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<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
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<article-id pub-id-type="publisher-id">1465894</article-id>
<article-id pub-id-type="doi">10.3389/feart.2025.1465894</article-id>
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<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
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<title-group>
<article-title>Deep crustal composition and Late Paleozoic geotectonic evolution in West Junggar, China</article-title>
<alt-title alt-title-type="left-running-head">Xu et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2025.1465894">10.3389/feart.2025.1465894</ext-link>
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<contrib contrib-type="author">
<name>
<surname>Xu</surname>
<given-names>Shenglin</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<contrib contrib-type="author" corresp="yes">
<name>
<surname>Ding</surname>
<given-names>Weicui</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<contrib contrib-type="author" corresp="yes">
<name>
<surname>Ma</surname>
<given-names>Feizhou</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<xref ref-type="aff" rid="aff2">
<sup>2</sup>
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<xref ref-type="corresp" rid="c001">&#x2a;</xref>
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<name>
<surname>Chen</surname>
<given-names>Xuanhua</given-names>
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<sup>1</sup>
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<contrib contrib-type="author">
<name>
<surname>Shao</surname>
<given-names>Zhaogang</given-names>
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<sup>1</sup>
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<contrib contrib-type="author">
<name>
<surname>Han</surname>
<given-names>Lele</given-names>
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<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<contrib contrib-type="author">
<name>
<surname>Huang</surname>
<given-names>Penghui</given-names>
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<xref ref-type="aff" rid="aff1">
<sup>1</sup>
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<xref ref-type="aff" rid="aff3">
<sup>3</sup>
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<contrib contrib-type="author">
<name>
<surname>Shi</surname>
<given-names>Jianjie</given-names>
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<sup>1</sup>
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<surname>Yang</surname>
<given-names>Xinru</given-names>
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<sup>1</sup>
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<aff id="aff1">
<sup>1</sup>
<institution>SinoProbe Center</institution>, <institution>Chinese Academy of Geological Sciences and China Geological Survey</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>China Geological Survey</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>Beijing Research Institute of Geological Engineering Design</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/111619/overview">Derek Keir</ext-link>, University of Southampton, United Kingdom</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1191197/overview">Huan Li</ext-link>, Central South University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1820060/overview">Chang-Hao Xiao</ext-link>, Institute of Geomechanics Chinese Academy of Geological Sciences, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Weicui Ding, <email>dingweicuigis@163.com</email>; Feizhou Ma, <email>mfeizhou@mail.cgs.gov.cn</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>25</day>
<month>02</month>
<year>2025</year>
</pub-date>
<pub-date pub-type="collection">
<year>2025</year>
</pub-date>
<volume>13</volume>
<elocation-id>1465894</elocation-id>
<history>
<date date-type="received">
<day>17</day>
<month>07</month>
<year>2024</year>
</date>
<date date-type="accepted">
<day>20</day>
<month>01</month>
<year>2025</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2025 Xu, Ding, Ma, Chen, Shao, Han, Huang, Shi and Yang.</copyright-statement>
<copyright-year>2025</copyright-year>
<copyright-holder>Xu, Ding, Ma, Chen, Shao, Han, Huang, Shi and Yang</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The West Junggar area in the southwestern part of the Central Asian Orogenic Belt (CAOB), is one of the largest areas of growth of the Phanerozoic crust in the world that has experienced intense Late Paleozoic magmatic activity, where crust-mantle interaction is significant. The issue of crustal growth has long been regarded as one of the most fundamental in earth sciences. In light of the challenges posed by the composition of deep materials and the Late Paleozoic crustal growth in the West Junggar area, there is a continued need to systematically determine the spatial distribution characteristics of deep materials in the crust, analysis the growth pattern and growth volume of the crust, and enhance the Late Paleozoic tectonic evolution of the region. Focusing on granite type Sr-Nd-Pb-Hf isotopic mapping, this study found that the West Junggar area has the isotopic characteristics of high positive &#x3b5;Hf (t) and &#x3b5;Nd (t), low (87 Sr/86 Sr)<sub>i</sub>, and young crustal mode age, there is almost no old crystalline basement in the deep crust. During the Late Paleozoic, about 85% of West Junggar had 75%&#x2013;95% crustal growth, dominated by lateral crustal growth and material recirculation; about 15% of the area (connected to the Jietebudiao area) had 50%&#x2013;75% crustal growth, dominated by vertical crustal growth. The West Junggar area mainly experienced four orogenic stages in the Late Paleozoic. In the Early Carboniferous period (360&#x2013;320 Ma), there was significant intra-oceanic subduction, involving a substantial amount of juvenile material in lateral crustal accretion. The Late Carboniferous-Early Permian period (320&#x2013;294 Ma) is the post-orogenic extension stage, during which a massive amount of juvenile mantle source was added. This resulted in the most intense magmatism and crustal growth, which could have the growth of the crust potentially more than 75%. In the Early Permian period (294&#x2013;272 Ma), there was an intracontinental evolution stage and a decrease in the participation of juvenile material. During the Early Permian-Early Triassic period (272&#x2013;250 Ma), magmatic activity decreased significantly, where the southwestern region experienced high-temperature, low-pressure, crustal thinning extension. Despite this, the crust received juvenile material, and plutonic magma intrusion occurred.</p>
</abstract>
<kwd-group>
<kwd>Late Paleozoic</kwd>
<kwd>Sr-Nd-Pb-Hf mapping</kwd>
<kwd>material composition</kwd>
<kwd>crustal growth</kwd>
<kwd>geotectonic evolution</kwd>
<kwd>West Junggar</kwd>
</kwd-group>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Structural Geology and Tectonics</meta-value>
</custom-meta>
</custom-meta-wrap>
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</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Isotopic tracing is a crucial tool for chemical geodynamic studies. It is one of the most important methods for analyzing the evolutionary history of the crust and mantle, identifying the material composition of the lithosphere, and exploring the deep dynamical processes of the Earth (<xref ref-type="bibr" rid="B83">Zheng et al., 1998</xref>; <xref ref-type="bibr" rid="B56">Wang and Hou, 2018</xref>; <xref ref-type="bibr" rid="B28">Hou and Wang, 2018</xref>). Isotopic mapping focuses on the continental lithosphere, using regional magmatic isotope data to reveal deep material composition and explore tectonic boundaries. This provides important support for understanding the growth of the continental crust and the tectonic evolution.</p>
<p>CAOB is one of the largest accretionary orogenic belts in the world, spanning over 5,000 km from the Siberian Craton to the European Craton and the North China Craton (<xref ref-type="bibr" rid="B61">Xiao et al., 2012</xref>; <xref ref-type="bibr" rid="B15">Chen et al., 2012a</xref>, <xref ref-type="bibr" rid="B10">Chen et al., 2012b</xref>, <xref ref-type="bibr" rid="B9">Chen et al., 2013a</xref>, <xref ref-type="bibr" rid="B8">Chen et al., 2016</xref>, <xref ref-type="bibr" rid="B13">Chen et al., 2022</xref>; <xref ref-type="bibr" rid="B40">Lkhagvasuren et al., 2020</xref>; <xref ref-type="bibr" rid="B37">Li et al., 2017</xref>; <xref ref-type="bibr" rid="B48">Sun et al., 2017</xref>; <xref ref-type="bibr" rid="B60">Wu et al., 2017</xref>; <xref ref-type="bibr" rid="B70">Yang et al., 2023</xref>; <xref ref-type="bibr" rid="B69">Yang et al., 2024</xref>) as a giant suture zone (<xref ref-type="fig" rid="F1">Figure 1A</xref>). During the Late Paleozoic, the western part of the CAOB experienced significant crust-mantle interactions. This led to the development of numerous high-magnesium andesites, island-arc granites, adakite, and picrite, which are important indicators of regional oceanic crustal subduction (<xref ref-type="bibr" rid="B77">Zhang and Huang, 1992</xref>; <xref ref-type="bibr" rid="B3">Buslov et al., 2004</xref>). As an important component of the western section of the CAOB (<xref ref-type="fig" rid="F1">Figure 1B</xref>), the Phanerozoic&#x2019;s crustal growth is of particular significance, and research findings are abundant (<xref ref-type="bibr" rid="B45">Shen et al., 2015</xref>; <xref ref-type="bibr" rid="B31">Jahn, 2004</xref>; <xref ref-type="bibr" rid="B14">Chen et al., 2014</xref>; <xref ref-type="bibr" rid="B66">Xu et al., 2022a</xref>; <xref ref-type="bibr" rid="B38">Liu et al., 2023</xref>). The crustal growth during the Late Paleozoic is manifested as follows: &#x2460; The crust exhibits significant lateral and vertical accretion and has a multi-stage evolutionary process. &#x2461; There is an intense interaction between the crust and mantle, with clear material cycling and multi-rotation characteristics (<xref ref-type="bibr" rid="B23">Han et al., 1998</xref>; <xref ref-type="bibr" rid="B24">Han et al., 2006</xref>; <xref ref-type="bibr" rid="B86">Zhu Y. F et al., 2007</xref>; <xref ref-type="bibr" rid="B62">Xiao et al., 2008</xref>; <xref ref-type="bibr" rid="B66">Xu et al., 2019a</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(A)</bold> Simplified tectonic sketch in the southwest of the Central Asian Orogenic Belt, <bold>(B)</bold> Tectonic setting in the western part in the West Junggar. (Modified after <xref ref-type="bibr" rid="B3">Buslov et al., 2004</xref>; <xref ref-type="bibr" rid="B14">Chen et al., 2014</xref>; <xref ref-type="bibr" rid="B66">Xu et al., 2022a</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1465894-g001.tif"/>
</fig>
<p>The studies on CAOB have shown that the Phanerozoic crustal growth may exceed 50% and is one of the most significant Phanerozoic crustal growth regions in the world (<xref ref-type="bibr" rid="B29">Huang et al., 2018</xref>; <xref ref-type="bibr" rid="B56">Wang and Hou, 2018</xref>). Some scholars have expressed differing views (<xref ref-type="bibr" rid="B39">Liu and Nie, 2015</xref>; <xref ref-type="bibr" rid="B41">Lv et al., 2017</xref>).</p>
<p>In the past, research on the source areas and crustal growth of magmatism in the West Junggar area has been carried out by different types of magmatism, resulting in a substantial accumulation of research information. However, the spatial distribution characteristics of deep crustal materials, the delineation of isotopic crustal boundaries in the region, and the quantitative-semi-quantitative estimation of crustal growth have not been systematically analyzed, resulting in a pattern of crustal growth in the West Junggar area that still needs to be studied in depth. <xref ref-type="bibr" rid="B66">Xu et al. (2022a)</xref> conducted Sr-Nd-Pb isotope studies in the West Junggar area. This paper combines their research results with the extensive collection of Hf isotope data published by previous authors (<xref ref-type="bibr" rid="B7">Chen S. S. et al., 2013</xref>; <xref ref-type="bibr" rid="B73">Yin et al., 2016</xref>; <xref ref-type="bibr" rid="B32">Jiang et al., 2015</xref>; <xref ref-type="bibr" rid="B55">Wang et al., 2017</xref>; <xref ref-type="bibr" rid="B71">Yang et al., 2015</xref>; <xref ref-type="bibr" rid="B34">Jin et al., 2016</xref>; <xref ref-type="bibr" rid="B53">Tian and Yang, 2015</xref>; <xref ref-type="bibr" rid="B22">Geng et al., 2009</xref>; <xref ref-type="bibr" rid="B81">Zhang and Zhang, 2014</xref>; <xref ref-type="bibr" rid="B36">Li et al., 2014</xref>; <xref ref-type="bibr" rid="B35">Li et al., 2015</xref>; <xref ref-type="bibr" rid="B49">Tang et al., 2012</xref>; <xref ref-type="bibr" rid="B6">Chen J. F. et al., 2015</xref>; <xref ref-type="bibr" rid="B74">Yin et al., 2015</xref>; <xref ref-type="bibr" rid="B59">Wu et al., 2018</xref>; <xref ref-type="bibr" rid="B43">Shen et al., 2017</xref>; <xref ref-type="bibr" rid="B57">Wang X. S. et al., 2018</xref>; <xref ref-type="bibr" rid="B78">Zhang et al., 2018</xref>; <xref ref-type="bibr" rid="B65">Xu et al., 2019b</xref>; <xref ref-type="bibr" rid="B63">Xu et al., 2020</xref>; <xref ref-type="bibr" rid="B67">Xu et al., 2022b</xref>), has added the Hf isotope data for key areas in the study (<xref ref-type="sec" rid="s12">Supplementary Table S1</xref>). It comprehensively explores the Sr-Nd-Pb-Hf isotopic composition of granite analogs in the West Junggar area. The Kriging interpolation method (<xref ref-type="bibr" rid="B4">Chen et al., 2007</xref>) has generated the Sr-Nd-Pb-Hf isotope contour maps in the Suffer 14 software. We combine with the regional tectonic background, analyze the composition of deep crustal materials, delineate the tectonic boundaries of the crust in the region, explore the amount of crustal growth, growth periods, and patterns, and explore the late Paleozoic tectonic evolution of West Junggar.</p>
</sec>
<sec id="s2">
<title>2 Regional geological background</title>
<sec id="s2-1">
<title>2.1 Regional faults</title>
<p>The West Junggar Faults System is located between the Chenggis-Junggar Fault, the Tianshan Fault, and the Irtysh Strike-slip Fault (<xref ref-type="fig" rid="F1">Figure 1B</xref>). The region is characterized by large-scale left or right lateral strike-slip faults (<xref ref-type="bibr" rid="B12">Chen et al., 2009</xref>; <xref ref-type="bibr" rid="B16">Chen et al., 2015</xref>; <xref ref-type="bibr" rid="B25">Han et al., 2019</xref>; <xref ref-type="bibr" rid="B18">Ding et al., 2020</xref>). The left-lateral strike-slip faults consist of three large-scale faults: the Darabut Fault, the Karamay Fault, and the Baerluke Fault. And a series of smaller-scale secondary faults. The right-lateral strike-slip faults are primarily composed of large-scale faults, including the Zalulshan-Labashan Fault and the Abbey Lake Fault (<xref ref-type="fig" rid="F2">Figure 2</xref>).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Stratigraphic, structure-magmatic diagram of the West Junggar Area. <bold>(A, B)</bold> shows the location of the profile in <xref ref-type="fig" rid="F8">Figure 8</xref>. (Modified after <xref ref-type="bibr" rid="B17">Chen et al., 2011</xref>, <xref ref-type="bibr" rid="B9">Chen et al., 2015a</xref>, <xref ref-type="bibr" rid="B11">Chen et al., 2017</xref>).</p>
</caption>
<graphic xlink:href="feart-13-1465894-g002.tif"/>
</fig>
</sec>
<sec id="s2-2">
<title>2.2 Stratigraphy</title>
<p>Sedimentary strata have been widely distributed in the West Junggar area since the Phanerozoic era, with the Paleozoic era being the most developed (<xref ref-type="bibr" rid="B26">He et al., 2004</xref>; <xref ref-type="fig" rid="F2">Figure 2</xref>). The sedimentary strata can be divided into two parts: one is the Early Paleozoic metamorphic stratigraphy, which is dominated by flysch formation and ophiolite m&#xe9;lange, with strong metamorphism and deformation; the other is the Late Paleozoic pyroclastic sedimentary formation, which consists of giant-thick marine-continental slope-face sedimentary rocks (<xref ref-type="bibr" rid="B85">Zhu et al., 2013</xref>).</p>
</sec>
<sec id="s2-3">
<title>2.3 Ophiolite m&#xe9;lange</title>
<p>Regional ophiolite m&#xe9;langes such as Darabut, Karamay, and Baerluke are distributed along the main fault zones (<xref ref-type="fig" rid="F2">Figure 2</xref>). The rock compositions include serpentinite peridotite, dunite, serpentine, pyroxenite, gabbro, diabase, basalt, oceanic plagiogranite, and siliceous rocks.</p>
</sec>
<sec id="s2-4">
<title>2.4 Magmatism</title>
<p>The Late Paleozoic magmatic activity in the region was intense, with abundant rock types, divided into large granitic basement and small and medium-sized rock strains (<xref ref-type="fig" rid="F2">Figure 2</xref>).</p>
<p>The granite basement comprises the Miaoergou, Kurumusu, Karamay, and Hatu batholiths. The rocks consist mainly of A-type granites, such as alkaline and monzonitic granite. These rocks are characterized by high silica, quasi-alumina-weak per aluminum, high-K calc-alkaline, low magnesium, and ferrum, which belong to the post-collisional orogenic stage of the Late Carboniferous-Early Permian (<xref ref-type="bibr" rid="B24">Han et al., 2006</xref>; <xref ref-type="bibr" rid="B47">Su et al., 2006</xref>; <xref ref-type="bibr" rid="B84">Zhou et al., 2008</xref>).</p>
<p>The small and medium-sized rock strains are dispersed, and the rocks consist mainly of granodiorite, biotite granite, quartz diorite, and diorite porphyrite.</p>
<p>These rocks may have formed during the Middle-Late Carboniferous subduction of the mid-ocean ridge or in the island arc environment, and some of the island arc granites have obvious adakite characteristics (<xref ref-type="bibr" rid="B22">Geng et al., 2009</xref>; <xref ref-type="bibr" rid="B79">Zhang et al., 2006</xref>; <xref ref-type="bibr" rid="B52">Tang et al., 2009</xref>; <xref ref-type="bibr" rid="B50">Tang et al., 2010a</xref>; <xref ref-type="bibr" rid="B51">Tang et al., 2010b</xref>; <xref ref-type="bibr" rid="B44">Shen et al., 2009</xref>).</p>
</sec>
</sec>
<sec id="s3">
<title>3 Sample preparation and analytical methods</title>
<p>Based on the completion of the U-Pb dating of the sample zircon, the zircon Lu-Hf isotope analysis was carried out at the State Key Laboratory of Continental Dynamics of Northwestern University, where the location of the zircon Lu-Hf isotope measurement point and the location of the U-Pb dating measurement point is the same magmatic growth ring belt within the same zircon grain. The laser ablation system is a 193 nm excimer laser ablation system (RESOlution M-50, ASI) with a frequency of 5 Hz, a spot size of 43 &#x3bc;m, and a carrier gas of high-purity helium. Lu-Hf isotopes were analyzed by multi-reception plasma mass spectrometry (Nu Plas Ma II MC-ICPMS). During the analysis, international standard zircon samples 91,500 and Mud Tank were used as monitoring samples, and a set of international standard samples was inserted every 8 samples. The data acquisition mode was TRA mode with an integration time of 0.2 s, a background acquisition time of 30 s, a sample integration time of 50 s, and a purge time of 40 s. The specific test steps and methods are described in detail in <xref ref-type="bibr" rid="B2">Bao et al. (2017)</xref> and <xref ref-type="bibr" rid="B76">Yuan et al. (2008)</xref>. Among them, the average value of <sup>176</sup>Hf/<sup>177</sup> Hf determination of standard sample 91,500 is 0.282,313 &#xb1; 0.000021 (2&#x3c3;), and the average value of <sup>176</sup>Hf/<sup>177</sup> Hf determination of standard sample Mud Tank is 0.282,524 &#xb1; 0.000013 (2&#x3c3;), and the test data of the standard samples are all within the error range (<xref ref-type="bibr" rid="B76">Yuan et al., 2008</xref>), indicating that the test results of the samples in this paper are reliable. The detailed test results are shown in <xref ref-type="sec" rid="s12">Supplementary Appendix Table S2</xref>.</p>
</sec>
<sec id="s4">
<title>4 Regional isotope characterization</title>
<sec id="s4-1">
<title>4.1 Sr-Nd-Pb isotopes characterization</title>
<p>The West Junggar area is characterized by higher (<sup>143</sup> Nd/<sup>144</sup> Nd)i values and positive <italic>&#x3b5;</italic>
<sub>Nd</sub> (t) values, with an overall range of &#x3b5;Nd(t) values of 2.29&#x2013;8.75, and an overall range of crustal model ages of 345&#x2013;851 Ma (<xref ref-type="bibr" rid="B66">Xu et al., 2022a</xref>). The basement of the West Junggar region is dominated by juvenile crust (<xref ref-type="fig" rid="F3">Figure 3</xref>). The Nd isotope maps show the distribution of isotope provinces, which are divided into three-high, three-medium, and one-low, with material sources from Paleoproterozoic, middle-late Neoproterozoic, and early Neoproterozoic material respectively.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>&#x3b5;Nd contour map of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g003.tif"/>
</fig>
<p>The isotopic ratio range for granites (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> in the West Junggar region is considerably wide, spanning from 0.697,397 to 0.708,336, which is coupled with the Nd isotopic signatures (<xref ref-type="bibr" rid="B66">Xu et al., 2022a</xref>). The Sr isotopic characteristics also suggest that the crust of the West Junggar area mainly originated from the juvenile crust, with minimal ancient crustal material. The Sr isotope maps show the distribution characteristics, with ultra-low-value, low-value, and medium-low-value provinces (<xref ref-type="fig" rid="F4">Figure 4</xref>).</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Granites (87 Sr/86 Sr)i Contour map of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g004.tif"/>
</fig>
<p>The ratio range for (<sup>206</sup>Pb/<sup>204</sup>Pb)<sub>i</sub> of the West Junggar area spans from 17.4975 to 19.0352 (<xref ref-type="bibr" rid="B66">Xu et al., 2022a</xref>), indicating that the crust of the study region did not mixed the ancient crust during the Late Paleozoic magmatic intrusion process. The Pb isotope maps show the distribution characteristics, with high-value, medium-value, and low-value provinces (<xref ref-type="fig" rid="F5">Figure 5</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>(206 Pb/204 Pb)i Contour map of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g005.tif"/>
</fig>
</sec>
<sec id="s4-2">
<title>4.2 Hf isotopic characterization</title>
<p>The West Junggar region is characterized by higher <sup>176</sup>Hf/<sup>177</sup>Hf ratios and positive <italic>&#x3b5;</italic>
<sub>Hf</sub> (t) values, with individual sample values displaying a broad range of variability. The overall mean range of &#x3b5;Nd(t) values and crustal model ages are 6.67&#x2013;16.82 and 251&#x2013;893 Ma respectively The minimum value of <italic>&#x3b5;</italic>
<sub>Hf</sub> (t) ranges from 2.79 to 14.49, and the maximum value of crustal model age is 425&#x2013;1,148 Ma. The crust of the West Junggar area is mainly juvenile crust, which can be divided into three levels of Hf isotope provinces (<xref ref-type="fig" rid="F6">Figure 6</xref>): High <italic>&#x3b5;</italic>
<sub>Hf</sub> value province, Medium <italic>&#x3b5;</italic>
<sub>Hf</sub> value province, and Low <italic>&#x3b5;</italic>
<sub>Hf</sub> value provinces. The high <italic>&#x3b5;</italic>
<sub>Hf</sub> values provinces are mainly distributed in the numerous rock masses proximal to the Darabut Fault and the partial rock mass of the north-central segment in the Mayile Fault. The Medium <italic>&#x3b5;</italic>
<sub>Hf</sub> value province is mainly distributed in the area around the Tiechanggou batholith-western Miaoergou batholith-Labahedong batholith. The northwest of Karamay, south of Tiechanggou batholith, near Tuoli County, and the Jietebudiao batholith exhibit relatively low <italic>&#x3b5;</italic>
<sub>Hf</sub> values.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Contour map of the mean value of &#x3b5;Hf of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g006.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="discussion" id="s5">
<title>5 Discussion</title>
<sec id="s5-1">
<title>5.1 Deep material composition</title>
<p>Geophysical exploration combined with surface geological surveys has been one of the most important means of probing the composition of the lithosphere. <xref ref-type="bibr" rid="B66">Xu et al. (2022a)</xref> concluded that there is a certain degree of correspondence between the aeromagnetic anomalous area and the isotope anomalous area, as evidenced by comparative analysis of regional aeromagnetic maps, gravity maps, and Sr-Nd-Pb contour maps. The Hf isotopic signatures of the rocks can indicate the properties of the deep source region. The Hf-Nd isotopic decoupling due to multiple factors can be excluded by calculating the average Hf isotope values and analyzing them compared to Nd isotopes. The whole-rock Sr-Nd-Pb isotope results of magma-mixed granites reflect the process of magma mixing, which cannot completely exclude the interference of ancient materials. Since Hf isotope values can be measured from single zircons and have a wide range of values in magmatic samples, it is possible to explore the presence of ancient material through Hf isotope signatures. The Sr-Nd-Pb isotope results generally indicate the absence of an ancient crystalline basement probably in the West Junggar region. To investigate the properties of the deep material source area, mean crustal model age maps were produced using the Hf isotopes&#x2019; arithmetic mean value and compared with the Nd isotope contour map. Additionally, the maximum value of the crustal model age map is produced using the minimum value of the Hf isotopes, which aids in the analysis of the composition of the deep ancient materials in the West Junggar area.</p>
<p>The age range of ancient crustal materials in the West Junggar area is extensive. (1) The maximum crustal model ages in some areas are about 400&#x2013;550 Ma, which is near the Hongshan batholith, the Miaoergou batholith, and the Dulunhedong batholith near the Darabut fault, which indicates that the deep oldest crustal materials have been formed in the Early Paleozoic. (2) The maximum crustal model ages of large rock bases such as Miaoergou batholith, Hatu batholith, Tiechanggou batholith, Akbastao batholith, Hatu batholith, and Kurumusu batholith are &#x223c;550&#x2013;700 Ma, indicating that the deep oldest crustal material may have formed in the late Neoproterozoic. (3) The maximum crustal model ages in the southern part of Karamay, the northern part of Hongshan batholith, the southern and the western part of the Tuoli, and the Jietebudiao batholith is &#x223c;700&#x2013;1,000 Ma, indicating that the oldest crustal material at depth may have formed in the Early Neoproterozoic (<xref ref-type="fig" rid="F7">Figure 7</xref>).</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Contour map of Hf crustal model age maximum of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g007.tif"/>
</fig>
<p>In this paper, we produced a Pb-Nd-Hf isotope typical profile (The location of the profile is shown in <xref ref-type="fig" rid="F2">Figure 2</xref>). To discuss the boundaries of the regional tectonics and the deep materials and the properties of the deep crust, we compared and analyzed the profile map between the magnetotelluric sounding (<xref ref-type="bibr" rid="B68">Xu et al., 2016</xref>), (<sup>206</sup>Pb/<sup>204</sup>Pb)<sub>i</sub>, Hf crustal model maximum age and Nd model age comprehensively (<xref ref-type="fig" rid="F8">Figure 8</xref>).</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Geological-geophysical-isotopic characterization of typical profiles of the West Junggar Area. <bold>(A)</bold> Magnetotelluric sounding profile (<xref ref-type="bibr" rid="B68">Xu et al., 2016</xref>), <bold>(B)</bold> (<sup>206</sup> Pb/<sup>204</sup> Pb)i profile, <bold>(C)</bold> Hf maximum mode age profile, <bold>(D)</bold> Nd model age profile. Profile location: <bold>(A)</bold> Emin County. <bold>(B)</bold> Karamay City. <bold>(A, B)</bold> represents the location of the section in <xref ref-type="fig" rid="F2">Figure 2</xref>.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g008.tif"/>
</fig>
<p>Although there are some differences in resistivity between the two sides of the Baerluk fault, Nd-Pb-Hf isotope values are more consistent, both indicating the age of deep crust material is relatively older. Near the Mayile Fault, the value of (<sup>206</sup>Pb/<sup>204</sup>Pb)<sub>i</sub> shows a decreasing trend, and the Nd-Hf mode age becomes younger, indicating that the age of deep material is gradually becoming younger.</p>
<p>In the region between the Mayile Fault and the Darabut Fault, the variations of Nd-Pb-Hf isotopic and the deep materials are relatively consistent, and have good correspondence. There are obvious electrical differences on both sides of the Darabut Fault, the Hatu Fault, and the Mayile Fault, which are also the inflection points of Nd-Pb-Hf isotope changes. It can be concluded that there are highly comparable in some features of the geology, geophysics, and geochemistry of the West Junggar area through the above joint sections comparative study. It shows that the Isotopic mapping can provide sufficient evidence of deep material for the deep lithosphere study.</p>
</sec>
<sec id="s5-2">
<title>5.2 Deep material evolution</title>
<p>Previous studies have significant controversial on the crustal growth of the CAOB during the Phanerozoic (<xref ref-type="bibr" rid="B72">Yang et al., 2017</xref>; <xref ref-type="bibr" rid="B29">Huang et al., 2018</xref>; <xref ref-type="bibr" rid="B58">Wang T. et al., 2018</xref>; <xref ref-type="bibr" rid="B41">Lv et al., 2017</xref>). <xref ref-type="bibr" rid="B66">Xu et al. (2022a)</xref> concluded that the mantle contribution values of West Junggar are all greater than 50%, concentrating on 75%&#x2013;95% by performing Sr-Nd-Pb Isotopic mapping in the West Junggar area. It is indicated that the crustal growth volume of the West Junggar area is huge in the Late Paleozoic, the whole is greater than 50%.</p>
<p>In this paper, we map the scatter plot of Hf isotopes in the West Junggar area to discuss the evolution of deep crust during the Late Paleozoic (<xref ref-type="fig" rid="F9">Figure 9</xref>). During the Early Carboniferous (&#x223c;360&#x2013;320 Ma), the Hf isotope values of the West Junggar area exhibited a gradual increase trend, indicating that the contribution degree of mantle source material to the crust is gradually increasing. During the Late Carboniferous-Early Permian (&#x223c;320&#x2013;294 Ma), in the West Junggar region, the Hf isotopic signature indicates that the predominant magmatism and the most significant crustal growth (the majority of the crustal growth volume was greater than 75%) due to the contribution of a considerable amount of mantle source material. Since the Early Permian (&#x223c;294 Ma), there has been a notable decrease in the contribution of the juvenile mantle source material to the West Junggar region. Although the isotopic values of intermediate-acid magmatism in the area still exhibit a relatively younger signature, the contribution of the juvenile material shows a gradual weakening trend compared with the previous peak of magmatism. During the Middle Permian to the Early Triassic, most regions of West Junggar experienced a quiescence period concerning hypogene magmatic activity, there were nevertheless significant deep magmatic intrusions in the southwestern Jietebudiao area (<xref ref-type="bibr" rid="B63">Xu et al., 2020</xref>). Furthermore, the contribution of juvenile material exhibits an upward trend.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Hf isotopic composition of Early Carboniferous-Early Triassic of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g009.tif"/>
</fig>
</sec>
<sec id="s5-3">
<title>5.3 Geotectonic evolution</title>
<p>The geotectonic evolution of the West Junggar area is controlled by the opening and closure of the Junggar Ocean closely. Existing evidence indicates that the primary evolutionary phase of the Junggar Ocean has been ongoing since the early Paleozoic.</p>
<p>Among them, the West Junggar Tangbala ophiolite m&#xe9;langes (limited ocean basin) with the blueschist metamorphism (458&#x2013;470 Ma; <xref ref-type="bibr" rid="B80">Zhang, 1997</xref>), the Hongguleleng ophiolite m&#xe9;langes (<xref ref-type="bibr" rid="B77">Zhang and Huang, 1992</xref>; <xref ref-type="bibr" rid="B82">Zhang and Guo, 2010</xref>), and the Taerbahatai Kujibai ophiolite m&#xe9;langes (<xref ref-type="bibr" rid="B87">Zhu and Xu, 2006</xref>) were formed in the Ordovician (<xref ref-type="bibr" rid="B27">He et al., 2007</xref>). The Karamay ophiolite m&#xe9;langes may form in the Cambrian-Ordovician (<xref ref-type="bibr" rid="B27">He et al., 2007</xref>; <xref ref-type="bibr" rid="B86">Zhu et al., 2007</xref>). The Darabut ophiolite m&#xe9;langes was formed in the Early Devonian (<xref ref-type="bibr" rid="B21">Feng et al., 1989</xref>; <xref ref-type="bibr" rid="B77">Zhang and Huang, 1992</xref>). These Early Paleozoic ophiolitic m&#xe9;langes suggest that the West Junggar area was in the stage of oceanic basin evolution before the Early Carboniferous. So, the West Junggar area experienced the following four periods of tectonic evolution during the Late Paleozoic (<xref ref-type="fig" rid="F10">Figure 10</xref>):<list list-type="simple">
<list-item>
<p>(1) The Early Carboniferous Period (360&#x2013;320 Ma). The Junggar Ocean underwent intra-oceanic subduction (<xref ref-type="bibr" rid="B72">Yang et al., 2017</xref>) and formed an intra-oceanic arc represented by the Bogutu Island Arc (<xref ref-type="bibr" rid="B54">Tong et al., 2014</xref>), which is similar to the multi-oceanic island form of the West Pacific tectonic domain. The arc is dominated by I-type granitoids (including adakites) and deposits a set of huge deep-sea and semi-deep-sea sedimentary constructions (<xref ref-type="bibr" rid="B1">An and Zhu, 2009</xref>). A large amount of juvenile crust was continuously added under the oceanic crust and islands of the West Junggar area as the subduction progressed. The Hf isotopes overall exhibited a trend of gradual increase, and the crust underwent lateral accretion.</p>
</list-item>
<list-item>
<p>(2) The Late Carboniferous-Early Permian Period (320&#x2013;294 Ma). The West Junggar area completed the ocean-land tectonic transition as the weakened subduction gradually of the Junggar Ocean (<xref ref-type="bibr" rid="B46">Shi et al., 2017</xref>; <xref ref-type="bibr" rid="B64">Xu et al., 2019a</xref>; <xref ref-type="bibr" rid="B42">Ma et al., 2020</xref>). Under the post-orogenic extension of the tectonic background characterized by crustal stretching and thinning, lower pressure, and mantle magma upwelled. The lower and middle crust was molten by heat, and the extremely intense magmatism, a large granitic basement dominated by A-type granites was formed (<xref ref-type="bibr" rid="B24">Han et al., 2006</xref>; <xref ref-type="bibr" rid="B30">Huang et al., 2016</xref>; <xref ref-type="bibr" rid="B5">Chen et al., 2010</xref>). The I-type granite with characteristics of crust-mantle mixing was formed by the mixing between basite formed by the lower-middle crust and acidic magma chamber. Some of these contributed to the growth crust of the Western Junggar region in the form of the intermediate-basic dike along the tensile fissure (<xref ref-type="bibr" rid="B67">Xu et al., 2022b</xref>; <xref ref-type="bibr" rid="B19">Duan et al., 2021</xref>). The sedimentary construction has transitioned from deep-sea to semi-deep-sea facies evolved into continental slope facies in the West Junggar area as the extension ongoing, the crust thickened, and seawater receded (<xref ref-type="bibr" rid="B26">He et al., 2004</xref>; <xref ref-type="bibr" rid="B33">Ji and Li, 1998</xref>). In general, the Late Carboniferous-Early Permian was the most intense period of magmatism in the West Junggar area. The crustal growth may have been dominated by the recirculation of Paleoproterozoic oceanic crust or oceanic island arcs, or with a small amount of juvenile material formed directly by mantle magmatism during the basement intrusion, and the crustal growth volume may have been as high as 75% or more in most areas.</p>
</list-item>
<list-item>
<p>(3) The Early Permian Period (294&#x2013;272 Ma). The magmatic activity in the West Junggar area was weakened, and the contribution of juvenile materials showed a gradual weakening trend compared with the previous peak period of magmatic activity (<xref ref-type="bibr" rid="B75">Yin et al., 2011</xref>). The emergence of the red mullite assemblage (<xref ref-type="bibr" rid="B85">Zhu et al., 2013</xref>) indicated that the West Junggar area was already in the intra-terrestrial evolution stage.</p>
</list-item>
<list-item>
<p>(4) The Early Permian-Early Triassic Period (272&#x2013;250 Ma). The deep magmatic intrusion observed in most areas of the West Junggar had largely finished, except in the southwestern region, where the Jietebudiao batholith was still undergoing multiple phases of deep magmatic intrusion (<xref ref-type="bibr" rid="B63">Xu et al., 2020</xref>). Under a high-temperature, low-pressure, crustal-thinning extensional environment, in the Jietebudiao area, the upwelling of mantle magmas brought a considerable amount of heat and juvenile materials, resulting in the formation of shell-mantle mixed-source I-type granites and highly differentiated I-type granites, in which the crust is predominantly vertically accretionary. Most areas of West Junggar in a weather and denudation intracontinental setting controlled by the Continued crustal uplift during the Middle and Late Permian, which resulted in the absence of the Middle and Upper Permian.</p>
</list-item>
</list>
</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Carboniferous-Permian tectonic evolutionary pattern of the West Junggar Area.</p>
</caption>
<graphic xlink:href="feart-13-1465894-g010.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="conclusion" id="s6">
<title>6 Conclusion</title>
<p>
<list list-type="simple">
<list-item>
<p>(1) Whole-rock Sr-Nd-Pb-Hf Isotopic mapping studies indicate that the deep material in the West Junggar area is dominated by the Paleozoic juvenile crust, with a limited ancient crystalline basement.</p>
</list-item>
<list-item>
<p>(2) The West Junggar area is characterized by higher positive &#x3b5;Hf(t), higher positive &#x3b5;Nd(t), lower (<sup>87</sup> Sr/<sup>86</sup> Sr)<sub>i</sub>, and young crustal model ages. During the Late Paleozoic Carboniferous-Permian, &#x223c;85% of the area of West Junggar had a crustal growth volume of 75%&#x2013;95%, which was dominated by lateral crustal growth and material recirculation. &#x223c;15% of the area (the Jietebudiao area) had a crustal growth volume of 50%&#x2013;75%, which was dominated by vertical crustal growth.</p>
</list-item>
<list-item>
<p>(3) The West Junggar area experienced the multistage evolution during the Late Paleozoic: The Early Carboniferous was characterized by intra-oceanic subduction with the juvenile material constantly contributing to the lateral accretion of the crust. During the post-orogenic extension stage in Late Carboniferous - Early Permian, the magmatism was concentrated during this period and the huge amount of juvenile mantle source mixed, and the crustal growth volume may be as high as 75% or more. In the Early Permian, the region entered the intracontinental evolution stage, magmatic activity weakened, and the involvement of juvenile material gradually decreased. During the Middle Permian-Early Triassic, the southwestern Jietebudiao region remains the magmatism activity and resulting in the increased amount of juvenile material contributed to the crust growth.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s7">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s12">Supplementary Material</xref>, further inquiries can be directed to the corresponding authors.</p>
</sec>
<sec sec-type="author-contributions" id="s8">
<title>Author contributions</title>
<p>SX: Conceptualization, Data curation, Formal Analysis, Investigation, Methodology, Project administration, Resources, Supervision, Validation, Visualization, Writing&#x2013;original draft, Writing&#x2013;review and editing. WD: Conceptualization, Data curation, Formal Analysis, Investigation, Project administration, Software, Supervision, Visualization, Writing&#x2013;review and editing. FM: Formal Analysis, Investigation, Writing&#x2013;review and editing. XC: Conceptualization, Formal Analysis, Funding acquisition, Data curation, Writing&#x2013;original draft, Investigation, Methodology. ZS: Data curation, Funding acquisition, Investigation, Writing&#x2013;review and editing. LH: Software, Visualization, Writing&#x2013;review and editing. PH: Data curation, Investigation, Writing&#x2013;original draft. JS: Investigation, Software, Writing&#x2013;original draft. XY: Software, Writing&#x2013;review and editing.</p>
</sec>
<sec sec-type="funding-information" id="s9">
<title>Funding</title>
<p>The author(s) declare that financial support was received for the research, authorship, and/or publication of this article. This study was financially supported by the China National Science and Technology Major Project (2024ZD1001106), the China Geological Survey (DD20230008, DD20230229, DD20160083) and the Fundamental Research Funds for the Chinese Academy of Geological Sciences (JKY202011).</p>
</sec>
<ack>
<p>We thank the members of the Deep Geology Department of the Chinese Academy of Geological Sciences for their assistance.</p>
</ack>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec id="s12">
<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2025.1465894/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2025.1465894/full&#x23;supplementary-material</ext-link>
</p>
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<supplementary-material xlink:href="DataSheet3.pdf" id="SM2" mimetype="application/pdf" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="DataSheet1.pdf" id="SM3" mimetype="application/pdf" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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