th align="left">HYS1</th>
<th align="left">HYS2</th>
<th align="left">HYS3</th>
<th align="left">HYS4</th>
<th align="left">SJQ1</th>
<th align="left">SJQ2</th>
<th align="left">SJQ3</th>
<th align="left">SJQ4</th>
<th align="left">SBMME1</th>
<th align="left">SBMME2</th>
<th align="left">SBMME3</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">SiO<sub>2</sub>
</td>
<td align="left">76.30</td>
<td align="left">76.92</td>
<td align="left">77.41</td>
<td align="left">77.29</td>
<td align="left">76.61</td>
<td align="left">76.37</td>
<td align="left">77.49</td>
<td align="left">76.61</td>
<td align="left">77.30</td>
<td align="left">76.72</td>
<td align="left">77.12</td>
<td align="left">77.38</td>
<td align="left">67.33</td>
<td align="left">55.37</td>
<td align="left">63.29</td>
</tr>
<tr>
<td align="left">TiO<sub>2</sub>
</td>
<td align="left">0.05</td>
<td align="left">0.22</td>
<td align="left">0.07</td>
<td align="left">0.07</td>
<td align="left">0.04</td>
<td align="left">0.06</td>
<td align="left">0.09</td>
<td align="left">0.08</td>
<td align="left">0.10</td>
<td align="left">0.08</td>
<td align="left">0.07</td>
<td align="left">0.07</td>
<td align="left">0.52</td>
<td align="left">0.88</td>
<td align="left">0.70</td>
</tr>
<tr>
<td align="left">Al<sub>2</sub>O<sub>3</sub>
</td>
<td align="left">12.14</td>
<td align="left">11.25</td>
<td align="left">11.51</td>
<td align="left">12.15</td>
<td align="left">12.29</td>
<td align="left">12.28</td>
<td align="left">11.54</td>
<td align="left">12.29</td>
<td align="left">11.50</td>
<td align="left">12.11</td>
<td align="left">12.17</td>
<td align="left">11.97</td>
<td align="left">14.93</td>
<td align="left">16.26</td>
<td align="left">15.59</td>
</tr>
<tr>
<td align="left">TFe<sub>2</sub>O<sub>3</sub>
</td>
<td align="left">1.41</td>
<td align="left">1.84</td>
<td align="left">1.18</td>
<td align="left">0.71</td>
<td align="left">0.98</td>
<td align="left">0.89</td>
<td align="left">0.97</td>
<td align="left">1.09</td>
<td align="left">1.72</td>
<td align="left">0.95</td>
<td align="left">0.75</td>
<td align="left">0.88</td>
<td align="left">3.47</td>
<td align="left">7.57</td>
<td align="left">5.52</td>
</tr>
<tr>
<td align="left">FeO</td>
<td align="left">0.46</td>
<td align="left">0.69</td>
<td align="left">0.78</td>
<td align="left">0.44</td>
<td align="left">0.46</td>
<td align="left">0.81</td>
<td align="left">0.75</td>
<td align="left">0.31</td>
<td align="left">0.84</td>
<td align="left">0.57</td>
<td align="left">0.50</td>
<td align="left">0.38</td>
<td align="left">1.61</td>
<td align="left">4.73</td>
<td align="left">3.17</td>
</tr>
<tr>
<td align="left">MnO</td>
<td align="left">0.03</td>
<td align="left">0.05</td>
<td align="left">0.01</td>
<td align="left">0.03</td>
<td align="left">0.04</td>
<td align="left">0.01</td>
<td align="left">0.02</td>
<td align="left">0.02</td>
<td align="left">0.04</td>
<td align="left">0.02</td>
<td align="left">0.04</td>
<td align="left">0.02</td>
<td align="left">0.08</td>
<td align="left">0.19</td>
<td align="left">0.13</td>
</tr>
<tr>
<td align="left">MgO</td>
<td align="left">0.09</td>
<td align="left">0.16</td>
<td align="left">0.10</td>
<td align="left">0.19</td>
<td align="left">0.06</td>
<td align="left">0.07</td>
<td align="left">0.26</td>
<td align="left">0.25</td>
<td align="left">0.09</td>
<td align="left">0.21</td>
<td align="left">0.23</td>
<td align="left">0.18</td>
<td align="left">1.71</td>
<td align="left">5.26</td>
<td align="left">2.45</td>
</tr>
<tr>
<td align="left">CaO</td>
<td align="left">0.40</td>
<td align="left">0.21</td>
<td align="left">0.35</td>
<td align="left">0.21</td>
<td align="left">0.42</td>
<td align="left">0.41</td>
<td align="left">0.45</td>
<td align="left">0.46</td>
<td align="left">0.19</td>
<td align="left">0.36</td>
<td align="left">0.42</td>
<td align="left">0.39</td>
<td align="left">3.05</td>
<td align="left">6.97</td>
<td align="left">4.37</td>
</tr>
<tr>
<td align="left">Na<sub>2</sub>O</td>
<td align="left">4.14</td>
<td align="left">3.98</td>
<td align="left">4.28</td>
<td align="left">4.21</td>
<td align="left">4.23</td>
<td align="left">4.38</td>
<td align="left">4.08</td>
<td align="left">3.99</td>
<td align="left">4.28</td>
<td align="left">4.40</td>
<td align="left">4.24</td>
<td align="left">4.25</td>
<td align="left">3.49</td>
<td align="left">4.19</td>
<td align="left">3.38</td>
</tr>
<tr>
<td align="left">K<sub>2</sub>O</td>
<td align="left">4.51</td>
<td align="left">4.67</td>
<td align="left">4.04</td>
<td align="left">4.59</td>
<td align="left">4.30</td>
<td align="left">4.38</td>
<td align="left">4.10</td>
<td align="left">4.62</td>
<td align="left">4.26</td>
<td align="left">4.34</td>
<td align="left">4.25</td>
<td align="left">4.31</td>
<td align="left">3.51</td>
<td align="left">1.70</td>
<td align="left">2.89</td>
</tr>
<tr>
<td align="left">P<sub>2</sub>O<sub>5</sub>
</td>
<td align="left">0.01</td>
<td align="left">0.03</td>
<td align="left">0.01</td>
<td align="left">0.02</td>
<td align="left">0.01</td>
<td align="left">0.01</td>
<td align="left">0.02</td>
<td align="left">0.03</td>
<td align="left">0.02</td>
<td align="left">0.01</td>
<td align="left">0.02</td>
<td align="left">0.01</td>
<td align="left">0.13</td>
<td align="left">0.17</td>
<td align="left">0.15</td>
</tr>
<tr>
<td align="left">LOI</td>
<td align="left">0.57</td>
<td align="left">0.39</td>
<td align="left">0.56</td>
<td align="left">0.23</td>
<td align="left">0.35</td>
<td align="left">0.83</td>
<td align="left">0.79</td>
<td align="left">0.28</td>
<td align="left">0.26</td>
<td align="left">0.57</td>
<td align="left">0.51</td>
<td align="left">0.38</td>
<td align="left">1.10</td>
<td align="left">1.24</td>
<td align="left">1.17</td>
</tr>
<tr>
<td align="left">Total</td>
<td align="left">99.65</td>
<td align="left">99.74</td>
<td align="left">99.52</td>
<td align="left">99.70</td>
<td align="left">99.31</td>
<td align="left">99.69</td>
<td align="left">99.81</td>
<td align="left">99.72</td>
<td align="left">99.77</td>
<td align="left">99.77</td>
<td align="left">99.82</td>
<td align="left">99.84</td>
<td align="left">99.33</td>
<td align="left">99.81</td>
<td align="left">99.66</td>
</tr>
<tr>
<td align="left">Tzr (&#xb0;C)</td>
<td align="left">839</td>
<td align="left">798</td>
<td align="left">733</td>
<td align="left">789</td>
<td align="left">797</td>
<td align="left">796</td>
<td align="left">803</td>
<td align="left">838</td>
<td align="left">892</td>
<td align="left">788</td>
<td align="left">815</td>
<td align="left">789</td>
<td align="left">739</td>
<td align="left">654</td>
<td align="left">718</td>
</tr>
<tr>
<td align="left">A/CNK</td>
<td align="left">0.98</td>
<td align="left">0.94</td>
<td align="left">0.95</td>
<td align="left">0.99</td>
<td align="left">0.99</td>
<td align="left">0.97</td>
<td align="left">0.96</td>
<td align="left">0.99</td>
<td align="left">0.96</td>
<td align="left">0.96</td>
<td align="left">0.99</td>
<td align="left">0.97</td>
<td align="left">0.99</td>
<td align="left">0.76</td>
<td align="left">0.94</td>
</tr>
<tr>
<td align="left">A/NK</td>
<td align="left">1.04</td>
<td align="left">0.97</td>
<td align="left">1.01</td>
<td align="left">1.02</td>
<td align="left">1.06</td>
<td align="left">1.03</td>
<td align="left">1.03</td>
<td align="left">1.06</td>
<td align="left">0.99</td>
<td align="left">1.01</td>
<td align="left">1.05</td>
<td align="left">1.03</td>
<td align="left">1.56</td>
<td align="left">1.86</td>
<td align="left">1.79</td>
</tr>
<tr>
<td align="left">Na<sub>2</sub>O &#x2b; K<sub>2</sub>O</td>
<td align="left">8.65</td>
<td align="left">8.66</td>
<td align="left">8.32</td>
<td align="left">8.80</td>
<td align="left">8.53</td>
<td align="left">8.76</td>
<td align="left">8.18</td>
<td align="left">8.61</td>
<td align="left">8.54</td>
<td align="left">8.74</td>
<td align="left">8.49</td>
<td align="left">8.56</td>
<td align="left">7.00</td>
<td align="left">5.89</td>
<td align="left">6.27</td>
</tr>
<tr>
<td align="left">K<sub>2</sub>O/Na<sub>2</sub>O</td>
<td align="left">1.09</td>
<td align="left">1.17</td>
<td align="left">0.94</td>
<td align="left">1.09</td>
<td align="left">1.02</td>
<td align="left">1.00</td>
<td align="left">1.00</td>
<td align="left">1.16</td>
<td align="left">1.00</td>
<td align="left">0.99</td>
<td align="left">1.00</td>
<td align="left">1.01</td>
<td align="left">1.01</td>
<td align="left">0.41</td>
<td align="left">0.86</td>
</tr>
<tr>
<td align="left">AR</td>
<td align="left">5.44</td>
<td align="left">7.17</td>
<td align="left">5.70</td>
<td align="left">5.94</td>
<td align="left">5.09</td>
<td align="left">5.46</td>
<td align="left">5.29</td>
<td align="left">5.16</td>
<td align="left">6.43</td>
<td align="left">5.69</td>
<td align="left">5.14</td>
<td align="left">5.51</td>
<td align="left">2.28</td>
<td align="left">1.68</td>
<td align="left">1.92</td>
</tr>
<tr>
<td align="left">Sc</td>
<td align="left">1.1</td>
<td align="left">1.8</td>
<td align="left">3.5</td>
<td align="left">4.2</td>
<td align="left">1.5</td>
<td align="left">1.8</td>
<td align="left">1.5</td>
<td align="left">3.4</td>
<td align="left">1.1</td>
<td align="left">2.6</td>
<td align="left">3.2</td>
<td align="left">2.6</td>
<td align="left">8.5</td>
<td align="left">18.2</td>
<td align="left">15.4</td>
</tr>
<tr>
<td align="left">V</td>
<td align="left">2.3</td>
<td align="left">3.6</td>
<td align="left">16.0</td>
<td align="left">25.8</td>
<td align="left">2.2</td>
<td align="left">10.9</td>
<td align="left">18.2</td>
<td align="left">2.0</td>
<td align="left">2.6</td>
<td align="left">11.2</td>
<td align="left">1.8</td>
<td align="left">3.9</td>
<td align="left">37.6</td>
<td align="left">125.4</td>
<td align="left">94.5</td>
</tr>
<tr>
<td align="left">Cr</td>
<td align="left">2.3</td>
<td align="left">4.2</td>
<td align="left">7.6</td>
<td align="left">8.7</td>
<td align="left">1.8</td>
<td align="left">5.2</td>
<td align="left">68.9</td>
<td align="left">0.9</td>
<td align="left">2.5</td>
<td align="left">5.6</td>
<td align="left">1.0</td>
<td align="left">0.9</td>
<td align="left">12.5</td>
<td align="left">128.6</td>
<td align="left">40.6</td>
</tr>
<tr>
<td align="left">Co</td>
<td align="left">2.0</td>
<td align="left">2.2</td>
<td align="left">3.5</td>
<td align="left">1.1</td>
<td align="left">2.0</td>
<td align="left">2.0</td>
<td align="left">0.5</td>
<td align="left">0.4</td>
<td align="left">2.0</td>
<td align="left">2.6</td>
<td align="left">0.4</td>
<td align="left">0.3</td>
<td align="left">11.2</td>
<td align="left">22.4</td>
<td align="left">18.8</td>
</tr>
<tr>
<td align="left">Ni</td>
<td align="left">1.2</td>
<td align="left">1.8</td>
<td align="left">4.3</td>
<td align="left">5.3</td>
<td align="left">0.5</td>
<td align="left">2.7</td>
<td align="left">5.1</td>
<td align="left">0.8</td>
<td align="left">1.5</td>
<td align="left">3.0</td>
<td align="left">0.8</td>
<td align="left">0.5</td>
<td align="left">9.9</td>
<td align="left">50.0</td>
<td align="left">29.9</td>
</tr>
<tr>
<td align="left">Cu</td>
<td align="left">4.7</td>
<td align="left">7.6</td>
<td align="left">13.3</td>
<td align="left">3.8</td>
<td align="left">25.9</td>
<td align="left">11.3</td>
<td align="left">2.4</td>
<td align="left">3.8</td>
<td align="left">5.5</td>
<td align="left">11.6</td>
<td align="left">4.1</td>
<td align="left">2.4</td>
<td align="left">17.2</td>
<td align="left">75.2</td>
<td align="left">56.2</td>
</tr>
<tr>
<td align="left">Zn</td>
<td align="left">133.9</td>
<td align="left">135.2</td>
<td align="left">121.5</td>
<td align="left">52.3</td>
<td align="left">106.3</td>
<td align="left">128.3</td>
<td align="left">50.9</td>
<td align="left">48.7</td>
<td align="left">111.3</td>
<td align="left">114.7</td>
<td align="left">49.1</td>
<td align="left">42.9</td>
<td align="left">48.4</td>
<td align="left">92.3</td>
<td align="left">77.3</td>
</tr>
<tr>
<td align="left">W</td>
<td align="left">0.5</td>
<td align="left">0.5</td>
<td align="left">0.7</td>
<td align="left">0.6</td>
<td align="left">1.5</td>
<td align="left">0.8</td>
<td align="left">0.6</td>
<td align="left">0.8</td>
<td align="left">0.2</td>
<td align="left">0.7</td>
<td align="left">0.5</td>
<td align="left">0.8</td>
<td align="left">0.5</td>
<td align="left">2.5</td>
<td align="left">1.6</td>
</tr>
<tr>
<td align="left">Ga</td>
<td align="left">28.6</td>
<td align="left">20.7</td>
<td align="left">18.9</td>
<td align="left">25.3</td>
<td align="left">22.8</td>
<td align="left">19.9</td>
<td align="left">25.9</td>
<td align="left">26.2</td>
<td align="left">22.7</td>
<td align="left">20.5</td>
<td align="left">25.7</td>
<td align="left">23.9</td>
<td align="left">14.8</td>
<td align="left">17.4</td>
<td align="left">16.8</td>
</tr>
<tr>
<td align="left">Rb</td>
<td align="left">228.8</td>
<td align="left">210.6</td>
<td align="left">178.5</td>
<td align="left">345.9</td>
<td align="left">333.6</td>
<td align="left">194.5</td>
<td align="left">358.1</td>
<td align="left">332.4</td>
<td align="left">146.2</td>
<td align="left">231.1</td>
<td align="left">335.3</td>
<td align="left">321.8</td>
<td align="left">112.3</td>
<td align="left">69.3</td>
<td align="left">98.8</td>
</tr>
<tr>
<td align="left">Sr</td>
<td align="left">6.1</td>
<td align="left">7.8</td>
<td align="left">6.5</td>
<td align="left">3.9</td>
<td align="left">3.2</td>
<td align="left">5.3</td>
<td align="left">5.8</td>
<td align="left">11.6</td>
<td align="left">3.8</td>
<td align="left">37.5</td>
<td align="left">11.7</td>
<td align="left">7.3</td>
<td align="left">298.3</td>
<td align="left">297.3</td>
<td align="left">290.4</td>
</tr>
<tr>
<td align="left">Y</td>
<td align="left">153.2</td>
<td align="left">48.9</td>
<td align="left">141.5</td>
<td align="left">115.8</td>
<td align="left">122.3</td>
<td align="left">114.6</td>
<td align="left">156.2</td>
<td align="left">98.9</td>
<td align="left">54.1</td>
<td align="left">103.8</td>
<td align="left">99.8</td>
<td align="left">95.6</td>
<td align="left">23.0</td>
<td align="left">48.2</td>
<td align="left">38.6</td>
</tr>
<tr>
<td align="left">Zr</td>
<td align="left">292.6</td>
<td align="left">194.5</td>
<td align="left">87.2</td>
<td align="left">165.7</td>
<td align="left">181.2</td>
<td align="left">187.3</td>
<td align="left">197.2</td>
<td align="left">285.6</td>
<td align="left">503.2</td>
<td align="left">169.8</td>
<td align="left">221.9</td>
<td align="left">169.5</td>
<td align="left">107.9</td>
<td align="left">79.8</td>
<td align="left">98.9</td>
</tr>
<tr>
<td align="left">Nb</td>
<td align="left">15.2</td>
<td align="left">17.2</td>
<td align="left">7.8</td>
<td align="left">17.9</td>
<td align="left">16.5</td>
<td align="left">9.2</td>
<td align="left">15.8</td>
<td align="left">15.9</td>
<td align="left">10.3</td>
<td align="left">12.7</td>
<td align="left">14.9</td>
<td align="left">12.8</td>
<td align="left">5.3</td>
<td align="left">8.3</td>
<td align="left">7.2</td>
</tr>
<tr>
<td align="left">Ba</td>
<td align="left">8.0</td>
<td align="left">8.2</td>
<td align="left">9.7</td>
<td align="left">27.0</td>
<td align="left">6.1</td>
<td align="left">19.3</td>
<td align="left">7.2</td>
<td align="left">31.9</td>
<td align="left">17.4</td>
<td align="left">54.2</td>
<td align="left">30.7</td>
<td align="left">7.9</td>
<td align="left">379.9</td>
<td align="left">162.3</td>
<td align="left">275.1</td>
</tr>
<tr>
<td align="left">Hf</td>
<td align="left">10.6</td>
<td align="left">10.0</td>
<td align="left">4.2</td>
<td align="left">9.1</td>
<td align="left">8.8</td>
<td align="left">9.0</td>
<td align="left">10.8</td>
<td align="left">13.9</td>
<td align="left">10.7</td>
<td align="left">7.8</td>
<td align="left">10.8</td>
<td align="left">9.1</td>
<td align="left">3.4</td>
<td align="left">2.9</td>
<td align="left">3.3</td>
</tr>
<tr>
<td align="left">Ta</td>
<td align="left">1.3</td>
<td align="left">1.1</td>
<td align="left">0.9</td>
<td align="left">2.9</td>
<td align="left">1.7</td>
<td align="left">1.2</td>
<td align="left">1.5</td>
<td align="left">2.4</td>
<td align="left">0.8</td>
<td align="left">1.5</td>
<td align="left">2.8</td>
<td align="left">1.9</td>
<td align="left">0.7</td>
<td align="left">0.8</td>
<td align="left">0.8</td>
</tr>
<tr>
<td align="left">Pb</td>
<td align="left">33.4</td>
<td align="left">30.7</td>
<td align="left">41.3</td>
<td align="left">29.7</td>
<td align="left">28.4</td>
<td align="left">37.3</td>
<td align="left">41.2</td>
<td align="left">29.8</td>
<td align="left">7.5</td>
<td align="left">35.1</td>
<td align="left">30.9</td>
<td align="left">29.8</td>
<td align="left">11.9</td>
<td align="left">7.1</td>
<td align="left">10.0</td>
</tr>
<tr>
<td align="left">Th</td>
<td align="left">19.5</td>
<td align="left">17.7</td>
<td align="left">12.9</td>
<td align="left">35.5</td>
<td align="left">17.7</td>
<td align="left">15.6</td>
<td align="left">41.7</td>
<td align="left">28.7</td>
<td align="left">7.3</td>
<td align="left">18.7</td>
<td align="left">33.8</td>
<td align="left">32.9</td>
<td align="left">11.2</td>
<td align="left">5.4</td>
<td align="left">8.9</td>
</tr>
<tr>
<td align="left">U</td>
<td align="left">8.0</td>
<td align="left">4.5</td>
<td align="left">6.5</td>
<td align="left">5.9</td>
<td align="left">3.9</td>
<td align="left">4.2</td>
<td align="left">6.8</td>
<td align="left">3.9</td>
<td align="left">2.0</td>
<td align="left">4.9</td>
<td align="left">3.1</td>
<td align="left">3.8</td>
<td align="left">2.2</td>
<td align="left">4.3</td>
<td align="left">3.4</td>
</tr>
<tr>
<td align="left">La</td>
<td align="left">38.63</td>
<td align="left">35.27</td>
<td align="left">15.24</td>
<td align="left">31.90</td>
<td align="left">15.98</td>
<td align="left">19.57</td>
<td align="left">12.57</td>
<td align="left">28.90</td>
<td align="left">41.25</td>
<td align="left">24.10</td>
<td align="left">30.74</td>
<td align="left">19.15</td>
<td align="left">16.38</td>
<td align="left">20.09</td>
<td align="left">19.23</td>
</tr>
<tr>
<td align="left">Ce</td>
<td align="left">102.01</td>
<td align="left">98.61</td>
<td align="left">35.57</td>
<td align="left">73.60</td>
<td align="left">36.95</td>
<td align="left">29.16</td>
<td align="left">35.70</td>
<td align="left">65.12</td>
<td align="left">96.89</td>
<td align="left">56.73</td>
<td align="left">70.81</td>
<td align="left">48.94</td>
<td align="left">29.66</td>
<td align="left">48.69</td>
<td align="left">35.18</td>
</tr>
<tr>
<td align="left">Pr</td>
<td align="left">11.36</td>
<td align="left">4.27</td>
<td align="left">3.13</td>
<td align="left">10.39</td>
<td align="left">6.34</td>
<td align="left">4.20</td>
<td align="left">5.17</td>
<td align="left">9.71</td>
<td align="left">12.13</td>
<td align="left">6.14</td>
<td align="left">9.94</td>
<td align="left">8.67</td>
<td align="left">4.64</td>
<td align="left">8.33</td>
<td align="left">6.68</td>
</tr>
<tr>
<td align="left">Nd</td>
<td align="left">39.92</td>
<td align="left">37.44</td>
<td align="left">18.96</td>
<td align="left">42.90</td>
<td align="left">24.19</td>
<td align="left">19.27</td>
<td align="left">21.74</td>
<td align="left">31.80</td>
<td align="left">45.98</td>
<td align="left">27.59</td>
<td align="left">36.90</td>
<td align="left">31.84</td>
<td align="left">15.91</td>
<td align="left">30.57</td>
<td align="left">25.24</td>
</tr>
<tr>
<td align="left">Sm</td>
<td align="left">10.21</td>
<td align="left">3.48</td>
<td align="left">9.75</td>
<td align="left">12.61</td>
<td align="left">7.68</td>
<td align="left">8.91</td>
<td align="left">8.11</td>
<td align="left">9.87</td>
<td align="left">10.26</td>
<td align="left">7.94</td>
<td align="left">10.15</td>
<td align="left">11.81</td>
<td align="left">3.76</td>
<td align="left">7.09</td>
<td align="left">5.78</td>
</tr>
<tr>
<td align="left">Eu</td>
<td align="left">0.02</td>
<td align="left">0.09</td>
<td align="left">0.34</td>
<td align="left">0.05</td>
<td align="left">0.01</td>
<td align="left">0.12</td>
<td align="left">0.04</td>
<td align="left">0.03</td>
<td align="left">0.08</td>
<td align="left">0.16</td>
<td align="left">0.05</td>
<td align="left">0.03</td>
<td align="left">0.80</td>
<td align="left">0.97</td>
<td align="left">0.91</td>
</tr>
<tr>
<td align="left">Gd</td>
<td align="left">11.01</td>
<td align="left">10.21</td>
<td align="left">4.25</td>
<td align="left">10.51</td>
<td align="left">8.13</td>
<td align="left">8.23</td>
<td align="left">7.89</td>
<td align="left">9.51</td>
<td align="left">9.68</td>
<td align="left">7.96</td>
<td align="left">9.67</td>
<td align="left">9.15</td>
<td align="left">3.81</td>
<td align="left">6.69</td>
<td align="left">5.52</td>
</tr>
<tr>
<td align="left">Tb</td>
<td align="left">1.82</td>
<td align="left">1.89</td>
<td align="left">0.94</td>
<td align="left">2.39</td>
<td align="left">1.49</td>
<td align="left">1.73</td>
<td align="left">2.15</td>
<td align="left">2.34</td>
<td align="left">1.31</td>
<td align="left">1.54</td>
<td align="left">2.84</td>
<td align="left">1.97</td>
<td align="left">0.52</td>
<td align="left">0.96</td>
<td align="left">0.85</td>
</tr>
<tr>
<td align="left">Dy</td>
<td align="left">16.33</td>
<td align="left">14.26</td>
<td align="left">7.24</td>
<td align="left">16.80</td>
<td align="left">12.42</td>
<td align="left">10.61</td>
<td align="left">13.47</td>
<td align="left">15.11</td>
<td align="left">8.82</td>
<td align="left">11.65</td>
<td align="left">14.61</td>
<td align="left">15.39</td>
<td align="left">3.57</td>
<td align="left">6.87</td>
<td align="left">5.22</td>
</tr>
<tr>
<td align="left">Ho</td>
<td align="left">3.06</td>
<td align="left">3.84</td>
<td align="left">3.42</td>
<td align="left">3.51</td>
<td align="left">2.43</td>
<td align="left">2.97</td>
<td align="left">4.15</td>
<td align="left">3.01</td>
<td align="left">1.64</td>
<td align="left">2.21</td>
<td align="left">2.98</td>
<td align="left">3.41</td>
<td align="left">0.70</td>
<td align="left">1.30</td>
<td align="left">1.00</td>
</tr>
<tr>
<td align="left">Er</td>
<td align="left">11.43</td>
<td align="left">9.17</td>
<td align="left">10.61</td>
<td align="left">9.98</td>
<td align="left">8.21</td>
<td align="left">7.29</td>
<td align="left">12.91</td>
<td align="left">9.24</td>
<td align="left">5.24</td>
<td align="left">8.50</td>
<td align="left">9.02</td>
<td align="left">9.39</td>
<td align="left">2.36</td>
<td align="left">4.53</td>
<td align="left">3.74</td>
</tr>
<tr>
<td align="left">Tm</td>
<td align="left">1.74</td>
<td align="left">1.58</td>
<td align="left">1.20</td>
<td align="left">2.07</td>
<td align="left">1.28</td>
<td align="left">1.31</td>
<td align="left">2.91</td>
<td align="left">2.37</td>
<td align="left">0.78</td>
<td align="left">1.38</td>
<td align="left">2.35</td>
<td align="left">2.41</td>
<td align="left">0.36</td>
<td align="left">0.74</td>
<td align="left">0.65</td>
</tr>
<tr>
<td align="left">Yb</td>
<td align="left">11.96</td>
<td align="left">9.71</td>
<td align="left">13.51</td>
<td align="left">13.07</td>
<td align="left">8.94</td>
<td align="left">9.21</td>
<td align="left">18.61</td>
<td align="left">13.07</td>
<td align="left">4.67</td>
<td align="left">10.01</td>
<td align="left">12.83</td>
<td align="left">12.89</td>
<td align="left">2.55</td>
<td align="left">5.01</td>
<td align="left">3.88</td>
</tr>
<tr>
<td align="left">Lu</td>
<td align="left">1.83</td>
<td align="left">1.74</td>
<td align="left">0.94</td>
<td align="left">1.97</td>
<td align="left">1.31</td>
<td align="left">1.29</td>
<td align="left">2.81</td>
<td align="left">1.72</td>
<td align="left">0.80</td>
<td align="left">1.38</td>
<td align="left">1.29</td>
<td align="left">1.71</td>
<td align="left">0.40</td>
<td align="left">0.86</td>
<td align="left">0.66</td>
</tr>
<tr>
<td align="left">&#x3a3;REE</td>
<td align="left">261.33</td>
<td align="left">231.56</td>
<td align="left">122.65</td>
<td align="left">231.75</td>
<td align="left">135.36</td>
<td align="left">121.78</td>
<td align="left">148.23</td>
<td align="left">201.80</td>
<td align="left">239.54</td>
<td align="left">167.28</td>
<td align="left">214.18</td>
<td align="left">176.76</td>
<td align="left">85.42</td>
<td align="left">142.70</td>
<td align="left">114.54</td>
</tr>
<tr>
<td align="left">LREE</td>
<td align="left">202.15</td>
<td align="left">179.16</td>
<td align="left">82.99</td>
<td align="left">171.45</td>
<td align="left">91.15</td>
<td align="left">81.23</td>
<td align="left">83.33</td>
<td align="left">145.43</td>
<td align="left">206.60</td>
<td align="left">122.65</td>
<td align="left">158.59</td>
<td align="left">120.44</td>
<td align="left">71.15</td>
<td align="left">115.74</td>
<td align="left">93.02</td>
</tr>
<tr>
<td align="left">HREE</td>
<td align="left">59.18</td>
<td align="left">52.40</td>
<td align="left">39.66</td>
<td align="left">60.30</td>
<td align="left">44.21</td>
<td align="left">40.55</td>
<td align="left">64.90</td>
<td align="left">56.37</td>
<td align="left">32.94</td>
<td align="left">44.63</td>
<td align="left">55.59</td>
<td align="left">56.32</td>
<td align="left">14.27</td>
<td align="left">26.96</td>
<td align="left">21.52</td>
</tr>
<tr>
<td align="left">LREE/HREE</td>
<td align="left">3.42</td>
<td align="left">3.42</td>
<td align="left">2.09</td>
<td align="left">2.84</td>
<td align="left">2.06</td>
<td align="left">2.00</td>
<td align="left">1.28</td>
<td align="left">2.58</td>
<td align="left">6.27</td>
<td align="left">2.75</td>
<td align="left">2.85</td>
<td align="left">2.14</td>
<td align="left">4.99</td>
<td align="left">4.29</td>
<td align="left">4.32</td>
</tr>
<tr>
<td align="left">(La/Sm)N</td>
<td align="left">2.38</td>
<td align="left">6.38</td>
<td align="left">0.98</td>
<td align="left">1.59</td>
<td align="left">1.31</td>
<td align="left">1.38</td>
<td align="left">0.98</td>
<td align="left">1.84</td>
<td align="left">2.53</td>
<td align="left">1.91</td>
<td align="left">1.91</td>
<td align="left">1.02</td>
<td align="left">2.74</td>
<td align="left">1.78</td>
<td align="left">2.09</td>
</tr>
<tr>
<td align="left">(La/Yb)N</td>
<td align="left">2.18</td>
<td align="left">2.45</td>
<td align="left">0.76</td>
<td align="left">1.65</td>
<td align="left">1.21</td>
<td align="left">1.43</td>
<td align="left">0.46</td>
<td align="left">1.49</td>
<td align="left">5.96</td>
<td align="left">1.62</td>
<td align="left">1.62</td>
<td align="left">1.00</td>
<td align="left">4.33</td>
<td align="left">2.70</td>
<td align="left">3.34</td>
</tr>
<tr>
<td align="left">Mg&#x23;</td>
<td align="left">10.5</td>
<td align="left">13.5</td>
<td align="left">13.1</td>
<td align="left">32.3</td>
<td align="left">9.8</td>
<td align="left">12.3</td>
<td align="left">32.3</td>
<td align="left">29.0</td>
<td align="left">8.6</td>
<td align="left">28.3</td>
<td align="left">35.3</td>
<td align="left">26.7</td>
<td align="left">46.8</td>
<td align="left">55.3</td>
<td align="left">44.2</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn>
<p>Note: A/CNK, molar (Al<sub>2</sub>O<sub>3</sub>/(Cao &#x2b; K<sub>2</sub>O &#x2b; Na<sub>2</sub>O)); Mg &#x23;, 100&#xd7; MgO/(MgO&#x2b;0.505&#xd7; (Fe<sub>2</sub>O<sub>3</sub> &#xd7; 0.9&#x2b;FeO)), assuming that FeO is equal to 90% of the total Fe oxide; &#x3b4;Eu, Eu<sub>N</sub> &#xd7; 2/(Sm<sub>N</sub> &#x2b; Gd<sub>N</sub>), and the subscript &#x201c;N&#x201d; indicates chondrite standardization (<xref ref-type="bibr" rid="B89">Sun and Mc Donough, 1989</xref>).</p>
</fn>
</table-wrap-foot>
</table-wrap>
<p>The MMEs have lower contents of SiO<sub>2</sub> (55.37&#x2013;67.33 wt%) and total alkali (Na<sub>2</sub>O &#x2b; K<sub>2</sub>O) (5.89&#x2013;7.00 wt%) than the host rock, indicating a diorite composition. The TFeO (3.47&#x2013;7.57 wt%), MgO (1.27&#x2013;5.26 wt%), and CaO (3.05&#x2013;6.97 wt%) contents are significantly higher than those of the host granite, and the Al<sub>2</sub>O<sub>3</sub> content is higher (14.93&#x2013;16.26 wt%), indicating aluminum supersaturation (A/CNK &#x3d; 1.26&#x2013;1.49). However, the enclaves are relatively enriched in P<sub>2</sub>O<sub>5</sub> (0.13&#x2013;0.17 wt%) and Mg&#x23; (44.2&#x2013;55.3). The values are slightly higher than those of the host rocks, suggesting a mantle melt composition.</p>
<p>All host rock samples from Sabei, Huangyangshan, and Sujiquan fall into the granite field of the total alkali-silica (TAS) diagram (<xref ref-type="fig" rid="F4">Figure 4a</xref>), with MMEs falling into the granodiorite and monzodiorite areas. The host rock samples show weak peralkaline-metaluminous characteristics in the A/CNK-A/NK diagram (<xref ref-type="fig" rid="F4">Figure 4b</xref>), whereas the MME samples are peraluminous. Most of the host rock samples and MMEs fall into the high-K calc-alkaline series of the SiO<sub>2</sub>-K<sub>2</sub>O diagram (<xref ref-type="fig" rid="F4">Figure 4c</xref>).</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Classification of MMEs and their host granitoids. <bold>(a)</bold> (K<sub>2</sub>O &#x2b; Na<sub>2</sub>O) vs. SiO<sub>2</sub> (after <xref ref-type="bibr" rid="B68">Middlemost (1994)</xref>), <bold>(b)</bold> A/NK vs. A/CNK (after <xref ref-type="bibr" rid="B67">Maniar and Piccoli (1989)</xref>), and <bold>(c)</bold> SiO<sub>2</sub> vs. AR (after <xref ref-type="bibr" rid="B104">Wright (1969)</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g004.tif">
<alt-text content-type="machine-generated">Geological classification diagrams in three panels: (a) TAS diagram with fields for different rock types based on K&#x2082;O &#x2b; Na&#x2082;O and SiO&#x2082;. (b) A/NK vs. A/CNK plot categorizing rocks into metaluminous, peraluminous, and peralkaline. (c) K&#x2082;O vs. SiO&#x2082; chart with compositional lines for low-K tholeiitic to shoshonitic. Symbols indicate different granite types: Sabei, Huangyangshan, Sujiquan, and Sabei MME.</alt-text>
</graphic>
</fig>
<p>The Harker diagram (<xref ref-type="fig" rid="F5">Figures 5a&#x2013;h</xref>) indicates that the host granite samples plot in a concentrated zone, indicating a linear relationship between host granites and MMEs. Al<sub>2</sub>O<sub>3</sub>, MgO, CaO, MnO, FeO, TiO<sub>2</sub>, and TFe<sub>2</sub>O<sub>3</sub> are negatively correlated with SiO<sub>2</sub>; K<sub>2</sub>O is positively correlated with SiO<sub>2</sub>; TFeO is positively correlated with MgO; and Na<sub>2</sub>O shows no linear relationship with SiO<sub>2</sub>. Excellent linear correlations are observed for the dominant oxide ratios: Na<sub>2</sub>O/CaO vs. Al<sub>2</sub>O<sub>3</sub>/CaO, Na<sub>2</sub>O/CaO vs. SiO<sub>2</sub>/CaO, SiO<sub>2</sub>/MgO vs. Al<sub>2</sub>O<sub>3</sub>/MgO, and CaO/MnO vs. MgO/MnO (<xref ref-type="fig" rid="F6">Figure 6</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>
<bold>(a&#x2013;h)</bold> SiO<sub>2</sub> vs. major oxide variation diagrams of MMEs and host granites. <bold>(i)</bold> MgO vs. TFeO (after <xref ref-type="bibr" rid="B126">Zorpi et al. (1991)</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g005.tif">
<alt-text content-type="machine-generated">Nine scatter plots labeled a to i show relationships between SiO&#x2082; (x-axis) and various oxides (y-axis) for granites and MME samples. Colored symbols represent different granites and MME groups. Subplots a to h illustrate trends of Al&#x2082;O&#x2083;, CaO, FeO, K&#x2082;O, MgO, MnO, TiO&#x2082;, and Na&#x2082;O against SiO&#x2082;. Subplot i shows a plot of total FeO versus MgO with arrows indicating fractional crystallization and magma mixing processes. Each plot features clusters specific to granite types and MMEs.</alt-text>
</graphic>
</fig>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Diagram showing predominant oxide ratios of MMEs and host granites. <bold>(a)</bold> Al<sub>2</sub>O<sub>3</sub>/CaO vs. Na<sub>2</sub>O/CaO diagrams of MMEs and host granites; <bold>(b)</bold> SiO<sub>2</sub>/CaO vs. Na<sub>2</sub>O/CaO diagrams of MMEs and host granites; <bold>(c)</bold> Al<sub>2</sub>O<sub>3</sub>/CaO vs. SiO<sub>2</sub>/MgO diagrams of MMEs and host granites; <bold>(d)</bold> MgO/MnO vs. CaO/MnO diagrams of MMEs and host granites (Symbols/key consistent with <xref ref-type="fig" rid="F5">Figure 5</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g006.tif">
<alt-text content-type="machine-generated">Four scatter plots labeled a to d, illustrating chemical ratios. Plot a: Al&#x2082;O&#x2083;/CaO vs. Na&#x2082;O/CaO with a trend line labeled &#x22;Magma mixing.&#x22; Plot b: SiO&#x2082;/CaO vs. Na&#x2082;O/CaO with a similar trend line. Plot c: Al&#x2082;O&#x2083;/MgO vs. SiO&#x2082;/MgO, also showing magma mixing. Plot d: MgO/MnO vs. CaO/MnO with the same trend indication. Various symbols represent different data points across all plots.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s5-3">
<title>5.3 Trace and rare earth element</title>
<p>The results of the rare earth and trace element analyses for the Sabei, Huangyangshan, and Sujiquan plutons and the Sabei MMEs in the eastern KGB are listed in <xref ref-type="table" rid="T2">Table 2</xref>. The granite samples from the Sabei, Huangyangshan, and Sujiquan host rocks in the Karamaili East section exhibit elevated &#x3a3;REE contents ranging from 121.78 to 261.32 ppm, with &#x3a3; light REEs (LREEs) ranging from 81.23 to 206.60 ppm and &#x3a3; heavy REEs (HREEs) from 32.94 to 64.90 ppm. The &#x3a3;LREE/&#x3a3;HREE ratio is 1.28&#x2013;6.27.</p>
<p>The chondrite-normalized REE patterns for the granite samples from the Karamaili belt display a deep V-shaped distribution and a negative Eu anomaly (Eu/Eu&#x2a; &#x3d; 0.01&#x2013;0.34) (<xref ref-type="fig" rid="F7">Figure 7a</xref>). The host granites and MMEs exhibit the same signatures in the primitive mantle-normalized trace element spider diagram (<xref ref-type="fig" rid="F7">Figure 7b</xref>), characterized by systematic incompatible element enrichment, particularly in high field strength elements (HFSEs). Negative anomalies are observed at Ba, Sr, P, and Ti, while positive anomalies occur at Rb, Th, K, and the Zr-Hf pair. All samples display systematic Nb-Ta depletion relative to adjacent elements (Th, K, La-Ce). A spider diagram of the trace elements normalized to the primitive mantle indicates substantial Ba, Sr, P, Eu, and Ti depletion and relative depletion in Tb and Tm. HFSEs (Ta, Th, U) and LILEs (Rb, K, Pb) are relatively enriched (<xref ref-type="fig" rid="F7">Figure 7b</xref>). The granite zircon chondrite-normalized REE patterns reveal considerable LREE depletion and HREE enrichment, with La to Lu values showing a variation over five to six orders of magnitude, and a strong negative Eu anomaly (<xref ref-type="fig" rid="F7">Figure 7c</xref>). In contrast, no LREE and HREE fractionation is observed in the zircons from the MME, with only a slight negative Eu anomaly (<xref ref-type="fig" rid="F7">Figure 7d</xref>), indicative of plagioclase fractionation or retention during magma evolution, as Eu replaces Ca in plagioclase.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Chondrite-normalized REE patterns and primitive mantle-normalized trace element spider-diagrams for <bold>(a,b)</bold> Karamaili host and MMEs sample; and <bold>(c,d)</bold> Karamaili host and MMEs Zircon. Chondrite REE and primitive mantle values were normalized after <xref ref-type="bibr" rid="B89">Sun and Mc Donough (1989)</xref>.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g007.tif">
<alt-text content-type="machine-generated">Four graphs display geochemical data comparisons. Graph (a) shows trace elements normalized to chondrite, with various colored lines. Graph (b) shows trace elements normalized to the primitive mantle. Graph (c) compares host-rock zircon to chondrite, with bands of different colors. Graph (d) compares MME zircon to chondrite, highlighting data from different sources. Axes denote trace elements, and logarithmic scales are used on the y-axes.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s5-4">
<title>5.4 Whole rock Nd isotopes</title>
<p>Four samples were collected from the KGB for whole-rock Nd isotope analysis (<xref ref-type="table" rid="T3">Table 3</xref>), with four samples from the Sabei pluton (SB-1, SB-3, SBMME-1, SBMME-2), one from the Huangyangshan pluton (HYS-1), and one from the Sujiquan pluton (SJ-1).</p>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Whole-rock Nd isotope test data for samples from the Eastern Karamaili Belt.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Pluton</th>
<th align="left">Sample</th>
<th align="left">Sm</th>
<th align="left">Nd</th>
<th align="left">
<sup>147</sup>Sm/<sup>144</sup>Nd</th>
<th align="left">
<sup>143</sup>Nd/<sup>144</sup>Nd</th>
<th align="left">2&#x3c3;</th>
<th align="left">&#x3b5;Nd (0)</th>
<th align="left">&#x3b5;Nd(t)</th>
<th align="left">2&#x3c3;</th>
<th align="left">T<sub>DM</sub>
</th>
<th align="left">T<sub>2DM</sub>
</th>
<th align="left">T<sub>DMC</sub>
</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td rowspan="4" align="left">Sabei</td>
<td align="left">SB-1</td>
<td align="left">3.11</td>
<td align="left">13.48</td>
<td align="left">0.139577</td>
<td align="left">0.512787</td>
<td align="left">0.000008</td>
<td align="left">&#x2b;2.9</td>
<td align="left">&#x2b;4.0</td>
<td align="left">0.08</td>
<td align="left">750</td>
<td align="left">608</td>
<td align="left">615</td>
</tr>
<tr>
<td align="left">SB-3</td>
<td align="left">10.25</td>
<td align="left">39.83</td>
<td align="left">0.155523</td>
<td align="left">0.512805</td>
<td align="left">0.000007</td>
<td align="left">&#x2b;3.3</td>
<td align="left">&#x2b;4.1</td>
<td align="left">0.07</td>
<td align="left">908</td>
<td align="left">646</td>
<td align="left">611</td>
</tr>
<tr>
<td align="left">SBMME-1</td>
<td align="left">14.46</td>
<td align="left">44.63</td>
<td align="left">0.195819</td>
<td align="left">0.512921</td>
<td align="left">0.000008</td>
<td align="left">&#x2b;5.5</td>
<td align="left">&#x2b;5.5</td>
<td align="left">0.08</td>
<td align="left">1965</td>
<td align="left">488</td>
<td align="left">489</td>
</tr>
<tr>
<td align="left">SBMME-3</td>
<td align="left">6.32</td>
<td align="left">16.58</td>
<td align="left">0.230358</td>
<td align="left">0.512965</td>
<td align="left">0.000008</td>
<td align="left">&#x2b;6.4</td>
<td align="left">&#x2b;5.7</td>
<td align="left">0.08</td>
<td align="left">1707</td>
<td align="left">476</td>
<td align="left">473</td>
</tr>
<tr>
<td align="left">Huangyangshan</td>
<td align="left">HYS-1</td>
<td align="left">8.94</td>
<td align="left">39.91</td>
<td align="left">0.135395</td>
<td align="left">0.512808</td>
<td align="left">0.000008</td>
<td align="left">&#x2b;3.3</td>
<td align="left">&#x2b;4.5</td>
<td align="left">0.08</td>
<td align="left">669</td>
<td align="left">651</td>
<td align="left">575</td>
</tr>
<tr>
<td align="left">Sujiquan</td>
<td align="left">SJQ-2</td>
<td align="left">6.92</td>
<td align="left">29.85</td>
<td align="left">0.140099</td>
<td align="left">0.512800</td>
<td align="left">0.000006</td>
<td align="left">&#x2b;3.2</td>
<td align="left">&#x2b;4.3</td>
<td align="left">0.06</td>
<td align="left">728</td>
<td align="left">615</td>
<td align="left">595</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="table" rid="T3">Table 3</xref> shows that the Sm/Nd ratios for the Sabei, Huangyangshan, and Sujiquan plutons range from 0.135 to 0.156, with similar ratios for different rock types, implying a uniform source material and a relatively closed Sm-Nd system during petrogenesis. These values are lower than the chondritic <sup>147</sup>Sm/<sup>144</sup>Nd ratio of 0.1967 (<xref ref-type="bibr" rid="B36">Hamilton et al., 1983</xref>). The <sup>143</sup>Nd/<sup>144</sup>Nd ratios of 0.512787&#x2013;0.512808 and &#x3b5;Nd(t) values for the Sabei, Huangyangshan, and Sujiquan rocks fall in the range &#x2b;4.0 to &#x2b;4.5, with T<sub>2DM</sub> values ranging from 608 to 651.</p>
<p>In contrast, the SBMMEs exhibit higher Sm/Nd ratios (0.196&#x2013;0.230), <sup>143</sup>Nd/<sup>144</sup>Nd ratios from 0.512921 to 0.512965, and &#x3b5;Nd(t) values from &#x2b;5.5 to &#x2b;5.7. T<sub>2DM</sub> values of 476&#x2013;488 are obtained for the Sabei MMEs.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s6">
<title>6 Discussions</title>
<sec id="s6-1">
<title>6.1 Time constraints for plutons</title>
<p>The Carboniferous was the critical stage of tectonic transformation in Eastern Junggar. Therefore, constraining the evolutionary period of siliceous magmatic activity in the Karamaili area is crucial (<xref ref-type="bibr" rid="B23">Chen et al., 2010</xref>; <xref ref-type="bibr" rid="B120">Zhang et al., 2010</xref>; <xref ref-type="bibr" rid="B56">Li et al., 2015</xref>). Previous studies have suggested that the emplacement time in the KGB was 328&#x2013;283 Ma (<xref ref-type="bibr" rid="B38">Han et al., 2006</xref>; <xref ref-type="bibr" rid="B57">Lin et al., 2007</xref>; <xref ref-type="bibr" rid="B88">Su et al., 2008</xref>; <xref ref-type="bibr" rid="B92">Tang et al., 2009</xref>; <xref ref-type="bibr" rid="B118">Yang et al., 2009</xref>; <xref ref-type="bibr" rid="B31">Gan et al., 2010</xref>; <xref ref-type="bibr" rid="B39">Han et al., 2012</xref>). In this study, the LA-ICP-MS zircon U-Pb ages for the Sabei monzogranite, Huangyangshan biotite syenogranite, and Sujiquan biotite granite are 315.9 &#xb1; 2.4 Ma, 316.1 &#xb1; 2.2 Ma, and 319.4 &#xb1; 2.0 Ma, respectively. These ages indicate that the emplacement time of the plutons in the eastern section of the KGB can be constrained to 320&#x2013;315 Ma. The LA-ICP-MS zircon U-Pb age for the MMEs of the Sabei pluton is 313.9 &#xb1; 3.5 Ma. Field investigations reveal no discernible intrusive contacts between host granites and MMEs. Consequently, the geochronological data indicate that both lithological units have similar emplacement ages within the analytical uncertainty. It has been suggested that MMEs and granitic plutons are products of the synchronous evolution of the magma.</p>
</sec>
<sec id="s6-2">
<title>6.2 Petrogenesis of the granites and MMEs</title>
<p>The granites in the Sabei, Huangyangshan and Sujiquan plutons are characterized by high Si, K, and alkali contents. The CaO, MgO, Ta, Ba and TiO<sub>2</sub> contents are low, with 10,000 &#xd7; Ga/Al &#x3d; 3.06&#x2013;4.45. These values are significantly higher than the average values for I-type and S-type granites (2.10 and 2.28) and the relatively enriched HFSEs (Ta, Th, U) and LILEs (Rb, K, Pb), indicating geochemical characteristics similar to those of A-type granite. The strong negative Eu anomalies (&#x3b4;Eu &#x3d; 0.01&#x2013;0.34) and low Sr contents (3.2&#x2013;37.5 ppm, mean &#x3d; 9.2 ppm) differentiate these granites from highly fractionated I-type granite, They are important indicators of A-type granite (<xref ref-type="bibr" rid="B116">Xu et al., 2015</xref>). The whole-rock zircon saturation temperatures of the granites range from 735 &#xb0;C to 895 &#xb0;C, with most samples showing higher temperatures than typical zircon saturation temperatures of highly-fractionated I-type granite (average 764 &#xb0;C) (<xref ref-type="bibr" rid="B1">Alberto and Patino, 1997</xref>; <xref ref-type="bibr" rid="B48">King et al., 1997</xref>). This finding indicates that the magma partially melted under water-deficient conditions at temperatures of &#x3e;830 &#xb0;C, which is a typical A-type granite formation condition.</p>
<p>The KGB samples fall in the A-type granite area of the TFeO/MgO vs. 10000 Ga/Al discrimination diagram (<xref ref-type="fig" rid="F8">Figure 8a</xref>), indicating they differ from the I- and S-types. The geochemical characteristics are similar for A-type and highly fractionated I-type granites (<xref ref-type="bibr" rid="B48">King et al., 1997</xref>). Most of the Sabei, Huangyangshan, and Sujiquan pluton samples fall within the A-type granite area in the (K<sub>2</sub>O &#x2b; Na<sub>2</sub>O)/CaO vs. Zr &#x2b; Nb &#x2b; Ce &#x2b; Y diagram (<xref ref-type="fig" rid="F8">Figure 8b</xref>). Thus, they differ from the samples derived from the Kamusite and Laoyaquan plutons in the western part of the KGB, which fall within the highly differentiated I-type granite. The samples from the KGB fall within the A2-type granite area in the Nb, Y, Ce, and Yb classification diagrams (<xref ref-type="fig" rid="F8">Figures 8c,d</xref>), indicating orogenic A-type granite genesis. It differs from the non-orogenic A<sub>1</sub>-type granite, and the magma source has an affinity with island-arc basalts (IABs). These results, in conjunction with the geological features, including the location of the KGB at the plate margin and the delayed timing of ocean basin closure and subduction, suggest that the Sabei, Huangyangshan, and Sujiquan granites are typical quasi-aluminous, alkaline-high-potassium calc-alkaline A<sub>2</sub>-type granites.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Petrogenetic discriminant diagrams. <bold>(a)</bold> TFeO/MgO vs. 10000Ga/Al (from <xref ref-type="bibr" rid="B101">Whalen et al., 1987</xref>); <bold>(b)</bold> (K<sub>2</sub>O &#x2b; Na<sub>2</sub>O)/CaO vs. Zr &#x2b; Nb &#x2b; Ce &#x2b; Y (from <xref ref-type="bibr" rid="B101">Whalen et al., 1987</xref>); <bold>(c)</bold> Yb/Ta vs. Y/Nb; and <bold>(d)</bold> Nb-Y-Ce (from <xref ref-type="bibr" rid="B29">Eby, 1992</xref>) (A1 &#x3d; Intraplate rift or mantle plume; A2 &#x3d; Post-collisional or post-orogenic).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g008.tif">
<alt-text content-type="machine-generated">Geochemical diagrams showing granite classifications: (a) TFe&#x2082;O&#x2083;/MgO vs. 10000Ga/Al plot distinguishes A-type from I- and S-type granites. (b) (K&#x2082;O &#x2b; Na&#x2082;O)/CaO vs. Zr &#x2b; Nb &#x2b; Ce &#x2b; Y plot categorizes A-type and fractionated granites. (c) Yb/Ta vs. Y/Nb plot identifies overlaps among OIB, IAB, A1, and A2 classifications.(d) Ternary diagram for Nb, Y, and Ce shows distribution of different granite samples. Each diagram includes symbols representing various granite types and sources.</alt-text>
</graphic>
</fig>
<p>MMEs with different numbers, sizes, and shapes are widely observed in the Sabei and Huangyangshan plutons. The genesis of these enclaves is generally determined using four approaches: refractory residues of granite protolith melting (<xref ref-type="bibr" rid="B20">Chappell et al., 1987</xref>; <xref ref-type="bibr" rid="B18">Chappell and White, 1991</xref>; <xref ref-type="bibr" rid="B102">White et al., 1999</xref>; <xref ref-type="bibr" rid="B19">Chappell and Wyborn, 2012</xref>), xenoliths from the wall rock (<xref ref-type="bibr" rid="B66">Maas et al., 1997</xref>), the early crystallized cumulates from cognate magma (<xref ref-type="bibr" rid="B72">Noyes et al., 1983</xref>; <xref ref-type="bibr" rid="B26">Dahlquist, 2002</xref>; <xref ref-type="bibr" rid="B28">Donaire et al., 2005</xref>), and the mixing/mingling of magma (<xref ref-type="bibr" rid="B9">Baxter and Feely, 2002</xref>; <xref ref-type="bibr" rid="B6">Barbarin, 2005</xref>; <xref ref-type="bibr" rid="B84">S&#x142;aby and Martin, 2008</xref>).</p>
<p>The contacts between MMEs and host granites typically exhibit sharp macroscopic boundaries, occasionally displaying diffuse transitions, with ubiquitous dark fine-grained chilled margins. These textural features preclude an origin as xenoliths from the wall-rock or refractory residues of granite protolith melting. The pluton contains abundant dioritic MMEs characterized by magmatic fine-grained hypidiomorphic granular textures and massive structures, indicative of rapid crystallization under disequilibrium conditions. Petrogenetic constraints suggest that supercooled mafic magmatic blobs intruded into cooler felsic host magma during magma mixing. This process induced metasomatic replacement of early-crystallized plagioclase, forming K-feldspar reaction rims. The ubiquitous acicular to columnar apatite inclusions in the plagioclase, displaying distinct crystallographic orientations from host rock apatite, represent quench-crystallized products (<xref ref-type="bibr" rid="B5">Barbarin, 1988</xref>; <xref ref-type="bibr" rid="B7">Barbarin and Didier, 1992</xref>). These textural indicators, particularly the diagnostic acicular apatite morphologies, suggest significant thermal contrast (&#x3e;200 &#xb0;C) between mafic enclave-forming magma and host felsic magma, with rapid heat dissipation during crystallization. However, the MMEs are randomly distributed in the host granitoids, and petrological analysis reveals that they have magmatic textures and numerous disequilibrium textures, which are contradictory to autoliths, suggesting they likely formed through magma mixing. Transitional zones at the interfaces reveal plagioclase phenocrysts containing euhedral oscillatory-zoned cores overgrown by multiple generations of anhedral rims, recording episodic growth under fluctuating physicochemical conditions. Sector-zoned textures in the plagioclase indicate dynamic crystallization environments. The presence of relatively coarse-grained amphibole clusters within the MMEs indicates precursory crystallization of mafic phases prior to magma interaction (<xref ref-type="bibr" rid="B126">Zorpi et al., 1991</xref>), whereas felsic mineral assemblages formed during later-stage co-crystallization of residual enclave magma and host granodioritic melt under comparable cooling rates (Vernon, 1984). Chemical hybridization through interdiffusion between mafic and granodioritic magma to achieve a local equilibrium resulted in mutual geochemical modification. This petrogenetic mechanism accounts for the observed geochemical similarity in the major/trace element compositions and mineral assemblage between host rocks and MMEs.</p>
<p>In the Harker diagrams of major oxides versus SiO<sub>2</sub> (<xref ref-type="fig" rid="F5">Figure 5</xref>), the samples from this pluton exhibit well-defined negative linear correlations between Al<sub>2</sub>O<sub>3</sub>, CaO, FeO, K<sub>2</sub>O, MgO, MnO, TiO<sub>2</sub>, Na<sub>2</sub>O, and TFeO with increasing SiO<sub>2</sub> content. These systematic trends strongly suggest magma mixing between host granites and MMEs. Fractional crystallization typically generates trends due to sequential mineral phase removal (e.g., plagioclase and amphibole), whereas mixing systems preserve linear arrays reflecting binary endmember blending. The TFeO-MgO correlation diagram (<xref ref-type="fig" rid="F5">Figure 5i</xref>) supports this interpretation. All compositional data plot along established magma mixing trend lines, indicative of chemical hybridization between mafic and felsic melts. <xref ref-type="fig" rid="F6">Figure 6</xref> shows well-defined inverse linear correlations in key oxide ratios between MMEs and host granites. These trends reflect potential magma mixing evolutionary trends between the host granite and its enclaves. The primitive mantle-normalized spider diagrams (<xref ref-type="fig" rid="F7">Figure 7b</xref>) reveal broadly parallel patterns between enclaves and host rocks, consistent with assimilation-fractional crystallization (AFC) during coeval magma evolution (<xref ref-type="bibr" rid="B52">Lei et al., 2019</xref>). The AFC accounts for the observed geochemical similarity between the dioritic enclaves and granitic hosts, particularly the depletion in Nb, Ta, P, and Ti. These anomalies primarily reflect fractionation of accessory phases (e.g., apatite and Ti-bearing oxides), coupled with crustal contamination. The chondrite-normalized REE patterns display analogous LREE-enriched profiles, yet exhibit HREE crossover features between host rocks and enclaves (<xref ref-type="fig" rid="F7">Figure 7a</xref>). This finding suggests that the host granites and enclaves represent distinct but interacting magma batches.</p>
<p>The MMEs of the Sabei plutons exhibit the following features. (1) The zircon geochronology of the MMEs is 313.9 &#xb1; 3.5 Ma, whereas the age of the host granite is 315.9 &#xb1; 2.4 Ma, showing consistency in the formation chronology. This equivalence precludes the possibilities of refractory residues of granite protolith melting or xenoliths from the wall rock because both source materials would predate the host magma chronology (<xref ref-type="bibr" rid="B14">Brown and Fyfe, 1970</xref>; <xref ref-type="bibr" rid="B47">Kempton et al., 1987</xref>); (2) The host granite and MMEs exhibit different lithologies. Distinct boundaries exist between the round, oval, or droplet-shaped enclaves and the host rock, and plagioclase with a sieve structure is common (<xref ref-type="fig" rid="F2">Figure 2e</xref>). Therefore, these observations preclude the potential origins of the detachment of the early-stage crystallized homologous magma (<xref ref-type="bibr" rid="B73">O&#x2019;Hara, 1977</xref>). (3) Acicular apatite generally originates from rapidly cooling magma (<xref ref-type="bibr" rid="B107">Wyllie et al., 1962</xref>), i.e., its presence indicates rapid cooling. (4) The petrography of the MMEs indicates they have a magmatic origin and do not originate from the surrounding rock; i.e., they are not xenoliths. The similarity in the zircon U-Pb ages indicates that the MMEs and host rocks coexisted and were products of contemporaneous mafic and acidic magmas. (5) The TFeO vs. MgO diagram shows that the MMEs did not evolve along the crystallographic differentiation trend of mafic magma, but were distributed near the magma mixing trend line. This finding indicates an evolution toward the host granite composition (<xref ref-type="fig" rid="F5">Figure 5i</xref>), suggesting that the MMEs are represent hybridized melt blobs left over from the siliceous magma due to magma mixing during the uplift of the mafic magma. The age of the Sabei MMEs is consistent with that of the host granite and the characteristics of the trace elements and REE are similar, indicating a dioritic magmatic enclave. The magma is derived from mantle material and is a product of magma mixing.</p>
</sec>
<sec id="s6-3">
<title>6.3 Implications for tectonic setting</title>
<p>The Karamaili ophiolite m&#xe9;lange is considered a fragment of the eastern Karamaili Ocean in the Junggar Ocean (<xref ref-type="bibr" rid="B116">Xu et al., 2015</xref>). The expansion of the ocean basin likely occurred from the late Silurian to the late Devonian (<xref ref-type="bibr" rid="B45">Jian et al., 2003</xref>; <xref ref-type="bibr" rid="B83">Shu and Wang, 2003</xref>; <xref ref-type="bibr" rid="B114">Xu et al., 2011</xref>). Subsequently, the Junggar Ocean was subducted under the Siberian Plate at the edge of the continental block, generating accretionary wedges and continental margin volcanic arcs, such as the abundant late Devonian-Early Carboniferous island arcs and volcanic rocks observed in the area (<xref ref-type="bibr" rid="B53">Li, 1995</xref>; <xref ref-type="bibr" rid="B119">Zhang and Guo, 2010</xref>; <xref ref-type="bibr" rid="B15">Cai et al., 2012</xref>).</p>
<p>The Eastern Junggar exhibits the characteristics of a multi-island arc structure, with many island arc belts and fore-arc, and back-arc basins that formed during compression in the Early Carboniferous. Subsequently, the ocean basin closed, the island arcs merged, and the land mass was uplifted by extrusion in the middle Early Carboniferous. During the syn-collision orogenic phase, the subduction orogeny weakened, leading to the slab break-off of the subducted oceanic plate in the late Carboniferous. Subsequently, compression-extension tectonic transformation occurred, gradually transitioning into the post-collision extension stage and causing the underplating of large-scale mantle-derived materials. The basic magma intruded upward and partially melted the upper crustal material, resulting in the formation of large-scale siliceous magma, juvenile crustal growth, and the Late Carboniferous KGB (<xref ref-type="bibr" rid="B38">Han et al., 2006</xref>; <xref ref-type="bibr" rid="B86">Su et al., 2006</xref>; <xref ref-type="bibr" rid="B31">Gan et al., 2010</xref>; <xref ref-type="bibr" rid="B56">Li et al., 2015</xref>; <xref ref-type="bibr" rid="B123">Zhang et al., 2020</xref>).</p>
<p>As shown in the Y &#x2b; Nb-Rb diagram, most of the KGB samples fall in the intraplate granite area, indicating a formation environment comprising ridge granite, volcanic arc granite, and syn-collision granite (<xref ref-type="fig" rid="F9">Figure 9a</xref>). The R<sub>1</sub>-R<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> diagrams of the post-orogenic granites indicate that almost all KGB samples are post-orogenic, A-type granites (<xref ref-type="fig" rid="F9">Figure 9b</xref>). This result shows that the section formed in an extensional environment and a post-collision setting; thus, the granites differed significantly from those granites related to rift and continental uplift (<xref ref-type="fig" rid="F9">Figure 9c</xref>). In addition, the A-type granite in the KGB also falls into the post-orogenic (PA) field (<xref ref-type="fig" rid="F9">Figure 9d</xref>); thus, it differs from anorogenic granites. In summary, the results suggest that the A<sub>2</sub>-type granites in the Sabei, Huangyangshan, and Sujiquan plutons of the eastern KGB formed in an extensional environment and a post-collision geotectonic setting at the end of the orogenic event at around 320&#x2013;315 Ma.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>
<bold>(a)</bold> Rb vs. Y &#x2b; Nb (from <xref ref-type="bibr" rid="B74">Pearce et al., 1984</xref>); <bold>(b)</bold> R2 vs. R1 (from <xref ref-type="bibr" rid="B8">Batchelor and Bowden, 1985</xref>); <bold>(c)</bold> Al<sub>2</sub>O<sub>3</sub> vs. SiO<sub>2</sub> (from <xref ref-type="bibr" rid="B40">Harris et al., 1986</xref>); and <bold>(d)</bold> R1 vs. 10000Ga/Al (from <xref ref-type="bibr" rid="B41">Hong et al., 1995</xref>). RRG, rift-related granitoid; CEUG, continental epeirogenic uplift granitoid; POG, post-orogenic granitoid; IAG, island arc granitoid; CAG, continental arc granitoid; CCG, continental collision granitoid; VAG, volcanic-arc granites; Syn-COLG, syn-collisional granites; WPG, within-plate granites; ORG, ocean-ridge granites; Post-COLG, post-collisional granites; PA, post-orogenic granites; AA, anorogenic granites.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g009.tif">
<alt-text content-type="machine-generated">Four geochemical diagrams labeled a, b, c, and d display data points from various granite samples. Diagram a shows Rb vs. Y&#x2b;Nb, indicating zones like syn-COLG, WPG, VAG, and ORG. Diagram b plots R2 vs. R1, with areas marked for mantle plagiogranite and various collision stages. Diagram c presents Al&#x2082;O&#x2083; vs. SiO&#x2082;, categorizing IAG&#x2b;CAG&#x2b;CCG and POG. Diagram d displays R1 vs. 10,000Ga/Al, with PA and AA regions. Data points from studies by Sabei, Huangyangshan, Sujiquan, Kamusite, Laoyaquan, and Beilekuduke are circled in red on each chart.</alt-text>
</graphic>
</fig>
<p>In accordance with the different granites observed in the easternmost and westernmost KGB, the latest report suggests that the area was not an extensional environment in the late Carboniferous but was in transition from compression to extension. The western KGB experienced compression while the eastern KGB underwent extension during the Late Carboniferous (<xref ref-type="bibr" rid="B100">Wang et al., 2025</xref>), These discrete structures imply a high probability of the proposed conditions (<xref ref-type="fig" rid="F9">Figures 9a,c,d</xref>).</p>
</sec>
<sec id="s6-4">
<title>6.4 Magma mixing under crustal growth</title>
<p>Magma reservoirs serve as critical loci for analyzing upper crustal magmatic processes. Crystal mush&#x2014;formed through multiple magma intrusions (<xref ref-type="bibr" rid="B3">Bachmann and Bergantz, 2004</xref>; <xref ref-type="bibr" rid="B24">Coleman et al., 2004</xref>; <xref ref-type="bibr" rid="B33">Glazner et al., 2004</xref>; <xref ref-type="bibr" rid="B59">Lipman, 2007</xref>; <xref ref-type="bibr" rid="B70">Miller et al., 2009</xref>; <xref ref-type="bibr" rid="B60">Lipman and Bachmann, 2015</xref>; <xref ref-type="bibr" rid="B12">Blundy and Annen, 2016</xref>; <xref ref-type="bibr" rid="B65">Ma et al., 2020</xref>; <xref ref-type="bibr" rid="B125">Zhang et al., 2022</xref>)&#x2014;exhibits high crystallinity, elevated viscosity, and limited mobility, inhibiting convection, fractionation, and mixing (<xref ref-type="bibr" rid="B3">Bachmann and Bergantz, 2004</xref>; <xref ref-type="bibr" rid="B4">Bachmann and Huber, 2016</xref>; <xref ref-type="bibr" rid="B65">Ma et al., 2020</xref>). However, large-scale upwelling of mantle-derived mafic magma thermally rejuvenates viscous crystal-rich mush, elevating temperatures, reducing viscosity, increasing melt fraction, and decreasing crystallinity. Injection of this high-temperature mafic magma into cooler silicic host magma facilitates mixing, driving rapid compositional hybridization. This process can transform mafic melts into intermediate compositions (e.g., basaltic-andesite to diorite) through combined assimilation and fractional crystallization (<xref ref-type="bibr" rid="B25">Cooper and Kent, 2014</xref>; <xref ref-type="bibr" rid="B69">Miller, 2016</xref>; <xref ref-type="bibr" rid="B78">Rubin et al., 2017</xref>; <xref ref-type="bibr" rid="B43">Jackson et al., 2018</xref>; <xref ref-type="bibr" rid="B103">Wilson et al., 2021</xref>). The relatively low solidus temperature of dioritic magma promotes early crystallization, forming cumulate textures. Chemical exchange between MMEs and host granite diminishes as magmas cool (<xref ref-type="bibr" rid="B93">Wang, 2000</xref>). During flow emplacement, large enclave swarms may fragment into smaller MMEs (<xref ref-type="fig" rid="F2">Figure 2a</xref>). Buoyancy-driven ascent of crystal-rich mush through overlying strata may culminate in volcanic eruptions (<xref ref-type="bibr" rid="B2">Annen, 2009</xref>; <xref ref-type="bibr" rid="B85">Spera et al., 2016</xref>; <xref ref-type="bibr" rid="B65">Ma et al., 2020</xref>) (<xref ref-type="fig" rid="F10">Figures 10</xref>, <xref ref-type="fig" rid="F11">11</xref>).</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Tectonic evolution model map of the Junggar plate (modified after <xref ref-type="bibr" rid="B123">Zhang et al. (2020)</xref>). <bold>(a)</bold> Late early Devonian - early middle devonian plate subduction period. <bold>(b)</bold> Early Carboniferous synclinical period. <bold>(c)</bold> Late Carboniferous -Permian extensional period.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g010.tif">
<alt-text content-type="machine-generated">Illustration of geological processes between the Siberian and Junggar plates. (a) Subduction of oceanic crust beneath the Siberian plate and formation of lithospheric mantle. (b) Emergence of crust and magma activity at the upper and lower crust interface. (c) Extension and mantle upwelling processes under the Junggar Basin, with granite formation and magma mixing.</alt-text>
</graphic>
</fig>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Magma mixing model map of the Karamaili (modified after <xref ref-type="bibr" rid="B16">Cashman et al. (2017)</xref>; <xref ref-type="bibr" rid="B100">Wang et al. (2025)</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g011.tif">
<alt-text content-type="machine-generated">Illustration of a geological cross-section showing plate tectonics, volcanic activity, and magma movement. The Junggar and Siberia plates are depicted with continental crust, lithospheric mantle, and asthenosphere layers. Insets detail Kamusite and the magma reservoir, indicating magma upwelling through the crust. The diagram highlights volcanic rocks and their formation processes, including highly fractionated granite, MMEs, and basic magma intrusion.</alt-text>
</graphic>
</fig>
<p>As magma ascends from the magma reservoir toward the Earth&#x2019;s surface, mineral crystallization and fractionation can significantly alter its composition (<xref ref-type="bibr" rid="B30">Elburg, 1996</xref>). The MMEs have zircon U-Pb ages consistent with those of the host granites; however, compositional differences in major and trace elements are observed. As shown in <xref ref-type="fig" rid="F5">Figure 5i</xref>, the linear relationship between MMEs and the host granite is consistent with the magma evolutionary trends (<xref ref-type="bibr" rid="B51">Langmuir et al., 1978</xref>), suggesting that the MMEs and host granite are products of magma mixing rather than crystallization and fractionation. The mafic enclaves in the Sabei Pluton are dioritic rather than gabbroic. The Mg<sup>&#x23;</sup> value is higher than that of the host granite; however, the highest value 55.3 is smaller than the average value obtained for the primitive mantle (Mg<sup>&#x23;</sup>&#x3e;70) (<xref ref-type="bibr" rid="B11">Bloomer and Hawkins, 1987</xref>). The Mg<sup>&#x23;</sup> value is commonly used to indicate the degree of partial mantle melting. The mantle peridotite with a high Mg<sup>&#x23;</sup> value (&#x3e;90) may have undergone a higher degree of partial melting, whereas the Mg<sup>&#x23;</sup> value of the Sabei MMEs (maximum value of 55.3) suggests that the mantle-derived basic magma did not undergo extensive partial melting but was mixed with granitic magma during its ascent, leading to a simultaneous decrease in the Mg<sup>&#x23;</sup> value and SiO<sub>2</sub> content (<xref ref-type="fig" rid="F8">Figures 8b</xref>, <xref ref-type="fig" rid="F12">12</xref>). In addition, the MMEs in Sabei exhibit a mantle-crust evolutionary trend, which is characterized by a decreasing Sr content and an increasing Rb content which is not observed in the host granite. Unlike the Sabei granite, the MMEs have high Mg and Fe contents but low Si and Na contents. Moreover, the zircon U-Pb age is consistent with that of the host granite, recording syn-ascension mixing of mantle-derived mafic and crustal felsic magmas prior to Late Carboniferous emplacement.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Mg&#x23; vs. SiO<sub>2</sub> diagrams and field photographs of MMEs and their host granitoids. Mg&#x23; is calculated using 100 &#xd7; MgO/(MgO &#x2b; TFeO). Composition of metabasaltic and eclogite experimental melts and AFC curves are after <xref ref-type="bibr" rid="B76">Rapp and Brucewatson (1995)</xref>, <xref ref-type="bibr" rid="B77">Rapp et al. (1999)</xref>, and <xref ref-type="bibr" rid="B96">Wang et al. (2006)</xref>.</p>
</caption>
<graphic xlink:href="feart-13-1601135-g012.tif">
<alt-text content-type="machine-generated">Scatter plot showing Mg# versus SiO2 composition with image insets of rock samples. Sabei granites are pink circles, Huangyangshan granites are blue squares, Sujiquan granites are green triangles, and Sabei MMEs are orange diamonds. Sabei Samples show a rock near a hammer, Huangyangshan Samples present a rock with a pen, and Sujiquan Samples display a hammer on a rocky surface.</alt-text>
</graphic>
</fig>
<p>The CAOB experienced Phanerozoic juvenile crustal growth, with estimates exceeding 50% (<xref ref-type="bibr" rid="B81">&#x15e;eng&#xf6;r et al., 1993</xref>). The zircon &#x3b5;Hf (t) value and whole rock Nd isotope &#x3b5;Nd(t) of the granites in the East Junggar are significantly higher than zero, indicating substantial crustal growth in the region during the Late Paleozoic (<xref ref-type="bibr" rid="B87">Su et al., 2007</xref>; <xref ref-type="bibr" rid="B90">Tang et al., 2007</xref>; <xref ref-type="bibr" rid="B117">Yang et al., 2008</xref>; <xref ref-type="bibr" rid="B99">Wang et al., 2023</xref>). The zircon &#x3b5;Hf (t) values of the granites in the KGB are high, ranging from &#x2b;10.5 to &#x2b;14.7, which is close to the value for the depleted mantle (<xref ref-type="bibr" rid="B37">Han et al., 1997</xref>; <xref ref-type="bibr" rid="B21">Chen and Arakawa, 2005</xref>; <xref ref-type="bibr" rid="B23">Chen et al., 2010</xref>). This result suggests that the source is juvenile crust (<xref ref-type="bibr" rid="B106">Wu et al., 2007</xref>; <xref ref-type="bibr" rid="B95">Wang and Hou, 2018</xref>). In contrast, the granites of Western Junggar are characterized by lower &#x3b5;Hf(t) values (<xref ref-type="bibr" rid="B91">Tang et al., 2008</xref>; <xref ref-type="bibr" rid="B32">Geng et al., 2009</xref>). The whole-rock &#x3b5;Nd (t) values are &#x2b;4.0 to &#x2b;4.5 (as are the values obtained for the Sabei and Sujiquan plutons); all values are positive (<xref ref-type="fig" rid="F13">Figures 13a,b</xref>), indicating they may have been formed by the remelting of new crustal materials or the differentiation of mantle-derived magma (<xref ref-type="bibr" rid="B101">Whalen et al., 1987</xref>; <xref ref-type="bibr" rid="B37">Han et al., 1997</xref>; <xref ref-type="bibr" rid="B105">Wu et al., 2003</xref>; <xref ref-type="bibr" rid="B13">Bonin, 2007</xref>). The Sm/Nd-&#x3b5;Nd(t) diagram (<xref ref-type="fig" rid="F13">Figure 13a</xref>) indicates that the granites in the KGB are strongly influenced by continental contamination. The Sabei MMEs show a linear relationship with the host rock, reflecting the evolution of basic and siliceous magma. Additionally, the whole-rock Nd model age (T<sub>DM2</sub>) of the KGB is in the range 600&#x2013;650 Ma, suggesting its source area was the Neoproterozoic juvenile lower crust (<xref ref-type="bibr" rid="B97">Wang et al., 2009</xref>), which is consistent with the zircon Hf model age (T<sub>DM2</sub>) (<xref ref-type="bibr" rid="B124">Zhang et al., 2021</xref>). The Karamaili granite formed by remelting of earlier-accreted juvenile crustal material, which originated from depleted mantle sources during prior subduction (<xref ref-type="bibr" rid="B44">Jahn et al., 2000</xref>). Its emplacement reflects crustal reworking rather than primary growth. Crucially, &#x201c;vertical crustal growth&#x201d; refers to magmatic underplating at the crust-mantle boundary (<xref ref-type="bibr" rid="B79">Rudnick and Taylor, 1987</xref>), where new mantle-derived melts crystallize beneath pre-existing crust, increasing net crustal thickness and mass. During ascent, these juvenile magmas assimilated upper-crustal components (e.g., metasedimentary rocks), evidenced by inherited Proterozoic zircon cores and elevated &#x3b4;<sup>18</sup>O values. Concurrent magma mixing with mantle-derived melts generated MMEs, supported by disequilibrium textures and Hf-Nd isotope decoupling (<xref ref-type="bibr" rid="B46">Kemp et al., 2009</xref>). Spatial variations in the KGB manifest this process: shallow emplacement in the eastern Sabei and Sujiquan plutons preserved abundant MMEs due to limited residence time, whereas prolonged fractionation in western Kamusite pluton formed highly differentiated granites.</p>
<fig id="F13" position="float">
<label>FIGURE 13</label>
<caption>
<p>
<bold>(a)</bold> &#x3b5;Nd(t) vs. Sm/Nd (<xref ref-type="bibr" rid="B27">Dilek et al., 2008</xref>); <bold>(b)</bold> &#x3b5;Nd(t) vs. Age (<xref ref-type="bibr" rid="B34">Goldstein et al., 1984</xref>); <bold>(c)</bold> Nd-mode age profile of the Altai-Junggar-Beishan granite (modified after <xref ref-type="bibr" rid="B95">Wang and Hou (2018)</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1601135-g013.tif">
<alt-text content-type="machine-generated">Diagram with two graphs and a cross-section. Graph (a) shows &#x3B5;Nd(t) versus \(^{147}\)Sm/\(^{144}\)Nd, indicating crustal contamination and processes like crystal fractionation and partial melting. Graph (b) plots &#x3B5;Nd(t) against age, showing depleted mantle signature, and includes various granite types. The cross-section below illustrates crustal layers: older crust, juvenile crust, and ancient crust, highlighting tectonic belts. Data sources are cited in the legend.</alt-text>
</graphic>
</fig>
<p>In summary, the oceanic crust broke off and caused unbalanced delamination during the subduction at the end of the Late Carboniferous (<xref ref-type="bibr" rid="B124">Zhang et al., 2021</xref>), causing the partial melting of large amounts of mantle-derived materials. This event led to underplating at the bottom of the lower crust, triggering upwelling of the basic magma and resulting in the recharge and strong activation of the siliceous magmatic reservoir in the upper crust. Small amounts of basic magma caused the strong activation of the Kamusite and Laoyaquan plutons in the western part of the KGB. Thus, the high-silica melt was extracted from reactivated crystal mush from the high-silicon melt, forming highly differentiated granites with minimal magma mixing signatures. A large amount of basic magma was exchanged with the magma of the Sabei, Huangyangshan, and Sujiquan plutons in the eastern section. Many MMEs were formed by the mixing of basic and siliceous magma, which is manifesting as local-scale magma mixing. A slightly later gabbro pluton (311&#x2013;307 Ma) of non-ophiolitic origin in the KGB confirms the presence of basic magma in the Late Carboniferous (<xref ref-type="bibr" rid="B100">Wang et al., 2025</xref>). Additionally, a large number of diorite and gabbro veins formed in the Sujiquan and Huangyangshan granites in the eastern KGB, differing from the felsic veins that developed only in the Kamusite and Laoyaquan granites of the western KGB. Thus, the supply of basic magma was the dominant factor determining the final occurrence of siliceous magma, which implies both local-scale (mixing) and regional-scale (underplating) impacts of mafic magmatism. In other words, the geochemical linear evolution of the MMEs in the Sabei pluton shows that the injection of basic magma into siliceous magma is a continuous and multi-stage magmatic mixing (<xref ref-type="fig" rid="F5">Figure 5a&#x2013;i</xref>).</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s7">
<title>7 Conclusion</title>
<p>
<list list-type="simple">
<list-item>
<p>1. Zircon U-Pb ages of 315.9 &#xb1; 2.4 Ma, 316.1 &#xb1; 2.2 Ma, and 319.4 &#xb1; 2.0 Ma were obtained for the Sabei monzogranite, Huangyangshan biotite syenogranite, and Sujiquan biotite granite in the eastern KGB, intrusion during the Late Carboniferous. The 313.9 &#xb1; 3.5 Ma obtained for the Sabei MMEs is nearly identical to the age of the host granite.</p>
</list-item>
<list-item>
<p>2. The granites comprising the Sabei, Huangyangshan, and Sujiquan plutons are A<sub>2</sub>-type granites characterized by high contents of silica, potassium-richness, high-alkali content, and strongly negative Eu anomalies. These granites formed in post-collisional extensional environments, indicating the vertical growth of the juvenile crust during the Late Paleozoic.</p>
</list-item>
<list-item>
<p>3. The abundant MMEs in the granite of the Sabei pluton, which are dioritic enclaves, suggest magma mixing. They are the product of basic magma injected into felsic magma.</p>
</list-item>
<list-item>
<p>4. Spatial differences were observed in the evolution of the KGB. The western pluton was activated by basic magma, resulting in the formation of highly differentiated granites, such as the Kamusite granite. In contrast, the eastern plutons received large amounts of basic magma, forming A<sub>2</sub>-type granites rich in dioritic enclaves, such as the Sabei granite.</p>
</list-item>
<list-item>
<p>5. The formation of the Karamaili A-type granitic belt is associated with the vertical accretion of the late Paleozoic juvenile crust.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s8">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/supplementary material, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec sec-type="ethics-statement" id="s9">
<title>Ethics statement</title>
<p>Written informed consent was obtained from the individual(s), and minor(s)&#x2019; legal guardian/next of kin, for the publication of any potentially identifiable images or data included in this article.</p>
</sec>
<sec sec-type="author-contributions" id="s10">
<title>Author contributions</title>
<p>YS: Writing &#x2013; original draft, Software, Supervision, Methodology, Data curation, Writing &#x2013; review and editing, Investigation, Validation. BZ: Investigation, Supervision, Writing &#x2013; review and editing, Project administration, Methodology, Resources. YuY: Writing &#x2013; review and editing, Supervision, Data curation, Funding acquisition, Project administration. XZ: Supervision, Conceptualization, Writing &#x2013; review and editing, Software, Data curation. YaY: Investigation, Writing &#x2013; review and editing, Conceptualization, Supervision, Validation. YW: Validation, Supervision, Software, Writing &#x2013; review and editing.</p>
</sec>
<sec sec-type="funding-information" id="s11">
<title>Funding</title>
<p>The author(s) declare that financial support was received for the research and/or publication of this article. This work was supported by the National Key Research and Development Program (Grant No. 2022YFC3003700), Key R&#x26;D Program of Xinjiang Uygur Autonomous Region (Grant No. 2024B01015), and the Key Research and Development Program of Xinjiang Production and Construction Corps (Grant No. 2024AB077).</p>
</sec>
<sec sec-type="COI-statement" id="s12">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
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</sec>
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