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<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
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<article-id pub-id-type="publisher-id">1473101</article-id>
<article-id pub-id-type="doi">10.3389/feart.2024.1473101</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Petrogenesis and tectonic setting of the proto-tethyan dachaidan ophiolite, North China: insights from clinopyroxene chemistry and whole-rock Sr&#x2013;Nd&#x2013;Pb and zircon Hf isotopes</article-title>
<alt-title alt-title-type="left-running-head">Qu et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2024.1473101">10.3389/feart.2024.1473101</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Qu</surname>
<given-names>Yilin</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
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<contrib contrib-type="author" corresp="yes">
<name>
<surname>Liu</surname>
<given-names>Xijun</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
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<contrib contrib-type="author">
<name>
<surname>Liu</surname>
<given-names>Xiao</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2810596/overview"/>
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<contrib contrib-type="author">
<name>
<surname>Huang</surname>
<given-names>Qianwen</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
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<contrib contrib-type="author">
<name>
<surname>Yang</surname>
<given-names>Qijun</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<role content-type="https://credit.niso.org/contributor-roles/data-curation/"/>
<role content-type="https://credit.niso.org/contributor-roles/Writing - review &#x26; editing/"/>
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<contrib contrib-type="author">
<name>
<surname>Hu</surname>
<given-names>Rongguo</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2257193/overview"/>
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<contrib contrib-type="author">
<name>
<surname>Liu</surname>
<given-names>Pengde</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
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<contrib contrib-type="author">
<name>
<surname>Song</surname>
<given-names>Yujia</given-names>
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<sup>1</sup>
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<aff id="aff1">
<sup>1</sup>
<institution>Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration</institution>, <institution>Guilin University of Technology</institution>, <addr-line>Guilin</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi</institution>, <institution>Guilin University of Technology</institution>, <addr-line>Guilin</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>Guangxi Science Innovation Base for Formation and Exploration of Strategic Critical Mineral Resources</institution>, <institution>Guilin University of Technology</institution>, <addr-line>Guilin</addr-line>, <country>China</country>
</aff>
<aff id="aff4">
<sup>4</sup>
<institution>National Key Laboratory of Ecological Security and Resource Utilization in Arid Areas</institution>, <institution>Xinjiang Institute of Ecology and Geography</institution>, <institution>Chinese Academy of Sciences</institution>, <addr-line>Urumqi</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/938712/overview">Xiao-Ping Xia</ext-link>, Chinese Academy of Sciences (CAS), China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1586559/overview">Gaoxue Yang</ext-link>, Chang&#x2019;an University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1858185/overview">Fei Wu</ext-link>, China University of Geosciences Wuhan, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Xijun Liu, <email>xijunliu@glut.edu.cn</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>15</day>
<month>10</month>
<year>2024</year>
</pub-date>
<pub-date pub-type="collection">
<year>2024</year>
</pub-date>
<volume>12</volume>
<elocation-id>1473101</elocation-id>
<history>
<date date-type="received">
<day>30</day>
<month>07</month>
<year>2024</year>
</date>
<date date-type="accepted">
<day>27</day>
<month>09</month>
<year>2024</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2024 Qu, Liu, Liu, Huang, Yang, Hu, Liu and Song.</copyright-statement>
<copyright-year>2024</copyright-year>
<copyright-holder>Qu, Liu, Liu, Huang, Yang, Hu, Liu and Song</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<sec>
<title>Introduction</title>
<p>The Dachaidan ophiolites outcrop within an ultrahigh-pressure metamorphic belt along the northern margin of the Qaidam Basin. However, their age, source, and tectonic setting remain still in debate.</p>
</sec>
<sec>
<title>Method</title>
<p>In this study, we investigated the geochemistry and geochronology of the Dachaidan ophiolitic gabbros.</p>
</sec>
<sec>
<title>Results and Discussion</title>
<p>Zircon U&#x2013;Pb dating yielded a crystallization age of 510.0 &#xb1; 2.8 Ma and 510.0 &#xb1; 2.9 Ma for the gabbro. The gabbros have low SiO<sub>2</sub> contents (47.15&#x2013;50.10 wt.%) and high MgO contents (6.35&#x2013;9.04 wt.%) and Mg<sup>&#x23;</sup> values (55&#x2013;74). The total rare earth element (&#x2211;REE) contents are 8.35&#x2013;28.07 ppm, lower than those of normal-type mid-ocean ridge basalts (MORBs), and the gabbros exhibit light REE depletion or flat REE patterns, with small positive Eu anomalies (Eu/Eu&#x2a; &#x3d; 1.06&#x2013;1.40). Trace element patterns are depleted to enriched in Nb and Ta, similar to island arc rocks and MORB. Clinopyroxene thermobarometry indicates the parental magma of the gabbros formed by high-temperature (1,318&#xb0;C&#x2013;1,363&#xb0;C) and medium-pressure (1.27&#x2013;1.64 GPa) partial melting in a mantle wedge. The gabbros have depleted Sr&#x2013;Nd&#x2013;Pb-Hf isotopic compositions, with (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> &#x3d; 0.704586&#x2013;0.707441, &#x3b5;<sub>Nd</sub>(t) &#x3d; 4.7&#x2013;6.6, and zircon &#x3b5;<sub>Hf</sub>(t) &#x3d; 7.6&#x2013;11.4. The age-corrected Pb isotope ratios of these volcanic rocks are variable, with <sup>206</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 18.085&#x2013;18.253, <sup>207</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 15.595&#x2013;15.614, and <sup>208</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 37.880&#x2013;38.148, which are similar to the isotopic compositions of typical Indian MORBs. The source of the Dachaidan ophiolite is inferred to have been depleted mantle. The Dachaidan ophiolite likely formed in a forearc oceanic setting along the northern margin of the Qaidam Basin, during the initial subduction of an oceanic plate.</p>
</sec>
</abstract>
<kwd-group>
<kwd>North Qaidam ultrahigh-pressure metamorphic belt</kwd>
<kwd>early paleozoic</kwd>
<kwd>gabbro</kwd>
<kwd>petrogenesis</kwd>
<kwd>tectonic setting</kwd>
</kwd-group>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Geochemistry</meta-value>
</custom-meta>
</custom-meta-wrap>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>The Qinling&#x2013;Qilian&#x2013;Alxa&#x2013;Kunlun orogenic belt is the northernmost suture zone of the Proto-Tethys Ocean, and is an ideal region for studying plate convergence, oceanic&#x2013;continental subduction, magmatism, metamorphism, and deformation (<xref ref-type="bibr" rid="B58">Song et al., 2013</xref>). The Qilian orogenic belt extends westward into the Alxa orogenic belt and eastward into the Qinling orogenic belt. The Qilian orogenic belt is a key region for investigating the breakup of Rodinia and accretion of micro-continental blocks along the northern margin of Gondwana. It preserves important information on the tectonic evolution of the Proto-Tethys Ocean. The North Qaidam ultrahigh-pressure (UHP) metamorphic belt (NQUB) is located in the southernmost Qilian orogenic belt, and links the northern Oulongbuluke micro-continental and southern Qaidam blocks. Early Paleozoic deep continental subduction formed HP to UHP metamorphic rocks in this region (<xref ref-type="bibr" rid="B97">Yang et al., 1998</xref>; <xref ref-type="bibr" rid="B62">Song and Yang, 2001</xref>; <xref ref-type="bibr" rid="B41">Meng et al., 2003</xref>; <xref ref-type="bibr" rid="B65">Song et al., 2006</xref>; <xref ref-type="bibr" rid="B64">Song et al., 2014a</xref>; <xref ref-type="bibr" rid="B63">Song et al., 2004b</xref>, <xref ref-type="bibr" rid="B60">Song et al., 2019</xref>; <xref ref-type="bibr" rid="B8">Chen et al., 2007</xref>; <xref ref-type="bibr" rid="B109">Zhang et al., 2010</xref>; <xref ref-type="bibr" rid="B110">Zhang J. X. et al., 2017</xref>). Since j1990s, various types of UHP metamorphic rocks, such as eclogite with coesite-bearing quartz (<xref ref-type="bibr" rid="B96">Yang et al., 2001</xref>), coesite-bearing garnet peridotite (<xref ref-type="bibr" rid="B105">Zhang et al., 2009a</xref>), diamond-bearing garnet pyroxenite (<xref ref-type="bibr" rid="B63">Song et al., 2004b</xref>), and K-cymrite-bearing garnet peridotite (<xref ref-type="bibr" rid="B108">Zhang et al., 2009b</xref>), have been reported.</p>
<p>About tectonic setting of the NQUB, different researchers shared different opinions. Within the belt, most eclogites show characteristics of intraplate or continental flood basalts, suggesting the NQUB experienced UHP metamorphism (<xref ref-type="bibr" rid="B64">Song et al., 2004a</xref>; <xref ref-type="bibr" rid="B92">Xu et al., 2006</xref>). Isotopic dating indicates that the protolith ages of most eclogites in the region are 850&#x2013;750 Ma, with the peak metamorphic ages being 460&#x2013;420 Ma (<xref ref-type="bibr" rid="B6">Chen et al., 2009</xref>; <xref ref-type="bibr" rid="B61">Song et al., 2010</xref>; <xref ref-type="bibr" rid="B109">Zhang et al., 2010</xref>; <xref ref-type="bibr" rid="B106">Zhang G. B. et al., 2016</xref>; <xref ref-type="bibr" rid="B101">Yu et al., 2013</xref>). Some eclogites within the belt have geochemical features similar to those of oceanic basalts (<xref ref-type="bibr" rid="B113">Zhang et al., 2008</xref>; <xref ref-type="bibr" rid="B103">Zhang et al., 2013</xref>), suggestive of oceanic subduction within the NQUB. Zircon dating revealed the protolith of these eclogites formed at 517&#x2013;514 Ma, with metamorphic ages peak at 457&#x2013;440 Ma (<xref ref-type="bibr" rid="B105">Zhang et al., 2009a</xref>; <xref ref-type="bibr" rid="B108">Zhang et al., 2009b</xref>; <xref ref-type="bibr" rid="B111">Zhang et al., 2016</xref>), which led to the hypothesis that the NQUB experienced oceanic subduction prior to continental collision and orogenesis. However, controversy persists regarding the timing and tectonic evolution of oceanic subduction and processes in the NQUB. <xref ref-type="bibr" rid="B100">Yin et al. (2007)</xref> suggested that the NQUB resulted from southward subduction of the North Qilian oceanic crust, subduction of trench sediments, and uplift of overlying continental crustal materials. <xref ref-type="bibr" rid="B103">Zhang et al. (2013)</xref> proposed that northward oceanic subduction occurred from 540 to 450 Ma, followed by a period of continental subduction from 450 to 420 Ma. <xref ref-type="bibr" rid="B59">Song et al. (2014a)</xref> proposed a relationship between the NQUB and North Qilian orogenic belt, suggesting that the NQUB formed due to northward oceanic subduction in the North Qilian Ocean, which resulted in deep continental subduction of the Qilian&#x2013;NQUB block. In this model, the period from 460 to 440 Ma is considered to have been characterized by oceanic subduction, whereas deep continental subduction occurred from 440 to 420 Ma.</p>
<p>Most of research the NQUB focused on the Yuka, Lvliangshan, Xitieshan, and Dulan areas, including the geological and geochemical characteristics of eclogites, garnet-bearing (ultra) mafic rocks, and intermediate&#x2013;silicic intrusive rocks. For examples, previous studies have investigated eclogites, orthopyroxene-bearing garnet peridotites, and pyroxenitic garnet lherzolites in the Shaliuhe (Dulan) and Chachahe areas (<xref ref-type="bibr" rid="B18">Hao et al., 2001</xref>; <xref ref-type="bibr" rid="B80">Wang et al., 2020</xref>; <xref ref-type="bibr" rid="B51">Ren et al., 2022</xref>; <xref ref-type="bibr" rid="B82">Wang et al., 2022</xref>). In the Lvliangshan region, there are two types of eclogite: blocky and banded. The banded eclogites are considered to be metamorphosed crustal rocks of the Dakendaban Formation (<xref ref-type="bibr" rid="B79">Wang et al., 2001</xref>), which record two orogenic cycles. The Yuka&#x2013;Luofengpo eclogites were associated with the early orogenic cycle related to the assembly and breakup of the Rodinia supercontinent during the Paleo-Proterozoic, and a later orogenic cycle in the Early Paleozoic associated with oceanic expansion, subduction, and continent&#x2013;continent collision (<xref ref-type="bibr" rid="B52">Ren et al., 2019</xref>). <xref ref-type="bibr" rid="B87">Wu et al. (2008)</xref> investigated granites in the Sanchagou area in the western NQUB and suggested that, during the middle Permian, the NQUB was in a post-collisional intracontinental subduction setting. <xref ref-type="bibr" rid="B13">Dong et al. (2014)</xref> suggested that the late Permian granites along the northwestern margin of the Oulongbuluke Block formed in a volcanic arc, indicating the NQUB was experiencing oceanic&#x2013;continental subduction during the late Permian. However, <xref ref-type="bibr" rid="B15">Gao et al. (2019)</xref> proposed that the NQUB was already underwent oceanic&#x2013;continental subduction in the middle Permian. Further research is needed to resolve these issues.</p>
<p>Due to the close relationship between the geochemical characteristics of (ultra) mafic igneous rocks and their tectonic setting and mantle source, such rocks that formed during different tectonic stages have distinct geochemical features. These rocks can constrain crust-mantle interactions, deep mantle properties, and the tectonic evolution of orogenic belts (<xref ref-type="bibr" rid="B32">Li et al., 1995</xref>; <xref ref-type="bibr" rid="B112">Zhang et al., 1995</xref>; <xref ref-type="bibr" rid="B10">Cheng et al., 2016</xref>). Therefore, determining the evolution of the NQUB requires a systematic investigation of its (ultra) mafic rocks, particularly the ophiolite. This involves determining their ages, tectonic setting, and petrogenesis.</p>
<p>This study focused on the gabbros in the Dachaidan ophiolite in the NQUB. Based on detailed field investigations, systematic sampling was conducted, and the samples were subjected to petrological, zircon U&#x2013;Pb geochronological, mineral and whole-rock geochemical, and Sr&#x2013;Nd&#x2013;Pb&#x2013;Hf isotope analyses, in order to constrain their source characteristics and petrogenesis. Combining the results and regional geological data to provide new constraints on the tectonic setting and evolution of the NQUB and subduction in the northern Proto-Tethys.</p>
</sec>
<sec id="s2">
<title>2 Geological background and sample descriptions</title>
<sec id="s2-1">
<title>2.1 Geological background</title>
<p>The NQUB is located on the northeastern margin of the Qinghai&#x2013;Tibetan Plateau within Qinghai Province, China. It extends along the northern margin of the Qaidam Basin in a WNW&#x2013;ESE orientation. To the north, it is bordered by the Qilian terrane, while the Qaidam terrane lies to the south. To the east, it connects with the Qinling orogenic belt (<xref ref-type="fig" rid="F1">Figure 1</xref>). To the westernmost of NQUB, it cut by the Altun strike-slip fault. Approximately 300 km north of this belt is the Northern Qilian suture zone, which formed during the Caledonian Orogeny and is characterized by ophiolitic and low-temperature&#x2013;high-pressure metamorphic rocks (<xref ref-type="bibr" rid="B102">Zhang et al., 2012</xref>). From west to east, the NQUB contains the Lvliangshan&#x2013;Yuka, Xitieshan, and Dulan UHP metamorphic units. The rocks exposed within this belt were derived primarily from sedimentary protoliths and include paragneiss and granitic gneiss. In addition, eclogite, mafic granulite, and lens-shaped occurrences of garnet-bearing olivine gabbro occur in this region (<xref ref-type="bibr" rid="B58">Song et al., 2013</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(A)</bold> Sketch tectonic map showing the location of the Qaidam Block on the Tibetan Plateau. <bold>(B)</bold> Geological map of North Qaidam (modified after <xref ref-type="bibr" rid="B110">Zhang J. X. et al., 2017</xref>) and <bold>(C)</bold> geological map of the Lvliangshan area (modified after <xref ref-type="bibr" rid="B52">Ren et al., 2019</xref>). CAOB, Central Asian Orogenic Belt; NQSZ, North Qilian suture zone; NQOB, North Qaidam orogenic belt; WQOB, West Qinling orogenic belt; ATOB, Altyn orogenic belt; EKLOB, East Kunlun orogenic belt.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g001.tif"/>
</fig>
<p>The Oulongbuluke micro-continent is located between the Qilian terrane and the NQUB. This micro-continent has Neoproterozoic to Paleoproterozoic crystalline basement, with geological affinities to the South China Block. It has been proposed that the Oulongbuluke micro-continent separated from the South China Block at <italic>ca</italic>. 780 Ma, during subduction in the NQUB and leading to the migration of the micro-continent to the southern margin of the Qilian terrane. During the Early Paleozoic, a continental arc developed on the fragmented continental basement, transforming the Oulongbuluke micro-continent into an active continental margin (<xref ref-type="bibr" rid="B90">Xiao et al., 2009</xref>; <xref ref-type="bibr" rid="B76">Tung et al., 2012</xref>; <xref ref-type="bibr" rid="B77">Tung et al., 2013</xref>; <xref ref-type="bibr" rid="B93">Yan et al., 2015</xref>). Following closure of the North Qaidam Ocean, the Qaidam Block collided with the southern Oulongbuluke micro-continent within the southern Qilian terrane. This collisional event ultimately led to the formation of the NQUB.</p>
<p>The Tanjianshan Group consists of lower Paleozoic strata that are widespread in the NQUB, which crop out in a NW&#x2013;SE orientation. The group is in fault contact with the Archean Dawan Group and is in contact with strata of different ages via either faults or angular unconformities. The lower part of the Tanjianshan Group consists of intermediate&#x2013;mafic submarine volcanic rocks, while the upper part consists of clastic and carbonate rocks. Based on fossil assemblages, isotopic dating, and tectonothermal events, <xref ref-type="bibr" rid="B16">Gao et al. (2011)</xref> suggested that the Tanjianshan Group formed in an island arc and represents the products of different stages of oceanic&#x2013;continental subduction during the early Paleozoic (510&#x2013;460 Ma; i.e., Cambrian&#x2013;Ordovician).</p>
<p>Our study area is located in the Dachaidan region to the west of the NQUB. The main faults within the belt are NW&#x2013;SE-trending. In this region, the ophiolite unit is well-exposed and the different rock types are in tectonic contact. The lower stratigraphic units are strongly serpentinized and metamorphosed peridotites, while the middle units are metamorphosed cumulate gabbros (pyroxenites), with locally developed igneous cumulate textures. These textures are characterized by alternating light-colored bands with relatively high-An plagioclase and dark-colored bands with relatively high contents of mafic minerals. The upper units consist of volcanic rocks (i.e., amphibolites) of the Tanjianshan Group, which are intercalated with abundant pyroxenite (<xref ref-type="bibr" rid="B119">Zhu et al., 2014</xref>). In addition, this region contains outcrops of Precambrian metamorphosed basement (i.e., the Archean Dawan Group). The protoliths of these rocks include volcanic and clastic rocks, which have underwent medium-to high-grade metamorphism. Geochronological studies indicate that the age of the granitic gneiss in this region is <italic>ca</italic>. 952 Ma, which is production of crustal melting (<xref ref-type="bibr" rid="B33">Lin et al., 2006</xref>). There are outcrop two types of eclogite: (1) lens-shaped bodies within the granitic gneiss and (2) in association with the metamorphosed crustal rocks, which have either lens-shaped or layered structures. <xref ref-type="bibr" rid="B52">Ren et al. (2019)</xref> discovered eclogites with mid-ocean ridge basalt (MORB) characteristics in the Yuka&#x2013;Luofengpo area, which have ages of 1,280&#x2013;1,070 Ma. These eclogites are considered to be remnants of the Mesoproterozoic Mirovoi Ocean surrounding Rodinia superterrane, which underwent two utral high-pressure metamorphism during the Neoproterozoic (amphibolite facies) and Early Paleozoic (UHP metamorphism).</p>
</sec>
<sec id="s2-2">
<title>2.2 Sample descriptions</title>
<p>The gabbros have underwent variable degrees of metamorphism and have been transformed into amphibolite with a gray&#x2013;green color, granular crystalline texture, and blocky fabric (<xref ref-type="fig" rid="F2">Figures 2A, B</xref>). The main minerals include pyroxene (40 vol.%), clinopyroxene (30 vol.%), and hornblende (30 vol.%) (<xref ref-type="fig" rid="F2">Figures 2C&#x2013;F</xref>).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>
<bold>(A, B)</bold> Field photographs, and <bold>(C, E)</bold> plane- and <bold>(D, F)</bold> cross-polarized light photomicrographs of the Dachaidan gabbros. Mineral abbreviations: Hb, hornblende; Pl, plagioclase; Py, pyroxene.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g002.tif"/>
</fig>
</sec>
</sec>
<sec id="s3">
<title>3 Analytical methods</title>
<p>All analyses were carried out at the Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration, Guilin University of Technology, Guangxi, China. Zircon U-Pb dating and mineral trace element analyses were conducted with a 193 nm COMPexPro 102 ArF excimer LA system (GeoLas HD, Gottingen, Germany) coupled to an Agilent 7,900 quadrupole ICP-MS (i.e., LA&#x2013;ICP&#x2013;MS). Whole-rock major and trace elements were analyzed with a ZSX Primus II X-ray fluorescence (XRF) spectrometer and an Agilent 7500cx ICP-MS, respectively. The major element contents of minerals were measured with a JEOL JXA&#x2013;8230 electron probe microanalyzer (EPMA). Zircon Hf isotope analyses of the same zircon grains were conducted with an ArF excimer LA system attached to a Neptune Plasma MC-ICP-MS. Whole&#x2013;rock Sr&#x2013;Nd&#x2013;Hf isotope ratios were measured in solution with a Neptune plus multicollector (MC)&#x2013;ICP&#x2013;MS. The analytical methods are described in detail in the Supplementary Text.</p>
</sec>
<sec sec-type="results" id="s4">
<title>4 Results</title>
<sec id="s4-1">
<title>4.1 Zircon U&#x2013;Pb geochronology</title>
<p>Zircon U&#x2013;Pb isotopic dating was conducted on gabbro sample DC-399 and DC-400 from the Dachaidan ophiolite. Forty zircon grains were selected for analysis, and their CL images are predominantly gray&#x2013;black, with some appearing white. The zircon shape with elongate or short prismatic, and irregular shapes (<xref ref-type="fig" rid="F3">Figure 3A</xref>), with length:width ratios of 1:1 to 2:1. Individual zircon U&#x2013;Pb ages for each grain are presented in <xref ref-type="sec" rid="s12">Supplementary Table S1</xref>. The U and Th contents of the 40 zircon grains, they are 165&#x2013;2037 and 143&#x2013;3,225 ppm, respectively. The Th/U ratios range from 0.57 to 2.19, which are typical of magmatic zircons (<xref ref-type="bibr" rid="B124">Hoskin and Black, 2000</xref>). The <sup>206</sup>Pb/<sup>238</sup>U ages of the 40 zircon grains in the gabbro exhibit minimal variation and vary from 502 to 520 Ma. The weighted-mean ages are 510.0 &#xb1; 2.8 Ma and 510.0 &#xb1; 2.9 Ma, which represents the crystallization age of the gabbro. This indicates that the ophiolite in this region formed during the middle Cambrian. On a chondrite-normalized rare earth element (REE) diagram, the zircon grains exhibit light REE depletion, heavy REE enrichment ([Gd/Yb]<sub>N</sub> &#x3d; 0.029&#x2013;0.103), and distinct positive Ce and negative Eu anomalies (<xref ref-type="fig" rid="F3">Figures 3C, E</xref>).</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>
<bold>(A)</bold> Partial Zircon CL images, <bold>(B,D)</bold> U&#x2013;Pb concordia diagram, and <bold>(C,E)</bold> chondrite-normalized REE patterns for the Dachaidan gabbros. The red circles represent the sites of zircon U&#x2013;Pb dating analyses and the yellow circles represent the locations of zircon Hf isotope analyses.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g003.tif"/>
</fig>
</sec>
<sec id="s4-2">
<title>4.2 Whole-rock major and trace elements</title>
<p>Apart from sample DC-399, which has a LOI value of 5.01 wt.%, most of the gabbro samples from the Dachaidan ophiolite have low LOI values (&#x3c;3 wt.%), indicative of minimal weathering. The gabbros have relatively low and uniform SiO<sub>2</sub> (47.15&#x2013;49.63 wt.%) and TiO<sub>2</sub> (0.26&#x2013;0.75 wt.%) contents. The samples have elevated contents of Al<sub>2</sub>O<sub>3</sub> (14.84&#x2013;16.25 wt.%) and MgO (6.35&#x2013;9.04 wt.%), resulting in Mg<sup>&#x23;</sup> (Mg<sup>&#x23;</sup> &#x3d; molar MgO/[MgO &#x2b; Fe<sub>2</sub>O<sub>3</sub>
<sup>T</sup>] &#xd7; 100) values of 55&#x2013;74. These elevated MgO contents and Mg<sup>&#x23;</sup> values are indicative of a mafic parental magma. The total alkali contents (K<sub>2</sub>O &#x2b; Na<sub>2</sub>O) of the gabbros range from 2.52 to 3.00 wt.% (<xref ref-type="sec" rid="s12">Supplementary Table S2</xref>). On the Zr/TiO<sub>2</sub>&#x2013;Nb/Y diagram used for classifying igneous rocks (<xref ref-type="fig" rid="F4">Figure 4</xref>), the samples plot into the gabbro field.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Zr/TiO<sub>2</sub>&#x2013;Nb/Y diagram for the Dachaidan gabbros (after <xref ref-type="bibr" rid="B83">Winchester and Floyd, 1977</xref>).</p>
</caption>
<graphic xlink:href="feart-12-1473101-g004.tif"/>
</fig>
<p>In a chondrite-normalized trace element diagram (<xref ref-type="fig" rid="F5">Figure 5A</xref>), the gabbros are characterized by depletions of light REEs to flat REE patterns (La/Yb)<sub>N</sub> ratios are 0.51&#x2013;1.06, indicative of moderate enrichment in light REE. In addition, there are obvious positive Eu anomalies, with Eu/&#x2a;Eu values (2Eu<sub>N</sub>/[Sm<sub>N</sub> &#x2b; Gd<sub>N</sub>]) of 1.06&#x2013;1.40. The gabbros have relatively low and uniform total REE contents (&#x3a3;REE &#x3d; 8.35&#x2013;28.1 ppm; average &#x3d; 15.82 ppm). This average is less than that of normal-type MORBs (N-MORBs; &#x3a3;REE &#x3d; 39.1 ppm; <xref ref-type="bibr" rid="B71">Sun and McDonough, 1989</xref>). On a primitive-mantle-normalized trace element diagram (<xref ref-type="fig" rid="F5">Figure 5B</xref>), the gabbros exhibit depletions in Th and U, and positive Sr anomalies. These trace element features, and the positive Eu anomalies and lower &#x3a3;REE contents than N-MORBs, can be attributed to plagioclase accumulation in the gabbros. The results are listed in <xref ref-type="sec" rid="s12">Supplementary Table S2</xref>.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>
<bold>(A)</bold> Chondrite-normalized REE patterns and <bold>(B)</bold> primitive-mantle-normalized multi-element diagram for the Dachaidan gabbros (after <xref ref-type="bibr" rid="B71">Sun and McDonough, 1989</xref>).</p>
</caption>
<graphic xlink:href="feart-12-1473101-g005.tif"/>
</fig>
</sec>
<sec id="s4-3">
<title>4.3 Whole-rock Sr&#x2013;Nd-Pb and zircon Hf isotopes</title>
<p>Whole-rock measured and initial Sr&#x2013;Nd isotope ratios for the gabbros in the Dachaidan area are listed in <xref ref-type="sec" rid="s12">Supplementary Table S3</xref> and shown in <xref ref-type="fig" rid="F6">Figure 6</xref>. The gabbros exhibit significant variations in ((<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> from 0.704586 to 0.707441, which are much higher than depleted mantle source, may have been affected by alteration. The initial Nd isotope ratios are also indicative of a depleted mantle source, with &#x3b5;<sub>Nd</sub>(t) &#x3d; &#x2b;4.68 to &#x2b;6.59 (<xref ref-type="sec" rid="s12">Supplementary Table S3</xref>). The initial Sr&#x2013;Nd isotopic compositions of the gabbros are similar to those reported for basalts from the Lajishan oceanic plateau ((<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> values (0.70434&#x2013;0.70704), &#x3b5;<sub>Nd</sub>(t) values (0.9&#x2013;8.9)), as well as the Yuka boninites ((<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> values (0.7054&#x223c;0.7065), and the &#x3b5;<sub>Nd</sub> (t) values (4.1&#x223c;6.1)) and magnesian andesites (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> values (0.7059&#x223c;0.7067)), and &#x3b5;<sub>Nd</sub> (t) values (2.5&#x223c;5.3), and Proto-Tethyan oceanic ophiolites in the region (<xref ref-type="fig" rid="F6">Figure 6A</xref>). The age-corrected Pb isotope ratios of these volcanic rocks are variable, with <sup>206</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 18.085&#x2013;18.253, <sup>207</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 15.595&#x2013;15.614, and <sup>208</sup>Pb/<sup>204</sup>Pb(t) &#x3d; 37.880&#x2013;38.148. In plots of <sup>207</sup>, <sup>208</sup>Pb/<sup>204</sup>Pb vs <sup>206</sup>Pb/<sup>204</sup>Pb (<xref ref-type="fig" rid="F6">Figures 6C, D</xref>), all the samples plot above the Northern Hemisphere Reference Line (NHRL) and are similar to the isotopic compositions of typical Indian MORBs.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Sr-Nd <bold>(A)</bold>, zircon Hf <bold>(B)</bold> and Pb <bold>(C,D)</bold> isotope plots for the Dachaidan gabbros (Proto-Tethys data are from <xref ref-type="bibr" rid="B36">Liu et al., 2021</xref>; basalt data for the Lajishan oceanic plateau are from <xref ref-type="bibr" rid="B114">Zhang et al., 2017</xref>; Lajishan boninite data are from <xref ref-type="bibr" rid="B98">Yang et al., 2019</xref>; Xitieshan gabbro data are from <xref ref-type="bibr" rid="B69">Sun, 2020</xref>, Pacific, North Atlantic, Indian MORB and data are from the Pet DB database (<ext-link ext-link-type="uri" xlink:href="http://www.petdb.org/">http://www.petdb.org/</ext-link>) and the compilation of <xref ref-type="bibr" rid="B68">Stracke et al., 2003</xref>; the Northern Hemisphere Reference Line (NHRL) is from <xref ref-type="bibr" rid="B19">Hart, 1984</xref>). And three-component mixing model on plots of <sup>206</sup>Pb/<sup>204</sup>Pb(t) vs. <sup>207</sup>Pb/<sup>204</sup>Pb(t) <bold>(E)</bold> and <sub>&#x190;Nd</sub>(t) vs <sup>206</sup>Pb/<sup>204</sup>Pb(t) <bold>(F)</bold> for the Dachaidan gabbros (after Zhang et al., 2021), showing the amounts of Nd, Hf, and Pb from the subduction component that affected the source of the Dachaidan gabbros.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g006.tif"/>
</fig>
<p>The zircon Lu&#x2013;Hf isotope data for gabbro sample DC-399 and DC-400 are listed in <xref ref-type="sec" rid="s12">Supplementary Table S4</xref>. The initial Hf isotope ratios of the Dachaidan gabbros vary from 0.282678 to 0.282837. The weighted-mean is 0.282751, with a corresponding &#x3b5;<sub>Hf</sub>(t) value of &#x2b;10.0. All data plot above the chondritic uniform reservoir evolution line, indicative of a depleted mantle source (<xref ref-type="fig" rid="F6">Figure 6B</xref>). Single-stage Hf isotope model ages (t<sub>DM1</sub>) vary from 812 to 661 Ma, while two-stage Hf isotope model ages (t<sub>DM2</sub>) range from 977 to 731 Ma.</p>
</sec>
<sec id="s4-4">
<title>4.4 Clinopyroxene chemistry</title>
<p>We analyzed a relatively fresh clinopyroxene phenocryst (in sample DC-400) from a Dachaidan gabbro. Cation contents were calculated based on six oxygen atoms (<xref ref-type="sec" rid="s12">Supplementary Table S5</xref>). In back-scattered electron images of clinopyroxene within the gabbro, most clinopyroxene grains do not exhibit compositional zoning. They occur as large phenocrysts (2&#x2013;10 mm, but typically 3&#x2013;6 mm), microphenocrysts (0.5&#x2013;1.0 mm), and microcrysts within the matrix (<xref ref-type="fig" rid="F5">Figures 5</xref>&#x2013;<xref ref-type="fig" rid="F8">8</xref>). The SiO<sub>2</sub> contents are 48.31&#x2013;51.20 wt.%, MgO contents are 13.21&#x2013;15.00 wt.%, Mg<sup>&#x23;</sup> values are 63&#x2013;70, CaO contents are 11.60&#x2013;12.32 wt.%, FeO contents are 13.38&#x2013;16.45 wt.%, and TiO<sub>2</sub> contents are 0.10&#x2013;0.42 wt.%. Based on the Wo&#x2013;En&#x2013;Fs ternary diagram, the pyroxene can be classified as augite.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>
<bold>(A)</bold> Back-scattered electron image of sample DC-400. (Cpx &#x3d; pyroxene) and <bold>(B)</bold> ternary classification diagram of the analyzed pyroxenes.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g007.tif"/>
</fig>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>
<bold>(A)</bold> Chondrite-normalized REE patterns and <bold>(B)</bold> primitive-mantle-normalized trace element diagram for clinopyroxenes in the Dachaidan gabbros.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g008.tif"/>
</fig>
<p>Chondrite-normalized REE patterns and a primitive-mantle-normalized trace element diagram for the clinopyroxenes are shown in <xref ref-type="fig" rid="F8">Figures 8A, B</xref>. All the clinopyroxenes have similar REE and trace element patterns, suggestive of a common origin. The &#x3a3;REE contents are relatively low (13.50&#x2013;173.88 ppm), with (La/Sm)<sub>N</sub> &#x3d; 0.21&#x2013;0.92 and (La/Yb)<sub>N</sub> &#x3d; 0.19&#x2013;1.29 (<xref ref-type="sec" rid="s12">Supplementary Table S5</xref>). These values are indicative of significant depletion of light REEs as compared with middle and heavy REEs (<xref ref-type="fig" rid="F8">Figure 8A</xref>), and are associated with significant negative Eu anomalies (Eu/Eu<sup>&#x2a;</sup> &#x3d; 0.15&#x2013;0.77). Compared with gabbro sample DC-400, the clinopyroxenes exhibit clear depletions in Sr, Eu, Nb, Ta, Zr, and other REEs (<xref ref-type="fig" rid="F8">Figure 8B</xref>).</p>
</sec>
</sec>
<sec sec-type="discussion" id="s5">
<title>5 Discussion</title>
<sec id="s5-1">
<title>5.1 Effects of alteration</title>
<p>Microscopic observations indicate that metamorphic processes have affected the Dachaidan gabbros, resulting in well-developed amphibolite-facies mineral assemblages, particularly the presence of hornblende (<xref ref-type="fig" rid="F2">Figures 2C, D</xref>). Although alteration and metamorphic processes often mobilize large-ion lithophile elements (e.g., K, Rb, Sr, Ba, Cs, and Pb), REEs and high-field-strength elements (e.g., Nb, Ta, Zr, Hf, Th, and Ti) tend to remain relatively immobile (<xref ref-type="bibr" rid="B17">Hajash, 1984</xref>; <xref ref-type="bibr" rid="B116">Zhu et al., 2008</xref>; <xref ref-type="bibr" rid="B14">Escuder et al., 2010</xref>). This study predominantly relies on these less-mobile elements for the following discussion.</p>
<p>The gabbros have relatively high initial Sr isotope ratios of 0.704586&#x2013;0.707434, with an average of 0.705737 (<xref ref-type="sec" rid="s12">Supplementary Table S3</xref>). This is broadly equivalent to the Sr isotope ratios of MORBs (0.70229&#x2013;0.70613; <xref ref-type="bibr" rid="B53">Saunders et al., 1988</xref>), but higher than the Sr isotope ratios of ocean island basalts (OIBs), as typified by Hawaiian volcanic rocks with <sup>87</sup>Sr/<sup>86</sup>Sr &#x3d; 0.70317&#x2013;0.70412 (<xref ref-type="bibr" rid="B67">Stille et al., 1983</xref>). The elevated initial Sr isotope ratios may be due to contamination by crustal materials or subsequent seawater alteration. The gabbros in this region have only experienced minor crustal contamination, indicating seawater alteration is the likely cause of the elevated initial Sr isotope ratios.</p>
<p>Ophiolites are remnants of oceanic lithosphere and commonly underwent metasomatism by mantle fluids and subsequent seawater alteration during their formation. Strontium is a relatively mobile element and is susceptible to various post-magmatic alteration processes. In a &#x3b5;<sub>Nd</sub>(t)&#x2013;<sup>87</sup>Sr/<sup>86</sup>Sr diagram, &#x3b5;<sub>Nd</sub>(t) is almost constant with increasing <sup>87</sup>Sr/<sup>86</sup>Sr (<xref ref-type="fig" rid="F6">Figure 6A</xref>), which can be interpreted as the result of fluid metasomatism or seawater alteration (<xref ref-type="bibr" rid="B39">McCulloch et al., 1980</xref>). Neodymium is immobile element, and the Nd isotope ratio of weakly altered seafloor rocks remains largely unchanged until the water/rock ratio reaches 10<sup>5</sup> (<xref ref-type="bibr" rid="B40">McCulloch et al., 1981</xref>). In addition, zircon is a stable mineral that is hard to altered during weathering and metasomatic reaction, and consequently preserves its elemental and isotopic composition while its formation (<xref ref-type="bibr" rid="B31">Li et al., 2009</xref>).</p>
</sec>
<sec id="s5-2">
<title>5.2 Composition of the mantle source</title>
<p>The La/Yb ratio can be an indicator of the depth of source melting. A lower La/Yb ratio suggests shallow melting, with spinel being the primary residual phase in the source. Conversely, a higher La/Yb ratio indicates deeper melting, with garnet being the main residual phase in the source (<xref ref-type="bibr" rid="B94">Yang et al., 2007</xref>). The relatively low La/Sm, Sm/Yb, and Dy/Yb ratios of the studied samples suggest that partial melting occurred in a spinel lherzolite source and similar to the IBM forearc ophiolite mantle source (<xref ref-type="fig" rid="F9">Figure 9</xref>; <xref ref-type="bibr" rid="B113">Zhang et al., 2008</xref>).</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>
<bold>(A)</bold> La/Sm&#x2013;Sm/Yb (<xref ref-type="bibr" rid="B24">Kinzler, 1994</xref>) and <bold>(B)</bold> La/Yb&#x2013;Dy/Yb diagrams showing the effects of source lithology, degree of partial melting, and REE composition of the mantle source. Data for the IBM forearc basalts are from <xref ref-type="bibr" rid="B49">Reagan et al., 2010</xref>.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g009.tif"/>
</fig>
<p>Lead is a fluid-mobile element and is added to the mantle in the form of slab-derived fluids or sediment melts, which modifies the Pb isotopes in the mantle (<xref ref-type="bibr" rid="B45">Pearce and Peate, 1995</xref>). The addition of a small number of subducted sediments will change the Pb isotopic composition from that of depleted mantle to that of the subducted sediments (<xref ref-type="bibr" rid="B23">Kersting and Arculus, 1994</xref>). Therefore, Pb isotope data is a sensitive indicator for the involvement of subduction components in the mantle source. As such, we undertook three-component mixing in Nd&#x2013;Pb isotope space (<xref ref-type="fig" rid="F6">Figures 6E, F</xref>) to further constrain the nature of the subduction components. The modeling results suggest that less than 10% of a subduction component with variable amounts of slab-derived fluid and sediment melt could have generated the source of the parental melts of the Dachaidan gabbros. Previous studies have found that ophiolite altered by ocean floor alteration exhibits significant positive Eu anomalies (<xref ref-type="bibr" rid="B46">Philpotts et al., 1969</xref>; <xref ref-type="bibr" rid="B70">Sun and Nesbitt, 1978</xref>), therefore, we believe that the mantle source of Dachaidan gabbros has been mixed with slab-derived fluid, leading to Eu positive anomalies.</p>
<p>&#x3b5;<sub>Nd</sub>(t) values for the Dachaidan gabbros range from &#x2b;4.7 to &#x2b;6.6, indicative of derivation from a depleted mantle source. In general, if zircon &#x3b5;<sub>Hf</sub>(t) &#x3e; 0, the source is depleted mantle or newly formed young crust derived from depleted mantle. For the Dachaidan gabbros, the zircon &#x3b5;<sub>Hf</sub>(t) values of &#x2b;7.6 to &#x2b;11.4 indicate an isotopically depleted mantle source.</p>
</sec>
<sec id="s5-3">
<title>5.3 Crystal fractionation</title>
<p>The Dachaidan gabbros have moderate MgO contents (6.35&#x2013;9.04 wt.%) and Mg<sup>&#x23;</sup> values (55&#x2013;74), with low contents of Cr (22&#x2013;272 ppm) and Ni (65&#x2013;94 ppm), and do not contain olivine. This suggests olivine fractionation occurred during magma evolution. As Mg<sup>&#x23;</sup> decreases, Cr and Ni contents, and CaO/Al<sub>2</sub>O<sub>3</sub> ratios also decrease, indicative of fractionation involving olivine and clinopyroxene (<xref ref-type="fig" rid="F10">Figures 10A&#x2013;D</xref>). Mg<sup>&#x23;</sup> values are used as an indicator of fractional crystallization, with Mg<sup>&#x23;</sup> &#x3e;60 indicative of a (near-) primary magma (<xref ref-type="bibr" rid="B25">Langmuir et al., 1977</xref>). Samples DC-400, -401, and &#x2212;402 have relatively high Mg<sup>&#x23;</sup> values of 65&#x2013;74, similar to primary magmas. Conversely, samples DC-396 and -399 have Mg<sup>&#x23;</sup> &#x3d; 55&#x2013;59, indicative of fractional crystallization.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>PPlots of selected major and trace elements versus Mg<sup>&#x23;</sup> values for the Dachaidan gabbros <bold>(A-D)</bold> (modified after <xref ref-type="bibr" rid="B99">Yao et al., 2012</xref>).</p>
</caption>
<graphic xlink:href="feart-12-1473101-g010.tif"/>
</fig>
<p>The composition of clinopyroxene can provide important information on the magma evolution, including the type of parental magma, and the temperature and pressure of crystallization (<xref ref-type="bibr" rid="B27">Leterrier et al., 1982</xref>). Igneous thermobarometers can provide important insights into magma formation, and thus these were applied to the Dachaidan gabbros (<xref ref-type="bibr" rid="B47">Putirka, 2008</xref>).</p>
<p>The clinopyroxene in the gabbro is euhedral&#x2013;subhedral and has relatively uniform major and trace element compositions. This suggests the clinopyroxenes crystallized in a relatively closed magmatic system (<xref ref-type="bibr" rid="B5">Carracedo, 1999</xref>). By calculating the equilibrium constant K<sub>D</sub> (Fe&#x2013;Mg)<sup>cpx/liq</sup>, the state of equilibrium between clinopyroxene and the host rock can be determined. Based on experimental results, when K<sub>D</sub> (Fe&#x2013;Mg)<sup>cpx/liq</sup> is 0.2&#x2013;0.4 the clinopyroxene and host magma are in equilibrium (<xref ref-type="bibr" rid="B34">Liotard et al., 1988</xref>). We used the formula of Wood (1997) (K<sub>D</sub> [Fe&#x2013;Mg]<sup>cpx/liq</sup> &#x3d; 0.109 &#x2b; 0.186 &#xd7; Mg<sup>&#x23;</sup>
<sub>cpx</sub>) to calculate the equilibrium constant for the studied clinopyroxene. The range of K<sub>D</sub> (Fe&#x2013;Mg)<sup>cpx/liq</sup> values for the clinopyroxenes is 0.226&#x2013;0.239, indicative of equilibrium between clinopyroxene and the host magma. Therefore, the temperature and pressure calculated from clinopyroxenes in the Dachaidan gabbros can constrain the physicochemical conditions during magma formation.</p>
<p>We used the clinopyroxene&#x2013;melt equilibrium thermobarometer of <xref ref-type="bibr" rid="B47">Putirka (2008)</xref> to calculate the temperatures and pressures (<xref ref-type="sec" rid="s12">Supplementary Table S5</xref>). The crystallization temperatures range from 1,326&#xb0;C to 1,363&#xb0;C, with an average of 1,341&#xb0;C. The crystallization pressures vary from 1.27 to 1.64 GPa, with an average of 1.47 GPa.</p>
<p>To gain further insights into the gabbroic magmas, a comparison was made with MORB samples from the Mid-Atlantic Ridge and East Pacific Rise. The <italic>P&#x2013;T</italic> data calculated using the clinopyroxene thermobarometer plot within the anhydrous melting field for mid-ocean ridges (<xref ref-type="fig" rid="F11">Figure 11</xref>), indicating the Dachaidan gabbros formed in a high-temperature, moderate-pressure, anhydrous melting environment. The <italic>P&#x2013;T</italic> conditions of melting for the Dachaidan gabbros are similar to those of MORBs.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Temperatures and pressures obtained by clinopyroxene geothermobarometry for the Dachaidan gabbros. The purple field represents the temperatures and pressures calculated for MORBs (data from <xref ref-type="bibr" rid="B26">Lee et al., 2009</xref>).</p>
</caption>
<graphic xlink:href="feart-12-1473101-g011.tif"/>
</fig>
<p>In summary, the primary magmas of the Dachaidan gabbros were derived from depleted mantle, and partial melting occurred in spinel-facies mantle. There was then some fractional crystallization of minerals such as olivine and clinopyroxene, which ultimately resulted in the formation of the Mg-rich gabbros.</p>
</sec>
<sec id="s5-4">
<title>5.4 Tectonic setting</title>
<p>In the context of ophiolite formation, some studies have proposed that only a small proportion of ophiolites are the product of mid-ocean ridge spreading, and most form in supra-subduction zones (<xref ref-type="bibr" rid="B44">Pearce et al., 1984</xref>). Gabbros in ophiolites are derived from the mantle by partial melting and/or underwent subsequent fractional crystallization. Therefore, gabbros in ophiolites can constrain the geochemical characteristics of ophiolites in orogenic belts and provide insights into the tectonic setting of ophiolite formation.</p>
<p>Island arc basalts (IABs) and depleted MORBs typically have Ta and Nb contents of &#x3c;0.7 and &#x3c;12 ppm, respectively, with Nb/La &#x3c;1, Hf/Ta &#x3e;5, La/Ta &#x3e;15, and Ti/Y &#x3c;350. In contrast, within-plate basalts (WPBs), transitional MORBs (T-MORBs), and enriched MORBs (E-MORBs) have opposite features (<xref ref-type="bibr" rid="B11">Condie, 1989</xref>). The Dachaidan gabbros have low Ta (0.04&#x2013;0.23 ppm) and Nb (0.59&#x2013;2.79 ppm) contents, with Nb/La &#x3d; 0.80&#x2013;2.97, Hf/Ta &#x3d; 4.91&#x2013;7.95, La/Ta &#x3d; 7&#x2013;24, and Ti/Y &#x3d; 195&#x2013;260. Although some samples have low La/Ta ratios, the elemental abundances and ratios of the Dachaidan gabbros are similar to those IABs or depleted MORBs. In <xref ref-type="fig" rid="F12">Figure 12</xref>, the Dachaidan gabbros plot near the N-MORB trend and similar to the IBM forearc basalts mantle source.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Plots of trace element ratios for the Dachaidan gabbros <bold>(A,B)</bold> (Yuka MORB-like and MORB data are from <xref ref-type="bibr" rid="B117">Zhu, 2021</xref>; Lashuixia gabbro data are from <xref ref-type="bibr" rid="B37">Lu et al., 2018</xref>). Data for the IBM forearc basalts are from <xref ref-type="bibr" rid="B49">Reagan et al., 2010</xref>.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g012.tif"/>
</fig>
<p>In the 2Nb&#x2013;Zr/4&#x2013;Y tectonic discrimination diagram (<xref ref-type="fig" rid="F13">Figure 13A</xref>), the samples plot near the N-MORB and volcanic arc basalt fields, similar to Yuka MORB-like gabbros and basalts, and Lashuixia gabbros. In the V&#x2013;Ti/1,000 diagram (<xref ref-type="fig" rid="F13">Figure 13B</xref>), the samples plot in the IAB field, indicative of a subduction-related origin. In summary, the Dachaidan ophiolite exhibits the geochemical features of both N-MORBs and IABs. Volcanic rocks with such characteristics are typically associated with forearc basins above subduction zones (<xref ref-type="bibr" rid="B91">Xu et al., 2003</xref>; <xref ref-type="bibr" rid="B75">Tian et al., 2008</xref>; <xref ref-type="bibr" rid="B49">Reagan et al., 2010</xref>). Forearc basin volcanic rocks typically include basalts and high-Mg andesites. Previous studies in the Yuka&#x2013;Kaipinggou area have identified basalt, IAB, and magnesian andesite (<xref ref-type="bibr" rid="B104">Zhu, 2011</xref>; <xref ref-type="bibr" rid="B117">Zhu, 2021</xref>; <xref ref-type="bibr" rid="B122">Tuo, 2019</xref>), similar to the IBM forearc basalts (<xref ref-type="bibr" rid="B21">Ishizuka et al., 2014</xref>). Implying a possible forearc tectonic origin for the Dachaidan gabbro. In the V&#x2013;Ti/1,000 diagram (<xref ref-type="fig" rid="F13">Figure 13B</xref>), all samples plot within the Izu&#x2013;Bonin&#x2013;Mariana Forearc basalts and boninite fields. In addition to the above evidence, the TiO<sub>2</sub>, MgO, and FeO<sup>T</sup> contents of the samples in this study are similar to those of IBM basalt (TiO<sub>2</sub> from 0.67 to 1.64, MgO from 4.62 to 9.76 and FeO<sup>T</sup> content of 8.88&#x2013;14.16) (<xref ref-type="fig" rid="F13">Figures 13C, D</xref>).</p>
<fig id="F13" position="float">
<label>FIGURE 13</label>
<caption>
<p>
<bold>(A)</bold> 2Nb&#x2013;Zr/4&#x2013;Y tectonic setting discrimination diagram (after <xref ref-type="bibr" rid="B42">Meschede, 1986</xref>) and <bold>(B)</bold> V&#x2013;Ti/1000 diagram (after <xref ref-type="bibr" rid="B54">Shervais, 1982</xref>) for the Dachaidan gabbros (Yuka MORB-like and MORB data are from <xref ref-type="bibr" rid="B117">Zhu, 2021</xref>; Lashuixia gabbro data are from <xref ref-type="bibr" rid="B37">Lu et al., 2018</xref>). A&#x2160;, within-plate alkaline basalt; A&#x2161;, within-plate alkaline and tholeiitic basalts; B, enriched MORB; C, intraplate tholeiitic basalt; D, N-MORB and volcanic arc basalt; IAB, island arc basalt; MORB, mid-ocean ridge basalt; OIB, ocean island basalt.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g013.tif"/>
</fig>
<p>Due to the resistance of clinopyroxene to alteration during low-grade metamorphism and late-stage magmatic processes, its composition is useful for determining the tectonic setting (<xref ref-type="bibr" rid="B27">Leterrier et al., 1982</xref>). The SiO<sub>2</sub>, TiO<sub>2</sub>, and Al<sub>2</sub>O<sub>3</sub> contents of clinopyroxene are controlled mainly by its composition rather than the physicochemical conditions of crystallization (<xref ref-type="bibr" rid="B125">Brown et al., 1967</xref>). In the TiO<sub>2</sub>&#x2013;SiO<sub>2</sub>/100&#x2013;Na<sub>2</sub>O ternary diagram, the Dachaidan gabbros plot in the field for island arc tholeiites (IATs) and forearc basaltic andesites (BA-A). In a Ti&#x2013;Al (atomic proportions) diagram (<xref ref-type="fig" rid="F14">Figure 14B</xref>), most clinopyroxene plots in the fields for IATs, BA-A, and basaltic andesite (BA). The clinopyroxene in the Dachaidan gabbros has lower Ti contents and Ti/V ratios than MORB and BABB, similar to IATs and low-Ti basaltic andesites (<xref ref-type="fig" rid="F14">Figure 14C</xref>), indicative of crystallization from a high-Mg magma. This is consistent with the high Mg<sup>&#x23;</sup> values of the gabbro samples. Melting of a mantle wedge during subduction of hot and young oceanic lithosphere likely led to ophiolite formation under high-temperature and medium-pressure conditions. Both the whole-rock and clinopyroxene geochemical data confirm that the Dachaidan gabbros formed in a forearc setting. Previous studies have suggested that forearc tholeiites form during subduction initiation and the transition to a continental setting (<xref ref-type="bibr" rid="B123">Xiao et al., 2016</xref>). Therefore, the Dachaidan gabbros were the products of intra-oceanic subduction at the northern margin of the North Qaidam Ocean.</p>
<fig id="F14" position="float">
<label>FIGURE 14</label>
<caption>
<p>Tectonic discrimination diagrams for clinopyroxenes from the Dachaidan gabbros. <bold>(A)</bold> TiO<sub>2</sub>&#x2013;SiO<sub>2</sub>/100&#x2013;Na<sub>2</sub>O (<xref ref-type="bibr" rid="B2">Beccaluva et al., 1989</xref>). <bold>(B)</bold> Atomic Ti versus Al (<xref ref-type="bibr" rid="B2">Beccaluva et al., 1989</xref>). <bold>(C)</bold> Ti versus V (<xref ref-type="bibr" rid="B54">Shervais, 1982</xref>). BON, boninite; BA-A, back-arc andesite; IAT, island arc tholeiite; MORB, mid-ocean ridge basalt; WOPB, within-oceanic plate basalt; BABB, back-arc basin basalt.</p>
</caption>
<graphic xlink:href="feart-12-1473101-g014.tif"/>
</fig>
</sec>
<sec id="s5-5">
<title>5.5 Geodynamic processes</title>
<p>The NQUB contains granitic gneiss, pelitic gneiss, and sporadic occurrences of eclogite and garnet clinopyroxenite. It also contains island arc ophiolitic m&#xe9;lange, and collisional and post-collisional granites (<xref ref-type="bibr" rid="B88">Wu et al., 2004</xref>; <xref ref-type="bibr" rid="B89">Wu et al., 2007</xref>; <xref ref-type="bibr" rid="B87">Wu et al., 2008</xref>; <xref ref-type="bibr" rid="B86">Wu et al., 2014</xref>; <xref ref-type="bibr" rid="B118">Zhu et al., 2010</xref>; <xref ref-type="bibr" rid="B120">Zhu et al., 2012</xref>; <xref ref-type="bibr" rid="B119">Zhu et al., 2014</xref>; <xref ref-type="bibr" rid="B66">Song et al., 2015</xref>; <xref ref-type="bibr" rid="B115">Zhao et al., 2017</xref>). The rock assemblages associated with the eclogites suggest that the UHP metamorphic zone in the NQUB is typical of an early Paleozoic continental orogenic belt (<xref ref-type="bibr" rid="B52">Ren et al., 2019</xref>). Some eclogites have geochemical characteristics typical of oceanic basalts, indicative of derivation from either middle Proterozoic oceanic crust, as is the case for the Shaliuhe section in the South Dulan belt. This section consists of blueschist garnet, phengite&#x2013;garnet, and epidote&#x2013;garnet eclogites with the protolith ages from 1,280 to 1,070 Ma, the protolith may be Mesoproterozoic oceanic crust and a peak metamorphic age of 439&#x2013;430 Ma (<xref ref-type="bibr" rid="B52">Ren et al., 2019</xref>). Alternatively, these rocks may have been derived from early Paleozoic oceanic crust, as exemplified by the blueschist garnet eclogites from the Shaliuhe area, the protolith of these eclogites ages formed at 517&#x2013;514 Ma and peak metamorphic ages of 457&#x2013;440 Ma (<xref ref-type="bibr" rid="B105">Zhang et al., 2009a</xref>; <xref ref-type="bibr" rid="B108">Zhang et al., 2009b</xref>; <xref ref-type="bibr" rid="B106">Zhang et al., 2016</xref>). These findings provide insights into the presence of an early Cambrian Proto-Tethyan oceanic basin. In summary, the geological investigations of the NQUB revealed a complex tectonic history involving continental collision and the presence of an early Cambrian Proto-Tethyan oceanic basin.</p>
<p>
<xref ref-type="bibr" rid="B57">Song et al. (2014b)</xref> investigated the northern Qilian region and NQUB, where oceanic-type eclogites with a peak metamorphic age of 489&#x2013;464 Ma were previously identified (<xref ref-type="bibr" rid="B65">Song et al., 2006</xref>). This age is similar to the metamorphic age of oceanic eclogites in the NQUB, leading to the conclusion that the northern Qilian region and NQUB are part of the same geological system. The continental-type, UHP metamorphic belt in the NQUB formed by northward subduction that caused the Qilian&#x2013;NQUB block to undergo continental subduction. The UHP metamorphic rocks in the belt are considered to have formed by either exhumation along the subduction path or exhumation through bottom-driven uplift (<xref ref-type="bibr" rid="B65">Song et al., 2006</xref>; <xref ref-type="bibr" rid="B57">Song et al., 2014b</xref>; <xref ref-type="bibr" rid="B100">Yin et al., 2007</xref>). MORB-type ophiolites in the NQUB include the Dulan&#x2013;Shaliuhe section dated at 520 Ma (<xref ref-type="bibr" rid="B80">Wang et al., 2020</xref>) and the Amunike ophiolite dated at 485.6 Ma (<xref ref-type="bibr" rid="B29">Li et al., 2018</xref>). In addition, some mafic igneous rocks within the intercalated island arc m&#xe9;lange of the NQUB had diverse tectonic settings, such as island arc, back-arc basin, ocean island, and mid-ocean ridge environments. These include the 521 Ma Xitieshan OIB-type basalts (<xref ref-type="bibr" rid="B120">Zhu et al., 2012</xref>), 480 Ma Tuomoerite N-MORB-type basalts (<xref ref-type="bibr" rid="B82">Wang et al., 2022</xref>), and 542&#x2013;460 Ma island arc volcanic rocks (<xref ref-type="bibr" rid="B121">Yuan et al., 2002</xref>; <xref ref-type="bibr" rid="B55">Shi et al., 2003</xref>; <xref ref-type="bibr" rid="B81">Wang et al., 2023</xref>; <xref ref-type="bibr" rid="B78">Wang et al., 2005</xref>; <xref ref-type="bibr" rid="B118">Zhu et al., 2010</xref>, <xref ref-type="bibr" rid="B120">Zhu et al., 2012</xref>; <xref ref-type="bibr" rid="B119">Zhu et al., 2014</xref>; <xref ref-type="bibr" rid="B16">Gao et al., 2011</xref>). These features are similar to those of early Paleozoic oceanic eclogites in the Dulan region, which protolith age is 510 &#xb1; 19 Ma (<xref ref-type="bibr" rid="B105">Zhang et al., 2009a</xref>; <xref ref-type="bibr" rid="B108">Zhang et al., 2009b</xref>; <xref ref-type="bibr" rid="B106">Zhang G. B. et al., 2016</xref>). Consequently, we infer that there was an independent ocean (i.e., the North Qaidam Ocean) in the region during the early Paleozoic, and that the northern Qilian region and NQUB should not be considered to have been a single entity.</p>
<p>Geochronological studies have revealed that the eclogites in the Xitieshan experienced peak metamorphism at 458&#x2013;420 Ma (<xref ref-type="bibr" rid="B7">Chen et al., 2012</xref>; <xref ref-type="bibr" rid="B35">Liu et al., 2012</xref>; <xref ref-type="bibr" rid="B107">Zhang et al., 2013b</xref>; <xref ref-type="bibr" rid="B111">Zhang L. et al., 2016</xref>). The subordinate gneisses in the Xitieshan underwent prograde metamorphism from 460 to 455 Ma, followed by retrograde metamorphism at 425&#x2013;422 Ma (<xref ref-type="bibr" rid="B102">Zhang et al., 2012</xref>). The metamorphic ages of quartz diorites and eclogites intercalated with the subordinate gneisses in the Dulan region are 458&#x2013;421 Ma (<xref ref-type="bibr" rid="B95">Yang et al., 2005</xref>; <xref ref-type="bibr" rid="B9">Chen et al., 2008</xref>). Blueschist garnet eclogites in the Shaliuhe area have peak metamorphic ages of 457&#x2013;440 Ma (<xref ref-type="bibr" rid="B105">Zhang et al., 2009a</xref>; <xref ref-type="bibr" rid="B108">Zhang et al., 2009b</xref>; <xref ref-type="bibr" rid="B106">Zhang G. B. et al., 2016</xref>). All these ages indicate that subduction in the North Qaidam Ocean started at <italic>ca</italic>. 460 Ma and persisted until <italic>ca</italic>. 421 Ma. Given the oceanic nature of these rocks, this study suggests the Dachaidan gabbros were formed in an intra-oceanic forearc environment. The zircon U&#x2013;Pb age of 510 Ma indicates subduction in the North Qaidam Ocean started prior to 510 Ma.</p>
<p>We propose the early Paleozoic tectonic evolution of the NQUB was as follows. During 510&#x2013;460 Ma, the North Qaidam Ocean existed between the Qaidam Block and Oulongbuluke micro-continent. Subsequently, the ocean experienced northward subduction (<xref ref-type="fig" rid="F15">Figure 15A</xref>), which led to the development of a forearc ophiolite in the Dachaidan region, a back-arc basin ophiolite in the Tuomoerrite Basin, and other related features. The present-day NQUB ophiolite is considered to comprise remnants of the oceanic crust.</p>
<fig id="F15" position="float">
<label>FIGURE 15</label>
<caption>
<p>Schematic diagram of the early Paleozoic tectonic evolution of the NQOB (modified after <xref ref-type="bibr" rid="B4">Cai et al., 2021</xref>).</p>
</caption>
<graphic xlink:href="feart-12-1473101-g015.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="conclusion" id="s6">
<title>6 Conclusion</title>
<p>
<list list-type="simple">
<list-item>
<p>(1) The age of the Dachaidan gabbros is 510.0 &#xb1; 2.9 Ma and 510.0 &#xb1; 2.8 Ma, indicating the ophiolite in the region formed during the early Cambrian.</p>
</list-item>
<list-item>
<p>(2) The Dachaidan gabbros formed by decompression partial melting of depleted mantle.</p>
</list-item>
<list-item>
<p>(3) The Dachaidan gabbros have the geochemical characteristics of both island arc volcanic rocks and MORBs, indicating the northern margin of the Qaidam Basin was in an oceanic subduction setting during the early Cambrian.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s7">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s12">Supplementary Material</xref>, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s8">
<title>Author contributions</title>
<p>YQ: Writing&#x2013;original draft, Writing&#x2013;review and editing. XjL: Funding acquisition, Writing&#x2013;review and editing. XaL: Investigation, Writing&#x2013;review and editing. QH: Resources, Writing&#x2013;review and editing. QY: Data curation, Writing&#x2013;review and editing. RH: Formal Analysis, Writing&#x2013;review and editing. PL: Formal Analysis, Writing&#x2013;review and editing. YS: Formal Analysis, Writing&#x2013;review and editing.</p>
</sec>
<sec sec-type="funding-information" id="s9">
<title>Funding</title>
<p>The author(s) declare that financial support was received for the research, authorship, and/or publication of this article. Financial support for this research was provided by the National Natural Science Foundation of China (No. 92055208), and the Guangxi Science Innovation Base Construction Foundation (No. GuikeZY21195031), the Natural Science Foundation of Guangxi Province for Young Scholars (No. GuikeAD23026175). This research is a contribution to &#x201c;Xinjiang Tianchi Distinguished Expert&#x201d; by Xi-Jun Liu.</p>
</sec>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec id="s12">
<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2024.1473101/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2024.1473101/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="Table1.xlsx" id="SM1" mimetype="application/xlsx" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="DataSheet1.docx" id="SM2" mimetype="application/docx" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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