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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">1131338</article-id>
<article-id pub-id-type="doi">10.3389/feart.2023.1131338</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Implications of Nd isotopic mapping for crustal composition and metallogenesis in the Sanjiang orogenic belt (SW China)</article-title>
<alt-title alt-title-type="left-running-head">Yuan et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2023.1131338">10.3389/feart.2023.1131338</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Yuan</surname>
<given-names>Lingling</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2145087/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Chai</surname>
<given-names>Peng</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1962730/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Hou</surname>
<given-names>Zengqian</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zheng</surname>
<given-names>Yuanchuan</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Quan</surname>
<given-names>Haihui</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>Institute of Geology</institution>, <institution>Chinese Academy of Geological Sciences (CAGS)</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>State Key Laboratory of Geological Process and Mineral Resources</institution>, <institution>School of Earth Sciences and Resources</institution>, <institution>China University of Geosciences Beijing</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1634200/overview">Hao Hu</ext-link>, China University of Geosciences Wuhan, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1736082/overview">Xiaodong Deng</ext-link>, China University of Geosciences Wuhan, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/2045092/overview">Changming Wang</ext-link>, China University of Geosciences, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/2255609/overview">Xiaocui Chen</ext-link>, Guizhou Institute of Technology, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Peng Chai, <email>cx001chaipeng@163.com</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>09</day>
<month>05</month>
<year>2023</year>
</pub-date>
<pub-date pub-type="collection">
<year>2023</year>
</pub-date>
<volume>11</volume>
<elocation-id>1131338</elocation-id>
<history>
<date date-type="received">
<day>24</day>
<month>12</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>19</day>
<month>04</month>
<year>2023</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2023 Yuan, Chai, Hou, Zheng and Quan.</copyright-statement>
<copyright-year>2023</copyright-year>
<copyright-holder>Yuan, Chai, Hou, Zheng and Quan</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The Sanjiang orogenic belt, located in southwestern China and the southeastern Tibetan Plateau, includes a variety of economically important metal deposits. Previous studies have focused on Lu-Hf isotopic mapping to suggest its lithospheric architecture and mineralization. In this study, we provide the results of Nd isotopic mapping and compare them with the results of Hf isotopic mapping based on the similarity of Sm-Nd and Lu-Hf isotope systems, which indicate three juvenile domains with high &#x3b5;<sub>Nd</sub>(t) and young Nd model ages within the Eastern Qiangtang-Simao terrane, while presenting negative &#x3b5;<sub>Nd</sub>(t) values over the entire horizon. The very negative &#x3b5;<sub>Nd</sub>(t) and old Nd model ages found in the Tengchong-Baoshan terrane and Changning-Menglian suture suggest that these terranes are old and might be reworked. The Nd isotopic mapping of the Sanjiang orogenic belt also suggests a relationship between different lithospheric architectures and the locations of distinct ore deposits. Porphyry-skarn Cu&#x2013;Mo&#x2013;(Au) deposits occur in the juvenile crust, which has relatively high &#x3b5;<sub>Nd</sub>(t) (&#x2212;3.3&#x2013;5.1) and young T<sub>DM</sub> ages, whereas skarn and hydrothermal vein-type W&#x2013;Sn deposits and Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposits are located in the low-&#x3b5;<sub>Nd</sub>(t) area.</p>
</abstract>
<kwd-group>
<kwd>Sanjiang</kwd>
<kwd>Nd isotopic mapping</kwd>
<kwd>crustal composition</kwd>
<kwd>metallogenesis</kwd>
<kwd>crustal architecture</kwd>
</kwd-group>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Economic Geology</meta-value>
</custom-meta>
</custom-meta-wrap>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>The formation of the continental crust is a major consequence of planetary differentiation and has played a key role in the evolution of life and the climate of this planet (<xref ref-type="bibr" rid="B4">Campbell and Allen, 2008</xref>; <xref ref-type="bibr" rid="B14">Couzini&#xe9; et al., 2016</xref>), as well as in the formation of some ore deposits. The deep crust is not only a zone for crust-mantle interactions and material&#x2013;energy exchange processes but also a source of many felsic magmas and deep geothermal flows (<xref ref-type="bibr" rid="B38">Hou and Zhang, 2015</xref>). With the retention, storage, and subduction of mantle-derived magma at the bottom of the crust, the reworking of the old crust, the formation of juvenile material, and the lateral and vertical growth of the lithosphere occur in the deep crust; the mineralized metals are also adjusted for distribution and re-enrichment (<xref ref-type="bibr" rid="B33">Hou et al., 2015</xref>; <xref ref-type="bibr" rid="B38">Hou and Zhang, 2015</xref>). Thus, for understanding the formation of large mineralized systems and the spatial distribution of the assemblages of mineralized metals, it is critical to reveal the material composition and distribution of the deep lithosphere, in particular, the distribution of old and juvenile materials (<xref ref-type="bibr" rid="B38">Hou and Zhang, 2015</xref>; <xref ref-type="bibr" rid="B39">Hou et al., 2020</xref>). In collisional orogenic systems, the formation of the juvenile crust is considered to be relatively unimportant (e.g., <xref ref-type="bibr" rid="B45">Kerrich et al., 2005</xref>; <xref ref-type="bibr" rid="B26">Groves and Bierlein, 2007</xref>); in fact, large ore deposits are formed (e.g., <xref ref-type="bibr" rid="B32">Hou and Cook, 2009</xref>), which are suggested to be associated with the reworking of the old crust, remelting of the juvenile crust, and migration of crustal melts and fluids (e.g., <xref ref-type="bibr" rid="B32">Hou and Cook, 2009</xref>; <xref ref-type="bibr" rid="B54">Lu et al., 2013</xref>; <xref ref-type="bibr" rid="B33">Hou et al., 2015</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>).</p>
<p>Whole-rock Sm-Nd and zircon Lu-Hf isotopic mapping has recently been adopted as a tool for evaluating crustal evolution, which estimates the age of continental crust (e.g., <xref ref-type="bibr" rid="B19">DePaolo, 1988</xref>; <xref ref-type="bibr" rid="B20">DePaolo et al., 1991</xref>; <xref ref-type="bibr" rid="B46">Kovalenko et al., 2004</xref>) and constrains the localization of mineral deposits (<xref ref-type="bibr" rid="B60">Mole et al., 2013</xref>; <xref ref-type="bibr" rid="B61">Mole et al., 2014</xref>; <xref ref-type="bibr" rid="B33">Hou et al., 2015</xref>; <xref ref-type="bibr" rid="B8">Champion and Huston, 2016</xref>). Typically, the analogous behavior of Lu-Hf and Sm-Nd isotopic systems in mantle-derived magmas is considered to cause the positive correlation between &#x3b5;<sub>Hf</sub>(t) and &#x3b5;<sub>Nd</sub>(t) values (<xref ref-type="bibr" rid="B70">Vervoort and Patchett, 1996</xref>). However, Nd&#x2013;Hf isotopic decoupling has frequently been reported in previous petrological studies (e.g., <xref ref-type="bibr" rid="B2">Bizimis et al., 2004</xref>). Thus, comprehensively considering differential isotopic mapping can contribute to the understanding of the formation of the crust. The advantages of zircon Hf isotopic mapping include 1) high metadata precision, as determined <italic>in situ</italic>; and 2) the abundance of data due to its simple analytical process and relatively low cost. Conversely, it should be noted that &#x3b5;<sub>Hf</sub>(t) values from different zircon grains in a sample or different sites in a zircon vary greatly, up to more than ten <italic>&#x3b5;</italic> units. Thus, the representative values, mostly median data (<xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>) and weighted average data (<xref ref-type="bibr" rid="B33">Hou et al<italic>.</italic>, 2015</xref>), for Hf isotopic mapping are distinct according to different authors. However, the whole-rock Nd isotopic value is an objective average of a specific whole-rock sample and can be an unbiased method for the isotopic mapping of large areas and have more advantages than Hf isotope mapping of subjectively selected zircons (<xref ref-type="bibr" rid="B31">Hou and Wang, 2018</xref>).</p>
<p>The Sanjiang orogenic belt (SOB) has attracted considerable interest among the scientific community in terms of its orogenesis and metallogenesis (e.g., <xref ref-type="bibr" rid="B91">Yin and Harrison, 2000</xref>; <xref ref-type="bibr" rid="B36">Hou et al., 2007</xref>; <xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>; <xref ref-type="bibr" rid="B72">Wang et al., 2014</xref>). Several studies have focused on Lu-Hf isotopic mapping to suggest the terrane boundary and mineralization of porphyry Cu&#x2013;Au, orogenic-Au, and rare earth element deposits (<xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>). <xref ref-type="bibr" rid="B22">Du et al. (2016)</xref> stressed that the mapping of &#x3b5;<sub>Nd</sub>(t) and &#x3b5;<sub>Hf</sub>(t) using the method of Kriging interpolation proposed that the Changning-Menglian suture was the boundary of two different regional terranes, and indicated the empirical correlation between Nd isotopic mapping and differential mineralization. For instance, the granite-related W-Sn deposits occur in low-&#x3b5;<sub>Nd</sub>(t) and -&#x3b5;<sub>Hf</sub>(t) areas, while the porphyry-skarn Cu&#x2013;Mo mineralization is found in high positive &#x3b5;<sub>Hf</sub>(t) and higher negative &#x3b5;<sub>Nd</sub>(t) regions.</p>
<p>However, some fundamental issues are not fully explained, for example, the crustal structures and the tectonic evolutionary history reflected by both &#x3b5;<sub>Nd</sub>(t) and T<sub>DM</sub> values and the relationship between Nd isotopic mapping and further reasons for the appearance of some types of metallic mineralization, such as Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag and W&#x2013;Sn deposits, as well as the Cu&#x2013;Mo mineralization mentioned above. These issues are critical for understanding the crustal evolution and spatiotemporal distribution of distinct mineral deposits.</p>
<p>In order to further explain the issues mentioned above, we collected more isotopic data of igneous rocks (665 published whole-rock Rb-Sr and Sm-Nd isotopic analyses), which provided more details about the crustal composition. The isotopic mapping was contoured with the reverse distance weighted interpolation method, which was better for processing the small dataset. Then, we present an overview and re-evaluation of the Cu&#x2013;Au&#x2013;(Mo) mineralization, skarn, and hydrothermal vein-type W&#x2013;Sn and Ag&#x2013;Cu&#x2013;Pb&#x2012;Zn deposits in the SOB. We focus on 1) the spatiotemporal distribution of Nd isotopic data of igneous rocks; 2) the distribution and formation of juvenile and old components; and 3) the relationships between Nd isotopic mapping and different mineralizations.</p>
</sec>
<sec id="s2">
<title>2 Geological setting</title>
<p>The Sanjiang orogenic belt (SOB) is located within the eastern Himalayan-Tibetan orogen and is composed of three major rivers: Jinshajiang, Lancangjiang, and Nujiang (<xref ref-type="bibr" rid="B36">Hou et al., 2007</xref>; <xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>). Several major continental terranes are preserved in the SOB, including Zhongzan, Eastern Qiangtang, Western Qiangtang, a part of Lhasa, a part of Southern China, Simao, Baoshan, and Tengchong from north to south. The boundaries between the units are major sutures or magma arcs (<xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>; <xref ref-type="bibr" rid="B72">Wang et al., 2014</xref>; <xref ref-type="bibr" rid="B18">Deng et al., 2014b</xref>). We adopted the &#x201c;terrane&#x201d; division scheme of <xref ref-type="bibr" rid="B84">Xu et al. (2021)</xref> to simplify the calculation (<xref ref-type="fig" rid="F1">Figure 1</xref>). The Sanjiang orogenic belt is derived from two stages (<xref ref-type="bibr" rid="B16">Deng et al., 2020</xref>): accretionary orogenesis in the Palae-Mesozoic with the subduction of the Tethys and collisional orogenesis that began in the Cenozoic (approximately 65&#xa0;Ma) (<xref ref-type="bibr" rid="B39">Hou et al., 2020</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Simplified geological map of the Sanjiang orogenic belt, modified after <xref ref-type="bibr" rid="B17">Deng et al. (2014a)</xref> and <xref ref-type="bibr" rid="B84">Xu et al. (2021)</xref>. Abbreviations: ZYA, Zhongzan-Yidun arc terrane; EQST, Eastern Qiangtang-Simao Terrane; BT, Baoshan-Tengchong Terrane; and SCC, South China Craton.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g001.tif"/>
</fig>
<sec id="s2-1">
<title>2.1 Zhongzan-Yidun arc terrane</title>
<p>The Zhongzan-Yidun arc (ZYA) terrane is a combination of the Zhongzan block and the Yidun arc, bound by the Garze-Litang suture to the east and by the Jinshajiang suture to the west (<xref ref-type="fig" rid="F1">Figure 1</xref>). The Zhongzan block could have been derived from the Yangtze block because they have similar Paleozoic stratigraphic sequences and paleontological fossils (<xref ref-type="bibr" rid="B9">Chang, 2000</xref>; <xref ref-type="bibr" rid="B82">Xiao et al., 2004</xref>), and it is a result of the opening of the Garze-Litang ocean, which is a branch of the Paleo-Tethys (<xref ref-type="bibr" rid="B16">Deng et al., 2020</xref>) from the late Paleozoic. The Jinshajiang Ocean is another branch of the Paleo-Tethys and was closed in the Middle Triassic (<xref ref-type="bibr" rid="B16">Deng et al., 2020</xref>).</p>
<p>Magmatism in this terrane mainly occurred in the Late Triassic and Late Cretaceous periods (<xref ref-type="bibr" rid="B82">Xiao et al., 2004</xref>). The former is found as medium-to high-K calc-alkaline diorite, monzonite, granodiorite, granite, and volcanic rocks (<xref ref-type="bibr" rid="B65">Qu et al., 2002</xref>; <xref ref-type="bibr" rid="B30">He et al., 2013</xref>; <xref ref-type="bibr" rid="B81">Wu et al., 2014</xref>). The latter is mainly found as monzogranite, biotite granite, and granitic porphyry (<xref ref-type="bibr" rid="B65">Qu et al., 2002</xref>; <xref ref-type="bibr" rid="B76">Wang et al., 2014</xref>).</p>
</sec>
<sec id="s2-2">
<title>2.2 Eastern Qiangtang-Simao terrane</title>
<p>The eastern Qiangtang-Simao (EQST) terrane, which extends from north to south, constitutes the main and central parts of the SOB (<xref ref-type="fig" rid="F1">Figure 1</xref>). The Jinshajiang-Ailaoshan suture, which is located to the east of the EQST, was the westward subduction area of the branch of the Paleo-Tethys ocean, while the Longmucuo-Shuanghu-Changning-Menglian suture located to the west was the eastward subduction area of the main Paleo-Tethyan (<xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>; <xref ref-type="bibr" rid="B18">Deng et al., 2014b</xref>). The coupling of the subduction of the Proto-Tethys oceanic plate underneath the Simao block and the opening of the Paleo-Tethys ocean suggests that the Eastern Qiangtang and Simao blocks are two Gondwana-derived microcontinents (<xref ref-type="bibr" rid="B69">Usuki et al., 2013</xref>; <xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>). The Eastern Qiangtang block was amalgamated with the Western Qiangtang subterrane as the Qiangtang Terrane in the early Jurassic (<xref ref-type="bibr" rid="B34">Hou et al., 2003</xref>; <xref ref-type="bibr" rid="B89">Yang et al., 2014</xref>) and is the south-central part, while the Lhasa terrane, which is derived from the Australian margin of the Gondwana supercontinent (<xref ref-type="bibr" rid="B96">Zhu et al., 2013</xref>), is the southernmost part.</p>
<p>Magmatism in the area developed in the late Permian to very early Triassic in continental-margin arcs, such as the Jomda-Weixi arc along the northern Jinshajiang-Ailaoshan suture (<xref ref-type="bibr" rid="B99">Zi et al., 2012a</xref>; <xref ref-type="bibr" rid="B100">Zi et al., 2012b</xref>) and the Yaxuanqiao arc in the southern part (<xref ref-type="bibr" rid="B23">Fan et al., 2010</xref>; <xref ref-type="bibr" rid="B3">Cai et al., 2014</xref>; <xref ref-type="bibr" rid="B85">Xu et al., 2016</xref>). The Changning-Menglian Paleo-Tethys subducted beneath the Simao Terrane, resulting in the formation of the Yunxian-Jinggu Arc. This Arc was intruded by the Lincang granitic pluton, which consists of a peraluminous S-type granite with U&#x2012;Pb zircon aging from 248 to 203&#xa0;Ma (<xref ref-type="bibr" rid="B62">Peng et al., 2008</xref>; <xref ref-type="bibr" rid="B21">Dong et al., 2013</xref>; <xref ref-type="bibr" rid="B63">Peng et al., 2013</xref>). It is worth noting that the Eocene&#x2012;Oligocene potassic porphyry intrusions are large and widespread along the Jinshajiang-Red River deep-crustal fault zone in the Eastern Qiangtang block (<xref ref-type="bibr" rid="B89">Yang et al., 2014</xref>).</p>
</sec>
<sec id="s2-3">
<title>2.3 Baoshan-Tengchong Terrane</title>
<p>The Baoshan-Tengchong (BT) terrane consists of the Baoshan subterrane and Tengchong subterrane, which were once located at the northern margin of Gondwana and accreted to the Eurasian continent in the late Mesozoic (<xref ref-type="bibr" rid="B58">Metcalfe, 2006</xref>; <xref ref-type="bibr" rid="B43">Jin et al., 2014</xref>) (<xref ref-type="fig" rid="F1">Figure 1</xref>). The Baoshan subterrane experienced a similar trend, but the accretionary time might have been in the late Paleozoic to early Mesozoic (<xref ref-type="bibr" rid="B57">Metcalfe, 2013</xref>). The Changning-Menglian suture located to the east of the BT might have preserved the subduction of the Proto-Tethys and Paleo-Tethys oceanic plates (<xref ref-type="bibr" rid="B17">Deng et al., 2014a</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>). This suture correlates with the Longmu Tso-Shuanghu Suture in eastern Tibet.</p>
</sec>
<sec id="s2-4">
<title>2.4 South China Craton</title>
<p>The South China Craton (SCC) is a block with an Archean history (<xref ref-type="bibr" rid="B24">Gao et al., 1999</xref>). Continuous subduction and mantle plume activities following the breakup of the Columbia supercontinent resulted in large volumes of Neoproterozoic volcanic rocks (<xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>). The Jinshajiang-Ailaoshan suture, which is accompanied by Eocene&#x2013;Oligocene alkaline magmatic rocks along the western margin of the SCC (<xref ref-type="fig" rid="F1">Figure 1</xref>), was a result of the India-Asia continental collision during the Cenozoic and lithospheric thickening (<xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>).</p>
</sec>
</sec>
<sec id="s3">
<title>3 Petrography of samples</title>
<p>Granitoid and mafic igneous rocks occur widely in the SOB, which consists of several parallel orogens and are the result of distinct orogenic activities (<xref ref-type="bibr" rid="B15">Deng et al., 2013</xref>). The collision between India and Asia was initiated at approximately 70&#x2013;65&#xa0;Ma (<xref ref-type="bibr" rid="B91">Yin and Harrison, 2000</xref>), and the samples collected can be divided into two groups: pre-collisional (&#x2265;65&#xa0;Ma) and syn-collisional (&#x3c;65&#xa0;Ma) (<xref ref-type="bibr" rid="B39">Hou et al., 2020</xref>). It is important to note that the granite samples or pluton that were heavily contaminated by crustal material may show lower or uneven &#x3b5;<sub>Nd</sub>(t) values, thus masking the real information of the crustal component (<xref ref-type="bibr" rid="B56">Maier et al<italic>.</italic>, 2000</xref>). These samples with possible bias were excluded from the analyses to present the true distribution of Nd isotopic values. The data points plotted on the map (<xref ref-type="fig" rid="F2">Figure 2</xref>) that have different colors show that the &#x3b5;<sub>Nd</sub>(t) values are not very different from other adjacent data points, which could be from the same granite intrusions unless the intrusion ages of the samples are very different. The pre-collisional period covers a long span of time, from the Paleozoic to the entire Mesozoic, and the 79 samples collected were derived from all terranes except the SCC. These samples consisted of monzogranite, granodiorite, granite, leucocratic granite, and gneissose granite.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>&#x3b5;<sub>Nd</sub>(t) and ages of samples from the SOB.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g002.tif"/>
</fig>
<p>The other 141 samples collected during the post-collisional period occurred predominantly in the BT and SCC and partly in the EQST; none occurred in the ZYA. The latest U&#x2012;Pb age of the samples (YS-60) is 22.4&#xa0;Ma from the Red River shear belt (<xref ref-type="bibr" rid="B92">Zhang and Schaerer, 1999</xref>). The lithology of these relatively new samples is similar to that of the older samples and includes leucocratic granite, monzonitic granite porphyry, biotite granite porphyry, granite porphyry, and granite.</p>
<p>Overall, these igneous rocks are widespread in all terranes of the SOB, and their ages were obtained by the U&#x2012;Pb zircon method. These can be used to constrain the percentage of old continental and young mantle-derived juvenile components at the terrane scale (<xref ref-type="bibr" rid="B75">Wang et al., 2009</xref>; <xref ref-type="bibr" rid="B39">Hou et al., 2020</xref>).</p>
</sec>
<sec id="s4">
<title>4 Sr-Nd isotopic characteristics and mapping</title>
<sec id="s4-1">
<title>4.1 Nd isotopic interpretation</title>
<p>Previously published Nd isotopic data from 220 samples were used to evaluate the crustal evolution in this region over time based on existing zircon U&#x2012;Pb ages or other isotopic ages, such as Ar&#x2013;Ar or K&#x2013;Ar ages. To produce a data set for the SOB, a consistent method was used to recalculate the data (<xref ref-type="bibr" rid="B55">Maboko and Nakamura, 1996</xref>). The specific calculation methods and parameters are as follows (<xref ref-type="bibr" rid="B41">Jacobsen and Wasserburg, 1980</xref>; <xref ref-type="bibr" rid="B80">Wu et al., 2002</xref>).<disp-formula id="equ1">
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</disp-formula>where &#x3bb;&#x3d;6.54&#xd7;10<sup>&#x2212;12</sup>, (<sup>143</sup>Nd/<sup>144</sup>Nd)<sub>CHUR</sub>&#x3d;0.512638, (<sup>147</sup>Sm/<sup>144</sup>Nd)<sub>CHUR</sub>&#x3d;0.1967, f<sub>CC</sub>&#x3d;&#x2212;0.4, and f<sub>DM</sub>&#x3d;0.08592.</p>
</sec>
<sec id="s4-2">
<title>4.2 General characteristics</title>
<p>The data that were collected and recalculated are listed in <xref ref-type="sec" rid="s11">Supplementary Table S1</xref>. The age-corrected initial Sr isotopic ratios showed large variations from 0.700899 to 0.760444 (<xref ref-type="fig" rid="F3">Figure 3A</xref>), but most were between 0.703 and 0.715 (<xref ref-type="fig" rid="F3">Figure 3B</xref>). The &#x3b5;<sub>Nd</sub>(t) values varied from &#x2212;14.56 to 5.94, and most were &#x3c;0 and &#x3e;&#x2212;10 (<xref ref-type="fig" rid="F3">Figure 3</xref>). Positive &#x3b5;<sub>Nd</sub>(t) values from the EQST and SCC terranes were observed to a large extent in mafic rocks, followed by felsic dikes.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>&#x3b5;<sub>Nd</sub>(t) vs. (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> diagram of the SOB.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g003.tif"/>
</fig>
<p>Additionally, most samples had one-stage model ages (T<sub>DM</sub>) between 0.5 and 3.2&#xa0;Ga, with f<sub>Sm/Nd</sub> values ranging from &#x2212;0.68 to 0.75, and most rocks had f<sub>Sm/Nd</sub> values between &#x2212;0.2 and &#x2212;0.6 (except 55 samples) (<xref ref-type="fig" rid="F4">Figure 4</xref>). The model ages generally become older with increasing f<sub>Sm/Nd</sub>, which shows a linear correlation. Notably, the T<sub>DM</sub> of the rocks from the syn-collisional stage was usually younger than that from the pre-collisional stage. As shown in <xref ref-type="fig" rid="F5">Figure 5</xref>, T<sub>DM2</sub> was applied only to samples with values of f<sub>Sm/Nd</sub> &#x3e; &#x2212;0.2 and &#x3c; &#x2212;0.6 (<xref ref-type="bibr" rid="B75">Wang et al., 2009</xref>). The model age increased with decreasing &#x3b5;<sub>Nd</sub>(t) values, which suggests a linear correlation.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>f<sub>Sm/Nd</sub> <sup>&#x2212;</sup>vs. T<sub>DM1</sub> diagram of the SOB.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g004.tif"/>
</fig>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>&#x3b5;<sub>Nd</sub>(t) vs. the Nd model age; T<sub>DM2</sub> is used only for samples when f<sub>Sm/Nd</sub> &#x3e; &#x2212;0.2 and &#x3c; &#x2212;0.6.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g005.tif"/>
</fig>
</sec>
<sec id="s4-3">
<title>4.3 Nd isotopic contour mapping</title>
<p>Since the dataset was small, it was reasonable to apply the inverse distance weighted interpolation method, which uses the 12 nearest neighbors at a &#x201c;power&#x201d; (<xref ref-type="bibr" rid="B61">Mole et al., 2014</xref>; <xref ref-type="bibr" rid="B33">Hou et al., 2015</xref>), in ArcGIS to contour the &#x3b5;<sub>Nd</sub>(t) and T<sub>DM</sub> maps (<xref ref-type="bibr" rid="B75">Wang et al., 2009</xref>; <xref ref-type="bibr" rid="B61">Mole et al., 2014</xref>; <xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>). During the data processing, we attempted to minimize the subjective influence caused by manual screening to show the original distribution of the data as much as possible. All Nd isotope data were classified by the geometric interval method in ArcMap to ensure that the variation between intervals was fairly consistent and that the amount of data in each class range was approximately the same. Particularly, regarding the samples with different Nd isotope values in the same geographical coordinates, the arithmetic mean values were used as the points for mapping to avoid the bias caused by random selection in ArcGIS. As a result, 199 Nd isotopic values were used for mapping. The &#x3b5;<sub>Nd</sub>(t) values of rocks in the SOB were mostly negative, while positive values were observed in the southern, northern, and central parts of the EQST. The most negative values of &#x3b5;<sub>Nd</sub>(t) occurred in the BT and SCC, and the other areas contained &#x3b5;<sub>Nd</sub>(t) values between &#x2212;9.3 and &#x2212;1.9 (<xref ref-type="fig" rid="F6">Figure 6</xref>). Similarly, the youngest Nd model ages (0.58&#x2013;0.87&#xa0;Ga) occurred in the same position as the &#x3b5;<sub>Nd</sub>(t) values in the EQST, and the oldest (2.29&#x2013;3.03&#xa0;Ga) was found in the SCC and BT, while the other Nd model ages were mostly between 2.29 and 1.17&#xa0;Ga (<xref ref-type="fig" rid="F7">Figure 7</xref>).</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Contour map of &#x3b5;<sub>Nd</sub>(t) in the SOB. The unspecific legends are the same as those in <xref ref-type="fig" rid="F1">Figure 1</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g006.tif"/>
</fig>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Contour map of Nd model ages in the SOB. The unspecific legends are the same as those in <xref ref-type="fig" rid="F1">Figure 1</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g007.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="discussion" id="s5">
<title>5 Discussion</title>
<sec id="s5-1">
<title>5.1 Distribution and formation of crustal components</title>
<p>Hf&#x2013;Nd isotopic data were used to distinguish between juvenile and old crustal components (<xref ref-type="bibr" rid="B75">Wang et al., 2009</xref>; <xref ref-type="bibr" rid="B60">Mole et al., 2013</xref>; <xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>; <xref ref-type="bibr" rid="B25">Granseth et al., 2021</xref>; <xref ref-type="bibr" rid="B84">Xu et al., 2021</xref>). Juvenile crust, with isotopic values that plot on or close to the depleted mantle evolution line, is regarded as crustal material that is generated directly from the depleted mantle or remelted from material recently extracted from the depleted mantle. In contrast, the old or reworked crust refers to the preexisting crust that was remobilized by partial melting and/or erosion with sedimentation (<xref ref-type="bibr" rid="B1">Belousova et al<italic>.</italic>, 2010</xref>; <xref ref-type="bibr" rid="B29">Hawkesworth et al<italic>.</italic>, 2010</xref>; <xref ref-type="bibr" rid="B33">Hou et al<italic>.</italic>, 2015</xref>). The parent and daughter elements of the Sm-Nd isotope system are both rare earth elements (REEs) and generally behave similarly, which can be used to effectively suggest crustal processes and the source of the rocks in question (<xref ref-type="bibr" rid="B19">DePaolo, 1988</xref>; <xref ref-type="bibr" rid="B7">Champion, 2013</xref>). During the formation of juvenile crust, the Earth&#x2019;s crust is more enriched in Nd and Sm and has lower Sm/Nd ratios than the complementary depleted mantle reservoir as a result of lanthanide contraction. In other words, &#x3b5;<sub>Nd</sub>(t) values vary over time because of the different Sm/Nd ratios of mantle and crustal reservoirs (<xref ref-type="bibr" rid="B7">Champion, 2013</xref>). The values of &#x3b5;<sub>Nd</sub>(t) and Nd model ages are tools for distinguishing the possible sources of magma and the formation age of crustal source rocks separately (<xref ref-type="bibr" rid="B31">Hou and Wang, 2018</xref>) (<xref ref-type="fig" rid="F8">Figure 8</xref>). A comparison of Hf isotopic mapping from previous studies (<xref ref-type="fig" rid="F9">Figure 9</xref>) and Nd isotopes are discussed below.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>&#x3b5;<sub>Nd</sub>(t) vs. time, modified after <xref ref-type="bibr" rid="B7">Champion. (2013)</xref> <xref ref-type="fig" rid="F8">Figure 8</xref> &#x3b5;<sub>Nd</sub>(t) vs. age(a) and Nd model age vs. age(b).</p>
</caption>
<graphic xlink:href="feart-11-1131338-g008.tif"/>
</fig>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Contour map of &#x3b5;<sub>Hf</sub>(t) in the SOB, data from <xref ref-type="bibr" rid="B84">Xu et al. (2021)</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g009.tif"/>
</fig>
<sec id="s5-1-1">
<title>5.1.1 The juvenile component</title>
<p>The Nd isotopic system has become an important tool for constraining the age and mechanism of continental formation (<xref ref-type="bibr" rid="B8">Champion and Huston, 2016</xref>). For the SOB, high &#x3b5;<sub>Nd</sub>(t) values (&#x3e;&#x2212;1.9) occur mostly in three domains, as observed through Hf isotopic mapping (<xref ref-type="fig" rid="F9">Figure 9</xref>), while low &#x3b5;<sub>Nd</sub>(t) values (&#x3c;&#x2212;1.9) are observed over the whole horizon (<xref ref-type="fig" rid="F6">Figure 6</xref>).</p>
<p>In the northernmost part of the EQST, high &#x3b5;<sub>Nd</sub>(t) values with low Nd model ages (<xref ref-type="fig" rid="F6">Figures 6</xref>, <xref ref-type="fig" rid="F7">7</xref>) occur near the Jinshajiang Suture in the east and the Bangong-Nujiang Suture. The ages of samples with high &#x3b5;<sub>Nd</sub>(t) values were between 43 and 37&#xa0;Ma (<xref ref-type="fig" rid="F2">Figure 2</xref>), while the ages of the other samples around the area varied from 220 to 75&#xa0;Ma. This indicates either that the juvenile component resulting from the pre-collisional stage shrank or even partially disappeared since the collision transformed the original juvenile crust or that no crust-derived magmatic activity occurred near the Bangonghu-Nujiang suture due to a lack of remelting during the collisional period (<xref ref-type="bibr" rid="B39">Hou et al., 2020</xref>). This shows that subduction and collision might have resulted in a continuous accretion of the juvenile component.</p>
<p>In the accretionary orogenic belt, juvenile materials are either collaged in the orogenic belt as a residual oceanic crust or injected into the crust as mantle-derived arc magma, resulting in the formation and growth of continental crust (<xref ref-type="bibr" rid="B29">Hawkesworth et al., 2010</xref>). With the subduction of the oceanic lithosphere, the upper continental lithosphere often experiences transformation and destruction; as a result, the old crust might have been subducted and eroded when the juvenile lower crust was formed (<xref ref-type="bibr" rid="B13">Collins et al., 2011</xref>). These geological processes could also have occurred in the Tethys subduction accretionary orogenic stage before the formation of the Tibetan Plateau. During this period, mantle arc magma injection led to vertical crustal growth, and the juvenile crust was preserved in the continental collision orogenic belt as a magma arc and arc root (<xref ref-type="bibr" rid="B93">Zhang et al., 2020</xref>).</p>
<p>Similarly, in the center of the EQST, high &#x3b5;<sub>Nd</sub>(t) values occupy a small space where the ages of the samples are approximately 35&#xa0;Ma (<xref ref-type="bibr" rid="B53">Lu et al., 2013</xref>; <xref ref-type="bibr" rid="B50">Liu et al., 2017</xref>; <xref ref-type="bibr" rid="B95">Zhou et al., 2019</xref>), which is a part of the post-collisional stage. The rock type of these samples includes adakite-like monzogranite, potassic igneous rock, and barren porphyrite, and these felsic rocks were likely formed through crystal fractionation because 1) the felsic rocks have Sr-Nd isotopic components similar to the coeval mafic rocks (shoshonitic rocks) exposed in the western Yangtze (<xref ref-type="bibr" rid="B50">Liu et al., 2017</xref>); 2) the mafic rocks have been interpreted to be products of the partial melting of an enriched lithospheric mantle (<xref ref-type="bibr" rid="B27">Guo et al., 2005</xref>); and 3) the occurrence of mantle xenoliths (pyroxenite) within the Jianchuan and Xiaoqiaotou intrusions indicates that the source of the rocks should be in the lower thickened crust (approximately 55&#xa0;km) and that they were derived from an enriched lithospheric mantle source (<xref ref-type="bibr" rid="B94">Zhao et al., 2004</xref>). In summary, the coeval shoshonitic and potassic rocks appear to be associated with partial melting of the residual metasomatized lithospheric mantle as well as with the thickened lower crust in the Eocene, which means that continental growth occurred in the post-collisional stage.</p>
<p>In contrast, the &#x3b5;<sub>Nd</sub>(t) values of granites in the BT, which have ages between 53 and 65&#xa0;Ma, are very positive (&#x2212;13.9&#x223c;&#x2212;9.3) (<xref ref-type="bibr" rid="B10">Chen et al., 2007</xref>; <xref ref-type="bibr" rid="B12">Chen et al., 2015</xref>), while the Nd model ages of the rocks are old (&#x3e;1.53&#xa0;Ga). The source region of these granites, which is different from that cited above, might be the continental crust; in other words, they mainly originated from intracrustal reworking during tectonic events, since almost all isotopic characteristics, such as the old Nd model ages (<xref ref-type="fig" rid="F8">Figure 8</xref>), low &#x3b5;Hf(t) values (&#x2212;24 &#x223c; &#x2212;4) (<xref ref-type="bibr" rid="B10">Chen et al., 2007</xref>; <xref ref-type="bibr" rid="B12">Chen et al., 2015</xref>) and low &#x3b4;<sup>18</sup>O values (6.6&#x2013;8.3&#x2030;) (<xref ref-type="bibr" rid="B12">Chen et al., 2015</xref>), suggest this possibility.</p>
<p>In the southeasternmost part of the EQST, the highest &#x3b5;<sub>Nd</sub>(t) values correspond to the Ailaoshan Suture and the Yaxuanqiao Arc, and the samples used in this study can be divided into two groups by formation age: &#x223c;230&#xa0;Ma (<xref ref-type="bibr" rid="B48">Liu et al., 2014</xref>) and &#x223c;35&#xa0;Ma (<xref ref-type="bibr" rid="B83">Xin et al., 2020</xref>). The former does not contain coeval or earlier mafic-intermediate rocks, which indicates that these granites originated from a basic lower crust (<xref ref-type="bibr" rid="B48">Liu et al., 2014</xref>). The latter is similar to the former and lacks the coeval basic components and geochemical characteristics of the thickened lower crust (<xref ref-type="bibr" rid="B83">Xin et al., 2020</xref>). The Ailaoshan high-grade metamorphic belt is a complex derived from various petrographic compositions and formation ages. It includes granodiorite dikes (761&#x2013;829&#xa0;Ma) (<xref ref-type="bibr" rid="B64">Qi et al., 2012</xref>) and mylonitic porphyritic monzogranite (30.95&#xa0;Ma) (<xref ref-type="bibr" rid="B6">Cao et al., 2012</xref>). This belt was intensively deformed by the left-lateral shearing of the Ailaoshan-Red River between 30 and 17&#xa0;Ma (<xref ref-type="bibr" rid="B68">Tang et al., 2013</xref>). However, high &#x3b5;<sub>Nd</sub>(t) values and young Nd model ages do exist in the area, which suggests that some of the materials are from the mantle.</p>
<p>In summary, the juvenile component is relatively dispersed in the SOB and is mainly derived from the post-collisional stage.</p>
</sec>
<sec id="s5-1-2">
<title>5.1.2 Old Nd model ages in the SOB</title>
<p>The Nd model ages (T<sub>DM</sub>) of the sample rocks increase from the east (&#x3c;1.24&#xa0;Ga) to the west in the northern part (&#x3e;1.24&#xa0;Ga) of the SOB (<xref ref-type="fig" rid="F6">Figure 6</xref>). Although the overall Nd model ages are older than those of the Chinese Altai (<xref ref-type="bibr" rid="B75">Wang et al., 2009</xref>), the difference is not great in the north because of the lack of crust-derived magmatic activity in the EQST, which is not discussed below. This pattern also suggests that juvenile material was increasingly added in the eastward direction, which might be evidence of an episodic eastward extrusion of the Tibetan Plateau (<xref ref-type="bibr" rid="B59">Mo et al., 2007</xref>). It is worth mentioning that T<sub>DM</sub> increases with crystallization age in the pre-collisional stage, while it shows fluctuations in the post-collisional stage (<xref ref-type="fig" rid="F6">Figure 6</xref>).</p>
<p>The old Nd model ages boundary corresponds with the results of the contour map of the zircon Hf crustal model ages, which suggests that the Changning-Menglian sutures mark an important boundary that divides the region into an old, reworked crustal block and a juvenile crustal block (<xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>). The Changning-Menglian Suture is seen as the boundary between Gondwana to the east and Cathaysia to the west (<xref ref-type="bibr" rid="B44">Kapp et al., 2003</xref>; <xref ref-type="bibr" rid="B71">Wang et al., 2016</xref>). The distribution of Nd model ages in this study provides additional evidence to support this interpretation.</p>
<p>The ages of the peraluminous samples with old Nd model ages are concentrated in the Ordovician (502&#x2013;470&#xa0;Ma) within the BT (<xref ref-type="fig" rid="F8">Figure 8</xref>) (<xref ref-type="bibr" rid="B10">Chen et al., 2007</xref>; <xref ref-type="bibr" rid="B49">Liu et al., 2009</xref>; <xref ref-type="bibr" rid="B79">Wang et al., 2013</xref>), which corresponds with Cambrian-Ordovician magmatic activity along the northern margin of East Gondwana and represents magmatism during the post-Pan-African movement (<xref ref-type="bibr" rid="B90">Yin, 2006</xref>; <xref ref-type="bibr" rid="B77">Wang et al., 2012</xref>; <xref ref-type="bibr" rid="B97">Zhu et al., 2012</xref>; <xref ref-type="bibr" rid="B78">Wang et al., 2015</xref>). The source of the rocks with old model ages is the upper crust with contributions from metasedimentary material (<xref ref-type="bibr" rid="B10">Chen et al., 2007</xref>; <xref ref-type="bibr" rid="B49">Liu et al., 2009</xref>; <xref ref-type="bibr" rid="B79">Wang et al., 2013</xref>).</p>
</sec>
</sec>
<sec id="s5-2">
<title>5.2 Nd isotopic mapping and relationships with mineralization</title>
<p>Mo et al. (1993) stressed that the Zhongzan block, sandwiched between the Ganzi-Litang Suture and Jinshajiang Suture, was a breakaway part of the SCC. The old Nd model ages of granites occurred in the ZYC, which is connected to the upper middle part of the EQST through the Jinshajiang Suture (<xref ref-type="fig" rid="F7">Figure 7</xref>); these granites are mostly near the Yidun Arc, with intrusion ages of 103.7&#xa0;Ma to 75.2&#xa0;Ma from the north to the south (<xref ref-type="bibr" rid="B65">Qu et al., 2002</xref>), and older granites, such as the Daocheng granite, have an age of 216&#xa0;Ma (<xref ref-type="bibr" rid="B30">He et al., 2013</xref>). The samples from the EQST also have an age of ca. 245&#xa0;Ma (<xref ref-type="bibr" rid="B72">Wang et al., 2014</xref>). The old Nd model age and low &#x3b5;<sub>Nd</sub>(t) values may suggest that these felsic rocks originated from the same ancient crust of the SCC basement.</p>
<p>Many metal deposits occur in the SOB to form several metallogenic belts. <xref ref-type="fig" rid="F6">Figures 6</xref>&#x2013;<xref ref-type="fig" rid="F8">8</xref> show a strong empirical correlation between the different lithospheric architectures and the locations of distinct ore deposits. All porphyry Cu deposits are confined to juvenile crustal blocks, whereas skarn and hydrothermal vein-type W&#x2013;Sn deposits are located in the low-&#x3b5;<sub>Nd</sub>(t) area, while skarn and hydrothermal vein-type Pb&#x2012;Zn&#x2013;Cu&#x2013;Ag deposits occur between the two types of deposits (<xref ref-type="fig" rid="F6">Figure 6</xref>).</p>
<p>The Cenozoic porphyry-skarn Cu&#x2013;Mo&#x2013;(Au) deposits (<xref ref-type="bibr" rid="B74">Wang et al., 2005</xref>; <xref ref-type="bibr" rid="B37">Hou et al., 2006</xref>; <xref ref-type="bibr" rid="B54">Lu et al., 2013</xref>) occur in the juvenile crust within the EQST or along the suture with high &#x3b5;<sub>Nd</sub>(t) (&#x2212;3.3&#x2013;0) and young T<sub>DM</sub> ages (0.58&#x2013;1.17&#xa0;Ga). Representative porphyry Cu&#x2013;Mo&#x2013;(Au) deposits in the SOB are the Machangqing deposit [39&#xa0;Mt ore, with 0.64% Cu and 56&#xa0;Mt with 0.08% Mo (<xref ref-type="bibr" rid="B53">Lu et al., 2013</xref>)], the Beiya Au deposit [26&#xa0;Mt ore, with 2.26&#xa0;g/t Au, (<xref ref-type="bibr" rid="B53">Lu et al., 2013</xref>)], and many smaller deposits, such as the Changan, Tongchang, and Yao&#x2019;an deposits. These deposits are generally associated with potassic-enriched intrusions that were formed in the post-collisional stage (<xref ref-type="bibr" rid="B54">Lu et al., 2013</xref>; <xref ref-type="bibr" rid="B53">Lu et al., 2013</xref>; <xref ref-type="bibr" rid="B52">Lu et al., 2015</xref>). However, no significant porphyry Cu deposits were found in regions with low &#x3b5;<sub>Nd</sub>(t) values and old T<sub>DM</sub> ages. This distribution pattern also occurs in Lhasa Terrane, as revealed by Hf isotopic mapping (Hou et al<italic>.</italic>, 2015). This comparison indicates that the juvenile lower crust might have exerted first-order control on the formation of the porphyry Cu deposits. In the SOB, the juvenile component is mainly derived from the post-collisional stage and characterized by high-K calc-alkaline signatures with high Sr/Y values and &#x3b5;<sub>Nd</sub>(t) values (e.g., <xref ref-type="bibr" rid="B53">Lu et al., 2013</xref>). Arc magma interacted with the crust in an open environment; then, the fO<sub>2</sub> of magma decreased, which led to the accumulation of sulfides in the juvenile lower crust. At the post-collision stage, an upwelling of the asthenosphere triggered the melting of metal sulfide-rich crust, which resulted in the release of Cu into the magmatic system as the material source of Cu deposits (<xref ref-type="bibr" rid="B33">Hou et al., 2015</xref>). Furthermore, as representatives of the cumulates or residuals of Neoproterozoic arc magmas, the amphibolite xenoliths hosted by the Cenozoic stocks are enriched in Cu and Au (<xref ref-type="bibr" rid="B40">Hou et al., 2017</xref>), which reinforces the conclusion that the Cu&#x2013;Au-enriched low-crustal cumulates might be the metal source of the deposits, so the Cu&#x2013;Mo&#x2013;(Au) deposits typically occur at the cratonic edges or sutures.</p>
<p>The W&#x2013;Sn deposits are mainly located in the BT areas, with negative &#x3b5;<sub>Nd</sub>(t) (&#x2212;13&#x223c;&#x2212;6) and &#x3b5;<sub>Hf</sub>(t) values, and form the Tengchong-Lianghe Sn metallogenic zone. Previous studies have shown that the occurrence of these deposits tends to occur in the Late Cretaceous to early Eocene (<xref ref-type="bibr" rid="B42">Jiang et al., 2012</xref>; <xref ref-type="bibr" rid="B11">Chen et al., 2014</xref>; <xref ref-type="bibr" rid="B5">Cao et al., 2017</xref>; <xref ref-type="bibr" rid="B67">Sun et al., 2017</xref>), which is in concordance with the collisional timeline. A representative deposit, the Lailishan deposit, with an Ar-Ar age of hydrothermal muscovite of 50.4&#xa0;Ma (<xref ref-type="bibr" rid="B5">Cao et al., 2017</xref>), is a large tin deposit located in the midwestern region of Tengchong. The tin orebodies occur in the lower contact zones and the surrounding fractured zones of the granitic intrusion, with a weighted mean U&#x2013;Pb age of 50.6&#xa0;Ma (<xref ref-type="bibr" rid="B36">Hou et al., 2007</xref>; <xref ref-type="bibr" rid="B5">Cao et al., 2017</xref>). The Lailishan granite is characterized by high K, F, and S contents and a high initial <sup>87</sup>Sr/<sup>87</sup>Sr ratio (<xref ref-type="bibr" rid="B51">Lu and Wang, 1993</xref>), and it is rich in Al (Al<sub>2</sub>O<sub>3</sub>&#x3d; 14.70%&#x2013;15.27%), alkalis, Ca, REEs, and Ba (<xref ref-type="bibr" rid="B67">Sun et al., 2017</xref>), which suggests that the granites are S-type and related to the crustal anatexis. The &#x3b5;<sub>Nd</sub>(t) values are most negative when the T<sub>DM</sub> ages are the oldest. Both the geochemical characteristics and the results of Nd isotopic mapping suggest that the related igneous rocks are likely derived from the partial melting of predominantly ancient crustal material, which is consistent with the conclusion that S-type magmas are geographically related to W&#x2013;Sn mineralization (<xref ref-type="bibr" rid="B72">Wang et al., 2014</xref>). Correspondingly, the enrichment and mineralization of W&#x2013;Sn are not only related to the high differentiation of granitic magma but also restricted by the composition of the source area. The origin of W&#x2013;Sn deposits is the partial melting of the sedimentary rocks, which enriched the metal composition in the muscovite and biotite (<xref ref-type="bibr" rid="B66">Romer and Kroner, 2015</xref>). The age of the intrusion is within the syn-collision stage, which means the continental collision and subsequent crustal thickening in the BT resulted in the formation of S-type granites (<xref ref-type="bibr" rid="B98">Zhu et al., 2018</xref>) and related W-Sn deposits in the region (<xref ref-type="bibr" rid="B67">Sun et al., 2017</xref>).</p>
<p>Skarn and hydrothermal vein-type Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposits, such as the enormous Jinding Pb&#x2012;Zn deposit (200&#xa0;Mt ore with 6.1% Zn and 1.3% Pb) (<xref ref-type="bibr" rid="B86">Xue et al., 2003</xref>; <xref ref-type="bibr" rid="B47">Leach et al., 2017</xref>) and the Baiyangping Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposit (<xref ref-type="bibr" rid="B87">Xue et al., 2000</xref>; <xref ref-type="bibr" rid="B101">Zou et al., 2015</xref>), occur within the EQST with relatively low &#x3b5;<sub>Nd</sub>(t) and old T<sub>DM</sub> ages. The <sup>40</sup>Ar&#x2013;<sup>39</sup>Ar plateau age of silicification quartz in the Baiyangping deposit is 62.7&#xa0;Ma (<xref ref-type="bibr" rid="B86">Xue et al., 2003</xref>), and different age dating methods and samples provide varied ages for the Jinding deposit between 129 and 21&#xa0;Ma (e.g., <xref ref-type="bibr" rid="B88">Yalikun et al., 2018</xref>; <xref ref-type="bibr" rid="B73">Wang et al., 2022</xref>). However, almost all the Pb&#x2012;Zn&#x2013;Cu&#x2013;Ag deposits that occur in the area have the Nd isotopic characteristics of old crust, which indicates that the metal source was likely to be crustal materials. Similarly, geochemical and other isotopic characteristics, such as Pb isotope results (<xref ref-type="bibr" rid="B28">Hao et al., 2017</xref>), also support this conclusion. It is worth noting that the formation of the Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposits is controlled by trust-nappe structures (<xref ref-type="bibr" rid="B35">Hou et al., 2008</xref>).</p>
<p>In summary, the continent-continent collision of India and Asia resulted in the formation of distinct metal deposits based on the different locations and sources of partial melting. The juvenile crust was the base of porphyry-skarn Cu&#x2013;Mo&#x2013;(Au) deposits, and the melting of old crust or upper crust contributed to the occurrence of W&#x2013;Sn deposits and skarn and hydrothermal vein-type Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposits controlled by trust-nappe structures (<xref ref-type="fig" rid="F10">Figure 10</xref>).</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Schematic illustration of different deposits, modified after <xref ref-type="bibr" rid="B38">Hou and Zhang. (2015)</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1131338-g010.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="conclusion" id="s6">
<title>6 Conclusion</title>
<p>Nd isotopic mapping of the Sanjiang Orogenic Belt reveals that the &#x3b5;<sub>Nd</sub>(t) values in this area are relatively low, but three domains with relatively high &#x3b5;<sub>Nd</sub>(t) values and young Nd model ages occur within the Eastern Qiangtang-Simao Terrane, and the juvenile component in the SOB is mainly derived from the post-collisional stage, which could indicate continental growth. Porphyry-skarn Au&#x2013;Cu&#x2013;(Mo) and orogenic deposits are clustered in the relatively juvenile crust. W&#x2013;Sn and Pb&#x2012;Zn&#x2012;Cu&#x2012;Ag deposits are related to the old crust or upper crust.</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s7">
<title>Data availability statement</title>
<p>The original contribution presented in the study are included in the article/<xref ref-type="sec" rid="s12">Supplementary Material</xref>, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s8">
<title>Author contributions</title>
<p>LY and PC, writing and dealing with data; ZH and YZ provided opinions on paper writing; HQ participated in part of map making.</p>
</sec>
<sec id="s9">
<title>Funding</title>
<p>This work was supported by the National Key Research and Development Program of China (2019YFA0708602, 2022YFF0800903); National Natural Science Foundation of China (41973045, 41602084); Basic Science and Technology Research Fundings of the Institute of Geology, CAGS (J1905); Geological Survey Projects of the China Geological Survey (DD20221647); and the Opening Foundation of the Key Laboratory of Mineral Resources Evaluation in Northeast Asia, Ministry of Land and Resources (DBY-KF-18-02).</p>
</sec>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
<p>The reviewer CW declared a shared affiliation with the author YZ to the handling editor at time of review.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec id="s12">
<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2023.1131338/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2023.1131338/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="Table1.XLSX" id="SM1" mimetype="application/XLSX" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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