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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">1095135</article-id>
<article-id pub-id-type="doi">10.3389/feart.2023.1095135</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>The complex construction of a glaciovolcanic ridge with insights from the 2021 Fagradalsfjall Eruption (Iceland)</article-title>
<alt-title alt-title-type="left-running-head">Pollock et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/feart.2023.1095135">10.3389/feart.2023.1095135</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Pollock</surname>
<given-names>Meagen</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1736908/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Edwards</surname>
<given-names>Benjamin R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1671129/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Judge</surname>
<given-names>Shelley</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2097357/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Wallace</surname>
<given-names>Chloe</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Hiatt</surname>
<given-names>Alex</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Perpalaj</surname>
<given-names>Aleksander</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2093959/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Was</surname>
<given-names>Ellie</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2176896/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Hauksd&#xf3;ttir</surname>
<given-names>Steinunn</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>Department of Earth Sciences</institution>, <institution>The College of Wooster</institution>, <addr-line>Wooster</addr-line>, <addr-line>OH</addr-line>, <country>United States</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Department of Earth Sciences</institution>, <institution>Dickinson College</institution>, <addr-line>Dickinson</addr-line>, <addr-line>PA</addr-line>, <country>United States</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>&#xcd;SOR</institution>, <institution>Iceland GeoSurvey</institution>, <addr-line>Reykjavik</addr-line>, <country>Iceland</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/470096/overview">Alison Hollomon Graettinger</ext-link>, University of Missouri&#x2013;Kansas City, United States</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/114854/overview">James D. L. White</ext-link>, University of Otago, New Zealand</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1276168/overview">Chris Conway</ext-link>, National Institute of Advanced Industrial Science and Technology (AIST), Japan</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Meagen Pollock, <email>mpollock@wooster.edu</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Volcanology, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>07</day>
<month>03</month>
<year>2023</year>
</pub-date>
<pub-date pub-type="collection">
<year>2023</year>
</pub-date>
<volume>11</volume>
<elocation-id>1095135</elocation-id>
<history>
<date date-type="received">
<day>10</day>
<month>11</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>15</day>
<month>02</month>
<year>2023</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2023 Pollock, Edwards, Judge, Wallace, Hiatt, Perpalaj, Was and Hauksd&#xf3;ttir.</copyright-statement>
<copyright-year>2023</copyright-year>
<copyright-holder>Pollock, Edwards, Judge, Wallace, Hiatt, Perpalaj, Was and Hauksd&#xf3;ttir</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>Glaciovolcanic landforms provide global-scale records of paleoenvironmental conditions and yield insights into subglacial eruption processes. Models for the formation of glaciovolcanic ridges, or tindars, are relatively simple, proposing a monogenetic eruption and a fairly uniform stratigraphy with or without a single transition from effusive pillow lavas to explosive fragmental deposits. Others have suggested that tindars are more complicated. To build a more robust model for tindar formation, we conducted a field and geochemical study of Undirhl&#xed;&#xf0;ar ridge on the Reykjanes Peninsula in southwestern Iceland. We show that the ridge was built through a complex sequence of eruptive and intrusive events under dynamically changing ice conditions. Quarry walls expose a continuous cross-section of the ridge, revealing multiple pillow and fragmental units. Pillow lava orientations record the emplacement of discrete pillow-dominated lobes and the migration of volcanic activity between eruptive vents. Volatile contents in glassy pillow rinds show repeated pulses of pillow lava emplacement under glaciostatic conditions, with periods of fragmentation caused by depressurization. Variations in major elements, incompatible trace element ratios, and Pb-isotopes demonstrate that the eruption was fed from separate crustal melt reservoirs containing melts from a compositionally heterogeneous mantle source. A shift in mantle source signature of pillow lavas suggests that the primary ridge-building phase was triggered by the injection of magma into the crust. Within the growing edifice, magma was transported through dykes and irregularly shaped intrusions, which are up to 20% by area of exposed stratigraphy sequences. The model for tindar construction should consider the significant role of intrusions in the growth of the ridge, a detail that would be difficult to identify in natural erosional exposures. The 2021&#x2013;22 eruptions from the adjacent Fagradalsfjall vents allow us to draw parallels between fissure-fed eruptions in subaerial and ice-confined environments and test hypotheses about the composition of the mantle underlying the Reykjanes Peninsula. Both Fagradalsfjall and Undirhl&#xed;&#xf0;ar ridge eruptions may have occurred over similar spatial and temporal scales, been triggered by mixing events, erupted lavas with varying mantle source signatures, and focused volcanic activity along migrating vents. Differences in composition between the two locations are not related to systematic lateral variations in the underlying mantle. Rather, the Undirhl&#xed;&#xf0;ar ridge and Fagradalsfjall eruptions capture complex interactions among the crustal magma plumbing system, mantle source heterogeneity, and melting conditions for a moment in time.</p>
</abstract>
<kwd-group>
<kwd>glaciovolcanism</kwd>
<kwd>Iceland</kwd>
<kwd>Fagradalsfjall</kwd>
<kwd>geochemistry</kwd>
<kwd>volcano-ice interaction</kwd>
</kwd-group>
<contract-sponsor id="cn001">Division of Earth Sciences<named-content content-type="fundref-id">10.13039/100000160</named-content>
</contract-sponsor>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Glaciovolcanism creates global-scale records of paleoenvironmental conditions (<xref ref-type="bibr" rid="B97">Smellie and Edwards, 2016</xref>; <xref ref-type="bibr" rid="B96">Smellie, 2018</xref>) and magmatic-climatic system interactions. Dramatic glaciovolcanic eruptions in Iceland (Gj&#xe1;lp in 1996 and Eyjafjallaj&#xf6;kull in 2010) have driven research on glaciovolcanism over the past 2&#xa0;decades (<xref ref-type="bibr" rid="B97">Smellie and Edwards, 2016</xref>), yielding first-hand observations of the effects of the cryosphere on volcanic products (<xref ref-type="bibr" rid="B111">Edwards et al., 2022</xref>). Those products are used in paleoclimate studies to constrain the extent and thickness of past glaciers and ice sheets on Earth (e.g., <xref ref-type="bibr" rid="B61">Lescinsky and Fink, 2000</xref>; <xref ref-type="bibr" rid="B94">Smellie, 2008</xref>; <xref ref-type="bibr" rid="B106">Tuffen et al., 2010</xref>; <xref ref-type="bibr" rid="B17">Edwards et al., 2011</xref>) and on Mars (cf. <xref ref-type="bibr" rid="B97">Smellie and Edwards, 2016</xref>), and they provide critical insights into subglacial eruption dynamics, with implications for understanding flash flooding caused by rapid ice-melt (j&#xf6;kulhlaups) and other hazards related to volcano-ice interaction (<xref ref-type="bibr" rid="B32">Gudmundsson et al., 2008</xref>; <xref ref-type="bibr" rid="B79">Oddsson et al., 2016</xref>).</p>
<p>While globally significant, the details of glaciovolcanic eruptive processes are obscured by limited accessibility during active eruptions (<xref ref-type="bibr" rid="B33">Gudmundsson et al., 1997</xref>; <xref ref-type="bibr" rid="B35">Gudmundsson et al., 2004</xref>; <xref ref-type="bibr" rid="B36">Gudmundsson et al., 2012</xref>; <xref ref-type="bibr" rid="B34">Gudmundsson, 2005</xref>; <xref ref-type="bibr" rid="B16">Edwards et al., 2012</xref>; <xref ref-type="bibr" rid="B79">Oddsson et al., 2016</xref>). Much of our understanding derives from the parts of the eruption that break through the ice or from glaciovolcanic landforms that have been exposed by Holocene ice retreat, especially in Antarctica, Canada, and Iceland (e.g., <xref ref-type="bibr" rid="B51">Jones, 1969</xref>; <xref ref-type="bibr" rid="B52">Jones, 1970</xref>; <xref ref-type="bibr" rid="B44">H&#xf6;skuldsson et al., 2006</xref>; <xref ref-type="bibr" rid="B98">Smellie et al., 2008</xref>; <xref ref-type="bibr" rid="B18">Edwards et al., 2009</xref>; <xref ref-type="bibr" rid="B112">Edwards et al., 2020</xref>). Even these insights are limited by the variability of erosion processes, which frequently provide limited views into edifice interiors and effectively restrict access to stratigraphic information.</p>
<p>Tindars are elongate glaciovolcanic ridges not capped by flat-lying lava flows (<xref ref-type="bibr" rid="B51">Jones, 1969</xref>; <xref ref-type="bibr" rid="B93">Smellie, 2007</xref>; <xref ref-type="bibr" rid="B95">Smellie, 2013</xref>; <xref ref-type="bibr" rid="B46">Jakobsson and Gudmundsson, 2008</xref>). Analogous to linear tuyas of <xref ref-type="bibr" rid="B84">Russell et al. (2014)</xref>, tindars have a length to width ratio greater than 2:1 and consist of some combination of pillow lavas and tephra, depending on magmatic and ice conditions (<xref ref-type="bibr" rid="B46">Jakobsson and Gudmundsson, 2008</xref>; <xref ref-type="bibr" rid="B84">Russell et al., 2014</xref>). Most tindar formation models propose a monogenetic eruption under ice, with an initial pillow-building phase followed by a transition to explosive volcanic activity as water depth decreases (e.g., <xref ref-type="bibr" rid="B47">Jakobsson and Johnson, 2012</xref>). However, the complexity of pillow-dominated tindars has been demonstrated by detailed investigations of edifices that have been deeply dissected by erosion or other processes, such as mining (<xref ref-type="bibr" rid="B51">Jones, 1969</xref>; <xref ref-type="bibr" rid="B52">Jones, 1970</xref>; <xref ref-type="bibr" rid="B44">H&#xf6;skuldsson et al., 2006</xref>; <xref ref-type="bibr" rid="B18">Edwards et al., 2009</xref>; <xref ref-type="bibr" rid="B45">Hungerford et al., 2014</xref>; <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). Lithofacies variations have been attributed to changes in lava effusion rate, shifts in the magma source region, and fluctuating lake levels caused by ice melt and the development of drainage systems (<xref ref-type="bibr" rid="B75">Moore et al., 1995</xref>; <xref ref-type="bibr" rid="B44">H&#xf6;skuldsson et al., 2006</xref>; <xref ref-type="bibr" rid="B18">Edwards et al., 2009</xref>; <xref ref-type="bibr" rid="B45">Hungerford et al., 2014</xref>; <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>; <xref ref-type="bibr" rid="B79">Oddsson et al., 2016</xref>). Some complex pillow-dominated tindars show sustained hydrostatic conditions and short-lived (e.g., weeks to months) eruptive activity (<xref ref-type="bibr" rid="B45">Hungerford et al., 2014</xref>; <xref ref-type="bibr" rid="B107">Wilson and Russell, 2017</xref>), yet others are constructed by repeated eruptive events over longer time scales (e.g., years to decades) (<xref ref-type="bibr" rid="B18">Edwards et al., 2009</xref>; <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). Edifice architecture can be further complicated by the migration of the eruptive vent during ridge formation and the emplacement of subglacial lava flows in ice tunnels (<xref ref-type="bibr" rid="B45">Hungerford et al., 2014</xref>; <xref ref-type="bibr" rid="B79">Oddsson et al., 2016</xref>).</p>
<p>To better understand the construction of pillow-dominated tindars, we conducted a comprehensive lithostratigraphic and geochemical study of Undirhl&#xed;&#xf0;ar ridge in southwestern Iceland. Quarries along the ridge provide exceptional views of the internal tindar architecture. Recent effusive activity at Fagradalsfjall, which is located adjacent to Undirhl&#xed;&#xf0;ar ridge, has provided a modern subaerial analogue for fissure eruptions in the region. Our results include maps of lateral and vertical stratigraphic variations, measurements of individual pillow lava orientations, geochemical (major, trace, volatiles, limited isotopes) characterization of all mappable lithologies, and models of magma evolution and paleo-ice conditions. We describe the formation of Undirhl&#xed;&#xf0;ar from magma source to volcanic edifice, exploring the complex relationships among paleo-ice conditions, the underlying magmatic system, and eruptive dynamics. Our findings reveal the emplacement mechanisms for a growing pillow lava pile and the effects of magmatic processes on the composition of the resulting edifice. We compare our model to the 2021&#x2013;22 activity at nearby Fagradalsfjall, drawing new contrasts and parallels between fissure-fed eruptions in subaerial and ice-confined environments. Our work presents one of the most comprehensive geochemical and physical investigations of a single pillow-dominated tindar to date.</p>
</sec>
<sec id="s2">
<title>2 Geologic setting</title>
<p>The Reykjanes Peninsula in southwestern Iceland links the submarine Reykjanes Ridge to Iceland&#x2019;s Western Volcanic Zone through five en echelon NE-SW trending volcanic systems (<xref ref-type="fig" rid="F1">Figure 1</xref>; <xref ref-type="bibr" rid="B48">Jakobsson et al., 1978</xref>; <xref ref-type="bibr" rid="B85">Saemundsson, 1979</xref>; <xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>). The volcanic systems are delineated by geophysical patterns and structural features that show elongated swarms of dykes, fissures, faults, and craters that extend from central zones of magma upwelling and storage (<xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>). Holocene volcanic activity has generally migrated from east to west across the volcanic systems, occurring periodically every &#x223c;800&#x2013;1,000&#xa0;years (<xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>). Eruptions along the volcanic systems during the last glacial maximum (26.5&#x2013;19&#xa0;ka Late Weichselian glaciation; <xref ref-type="bibr" rid="B80">Patton et al., 2017</xref>) produced NE-trending glaciovolcanic tindar ridges that stand out in relief among younger, post-glacial lava flows (&#x3c;15&#xa0;ka) emplaced in ice-free environments (<xref ref-type="fig" rid="F1">Figure 1</xref>). Our study area is at the northern end of the Kr&#xfd;suv&#xed;k system.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Location of field area. <bold>(A)</bold> Satellite image (ESRI Satellite plugin for QGIS) showing relevant parts of the Reykjanes Peninsula, including the 5 main fissures zones (<xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>), the Fagradals eruption site, and the two quarries that bound the field area. <bold>(B)</bold> Same map elements as <bold>(A)</bold> but using geological mapping from &#xcd;SOR to highlight glaciovolcanic (brown shades) versus subaerial units.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g001.tif"/>
</fig>
<p>After &#x223c;800&#xa0;years of volcanic inactivity on the Reykjanes Peninsula (<xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>), eruptions recently occurred at Fagradalsfjall, which is immediately west of and adjacent to Kr&#xfd;suv&#xed;k. In February 2021, elevated seismicity and ground surface deformation suggested the migration of magma and magmatic fluids in the subsurface (<xref ref-type="bibr" rid="B9">Cubuk-Sabuncu et al., 2021</xref>; <xref ref-type="bibr" rid="B26">Geirsson et al., 2021</xref>; <xref ref-type="bibr" rid="B24">Fl&#xf3;venz et al., 2022</xref>; <xref ref-type="bibr" rid="B91">Sigmundsson et al., 2022</xref>). Intense earthquake swarms and changes in ground deformation patterns indicated the intrusion of a NE-SW-trending vertical segmented dyke with sustained magma inflow (<xref ref-type="bibr" rid="B91">Sigmundsson et al., 2022</xref>). On 19 March 2021, a fissure eruption began as an effusive outpouring of basaltic lava from closely-spaced vents (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). After about a month of activity, five additional vents opened along a 1&#xa0;km-long segment extending to the northeast (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). During this first eruptive phase, effusion rates were low to moderate (<xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>) and periodic fire fountaining from multiple vents built spatter cones and fed lava flows (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). After about 3&#xa0;months of activity, the eruption focused to one vent and effusion rates increased with more intense fire fountaining (<xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>; <xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). The expansion of the lava field was constrained by the topography of the surrounding ridges. Lava flows filled valleys by inflation and successive emplacement of later flows, then spilled into adjacent valleys (<xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). The eruption entered its final phase in September, forming a lava pond that partially drained before the eruption ceased on 18 September 2021 (<xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). On 3 August 2022, a second short-lived eruption began in Meradalir about 1&#xa0;km northeast of the 2021 main eruptive vent (<xref ref-type="bibr" rid="B29">Global Volcanism Program, 2022a</xref>). This eruption was preceded by a pattern of increased seismicity and ground deformation similar to the previous eruption (<xref ref-type="bibr" rid="B31">Global Volcanism Program, 2022c</xref>). Lasting about 2&#xa0;weeks, this eruption began as weak lava fountaining along a fissure, followed by a decrease in lava effusion rate and the development of a central cone that contained a lava pond and fed lava flows to the surrounding Meradalir valley (<xref ref-type="bibr" rid="B30">Global Volcanism Program, 2022b</xref>).</p>
<p>Kr&#xfd;suv&#xed;k, the volcanic system of which Undirhl&#xed;&#xf0;ar ridge is the northernmost section, is distinct among the volcanic systems on the Reykjanes Peninsula (<xref ref-type="fig" rid="F1">Figure 1</xref>). It is the only volcanic system to host a buried caldera, identified by circular geophysical anomalies at depth and the remnant at Lake Kleifarvatn (<xref ref-type="bibr" rid="B20">Eysteinsson, 2001</xref>; <xref ref-type="bibr" rid="B43">Hersir et al., 2020</xref>; <xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>). The ancient central volcano may have been rooted by an intrusive complex, evidenced by layered gabbroic xenoliths in volcanic ejecta and the eruption of evolved tholeiitic basalts (<xref ref-type="bibr" rid="B53">J&#xf3;nsson, 1978</xref>; <xref ref-type="bibr" rid="B86">S&#xe6;mundsson et al., 2020</xref>). The Kr&#xfd;suv&#xed;k geothermal area, in the southern part of the system, covers &#x223c;60&#xa0;km<sup>2</sup> and is bound by two NE-SW trending tindar complexes, N&#xfa;phl&#xed;&#xf0;arh&#xe1;ls-Vesturh&#xe1;ls to the west and Sveifluh&#xe1;ls to the east (<xref ref-type="bibr" rid="B43">Hersir et al., 2020</xref>). Along strike with Sveifluh&#xe1;ls to the northeast is Undirhl&#xed;&#xf0;ar ridge, an early Weischelian (118&#x2013;80&#xa0;kyr; Lambeck et al., 2006; <xref ref-type="bibr" rid="B87">S&#xe6;mundsson et al., 2016</xref>) pillow-dominated tindar. Undirhl&#xed;&#xf0;ar ridge is &#x223c;7&#xa0;km long and has been excavated at its northern extent in Undirhl&#xed;&#xf0;ar and Vatnsskar&#xf0; quarries, which are separated by &#x223c;3&#xa0;km and have walls &#x223c;100&#xa0;m high, exposing both longitudinal and across-axis cross sections of the ridge.</p>
<p>In a previous paper (<xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>), we presented the lithostratigraphic and compositional variations exposed in Undirhl&#xed;&#xf0;ar quarry. We proposed a model for the construction of the northern part of Undirhl&#xed;&#xf0;ar ridge that comprises at least three eruptive phases ranging in style from explosive to effusive (<xref ref-type="fig" rid="F10">Figure 10</xref> in <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). The pillow lava units comprising the core of the ridge were formed in an initial effusive phase that erupted magma from an incompatible element-enriched mantle source. This was followed by intrusions of a less-enriched magma and a second effusive phase that began with an explosive event. Because the first and second eruptive phases were fed by magmas from slightly different mantle sources, we hypothesized that magma resided in discrete melt bodies that experienced separate evolutionary histories, consistent with evidence for a local intrusive complex and the sheeted sill model for volcanic systems (<xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B66">Maclennan et al., 2003</xref>; <xref ref-type="bibr" rid="B15">Eason and Sinton, 2009</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). Lithologically, the boundary between the first and second eruptive phases is marked with deposits of vitric tuff-breccia, interpreted as products of subaqueous fire-fountaining, suggesting that pillow-forming eruptions may have been initiated by mild explosive activity. A final effusive phase produced a capping layer of pillow lavas that are geochemically related to the pillow lavas from the preceding effusive phase. While intrusions were also documented in this study, their importance to the overall ridge formation was not as well understood.</p>
<p>The Undirhl&#xed;&#xf0;ar study modified the existing model for subglacial pillow-forming eruptions (<xref ref-type="bibr" rid="B51">Jones, 1969</xref>; <xref ref-type="bibr" rid="B52">Jones, 1970</xref>; <xref ref-type="bibr" rid="B75">Moore et al., 1995</xref>; <xref ref-type="bibr" rid="B44">H&#xf6;skuldsson et al., 2006</xref>) by documenting multiple episodes of pillow lava emplacement and transitions in eruptive style that coincided with shifts in the underlying magmatic system. Here, we examine whether the model applies to the rest of the ridge by extending our work to Vatnsskar&#xf0; quarry and the &#x223c;3&#xa0;km length of the ridge between the quarries. Along the ridge, water-carved gullies offer &#x223c;100&#xa0;m high exposures of fragmental volcanic material, intrusions, pillow lavas, and glacial diamict. Vatnsskar&#xf0; quarry is &#x223c;750&#xa0;m long and exposes &#x223c;80&#xa0;m high walls that show several distinct pillow lava units, volcaniclastic units, and intrusions. Where Undirhl&#xed;&#xf0;ar quarry revealed glaciovolcanic processes at the margins of a tindar ridge, Vatnsskar&#xf0; quarry provides insights into glaciovolcanic processes nearer to the center of magma upwelling and storage within a volcanic system. Since our original model at Undirhl&#xed;&#xf0;ar in 2014, the adjacent Fagradalsfjall volcanic system erupted in 2021&#x2013;22, allowing us to draw parallels and observe contrasts between fissure eruptions in subaerial and ice-confined environments.</p>
</sec>
<sec sec-type="materials|methods" id="s3">
<title>3 Materials and methods</title>
<sec id="s3-1">
<title>3.1 Field mapping and sample collection</title>
<p>Field mapping at the quarries and along the ridge that connects them has been ongoing since 2009. We sampled and made measurements at a variety of scales. We measured &#x3e;100 individual pillow lava sizes and orientations using meter tape measures and Brunton compasses with clinometers. Trend and plunge data of pillow basalts for each locality were plotted using Stereonet (v. 11.4.5 <xref ref-type="bibr" rid="B1">Allmendinger et al., 2013</xref>; <xref ref-type="bibr" rid="B5">Cardozo and Allmendinger, 2013</xref>). Data were contoured using the Kamb contouring method. The average trend and plunge direction for pillows at each locality was calculated based on the center of the contoured pi-maxima. Data from localities close to each other were compared; if averages were similar, then the data were merged into one plot that represented a larger area.</p>
<p>A variety of approaches have been used to map vertical faces in the quarries, including laser range-finding, Gigapan technology, Structure-from-Motion, and drones. Sample and data collection sites were located using standard handheld GPS units, which are generally considered to have non-corrected positional errors of &#xb1; 5&#xa0;m or less. For samples where accurate elevations are critical, we used the Arctic DEM subsampled to 1.8&#xa0;m resolution to subsequently correct sample elevations to a consistent elevation model.</p>
<p>We note here that quarries, while providing unparalleled exposures and access to fresh samples, can have inherent disadvantages. For example, our field observations are largely centered on pillow lava units, which now dominate the stratigraphy at both quarries. It is possible that the unconsolidated tuff-breccia units originally occupied a larger proportion of the quarries but have been preferentially removed due to ease of mining.</p>
</sec>
<sec id="s3-2">
<title>3.2 Major and trace element analyses</title>
<p>Major and trace elements were measured on a total of 89 whole-rock samples, including 6 bombs from fragmental units, 57 pillow lavas, and 26 intrusions (<xref ref-type="table" rid="T1">Table 1</xref>; <xref ref-type="sec" rid="s12">Supplementary Table SA1</xref>). Whole-rock powders from fresh samples were prepared in alumina grinding containers and sieved through 325&#xa0;mesh. Loss on ignition (LOI) was determined by heating the powders for 1&#xa0;h at 950&#xb0;C following <xref ref-type="bibr" rid="B4">Boyd and Mertzman (1987)</xref>. Most samples were analyzed for major elements by X-ray fluorescence spectroscopy (XRF; 86 samples) at the College of Wooster following the methods of <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>. The XRF was drift corrected prior to each run and repeat analyses of standards shows reproducibility &#x3c;2%. Most trace elements were measured by inductively coupled plasma mass spectrometry (ICP-MS; 71 samples) at the Peter Hooper Lab, Washington State University, United States following standard methods (<xref ref-type="bibr" rid="B63">Lichte et al., 1987</xref>; <xref ref-type="bibr" rid="B49">Jarvis, 1988</xref>; <xref ref-type="bibr" rid="B13">Doherty, 1989</xref>; <xref ref-type="bibr" rid="B50">Jenner et al., 1990</xref>; <xref ref-type="bibr" rid="B64">Longerich et al., 1990</xref>). Analytical runs consisted of unknowns, standards, and drift correction solutions. Reproducibility is &#x3c;5% for rare Earth elements and &#x3c;10% for all other elements. Full analytical precision and accuracy details for XRF and ICP-MS analyses are provided in the <xref ref-type="sec" rid="s12">Supplementary Tables SA2&#x2013;SA4</xref>). A few samples (3) were analyzed at Duke University by directly coupled plasma atomic emission spectroscopy (DCP-AES) and ICP-MS following the methods of <xref ref-type="bibr" rid="B56">Klein et al. (1991)</xref>; <xref ref-type="bibr" rid="B7">Cheatham et al. (1993)</xref>, respectively. DCP-AES analyses show reproducibility of 1%&#x2013;2% for all major elements with the exception of K<sub>2</sub>O (&#x223c;10%) and P<sub>2</sub>O<sub>5</sub> (&#x3c; 8%). ICP-MS analyses at Duke show reproducibility of 1%&#x2013;5% for trace elements. Full quality assurance data for the Duke analyses are provided in the <xref ref-type="sec" rid="s12">Supplementary Material</xref> to <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>. Interlab comparison of duplicate samples analyzed by ICP-MS at Duke and Washington State Universities shows good agreement between methods (<xref ref-type="sec" rid="s12">Supplementary Table SA5</xref>).</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Geochemistry of selected Undirhl&#xed;&#xf0;ar ridge samples. Major elements (in wt. %) and select trace elements (bold) measured by XRF. All other trace elements measured by ICP-MS. Details of analytical methods are described in the text. All samples are whole-rock pillow lavas except 16MP03 (dyke). Location describes sample sites in Undirhl&#xed;&#xf0;ar quarry (UND), Vatnsskar&#xf0; quarry (VAT), or along the ridge between the quarries. Compositional group defined by La<sub>N</sub>/Sm<sub>N</sub> value as described in the text. The full geochemical dataset and quality data are available in the (<xref ref-type="sec" rid="s12">Supplementary Material</xref>).</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Sample ID</th>
<th align="center">16CW08</th>
<th align="center">16MP02</th>
<th align="center">VAT-NA-13-09</th>
<th align="center">VAT-SA-13-19</th>
<th align="center">VAT-SA-13-07</th>
<th align="center">16RH02</th>
<th align="center">16MP03</th>
</tr>
<tr>
<th align="left">Location</th>
<th align="center">Ridge</th>
<th align="center">UND</th>
<th align="center">VAT</th>
<th align="center">VAT</th>
<th align="center">VAT</th>
<th align="center">Ridge</th>
<th align="center">Ridge</th>
</tr>
<tr>
<th align="left">Compositional group</th>
<th align="center">More-enriched</th>
<th align="center">Less-enriched</th>
<th align="center">Less-enriched</th>
<th align="center">Less-enriched</th>
<th align="center">Mixed</th>
<th align="center">Mixed</th>
<th align="center">Mixed</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td colspan="8" align="left">Major Elements (wt.%)</td>
</tr>
<tr>
<td align="left">&#x2003;SiO<sub>2</sub>
</td>
<td align="center">49.08</td>
<td align="center">47.76</td>
<td align="center">47.74</td>
<td align="center">48.14</td>
<td align="center">47.95</td>
<td align="center">49.01</td>
<td align="center">49.25</td>
</tr>
<tr>
<td align="left">&#x2003;TiO<sub>2</sub>
</td>
<td align="center">1.74</td>
<td align="center">1.49</td>
<td align="center">1.82</td>
<td align="center">1.72</td>
<td align="center">1.59</td>
<td align="center">1.85</td>
<td align="center">2.01</td>
</tr>
<tr>
<td align="left">&#x2003;Al<sub>2</sub>O<sub>3</sub>
</td>
<td align="center">15.30</td>
<td align="center">16.54</td>
<td align="center">15.34</td>
<td align="center">15.60</td>
<td align="center">15.96</td>
<td align="center">15.10</td>
<td align="center">14.48</td>
</tr>
<tr>
<td align="left">&#x2003;FeO&#x2a;</td>
<td align="center">11.76</td>
<td align="center">10.94</td>
<td align="center">12.16</td>
<td align="center">11.98</td>
<td align="center">11.67</td>
<td align="center">12.71</td>
<td align="center">13.15</td>
</tr>
<tr>
<td align="left">&#x2003;MnO</td>
<td align="center">0.20</td>
<td align="center">0.18</td>
<td align="center">0.20</td>
<td align="center">0.20</td>
<td align="center">0.19</td>
<td align="center">0.21</td>
<td align="center">0.22</td>
</tr>
<tr>
<td align="left">&#x2003;MgO</td>
<td align="center">7.38</td>
<td align="center">8.88</td>
<td align="center">8.35</td>
<td align="center">8.10</td>
<td align="center">8.65</td>
<td align="center">7.16</td>
<td align="center">6.96</td>
</tr>
<tr>
<td align="left">&#x2003;CaO</td>
<td align="center">11.79</td>
<td align="center">11.83</td>
<td align="center">11.88</td>
<td align="center">11.71</td>
<td align="center">11.50</td>
<td align="center">11.12</td>
<td align="center">11.21</td>
</tr>
<tr>
<td align="left">&#x2003;Na<sub>2</sub>O</td>
<td align="center">2.32</td>
<td align="center">2.11</td>
<td align="center">2.17</td>
<td align="center">2.22</td>
<td align="center">2.19</td>
<td align="center">2.38</td>
<td align="center">2.23</td>
</tr>
<tr>
<td align="left">&#x2003;K<sub>2</sub>O</td>
<td align="center">0.25</td>
<td align="center">0.12</td>
<td align="center">0.16</td>
<td align="center">0.17</td>
<td align="center">0.16</td>
<td align="center">0.26</td>
<td align="center">0.28</td>
</tr>
<tr>
<td align="left">&#x2003;P<sub>2</sub>O<sub>5</sub>
</td>
<td align="center">0.19</td>
<td align="center">0.13</td>
<td align="center">0.17</td>
<td align="center">0.15</td>
<td align="center">0.14</td>
<td align="center">0.19</td>
<td align="center">0.21</td>
</tr>
<tr>
<td align="left">&#x2003;Sum</td>
<td align="center">100.00</td>
<td align="center">100.00</td>
<td align="center">99.99</td>
<td align="center">100.00</td>
<td align="center">99.99</td>
<td align="center">100.00</td>
<td align="center">100.00</td>
</tr>
<tr>
<td align="left">&#x2003;LOI</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">0.43</td>
<td align="center">0.32</td>
<td align="center">0.47</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
</tr>
<tr>
<td colspan="8" align="left">Trace Elements (ppm)</td>
</tr>
<tr>
<td align="left">&#x2003;Sc</td>
<td align="center">41.4</td>
<td align="center">35.7</td>
<td align="center">41.1</td>
<td align="center">40.4</td>
<td align="center">41.2</td>
<td align="center">40.8</td>
<td align="center">42.7</td>
</tr>
<tr>
<td align="left">&#x2003;V</td>
<td align="center">
<bold>342</bold>
</td>
<td align="center">
<bold>297</bold>
</td>
<td align="center">
<bold>308</bold>
</td>
<td align="center">
<bold>325</bold>
</td>
<td align="center">
<bold>315</bold>
</td>
<td align="center">
<bold>373</bold>
</td>
<td align="center">
<bold>394</bold>
</td>
</tr>
<tr>
<td align="left">&#x2003;Cr</td>
<td align="center">
<bold>130</bold>
</td>
<td align="center">
<bold>373</bold>
</td>
<td align="center">
<bold>368</bold>
</td>
<td align="center">
<bold>279</bold>
</td>
<td align="center">
<bold>270</bold>
</td>
<td align="center">
<bold>251</bold>
</td>
<td align="center">
<bold>160</bold>
</td>
</tr>
<tr>
<td align="left">&#x2003;Ni</td>
<td align="center">
<bold>82</bold>
</td>
<td align="center">
<bold>162</bold>
</td>
<td align="center">
<bold>120</bold>
</td>
<td align="center">
<bold>136</bold>
</td>
<td align="center">
<bold>109</bold>
</td>
<td align="center">
<bold>94</bold>
</td>
<td align="center">
<bold>74</bold>
</td>
</tr>
<tr>
<td align="left">&#x2003;Cu</td>
<td align="center">
<bold>135</bold>
</td>
<td align="center">
<bold>146</bold>
</td>
<td align="center">
<bold>126</bold>
</td>
<td align="center">
<bold>132</bold>
</td>
<td align="center">
<bold>133</bold>
</td>
<td align="center">
<bold>142</bold>
</td>
<td align="center">
<bold>179</bold>
</td>
</tr>
<tr>
<td align="left">&#x2003;Zn</td>
<td align="center">
<bold>93</bold>
</td>
<td align="center">
<bold>87</bold>
</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">
<bold>104</bold>
</td>
<td align="center">
<bold>107</bold>
</td>
</tr>
<tr>
<td align="left">&#x2003;Rb</td>
<td align="center">4.0</td>
<td align="center">1.5</td>
<td align="center">2.4</td>
<td align="center">2.8</td>
<td align="center">4.0</td>
<td align="center">4.7</td>
<td align="center">5.3</td>
</tr>
<tr>
<td align="left">&#x2003;Sr</td>
<td align="center">205</td>
<td align="center">217</td>
<td align="center">211</td>
<td align="center">209</td>
<td align="center">203</td>
<td align="center">175</td>
<td align="center">168</td>
</tr>
<tr>
<td align="left">&#x2003;Y</td>
<td align="center">24.77</td>
<td align="center">20.76</td>
<td align="center">24.68</td>
<td align="center">24.38</td>
<td align="center">25.14</td>
<td align="center">28.58</td>
<td align="center">30.76</td>
</tr>
<tr>
<td align="left">&#x2003;Zr</td>
<td align="center">94</td>
<td align="center">68</td>
<td align="center">83</td>
<td align="center">79</td>
<td align="center">89</td>
<td align="center">99</td>
<td align="center">107</td>
</tr>
<tr>
<td align="left">&#x2003;Nb</td>
<td align="center">12.95</td>
<td align="center">8.22</td>
<td align="center">
<bold>12</bold>
</td>
<td align="center">
<bold>10</bold>
</td>
<td align="center">
<bold>10</bold>
</td>
<td align="center">12.56</td>
<td align="center">13.51</td>
</tr>
<tr>
<td align="left">&#x2003;Cs</td>
<td align="center">0.05</td>
<td align="center">0.03</td>
<td align="center">0.03</td>
<td align="center">0.03</td>
<td align="center">0.05</td>
<td align="center">0.05</td>
<td align="center">0.07</td>
</tr>
<tr>
<td align="left">&#x2003;Ba</td>
<td align="center">72</td>
<td align="center">37</td>
<td align="center">47</td>
<td align="center">48</td>
<td align="center">63</td>
<td align="center">71</td>
<td align="center">75</td>
</tr>
<tr>
<td align="left">&#x2003;La</td>
<td align="center">9.38</td>
<td align="center">6.08</td>
<td align="center">7.47</td>
<td align="center">7.06</td>
<td align="center">8.58</td>
<td align="center">9.38</td>
<td align="center">10.03</td>
</tr>
<tr>
<td align="left">&#x2003;Ce</td>
<td align="center">21.89</td>
<td align="center">15.01</td>
<td align="center">18.41</td>
<td align="center">17.29</td>
<td align="center">20.55</td>
<td align="center">22.22</td>
<td align="center">23.88</td>
</tr>
<tr>
<td align="left">&#x2003;Pr</td>
<td align="center">3.07</td>
<td align="center">2.22</td>
<td align="center">2.70</td>
<td align="center">2.56</td>
<td align="center">2.95</td>
<td align="center">3.21</td>
<td align="center">3.41</td>
</tr>
<tr>
<td align="left">&#x2003;Nd</td>
<td align="center">13.97</td>
<td align="center">10.51</td>
<td align="center">12.85</td>
<td align="center">12.35</td>
<td align="center">13.71</td>
<td align="center">14.54</td>
<td align="center">15.79</td>
</tr>
<tr>
<td align="left">&#x2003;Sm</td>
<td align="center">3.86</td>
<td align="center">3.11</td>
<td align="center">3.75</td>
<td align="center">3.60</td>
<td align="center">3.84</td>
<td align="center">4.18</td>
<td align="center">4.49</td>
</tr>
<tr>
<td align="left">&#x2003;Eu</td>
<td align="center">1.44</td>
<td align="center">1.21</td>
<td align="center">1.38</td>
<td align="center">1.36</td>
<td align="center">1.46</td>
<td align="center">1.55</td>
<td align="center">1.62</td>
</tr>
<tr>
<td align="left">&#x2003;Tb</td>
<td align="center">0.79</td>
<td align="center">0.63</td>
<td align="center">0.77</td>
<td align="center">0.76</td>
<td align="center">0.78</td>
<td align="center">0.88</td>
<td align="center">0.93</td>
</tr>
<tr>
<td align="left">&#x2003;Gd</td>
<td align="center">4.46</td>
<td align="center">3.67</td>
<td align="center">4.44</td>
<td align="center">4.29</td>
<td align="center">4.56</td>
<td align="center">4.92</td>
<td align="center">5.33</td>
</tr>
<tr>
<td align="left">&#x2003;Dy</td>
<td align="center">5.01</td>
<td align="center">4.04</td>
<td align="center">4.81</td>
<td align="center">4.77</td>
<td align="center">4.92</td>
<td align="center">5.53</td>
<td align="center">5.89</td>
</tr>
<tr>
<td align="left">&#x2003;Ho</td>
<td align="center">1.01</td>
<td align="center">0.84</td>
<td align="center">1.00</td>
<td align="center">0.98</td>
<td align="center">1.02</td>
<td align="center">1.16</td>
<td align="center">1.22</td>
</tr>
<tr>
<td align="left">&#x2003;Er</td>
<td align="center">2.69</td>
<td align="center">2.23</td>
<td align="center">2.64</td>
<td align="center">2.68</td>
<td align="center">2.78</td>
<td align="center">3.15</td>
<td align="center">3.32</td>
</tr>
<tr>
<td align="left">&#x2003;Tm</td>
<td align="center">0.39</td>
<td align="center">0.32</td>
<td align="center">0.38</td>
<td align="center">0.39</td>
<td align="center">0.40</td>
<td align="center">0.45</td>
<td align="center">0.49</td>
</tr>
<tr>
<td align="left">&#x2003;Yb</td>
<td align="center">2.36</td>
<td align="center">1.95</td>
<td align="center">2.27</td>
<td align="center">2.34</td>
<td align="center">2.40</td>
<td align="center">2.83</td>
<td align="center">3.01</td>
</tr>
<tr>
<td align="left">&#x2003;Lu</td>
<td align="center">0.36</td>
<td align="center">0.30</td>
<td align="center">0.36</td>
<td align="center">0.37</td>
<td align="center">0.38</td>
<td align="center">0.44</td>
<td align="center">0.46</td>
</tr>
<tr>
<td align="left">&#x2003;Hf</td>
<td align="center">2.53</td>
<td align="center">1.87</td>
<td align="center">2.27</td>
<td align="center">2.22</td>
<td align="center">2.42</td>
<td align="center">2.69</td>
<td align="center">2.88</td>
</tr>
<tr>
<td align="left">&#x2003;Ta</td>
<td align="center">0.80</td>
<td align="center">0.51</td>
<td align="center">0.68</td>
<td align="center">0.67</td>
<td align="center">0.81</td>
<td align="center">0.80</td>
<td align="center">0.85</td>
</tr>
<tr>
<td align="left">&#x2003;Pb</td>
<td align="center">0.69</td>
<td align="center">0.46</td>
<td align="center">0.51</td>
<td align="center">0.62</td>
<td align="center">0.73</td>
<td align="center">0.76</td>
<td align="center">0.89</td>
</tr>
<tr>
<td align="left">&#x2003;Th</td>
<td align="center">0.67</td>
<td align="center">0.25</td>
<td align="center">0.40</td>
<td align="center">0.42</td>
<td align="center">0.58</td>
<td align="center">0.66</td>
<td align="center">0.71</td>
</tr>
<tr>
<td align="left">&#x2003;U</td>
<td align="center">0.21</td>
<td align="center">0.08</td>
<td align="center">0.13</td>
<td align="center">0.13</td>
<td align="center">0.17</td>
<td align="center">0.20</td>
<td align="center">0.22</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-3">
<title>3.3 Sr-Nd-Pb isotope analyses</title>
<p>Sr-Nd-Pb isotope ratios were measured on seven whole-rock powders from Undirhl&#xed;&#xf0;ar and Vatnsskar&#xf0; quarries by thermal ionization mass spectrometry (TIMS) at the University of North Carolina at Chapel Hill (<xref ref-type="table" rid="T2">Table 2</xref>). Samples were dissolved and cations were separated following the methods of (<xref ref-type="bibr" rid="B73">Miller and Glazner, 1995</xref>). Measurements were made on a VG Sector 54 mass spectrometer. Sr isotopes are referenced to <sup>87</sup>Sr/<sup>86</sup>Sr &#x3d; 0.710231 &#xb1; 9 (NBS 987, <italic>n</italic> &#x3d; 9). Nd isotopes are referenced to <sup>146</sup>Nd/<sup>144</sup>Nd &#x3d; 0.512102 &#xb1; 10 (JNdi, <italic>n</italic> &#x3d; 20).</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Radiogenic isotope data for whole-rock samples from Undirhl&#xed;&#xf0;ar ridge. Location describes sample site in Undirhl&#xed;&#xf0;ar (UND) or Vatnsskar&#xf0; (VAT) quarries. Compositional group defined by La<sub>N</sub>/Sm<sub>N</sub> value as described in the text. Major and trace element data for UND samples are reported in <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>. All samples are pillow lavas except for S-10-21 (dyke). Details of analytical methods are described in the text. Error is 2 <inline-formula id="inf1">
<mml:math id="m1">
<mml:mrow>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> standard deviation.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Sample ID</th>
<th align="left">Location</th>
<th align="left">Compositional group</th>
<th align="center">
<sup>206</sup>Pb/<sup>204</sup>Pb</th>
<th align="center">2&#x3c3;</th>
<th align="center">
<sup>207</sup>Pb/<sup>204</sup>Pb</th>
<th align="center">2&#x3c3;</th>
<th align="center">
<sup>208</sup>Pb/<sup>204</sup>Pb</th>
<th align="center">2&#x3c3;</th>
<th align="center">
<sup>208</sup>Pb/<sup>204</sup>Pb</th>
<th align="center">2&#x3c3;</th>
<th align="center">
<sup>143</sup>Nd/<sup>144</sup>Nd</th>
<th align="center">2&#x3c3;</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">VAT-NA-13&#x2013;09</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">18.8573</td>
<td align="center">0.0029</td>
<td align="center">15.5294</td>
<td align="center">0.0026</td>
<td align="center">38.4810</td>
<td align="center">0.0067</td>
<td align="center">0.703189</td>
<td align="center">0.000004</td>
<td align="center">0.513022</td>
<td align="center">0.0000041</td>
</tr>
<tr>
<td align="left">VAT-SA-13-10</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">18.7983</td>
<td align="center">0.0016</td>
<td align="center">15.5092</td>
<td align="center">0.0014</td>
<td align="center">38.3571</td>
<td align="center">0.0039</td>
<td align="center">0.703161</td>
<td align="center">0.000010</td>
<td align="center">0.513025</td>
<td align="center">0.0000062</td>
</tr>
<tr>
<td align="left">W-08-01</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">18.8316</td>
<td align="center">0.0032</td>
<td align="center">15.5181</td>
<td align="center">0.0028</td>
<td align="center">38.4313</td>
<td align="center">0.0076</td>
<td align="center">0.703181</td>
<td align="center">0.000004</td>
<td align="center">0.513025</td>
<td align="center">0.0000051</td>
</tr>
<tr>
<td align="left">S-10-23</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">18.8352</td>
<td align="center">0.0033</td>
<td align="center">15.5241</td>
<td align="center">0.0029</td>
<td align="center">38.4579</td>
<td align="center">0.0070</td>
<td align="center">0.70328</td>
<td align="center">0.000004</td>
<td align="center">0.512999</td>
<td align="center">0.0000041</td>
</tr>
<tr>
<td align="left">S-10-21</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">18.8216</td>
<td align="center">0.0012</td>
<td align="center">15.5105</td>
<td align="center">0.0011</td>
<td align="center">38.4034</td>
<td align="center">0.0031</td>
<td align="center">0.70317</td>
<td align="center">0.000004</td>
<td align="center">0.513026</td>
<td align="center">0.0000041</td>
</tr>
<tr>
<td align="left">S-10-25</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">18.8772</td>
<td align="center">0.0014</td>
<td align="center">15.5075</td>
<td align="center">0.0011</td>
<td align="center">38.4229</td>
<td align="center">0.0026</td>
<td align="center">0.703165</td>
<td align="center">0.000004</td>
<td align="center">0.51302</td>
<td align="center">0.0000092</td>
</tr>
<tr>
<td align="left">S-10-04</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">18.8709</td>
<td align="center">0.0012</td>
<td align="center">15.5122</td>
<td align="center">0.0011</td>
<td align="center">38.4239</td>
<td align="center">0.0027</td>
<td align="center">0.703163</td>
<td align="center">0.000004</td>
<td align="center">0.513034</td>
<td align="center">0.0000072</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-4">
<title>3.4 Volatile analyses</title>
<p>Volatiles (H<sub>2</sub>O and CO<sub>2</sub>) were measured on pristine glassy rims from 38 pillow lavas. In Undirhl&#xed;&#xf0;ar quarry, seven samples were collected from a cluster of adjacent pillows, four of which were collected from a single pillow (<xref ref-type="table" rid="T3">Table 3</xref>). For most samples, three glass chips were selected for analysis. Glass chips ranged in size from &#x3c;1&#xa0;mm to 7&#xa0;mm in diameter and were chosen to avoid significant weathering, alteration, phenocrysts, and vesicles. Chips were doubly polished into 100&#x2013;200&#xa0;micron-thick wafers. Thickness of each glass wafer was measured three times and averaged for each chip for a precision of &#xb1; 5&#xa0;microns. Wafers were analyzed by Fourier Transform Infrared Spectroscopy (FTIR) at the University of Massachusetts Amherst on a Bruker Tensor 27 FTIR with attached Hyperion 3000 microscope. FTIR spectra were obtained for a 10 &#xd7; 10 micron area using OPUS (version 7.2) software. Care was taken to avoid measuring sites adjacent to fractures, vesicles, crystals, and margins. At least three sites were measured for each chip, so each value reported represents the average of 3&#x2013;12&#xa0;spectra. Individual FTIR measurements are presented in the (<xref ref-type="sec" rid="s12">Supplementary Table SA7</xref>).</p>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Water contents, elevations, and saturation pressures of Undirhl&#xed;&#xf0;ar ridge samples. Location describes sample sites in Undirhl&#xed;&#xf0;ar quarry (UND), Vatnsskar&#xf0; quarry (VAT), or along the ridge between the quarries. Compositional group defined by La<sub>N</sub>/Sm<sub>N</sub> value as described in the text. H<sub>2</sub>O<sub>t</sub> and H<sub>2</sub>O<sub>m</sub> concentrations (in wt.%) are calculated averages of n number of FTIR spectra. Error is 2 <inline-formula id="inf2">
<mml:math id="m2">
<mml:mrow>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> standard deviation of uncertainty propagated through the Beer-Lambert Law. n.d. indicates values that were not determined. Elevations (in m) determined from a digital elevation model as described in the text. Ce (in ppm) determined on whole-rock samples. Pressure (in MPa) is H<sub>2</sub>O saturation pressure calculated using VolatileCalc (v. 2.0) assuming complete CO<sub>2</sub> degassing (i.e., CO<sub>2</sub> &#x3d; 0&#xa0;ppm) as described in text. Full compositional data and pressure calculations are available in <xref ref-type="sec" rid="s12">Supplementary Material</xref>. Four samples from the same pillow lava and seven samples from the cluster of adjacent pillows as shown in <xref ref-type="fig" rid="F11">Figure 11D</xref> are indicated with superscripts a and b, respectively.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Sample ID</th>
<th align="left">Location</th>
<th align="left">Compositional group</th>
<th align="center">H<sub>2</sub>O<sub>t</sub> (wt.%)</th>
<th align="center">2&#x3c3;</th>
<th align="center">n</th>
<th align="center">H<sub>2</sub>O<sub>m</sub> (wt.%)</th>
<th align="center">2&#x3c3;</th>
<th align="center">n</th>
<th align="center">Elevation (m)</th>
<th align="center">H<sub>2</sub>O<sub>m</sub>/H<sub>2</sub>O<sub>t</sub>
</th>
<th align="center">Ce (ppm)</th>
<th align="center">H<sub>2</sub>O/Ce</th>
<th align="center">Pressure (MPa)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">
<sup>a</sup>0613UAH06-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.36</td>
<td align="center">0.06</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.6</td>
</tr>
<tr>
<td align="left">
<sup>a</sup>0613UAH07-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.39</td>
<td align="center">0.08</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.6</td>
</tr>
<tr>
<td align="left">
<sup>a</sup>0613UAH08-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.35</td>
<td align="center">0.06</td>
<td align="center">6</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.4</td>
</tr>
<tr>
<td align="left">
<sup>a</sup>0613UAH09-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.39</td>
<td align="center">0.04</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.4</td>
</tr>
<tr>
<td align="left">
<sup>b</sup>0613UAH01-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.39</td>
<td align="center">0.08</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.6</td>
</tr>
<tr>
<td align="left">
<sup>b</sup>0613UAH04-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.4</td>
<td align="center">0.02</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">98</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.3</td>
</tr>
<tr>
<td align="left">
<sup>b</sup>0613UAH05-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.37</td>
<td align="center">0.08</td>
<td align="center">9</td>
<td align="center">0.05</td>
<td align="center">0.02</td>
<td align="center">2</td>
<td align="center">98</td>
<td align="center">0.14</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.6</td>
</tr>
<tr>
<td align="left">0613UAH11-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.36</td>
<td align="center">0.04</td>
<td align="center">6</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">103</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.4</td>
</tr>
<tr>
<td align="left">0613UAH12-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.38</td>
<td align="center">0.02</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">100</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.5</td>
</tr>
<tr>
<td align="left">0613UAH13-gl</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">0.28</td>
<td align="center">0.06</td>
<td align="center">11</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">126</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">0613UAH15-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.36</td>
<td align="center">0.08</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">143</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.4</td>
</tr>
<tr>
<td align="left">0613UAH16-gl</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">0.24</td>
<td align="center">0.04</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">142</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">0.7</td>
</tr>
<tr>
<td align="left">0613UAH17-gl</td>
<td align="left">UND</td>
<td align="left">more-enriched</td>
<td align="center">0.34</td>
<td align="center">0.04</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">104</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">1.3</td>
</tr>
<tr>
<td align="left">16BRE07</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.29</td>
<td align="center">0.02</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">165</td>
<td align="center">&#x2014;</td>
<td align="center">15.13</td>
<td align="center">192</td>
<td align="center">1.0</td>
</tr>
<tr>
<td align="left">16CW01</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.28</td>
<td align="center">0.08</td>
<td align="center">8</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">167</td>
<td align="center">&#x2014;</td>
<td align="center">14.84</td>
<td align="center">189</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">16CW02</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.19</td>
<td align="center">0.12</td>
<td align="center">21</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">145</td>
<td align="center">&#x2014;</td>
<td align="center">16.13</td>
<td align="center">118</td>
<td align="center">0.4</td>
</tr>
<tr>
<td align="left">16CW03</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">0.16</td>
<td align="center">0.04</td>
<td align="center">9</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">156</td>
<td align="center">&#x2014;</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">0.3</td>
</tr>
<tr>
<td align="left">16CW04</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">0.22</td>
<td align="center">0.1</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">152</td>
<td align="center">&#x2014;</td>
<td align="center">18.88</td>
<td align="center">117</td>
<td align="center">0.5</td>
</tr>
<tr>
<td align="left">16CW05</td>
<td align="left">UND</td>
<td align="left">less-enriched</td>
<td align="center">0.23</td>
<td align="center">0.1</td>
<td align="center">12</td>
<td align="center">0.02</td>
<td align="center">0.01</td>
<td align="center">3</td>
<td align="center">144</td>
<td align="center">0.09</td>
<td align="center">15.78</td>
<td align="center">146</td>
<td align="center">0.5</td>
</tr>
<tr>
<td align="left">16CW07</td>
<td align="left">Ridge</td>
<td align="left">mixed</td>
<td align="center">0.33</td>
<td align="center">0.1</td>
<td align="center">8</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">183</td>
<td align="center">&#x2014;</td>
<td align="center">21.95</td>
<td align="center">150</td>
<td align="center">1.2</td>
</tr>
<tr>
<td align="left">16CW08</td>
<td align="left">Ridge</td>
<td align="left">more-enriched</td>
<td align="center">0.29</td>
<td align="center">0.08</td>
<td align="center">9</td>
<td align="center">0.03</td>
<td align="center">0.01</td>
<td align="center">2</td>
<td align="center">120</td>
<td align="center">0.10</td>
<td align="center">21.89</td>
<td align="center">132</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">16CW09</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.23</td>
<td align="center">0.08</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">210</td>
<td align="center">&#x2014;</td>
<td align="center">17.17</td>
<td align="center">134</td>
<td align="center">0.6</td>
</tr>
<tr>
<td align="left">16MP04</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.16</td>
<td align="center">0.08</td>
<td align="center">10</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">177</td>
<td align="center">&#x2014;</td>
<td align="center">15.45</td>
<td align="center">104</td>
<td align="center">0.3</td>
</tr>
<tr>
<td align="left">16MP06</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.22</td>
<td align="center">0.08</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">138</td>
<td align="center">&#x2014;</td>
<td align="center">16.81</td>
<td align="center">131</td>
<td align="center">0.6</td>
</tr>
<tr>
<td align="left">16MP13</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.23</td>
<td align="center">0.06</td>
<td align="center">10</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">163</td>
<td align="center">&#x2014;</td>
<td align="center">15.75</td>
<td align="center">146</td>
<td align="center">0.6</td>
</tr>
<tr>
<td align="left">16MP14</td>
<td align="left">Ridge</td>
<td align="left">less-enriched</td>
<td align="center">0.25</td>
<td align="center">0.12</td>
<td align="center">10</td>
<td align="center">0.04</td>
<td align="center">0.02</td>
<td align="center">5</td>
<td align="center">131</td>
<td align="center">0.16</td>
<td align="center">16.33</td>
<td align="center">153</td>
<td align="center">0.7</td>
</tr>
<tr>
<td align="left">VAT-N-09-03</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.29</td>
<td align="center">0.06</td>
<td align="center">4</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">136</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">VAT-N-09-04</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.31</td>
<td align="center">0.04</td>
<td align="center">4</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">148</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">1.1</td>
</tr>
<tr>
<td align="left">VAT-NA-13-03</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.3</td>
<td align="center">0.08</td>
<td align="center">4</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">183</td>
<td align="center">&#x2014;</td>
<td align="center">17.22</td>
<td align="center">174</td>
<td align="center">1.0</td>
</tr>
<tr>
<td align="left">VAT-NA-13-06</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.28</td>
<td align="center">0.04</td>
<td align="center">4</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">140</td>
<td align="center">&#x2014;</td>
<td align="center">17.64</td>
<td align="center">159</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">VAT-NA-13-07</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.29</td>
<td align="center">0.08</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">140</td>
<td align="center">&#x2014;</td>
<td align="center">17.25</td>
<td align="center">168</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">VAT-NA-13-09</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.29</td>
<td align="center">0.12</td>
<td align="center">3</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">228</td>
<td align="center">&#x2014;</td>
<td align="center">18.41</td>
<td align="center">158</td>
<td align="center">1.0</td>
</tr>
<tr>
<td align="left">VAT-NA-13-16</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.31</td>
<td align="center">0.06</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">204</td>
<td align="center">&#x2014;</td>
<td align="center">17.66</td>
<td align="center">176</td>
<td align="center">1.1</td>
</tr>
<tr>
<td align="left">VAT-SA-13-02</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.25</td>
<td align="center">0.12</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">146</td>
<td align="center">&#x2014;</td>
<td align="center">17.05</td>
<td align="center">147</td>
<td align="center">1.2</td>
</tr>
<tr>
<td align="left">VAT-SA-13-04</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.24</td>
<td align="center">0.08</td>
<td align="center">4</td>
<td align="center">0.03</td>
<td align="center">0.01</td>
<td align="center">2</td>
<td align="center">147</td>
<td align="center">0.13</td>
<td align="center">15.56</td>
<td align="center">154</td>
<td align="center">0.7</td>
</tr>
<tr>
<td align="left">VAT-SA-13-10</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.29</td>
<td align="center">0.04</td>
<td align="center">12</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">140</td>
<td align="center">&#x2014;</td>
<td align="center">17.29</td>
<td align="center">168</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">VAT-SA-13-21</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.28</td>
<td align="center">0.06</td>
<td align="center">13</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">139</td>
<td align="center">&#x2014;</td>
<td align="center">17.86</td>
<td align="center">157</td>
<td align="center">0.9</td>
</tr>
<tr>
<td align="left">VAT-SA-13-24</td>
<td align="left">VAT</td>
<td align="left">less-enriched</td>
<td align="center">0.26</td>
<td align="center">0.06</td>
<td align="center">4</td>
<td align="center">n.d.</td>
<td align="center">&#x2014;</td>
<td align="center">&#x2014;</td>
<td align="center">132</td>
<td align="center">&#x2014;</td>
<td align="center">14.25</td>
<td align="center">182</td>
<td align="center">0.8</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>IR peak absorbance at &#x223c;3529&#xa0;cm<sup>-1</sup> was used to calculate total water (H<sub>2</sub>O<sub>t</sub>) concentration using the Beer-Lambert Law (<xref ref-type="bibr" rid="B100">Stolper, 1982</xref>). Glass density was 2,750 &#xb1; 55&#xa0;g/L, estimated using <xref ref-type="bibr" rid="B3">Bottinga and Weill (1972)</xref> and based on average composition of the sample suite. The molar absorption coefficient for H<sub>2</sub>O in basalt was 63 &#xb1; 3&#xa0;L/mol-cm (<xref ref-type="bibr" rid="B12">Dixon et al., 1995</xref>). Water speciation was not determined for most samples because spectra did not show measurable peaks at the 4,500&#xa0;cm<sup>-1</sup> and 5,200&#xa0;cm<sup>-1</sup> bands (<xref ref-type="bibr" rid="B69">Mcintosh et al., 2017</xref>). For the few samples with peaks detected at 1,630&#xa0;cm<sup>-1</sup>, spectra were analyzed using Spectragryph (v.1.2.16.1). Peak absorbance was determined on spectra corrected with adaptive baselines. Molecular water (H<sub>2</sub>O<sub>m</sub>) concentrations were calculated the Beer-Lambert law and the same parameters described above with a molar absorption coefficient of 25 &#xb1; 3&#xa0;L/mol-cm (<xref ref-type="bibr" rid="B12">Dixon et al., 1995</xref>). Uncertainty was estimated by propagating errors through the Beer Lamber Law for sample thickness, density, absorption coefficient, and absorbance based on repeated analyses of the same site. Average precision (1-&#x03b8;) for H<sub>2</sub>O<sub>t</sub> concentrations is 10%, which is consistent with previous studies of total water measurements made by FTIR (<xref ref-type="bibr" rid="B10">Dixon and Clague, 2001</xref>). Error for H<sub>2</sub>O<sub>m</sub> concentrations is higher because of additional uncertainty in absorbance intensity measured from adaptive baselines (<xref ref-type="bibr" rid="B70">McIntosh et al., 2022</xref>).</p>
<p>Most samples did not show a measurable CO<sub>2</sub> peak at &#x223c;2,360&#xa0;cm<sup>-1</sup>, and the CO<sub>2</sub> peaks that were observed did not consistently appear in the spectra, even within the same chip. Therefore, CO<sub>2</sub> values are interpreted to be below the lower limit of quantification (20&#xa0;ppm). The <xref ref-type="sec" rid="s12">Supplementary Material</xref> contains the data for the few CO<sub>2</sub> peaks that were detected. The Beer-Lambert Law was used to calculate the CO<sub>2</sub> concentration using the same parameters described above and a molar absorption coefficient of 945&#xa0;L/mol-cm for CO<sub>2</sub> (<xref ref-type="bibr" rid="B21">Fine and Stolper, 1985</xref>).</p>
<p>After FTIR analysis, 11 glass samples were carbon coated and analyzed for major elements by electron probe microanalysis (EPMA) at the University of Massachusetts Amherst. The Cameca SX 50 microprobe was operated under an acceleration voltage of 15&#xa0;keV, a beam current of 20&#xa0;nA, and a spot size of 30&#xa0;&#xb5;m. Full compositional data for the glass chips are provided in the (<xref ref-type="sec" rid="s12">Supplementary Table SA1</xref>).</p>
</sec>
<sec id="s3-5">
<title>3.5 Geochemical models</title>
<p>The alphaMELTS program (v. 1.9) was used to model crystallization and melting (<xref ref-type="bibr" rid="B99">Smith and Asimow, 2005</xref>). Using the MELTS thermodynamic model (<xref ref-type="bibr" rid="B28">Ghiorso and Sack, 1995</xref>), liquid lines of descent (LLD) were calculated for isobaric fractional crystallization at 1&#xa0;kb and 1,200&#xb0;C with 3&#xb0;C steps. A primitive aphyric lava was used for the parent magma (VAT-SA-13-07, MgO 8.6&#xa0;wt.%, La<sub>N</sub>/Sm<sub>N</sub> 1.44) with the addition of 0.5&#xa0;wt.% H<sub>2</sub>O. Initial Fe<sub>2</sub>O<sub>3</sub> was calculated from FeO in alphaMELTS at the FMQ buffer. The same conditions were used to calculate the liquidus phase for two additional parent magma compositions (16MP02 and S-10-18 from <xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). Using the pMELTS thermodynamic model (<xref ref-type="bibr" rid="B27">Ghiorso et al., 2002</xref>), mantle melts were generated through isentropic decompression melting starting at 4&#xa0;GPa and 1,500&#xb0;C with 0.01&#xa0;GPa steps. Melting was continuous with 0.05% residual porosity. Two mantle source compositions were modeled: Depleted MORB mantle (<xref ref-type="bibr" rid="B110">Workman and Hart, 2005</xref>) and enriched mantle comprising 95% DMM and 5% pyroxenite from <xref ref-type="bibr" rid="B58">Koornneef et al. (2012)</xref>. Trace element partition coefficients from <xref ref-type="bibr" rid="B71">McKenzie and O&#x2019;Nions (1991)</xref>, <xref ref-type="bibr" rid="B72">McKenzie and O&#x2019;Nions (1995)</xref> remained constant during melting. Melts were aggregated using the 1D aggregation model and extracted at 2.17&#xa0;GPa for both mantle sources.</p>
<p>VolatileCalc (v. 2.0) was used to calculate volatile saturation pressures (<xref ref-type="bibr" rid="B77">Newman and Lowenstern, 2002</xref>). Liquid temperatures were determined with alphaMELTS using glass or whole-rock compositions under the same conditions as the LLD models. Water concentrations were determined by FTIR. Because CO<sub>2</sub> solubility affects H<sub>2</sub>O saturation pressures, pressures were calculated at 0&#xa0;ppm and 15&#xa0;ppm CO<sub>2</sub>, representing complete and partial degassing. Full calculation data are provided in the (<xref ref-type="sec" rid="s12">Supplementary Table SA8</xref>).</p>
</sec>
</sec>
<sec sec-type="results" id="s4">
<title>4 Results</title>
<sec id="s4-1">
<title>4.1 Lithostratigraphy</title>
<p>We have broken out several different lithofacies, including: 1) Pillow lava, 2) tuff, 3) lapilli tuff, 4) tuff-breccia, 5) dykes, 6) massive, columnar-jointed basaltic intrusions, 7) and diamict (<xref ref-type="fig" rid="F2">Figures 2</xref>, <xref ref-type="fig" rid="F3">3</xref>). These lithofacies are essentially the same as those described in <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>, and so are not described in detail here. The most common pillow-dominated units comprise stacked pillow lavas with very little intra-pillow material (<xref ref-type="fig" rid="F4">Figure 4A</xref>). Tuff and lapilli tuff are limited to relatively thin interbeds between pillow units (<xref ref-type="fig" rid="F4">Figure 4B</xref>), although they are more extensive locally on the eastern side of the ridge. Tuff-breccia is present in larger masses (<xref ref-type="fig" rid="F3">Figures 3</xref>, <xref ref-type="fig" rid="F4">4C</xref>). Since the basic stratigraphy for Undirhli&#xf0;ar quarry was described by <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>, here we focus on describing Vatnsskar&#xf0; quarry and the ridge between the quarries.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Maps showing the morphology, sample locations, and geology of Undirhli&#xf0;ar ridge between Undirhli&#xf0;ar (Q&#x2013;N) and Vatnsskar&#xf0; (Q&#x2013;S) quarries. <bold>(A)</bold> Digital elevation model (DEM) showing the overall ridge morphology; data for the DEM from the ArcticDEM website, sampled at 1.0&#xa0;m resolution. <bold>(B)</bold> Locations of samples used in this study. <bold>(C)</bold> Geology of the ridge based on new mapping.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g002.tif"/>
</fig>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Stratigraphy of units at Vatnsskar&#x00f0; quarry. <bold>(A)</bold> Composited image of the quarry with interpreted distribution of units below <bold>(B)</bold>. <bold>(C)</bold> Close-up view of the palagonitized tuff-breccia that forms the bedrock to the ridge and is unconformably overlain by quarry units.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g003.tif"/>
</fig>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Field images of critical lithofacies. <bold>(A)</bold> Shallowly plunging pillow lava tubes from Lp2 in the central wall of Vatnsskar&#xf0; quarry. View is approximately 30&#xa0;m across horizontally. <bold>(B)</bold> Thinly laminated beds of tuff and lapilli tuff in the northeastern wall of Vatnsskar&#xf0; quarry (lens cap for scale). <bold>(C)</bold> View of tuff-breccia unit between Lp2 and Lp3 in the central wall of Vatnsskar&#xf0; quarry. Largest bombs/pillow fragments are approximately 50&#xa0;cm in diameter (outcrop was unreachable).</p>
</caption>
<graphic xlink:href="feart-11-1095135-g004.tif"/>
</fig>
<p>Undirhli&#xf0;ar ridge is the northern extension of a much larger composite tindar ridge complex that extends for more than 20&#xa0;km in total length (<xref ref-type="fig" rid="F1">Figure 1</xref>). The northern half of the Undirhli&#xf0;ar segment is dominated by intact pillow lavas and pillow lava rubble (<xref ref-type="fig" rid="F2">Figure 2C</xref>), which is sporadically directly overlain by a tan-brown, variably indurated diamicton interpreted to be of glacial origin. Approximately 1.5&#xa0;km south of Undirhli&#xf0;ar quarry, the east side of the ridge abruptly shifts from pillow rubble to variably palagonitized lapilli tuff and tuff-breccia. Where they are in contact, the fragmental materials appear to directly overlie pillow lava units; however, the palagonitized tephra deposits are absent from either of the quarries. In several places small dykes (&#x3c; 1&#xa0;m thick) cut through the tephra-rich east side deposits and appear to be less common, although still present, in pillow units along the west-central part of the ridge (<xref ref-type="fig" rid="F2">Figure 2C</xref>). Vatnsskar&#xf0; quarry marks the southern end of the study area, where mining operations as of 2021 have bisected approximately half of the ridge width.</p>
<p>Vatnsskar&#xf0; quarry, which is still active and expanding, is approximately 1&#xa0;km long and up to 80&#xa0;m from the quarry floor to the top of the ridge. Most of the Vatnsskar&#xf0; quarry walls expose longitudinal sections of the ridge, but the northern end exposes a cross section that is perpendicular to the length of the ridge. We have identified 7 different pillow lava units based on stratigraphy and location, 4 different primary fragmental units (tuff, lapilli tuff, tuff-breccia), and overlying glaciofluvial deposits (tuff-breccia/diamict <xref ref-type="fig" rid="F3">Figure 3</xref>). The north wall is dominated by pillow lavas, and because of their plunge orientations (see below), we have designated these pillows as a distinct unit (LpN; <xref ref-type="fig" rid="F3">Figure 3</xref>).</p>
<p>The walls of Vatnsskar&#xf0; quarry expose a continuous longitudinal section of the ridge, from the basal contact, through volcanic stratigraphy with multiple pillow and fragmental units, to capping sedimentary units (<xref ref-type="fig" rid="F3">Figure 3</xref>). The basal contact is exposed near the center of the walls, where the lowest pillows (Lp1) appear in lenses that lie unconformably over sedimentary layers of yellow diamict containing cobble-sized clasts of vesicular basalt. The upper contact of the basal pillows lavas (Lp1) is marked by a thin (cm-scale) layer of vitric tuff and a sharp contact with overlying pillows (Lp2). Lp2 comprises the bulk of the central and southern quarry walls. Within the pillows are isolated lenses of lapilli tuff and vitric tuff-breccia that include glassy basaltic bombs. Above Lp2 is a dark black vitric tuff breccia (TB) that dips downward and thickens to the northeast. This fragmental unit consists of a vitric lapilli tuff (LT) with some highly vesicular glassy fragments that gradually coarsens to bomb-dominated, with glassy bombs that are mostly vesiculated throughout (LT-TB). The TB unit contains lobes of a third pillow unit (Lp3). The upper portion of the Lp3-TB complex is marked by a relatively flat-lying contact with a fourth pillow unit (Lp4) that hosts irregularly shaped intrusions, which are described in detail below. Capping the Lp4-intrusion complex is another pillow unit (Lp5). We lose stratigraphic control above this pillow unit and find one more isolated pillow exposure (Lp6) in a roadcut at the top of the mine. Laterally to the south, the volcanic stratigraphy is capped by a sequence of sedimentary units that lies unconformably over the exposures in the central and southern walls. Most of the sedimentary unit comprises a clast-rich sandy diamict that stands out in relief, containing &#x223c;60% gravel-sized fragments and with weathered yellow to red appearance. Cobbles are rounded and striated. The matrix comprises glass and palagonitized sand-size grains. Within the sandy diamict is a 3&#xa0;m-thick unit of gray muddy diamict with sparse interbedded sandy lenses.</p>
<p>Pillow units are distinguished based on their appearance and orientations. For example, Lp1 and Lp2 show a sharp contrast in appearance: Pillow lavas in Lp1 are aphyric, variably fractured, and weathered brown-yellow, whereas Lp2 pillows are darker, fresher-looking, olivine-bearing and have fresh glassy rinds with corrugated textures. Pillow orientations differ among the quarry walls (<xref ref-type="fig" rid="F6">Figure 6</xref>). Lp2 pillows in the south wall plunge steeply to the southwest. Pillow units in the main quarry walls plunge to northwest. The north wall exposes a pillow unit (LpN) that plunges steeply to the south.</p>
<p>Irregular subhorizontal intrusions are present in all of the quarry walls (<xref ref-type="fig" rid="F3">Figures 3</xref>, <xref ref-type="fig" rid="F5">5</xref>). They appear as laterally extensive massive columnar jointed basalts that are irregular in shape with complex jointing patterns. Many of the irregular intrusions show chilled margins and glassy contacts with the surrounding pillow lavas. The intrusions are holocrystalline with visible plagioclase, olivine, and clinopyroxene phenocrysts and crystal size increasing toward the interior. Some parts of the intrusions are slightly vesiculated (&#x3c; 3%), although other locations along the margin have 10%&#x2013;15% vesicularity, showing mm-scale vesicles, and sparse larger (4&#x2013;5&#xa0;mm) pipe vesicles. These irregular intrusions also contain gabbroic and troctolitic xenoliths. The xenoliths tend to appear at the base of the intrusions.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Field images showing intrusions. <bold>(A)</bold> Dyke feeding overlying pillow lavas, Undirhli&#xf0;ar quarry. Person for scale. <bold>(B)</bold> Irregular intrusion into pillow lavas, Vatnsskar&#xf0; quarry. Maximum vertical dimension is 17&#xa0;m. <bold>(C)</bold> Sill-like intrusion, northern walls, Vatnsskar&#xf0; quarry. The intrusion is &#x223c;300&#xa0;m long and 38&#xa0;m tall.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g005.tif"/>
</fig>
<p>Ridge-parallel dykes cut through the pillow units on the southernmost and northernmost walls that expose cross-sections perpendicular to the ridge (<xref ref-type="fig" rid="F3">Figure 3</xref>). The dykes are &#x223c;1&#x2013;1.5&#xa0;m wide with chilled margins. They display well developed columnar joints and patterns in vesicularity (pipe vesicles perpendicular to margins and vesicle bands parallel to margins). The cores of some dykes are glassy, vesiculated, and fragmented. Ridge-perpendicular dykes are less abundant but also present.</p>
<p>In Undirhl&#xed;&#xf0;ar quarry, pillows in the central part of the quarry generally have southwest trends (236&#xb0;&#x2013;256&#xb0;) with low plunges (<xref ref-type="fig" rid="F6">Figure 6</xref>). These data are consistent with eruption from a vent trending perpendicular to the main ridge axis. However, pillows in the area to the south (pw07-pw10), have northwest trends (307&#xb0;) with low plunges, suggesting an eruptive vent to the southeast. In Vatnsskar&#xf0; quarry, a number of areas show pillows with plunge orientations that are also consistent with eruption from small fissures with a variety of orientations with respect to the main ridge axis (<xref ref-type="fig" rid="F6">Figure 6</xref>). For example, pillows in the south wall (Lp2) show plunge directions opposite to pillows exposed in an erosional gully adjacent and south to the quarry.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Quantification of pillow orientations. <bold>(A)</bold> Satellite image of the Central Wall of Undirhli&#xf0;ar showing populations of pillow plunges. <bold>(B)</bold> Satellite image of the central and southern walls at Vatnsskar&#xf0; quarry showing populations of pillow plunges. In <bold>(A, B)</bold> yellow arrows show the general trend of the overall ridge, and orange arrows show fissure trends inferred from pillow plunge directions.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g006.tif"/>
</fig>
</sec>
<sec id="s4-2">
<title>4.2 Major and trace element geochemistry</title>
<p>Within the Undirhl&#xed;&#xf0;ar ridge suite, samples form distinct geochemical clusters defined by Rare Earth Element (REE) patterns (<xref ref-type="fig" rid="F7">Figure 7</xref>). Based on relative light REE (LREE) enrichment, we divide the Undirhl&#xed;&#xf0;ar ridge samples into three compositional groups. Most of the suite comprises the &#x201c;less-enriched&#x201d; group with chondrite-normalized (<xref ref-type="bibr" rid="B68">McDonough and Sun, 1995</xref>) La<sub>N</sub>/Sm<sub>N</sub> less than 1.31. The &#x201c;more-enriched&#x201d; group overlaps the less-enriched group in REE abundance but has La<sub>N</sub>/Sm<sub>N</sub> ratios greater than 1.50. The &#x201c;mixed&#x201d; group has La<sub>N</sub>/Sm<sub>N</sub> ratios between 1.37 and 1.49 and shows the highest REE abundances in the suite. All of the Undirhl&#xed;&#xf0;ar ridge samples have smooth REE patterns with no or slightly positive Eu anomalies.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Rare Earth element (REE) concentrations normalized to chondrite values from <xref ref-type="bibr" rid="B68">McDonough and Sun (1995)</xref>. <bold>(A)</bold> Reykjanes Peninsula (light blue circles), including the Fagradalsfjall 2021 eruption (medium blue triangles). Undirhl&#xed;&#xf0;ar ridge extrusive (diamonds) and intrusive (squares) samples shown in <bold>(B</bold>&#x2013;<bold>D)</bold>, grouped by La<sub>N</sub>/Sm<sub>N</sub> values: <bold>(B)</bold> La<sub>N</sub>/Sm<sub>N</sub> &#x3c; 1.31 (less enriched), <bold>(C)</bold> La<sub>N</sub>/Sm<sub>N</sub> &#x3e; 1.50 (more enriched), <bold>(D)</bold> 1.37 &#x3c; La<sub>N</sub>/Sm<sub>N</sub> &#x3c; 1.49 (mixed). <bold>(E)</bold> Black lines show alphaMELTS model melt compositions for depleted (DMM) and enriched (5% pyroxenite) mantle sources, illustrating how mixing between two mantle source compositions can generate the Undirhl&#xed;&#xf0;ar ridge data. <bold>(F)</bold> Gray field show alphaMELTS model liquid compositions for up to 30% fractional crystallization illustrating how variable extents of crystallization affect REE abundance. See text for model details. Undirhl&#xed;&#xf0;ar ridge data from this study and (<xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). Reykjanes Peninsula data (light blue circles), excluding picrites, from (<xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and Sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al., 2016</xref>). Fagradalsfjall data (triangles) from (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>).</p>
</caption>
<graphic xlink:href="feart-11-1095135-g007.tif"/>
</fig>
<p>Undirhl&#xed;&#xf0;ar ridge REE data overlap with enriched lavas from the Reykjanes Peninsula but show a more restricted range in LREE enrichment (<xref ref-type="fig" rid="F7">Figure 7</xref>). Reykjanes Peninsula lavas show La<sub>N</sub>/Sm<sub>N</sub> ranging from 1.20 to 1.67 (<xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and Sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al., 2016</xref>). Fagradalsfjall lavas show a wider range in La<sub>N</sub>/Sm<sub>N</sub> (1.24&#x2013;2.74) and extend to lower REE abundances (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). Using incompatible trace element ratios, <xref ref-type="bibr" rid="B25">Gee et al. (1998)</xref> divided Reykjanes Peninsula samples into &#x201c;depleted&#x201d; (Nb/Zr &#x3c; 0.08) and &#x201c;enriched&#x201d; (Nb/Zr &#x3e; 0.08) groups. <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> further subdivided enriched historical Reykjanes Peninsula lavas into &#x201c;less-enriched&#x201d; (Nb/Zr 0.10&#x2013;0.13, La<sub>N</sub>/Sm<sub>N</sub> 1.21&#x2013;1.36) and &#x201c;more-enriched&#x201d; (Nb/Zr 0.13&#x2013;0.14, La<sub>N</sub>/Sm<sub>N</sub> 1.38&#x2013;1.48) groups based on incompatible trace element ratios and LREE enrichment. By these definitions, all of the Undirhl&#xed;&#xf0;ar ridge samples are enriched. Like <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref>, we observe more-enriched and less-enriched subdivisions within the Undirhl&#xed;&#xf0;ar ridge dataset. Our more-enriched group shows higher La<sub>N</sub>/Sm<sub>N</sub> values than the more-enriched group of <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref>. Our mixed group would have been classified by <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> as &#x201c;more-enriched,&#x201d; but we choose to separate the mixed samples because of compositional differences.</p>
<p>The three compositional groups show variations that are distinguishable in major element space (<xref ref-type="fig" rid="F8">Figure 8</xref>). In general, with decreasing MgO, the Undirhl&#xed;&#xf0;ar ridge suite shows decreasing Al<sub>2</sub>O<sub>3</sub> and CaO, increasing FeO<sup>T</sup>, TiO<sub>2</sub>, and Na<sub>2</sub>O, and relatively flat SiO<sub>2</sub> values. The less-enriched group encompasses the entire range of MgO found in the dataset, extending to the highest MgO values (MgO &#x3e;9.0&#xa0;wt.%). The high-MgO samples are dominated by olivine-phyric intrusions and pillow lavas. At a given value of MgO, some less-enriched samples show elevated Al<sub>2</sub>O<sub>3</sub> and CaO and lower FeO<sup>T</sup> and K<sub>2</sub>O. These samples are plagioclase-phyric pillow lavas. The mixed and more-enriched groups are distinguished by where they overlap with the less-enriched group. Mixed group samples dominate the low-MgO range of the Undirhl&#xed;&#xf0;ar ridge dataset. More-enriched samples fall toward the lower edges of TiO<sub>2</sub>, FeO<sup>T</sup>, and Al<sub>2</sub>O<sub>3</sub> fields and the higher edges of CaO field defined by the less-enriched samples. The most notable distinction among the three compositional groups is in K<sub>2</sub>O. For a given value of MgO, the more-enriched group shows the greatest variability in K<sub>2</sub>O and extends to higher values. This distinction is clearly observed in the ratio of K<sub>2</sub>O/TiO<sub>2</sub>, where the more-enriched group shows the highest values (avg. 0.18 &#xb1; 0.04, <italic>n</italic> &#x3d; 25), the less-enriched group shows the lowest values (avg. 0.10 &#xb1; 0.03, <italic>n</italic> &#x3d; 107), and the mixed group spans the range of the suite.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Major elements vs. MgO in wt% with symbols and colors as in <xref ref-type="fig" rid="F7">Figure 7.</xref> <bold>(A)</bold> Al<sub>2</sub>O<sub>3</sub>, <bold>(B)</bold> CaO, <bold>(C)</bold> FeO<sup>T</sup>, <bold>(D)</bold> TiO<sub>2</sub>, <bold>(E)</bold> Na<sub>2</sub>O, <bold>(F)</bold> K<sub>2</sub>O, <bold>(G)</bold> SiO<sub>2</sub>, <bold>(H)</bold> K<sub>2</sub>O/TiO<sub>2</sub>. All iron is recalculated as total FeO (FeO<sup>T</sup>). Data have been normalized to 100% on an anhydrous basis. Error bars show 2 <inline-formula id="inf3">
<mml:math id="m3">
<mml:mrow>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> standard deviation on panels <bold>(G, H)</bold>. On all other panels, symbols are larger than 2 <inline-formula id="inf4">
<mml:math id="m4">
<mml:mrow>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> standard deviation. Symbols with (&#x2b;) are plagioclase phyric and (x) are olivine phyric. Red line shows alphaMELTS model liquid line of descent of 1&#xa0;kbar fractional crystallization. See text for model details. Undirhl&#xed;&#xf0;ar ridge data from this study and <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>. Reykjanes Peninsula data (light blue circles), excluding picrites, from (<xref ref-type="bibr" rid="B48">Jakobsson et al., 1978</xref>; <xref ref-type="bibr" rid="B8">Condomines et al., 1983</xref>; <xref ref-type="bibr" rid="B42">Hemond et al., 1988</xref>; <xref ref-type="bibr" rid="B41">Hemond et al., 1993</xref>; <xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B92">Skovgaard et al., 2001</xref>; <xref ref-type="bibr" rid="B22">Fitton et al., 2003</xref>; <xref ref-type="bibr" rid="B74">Momme et al., 2003</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B65">Maclennan, 2008</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B47">Jakobsson and Johnson, 2012</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and Sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al., 2016</xref>). Fagradalsfjall whole rock (medium blue triangles) and glass (open triangles) data from <xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref> and <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g008.tif"/>
</fig>
<p>Overall, the Undirhl&#xed;&#xf0;ar ridge samples are tholeiitic basalts similar in major element composition to other lavas from the Reykjanes Peninsula (<xref ref-type="bibr" rid="B48">Jakobsson et al., 1978</xref>; <xref ref-type="bibr" rid="B8">Condomines et al., 1983</xref>; <xref ref-type="bibr" rid="B42">Hemond et al., 1988</xref>; <xref ref-type="bibr" rid="B41">Hemond et al., 1993</xref>; <xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B92">Skovgaard et al., 2001</xref>; <xref ref-type="bibr" rid="B22">Fitton et al., 2003</xref>; <xref ref-type="bibr" rid="B74">Momme et al., 2003</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B65">Maclennan, 2008</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B47">Jakobsson and Johnson, 2012</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and Sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al., 2016</xref>). Reykjanes Peninsula samples span a slightly wider range in MgO compared to Undirhl&#xed;&#xf0;ar ridge (<xref ref-type="fig" rid="F8">Figure 8</xref>). Like the Undirhl&#xed;&#xf0;ar compositional groups, the less- and more-enriched compositional groups of <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> are distinct in major elements. Namely, the less-enriched group shows lower MgO, K<sub>2</sub>O, and TiO<sub>2</sub> and higher SiO<sub>2</sub> and Fe<sub>2</sub>O<sub>3</sub> than the more-enriched group (<xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). Although we observe that our less-enriched samples are lower in K<sub>2</sub>O than our more-enriched samples, the other patterns identified by <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> do not apply to the Undirhl&#xed;&#xf0;ar ridge data. Our less-enriched samples are higher in TiO<sub>2</sub> and lower in SiO<sub>2</sub> compared to our more-enriched samples (<xref ref-type="fig" rid="F8">Figure 8</xref>). Our compositional groups span most of the range of MgO values (<xref ref-type="fig" rid="F9">Figure 9A</xref>) and show no correlation with FeO<sup>T</sup> (<xref ref-type="fig" rid="F9">Figure 9B</xref>).</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Trace element variations with symbols and colors as in <xref ref-type="fig" rid="F7">Figure 7.</xref> <bold>(A)</bold> La<sub>N</sub>/Sm<sub>N</sub> vs. MgO, <bold>(B)</bold> La<sub>N</sub>/Sm<sub>N</sub> vs. FeO<sup>T</sup>, <bold>(C)</bold> La<sub>N</sub>/Sm<sub>N</sub> vs. Zr/Y, and <bold>(D)</bold> 1/Y vs. Zr/Y for Undirhl&#xed;&#xf0;ar ridge. <bold>(E)</bold> La<sub>N</sub>/Sm<sub>N</sub> vs. Zr/Y and <bold>(F)</bold> Nb/Zr vs. Zr/Y for Undirhl&#xed;&#xf0;ar ridge, Reykjanes Peninsula, and the 2021 eruption of Fagradalsfjall. Arrows in <bold>(A)</bold> through <bold>(D)</bold> indicate the direction of trends caused by mixing and crystallization. Scatter in the data in <bold>(A, C)</bold> indicates variable extents of crystallization. The lack of correlation between trace element ratios and major element indicators of melting in <bold>(D)</bold> suggests mixing. Curves in <bold>(E, F)</bold> show mixing between two depleted mantle components (D1 and D2), the main basaltic plume component (&#x201c;E&#x201d; for Eldgj&#xe1;), and the alkalic component (&#x201c;S&#x201d; for Sn&#xe6;fellsnes) after (<xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>). Mantle compositions from (<xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>). Reykjanes Peninsula data (light blue circles), excluding picrites, from (<xref ref-type="bibr" rid="B108">Wood et al., 1979</xref>; <xref ref-type="bibr" rid="B6">Chauvel and H&#xe9;mond, 2000</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al, 2016</xref>). Fagradalsfjall data (triangles) from <xref ref-type="bibr" rid="B2">Bindeman et al. (2022)</xref> and <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al. (2022)</xref>. Error bars show 2 <inline-formula id="inf5">
<mml:math id="m5">
<mml:mrow>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> standard deviation.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g009.tif"/>
</fig>
<p>The Undirhl&#xed;&#xf0;ar ridge dataset shows positive correlations between LREE and incompatible trace element enrichment (<xref ref-type="fig" rid="F9">Figure 9</xref>). The more-enriched samples have higher incompatible trace element ratios (Zr/Y 3.6-4.0) compared to the less-enriched group (Zr/Y 3.1-3.6). The mixed samples have incompatible trace element ratios that fall between the more- and less-enriched groups. Undirhl&#xed;&#xf0;ar ridge samples overlap with enriched samples from the Reykjanes Peninsula, which encompass greater ranges in incompatible trace element ratios (<xref ref-type="bibr" rid="B108">Wood et al., 1979</xref>; <xref ref-type="bibr" rid="B6">Chauvel and H&#xe9;mond, 2000</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>; <xref ref-type="bibr" rid="B14">Eason and Sinton, 2015</xref>; <xref ref-type="bibr" rid="B37">Halld&#xf3;rsson et al., 2016</xref>).</p>
<p>The three compositional groups are correlated with spatial location along the ridge. Almost all of the more-enriched samples are found in the basal stratigraphic units at lower elevations in Undirhl&#xed;&#xf0;ar quarry. Mixed samples are the least abundant in the suite and most are located along the ridge between the quarries. The less-enriched group is the most abundant in the suite, found in the dykes and upper units in Undirhl&#xed;&#xf0;ar quarry, along the ridge, and heavily concentrated in Vatnsskar&#xf0; quarry. The single sample from the basal, weathered unit in Vatnsskar&#xf0; quarry is compositionally distinct from the rest of the suite with a much higher Nb/Zr ratio (<xref ref-type="fig" rid="F9">Figure 9</xref>).</p>
<p>Within the quarries, we observe patterns in trace element compositions related to lithostratigraphic units. Almost all of the Vatnsskar&#xf0; quarry extrusive samples belong to the less-enriched group; the exceptions are two mixed-group samples (a bomb from a tuff breccia unit and a single pillow lava). Within the less-enriched extrusive units, we observe a shift in trace element ratios that correlates with a stratigraphic break between exposures from north to south. Pillow lavas in the north wall show identically low values of La<sub>N</sub>/Sm<sub>N</sub> (1.20). Pillow lavas in the other Vatnsskar&#xf0; quarry exposures show a range of La<sub>N</sub>/Sm<sub>N</sub> values that encompasses most of the range of the less-enriched suite (1.21&#x2013;1.27). The transition between north wall and the rest of the Vatnsskar&#xf0; quarry occurs over a distance of tens of meters. In general, Vatnsskar&#xf0; quarry intrusions show similar REE patterns and abundances to the pillows into which they intrude. However, in Undirhl&#xed;&#xf0;ar quarry, less-enriched dykes intrude through more-enriched pillow lavas in the lower stratigraphic units.</p>
</sec>
<sec id="s4-3">
<title>4.3 Sr-Nd-Pb isotopes</title>
<p>Undirhl&#xed;&#xf0;ar ridge radiogenic isotope compositions (Sr-Nd-Pb) encompass a narrow range that overlaps with isotopically enriched lavas from the Reykjanes Peninsula (<xref ref-type="table" rid="T2">Table 2</xref>; <xref ref-type="fig" rid="F10">Figure 10</xref>; <xref ref-type="bibr" rid="B89">Schilling, 1973</xref>; <xref ref-type="bibr" rid="B102">Sun and Jahn, 1975</xref>; <xref ref-type="bibr" rid="B8">Condomines et al., 1983</xref>; <xref ref-type="bibr" rid="B41">Hemond et al., 1993</xref>; <xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B22">Fitton et al., 2003</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). Within dataset limits, Undirhl&#xed;&#xf0;ar ridge is consistent with several isotopic relationships observed in other lavas from the Reykjanes Peninsula. First, radiogenic isotopes show positive correlations with trace element ratios (<xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). Although six of the seven Undirhl&#xed;&#xf0;ar ridge samples are from the less-enriched compositional group, the single more-enriched sample shows greater <sup>206</sup>Pb/<sup>204</sup>Pb (<xref ref-type="fig" rid="F10">Figure 10</xref>). Second, in their suite of historical Reykjanes Peninsula lavas, <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> observed that their less- and more-enriched compositional groups were nearly identical in radiogenic Nd and Sr compositions and showed linear correlations in Pb-Pb isotope space. With the exception of a pillow lava from the upper units at Undirhl&#xed;&#xf0;ar quarry (S-10-23), the Undirhl&#xed;&#xf0;ar ridge samples also overlap in <sup>143</sup>Nd/<sup>144</sup>Nd and <sup>87</sup>Sr/<sup>86</sup>Sr compositions and show linear Pb-Pb isotope patterns (<xref ref-type="fig" rid="F10">Figure 10</xref>). Third, <xref ref-type="bibr" rid="B81">Peate et al. (2009)</xref> observed that the Reykjanes Peninsula data plot below the Northern Hemisphere Reference Line (NHRL) for <sup>207</sup>Pb/<sup>204</sup>Pb (negative <inline-formula id="inf6">
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<sup>208</sup>Pb). All of the Undirhl&#xed;&#xf0;ar ridge samples show negative <inline-formula id="inf8">
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<sup>207</sup>Pb values, forming a linear trend that extends toward more positive values. The Undirhl&#xed;&#xf0;ar ridge samples also show <inline-formula id="inf9">
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<sup>208</sup>Pb values that are positive or near zero.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Isotope compositions with symbols and colors as in <xref ref-type="fig" rid="F7">Figure 7</xref>. <bold>(A)</bold> La<sub>N</sub>/Sm<sub>N</sub> vs. <sup>206</sup>Pb/<sup>204</sup>Pb, <bold>(B)</bold> <sup>143</sup>Nd/<sup>144</sup>Nd vs. <sup>87</sup>Sr/<sup>86</sup>Sr, <bold>(C)</bold> <sup>207</sup>Pb/<sup>204</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb, <bold>(D)</bold> <sup>208</sup>Pb/<sup>204</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb, <bold>(E)</bold> <inline-formula id="inf10">
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<sup>207</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb, <bold>(F)</bold> <inline-formula id="inf11">
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<sup>208</sup>Pb vs. <sup>206</sup>Pb/<sup>204</sup>Pb. The more enriched Undirhl&#xed;&#xf0;ar ridge sample shows higher <sup>206</sup>Pb/<sup>204</sup>Pb than the less enriched samples. Curves in <bold>(B)</bold> through <bold>(F)</bold> show mixing between mantle components defined in <xref ref-type="fig" rid="F9">Figure 9</xref> (<xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>). Mantle compositions from (<xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>). <inline-formula id="inf12">
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<sup>207</sup>Pb and <inline-formula id="inf13">
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<sup>208</sup>Pb are 100 x the vertical deviations from the Northern Hemisphere Reference Line (after Hart, 1984; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>). Undirhl&#xed;&#xf0;ar ridge data fall within the fields defined by the mixing curves, forming linear trends on Pb-isotope plots <bold>(C&#x2013;F)</bold>. Undirhl&#xed;&#xf0;ar ridge samples overlap with the more isotopically-enriched Reykjanes Peninsula data. Reykjanes Peninsula data (light blue circles), excluding picrites, from (<xref ref-type="bibr" rid="B89">Schilling, 1973</xref>; <xref ref-type="bibr" rid="B102">Sun and Jahn, 1975</xref>; <xref ref-type="bibr" rid="B8">Condomines et al., 1983</xref>; <xref ref-type="bibr" rid="B41">Hemond et al., 1993</xref>; <xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B22">Fitton et al., 2003</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). Fagradalsfjall data (triangles) from (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). Error bars show 2 <inline-formula id="inf14">
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</inline-formula> error.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g010.tif"/>
</fig>
<p>On Pb-Pb isotope plots, the less-enriched Undirhl&#xed;&#xf0;ar ridge samples create a linear array (<xref ref-type="fig" rid="F10">Figure 10</xref>). The ends of the linear array are bracketed by samples from Vatnsskar&#xf0; quarry, with the least isotopically enriched sample from the southern end and the most isotopically enriched sample from &#x3c;1&#xa0;km away in the northern end. Samples from the upper stratigraphic units of Undirhl&#xed;&#xf0;ar quarry fall between the Vatnsskar&#xf0; quarry samples. The single sample from the more-enriched group represents the lower stratigraphic units in Undirhl&#xed;&#xf0;ar quarry. Although this sample clusters with the less-enriched samples on a plot of <sup>143</sup>Nd/<sup>144</sup>Nd vs. <sup>87</sup>Sr/<sup>86</sup>Sr, it falls below the linear trend defined by the Vatnsskar&#xf0; endmembers Pb-Pb isotope plots. The more-enriched sample also has the most negative <inline-formula id="inf16">
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<sup>208</sup>Pb values in the sample suite.</p>
</sec>
<sec id="s4-4">
<title>4.4 Volatile concentrations</title>
<p>Water concentrations for Undirhl&#xed;&#xf0;ar ridge were analyzed from fresh glass chips that showed vitreous surface textures, sparse plagioclase microlites, and vesicularity &#x3c;20% (<xref ref-type="table" rid="T3">Table 3</xref>; <xref ref-type="fig" rid="F11">Figure 11</xref>). Water speciation was not determined for most samples, so measurements represent total water (H<sub>2</sub>O<sub>t</sub>) concentration. FTIR mapping reveals homogeneous water concentrations within the glass. Highest water concentrations are observed around fractures and vesicles, which were avoided during data acquisition (<xref ref-type="sec" rid="s12">Supplementary Figure SA1</xref>). Only five of the 22 samples produced a detectable peak CO<sub>2</sub> peak at the 2,360&#xa0;cm<sup>-1</sup> position, indicating that measured CO<sub>2</sub> values are at or below detection limits (&#x3c; 20&#xa0;ppm).</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Water concentrations in glass samples from Undirhl&#xed;&#xf0;ar ridge. Symbols and colors as in <xref ref-type="fig" rid="F7">Figure 7</xref>. <bold>(A)</bold> Elevation vs. H<sub>2</sub>O (wt.%) for pillow lavas from this study. H<sub>2</sub>O generally decreases with increasing elevation. More-enriched samples show higher H<sub>2</sub>O concentrations than less-enriched samples. Error bars show 2 <inline-formula id="inf18">
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</inline-formula> standard deviation. Elevations determined from DEM as described in text. <bold>(B)</bold> Calculated H<sub>2</sub>O saturation pressures (MPa) assuming complete CO<sub>2</sub> degassing. Error bars based on 2 <inline-formula id="inf19">
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</inline-formula> H<sub>2</sub>O values. Solid line shows glaciostatic pressures for 200&#xa0;m thick ice. <bold>(C)</bold> H<sub>2</sub>O (wt.%) vs. Ce (ppm). Solid line shows H<sub>2</sub>O/Ce ratio for less-enriched samples (153 &#xb1; 24) <bold>(D)</bold> Location of nine glassy rims sampled from a cluster of adjacent pillows in Undirhl&#xed;&#xf0;ar quarry. Four samples (0613UAH06-09) were collected from the same pillow. Hammer is 42&#xa0;cm long. Samples shown in <bold>(D)</bold> overlap at the lowest elevations on <bold>(A)</bold>.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g011.tif"/>
</fig>
<p>To check if water concentrations represent magmatic conditions, we measured water speciation when possible. Only five samples produced measurable H<sub>2</sub>O<sub>m</sub> peaks at the 1,630&#xa0;cm<sup>-1</sup> band (<xref ref-type="table" rid="T3">Table 3</xref>). Secondary hydration enriches volcanic glasses in H<sub>2</sub>O<sub>m</sub> (e.g., <xref ref-type="bibr" rid="B69">Mcintosh et al., 2017</xref>). Most samples did not show measurable H<sub>2</sub>O<sub>m</sub>. For the few samples that showed measurable peaks, H<sub>2</sub>O<sub>m</sub>/H<sub>2</sub>O<sub>t</sub> ratios are less than the values found in experiments of basaltic glasses quenched at high temperatures (<xref ref-type="bibr" rid="B12">Dixon et al., 1995</xref>), suggesting that the analzyed glasses in this study did not experience secondary hydration (e.g., <xref ref-type="bibr" rid="B88">Sano and Yamashita, 2019</xref>). To determine if water concentrations from a single pillow represent the conditions for surrounding lavas, we conducted detailed sampling of adjanced pillow lavas and assessed small-scale (&#x3c; 1&#xa0;m) spatial variations in H<sub>2</sub>O<sub>t</sub> concentrations (<xref ref-type="fig" rid="F11">Figure 11</xref>). The four samples taken from the same pillow in Undirhl&#xed;&#xf0;ar quarry have measured H<sub>2</sub>O<sub>t</sub> concentrations that are similar within analytical error (<xref ref-type="table" rid="T3">Table 3</xref>). Likewise, the samples from the cluster of adjacent pillows are within analytical error of one another. Therefore, we find that the H<sub>2</sub>O<sub>t</sub> data measured by FTIR on individual pillow lavas are reproducible and representative of the unit in which the pillow lava was erupted.</p>
<p>Water concentrations for Undirhl&#xed;&#xf0;ar ridge span a wide range (0.16&#x2013;0.40&#xa0;wt.%) and generally decrease with increasing elevation (<xref ref-type="fig" rid="F11">Figure 11</xref>). We observe the greatest range of water contents (0.19&#x2013;0.36&#xa0;wt.%) at &#x223c;145&#xa0;m elevation. Water concentrations are most variable over the smallest spatial scales in Undirhl&#xed;&#xf0;ar quarry, where contents change from 0.23&#x2013;0.40&#xa0;wt.% H<sub>2</sub>O over walls that are &#x223c;50&#xa0;m high and &#x223c;150&#xa0;m long. Conversely, Vatnsskar&#xf0; quarry is dominated by less-enriched samples and shows a narrower range of H<sub>2</sub>O concentrations (0.24&#x2013;0.31&#xa0;wt.%), despite exposing walls that are taller (&#x223c;80&#xa0;m) and longer (&#x223c;750&#xa0;m).</p>
<p>Calculated water saturation pressures mimic the pattern of water concentrations (<xref ref-type="fig" rid="F11">Figure 11</xref>). Assuming complete CO<sub>2</sub> degassing, saturation pressures range from 0.3&#xa0;MPa to 1.6&#xa0;MPa. Using densities of 0.917&#xa0;g/cm<sup>3</sup> for ice and 1.000&#xa0;g/cm<sup>3</sup> for water, saturation pressures correspond to ice thicknesses up to 178 &#xb1; 33&#xa0;m and water depths up to 163 &#xb1; 31&#xa0;m. The decrease in saturation pressure with elevation generally follows a linear trend predicted by glaciostatic conditions under 200&#xa0;m-thick ice. However, most less-enriched samples between &#x223c;120&#xa0;m and &#x223c;180&#xa0;m in elevation fall below the glaciostatic curve.</p>
<p>The significant decrease in water contents starting at &#x223c;120&#xa0;m in elevation is correlated with a shift in trace element ratios (<xref ref-type="fig" rid="F11">Figure 11</xref>). More-enriched samples show greater H<sub>2</sub>O concentrations (average 0.37 &#xb1; 0.03&#xa0;wt.%, <italic>n</italic> &#x3d; 12) and less-enriched samples show lower H<sub>2</sub>O concentrations (average 0.25 &#xb1; 0.04&#xa0;wt.%, <italic>n</italic> &#x3d; 25). To examine the influence of degassing and magma differentiation on water contents, we compared H<sub>2</sub>O to Ce, a trace element that behaves similarly during magmatic processes (e.g., <xref ref-type="bibr" rid="B88">Sano and Yamashita, 2019</xref>). Water contents show a positive linear correlation with Ce. Less-enriched samples show a wide range in H<sub>2</sub>O/Ce ratios (average 153 &#xb1; 24, <italic>n</italic> &#x3d; 20). Samples from the mixed and more-enriched groups fall along a line with a slope that matches the H<sub>2</sub>O/Ce ratio of the less-enriched group.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s5">
<title>5 Discussion</title>
<sec id="s5-1">
<title>5.1 Magma generation and evolution</title>
<p>Compositional data indicate that mantle source and crustal processes both play essential roles in the formation and evolution of magma at Undirhl&#xed;&#xf0;ar ridge. Some variability in major element and REE patterns is consistent with the effects of crystallization and crystal accumulation (<xref ref-type="fig" rid="F7">Figures 7</xref>, <xref ref-type="fig" rid="F8">8</xref>). This is demonstrated in the major element trends of increasing FeO<sup>T</sup>, TiO<sub>2</sub>, and Na<sub>2</sub>O and decreasing Al<sub>2</sub>O<sub>3</sub> and CaO with decreasing MgO. The most evolved samples in the suite show the greatest REE abundances. The effects of crystal accumulation are apparent in olivine-phyric lavas that show elevated MgO and plagioclase-phyric lavas that show elevated Al<sub>2</sub>O<sub>3</sub> and positive Eu anomalies.</p>
<p>The observed compositional variations are consistent with thermodynamic models of fractional crystallization (<xref ref-type="fig" rid="F7">Figures 7</xref>, <xref ref-type="fig" rid="F8">8</xref>). Isobaric shallow fractional crystallization of a primitive parent magma from the mixed group shows a typical basaltic crystallization sequence of ol, ol &#x2b; pl, and ol &#x2b; pl &#x2b; cpx. The resulting LLD forms downward curving paths in Al<sub>2</sub>O<sub>3</sub> and CaO and linear upward paths in FeO<sup>T</sup>, TiO<sub>2</sub>, and Na<sub>2</sub>O that follow major element patterns. REE abundances can also be explained by varying degrees of crystallization, which do not affect the slope of REE patterns but cause relative REE abundances to increase in more evolved lavas. The higher REE abundances of the mixed samples can be generated by up to 30% crystallization. Much of the scatter in major element and REE patterns can be explained by variable degrees of crustal-level crystallization.</p>
<p>While all of the Undirhl&#xed;&#xf0;ar ridge magmas evolved in the crust, the samples cannot be related to each other by cooling of a single parent magma. This is demonstrated by the scatter in major and trace elements, particularly in SiO<sub>2</sub>, K<sub>2</sub>O, K<sub>2</sub>O/TiO<sub>2</sub>, and La<sub>N</sub>/Sm<sub>N</sub> at a given value of MgO (<xref ref-type="fig" rid="F8">Figures 8</xref>, <xref ref-type="fig" rid="F9">9</xref>). More-enriched samples follow major element trends that parallel the modeled LLD at lower values of TiO<sub>2</sub>, FeO<sup>T</sup>, and Al<sub>2</sub>O<sub>3</sub> and higher values of CaO, suggesting a different parent magma composition. Separate parent magmas are also indicated by modeled liquidus phases. For parent magmas from the from the mixed group (VAT-SA-13-07) and the less-enriched group (16MP02), the modeled liquidus phase is olivine; for a parent magma from the more-enriched group (S-10-18), the liquidus phase is clinopyroxene. In <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>, we argued that the less-enriched and more-enriched groups follow separate LLD and proposed a model for crystallization in separate crustal reservoirs. At that time, we had not identified the mixed samples from the ridge. Our expanded dataset confirms that the Undirhl&#xed;&#xf0;ar ridge magmas cannot be derived from crystallization of a single parent magma in the same melt reservoir. The major and trace element variability are consistent with variations in mantle melting or source composition underlying Undirhl&#xed;&#xf0;ar ridge.</p>
<p>In <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref>, we argued that the compositional variations in Undirhl&#xed;&#xf0;ar quarry could be explained by mixing of mantle melts extracted from over a range of depths, but our expanded study shows that the compositional groups are likely related to mantle heterogeneity. In our expanded dataset, we observe no correlation between La<sub>N</sub>/Sm<sub>N</sub> and FeO<sup>T</sup> (<xref ref-type="fig" rid="F9">Figure 9</xref>), a major element indicator of degree and pressure of melting. Undirhl&#xed;&#xf0;ar ridge samples also have smooth REE patterns with no difference in degree of HREE fractionation between the compositional groups (<xref ref-type="fig" rid="F7">Figure 7</xref>), suggesting a relatively constant degree of melting from shallow depths. Instead of variations in melting of a homogeneous mantle source, the variability in Pb isotopes in our expanded dataset demonstrate that the source mantle cannot be a single homogeneous composition.</p>
<p>Mantle source heterogeneity must influence the compositional variability in the Undirhl&#xed;&#xf0;ar ridge magmas. Variable enrichment in incompatible elements and radiogenic isotopes in Iceland have been attributed to aggregation of melts from heterogeneous mantle that are extracted over a range of depths (<xref ref-type="bibr" rid="B40">Hanan and Schilling, 1997</xref>; <xref ref-type="bibr" rid="B6">Chauvel and H&#xe9;mond, 2000</xref>; <xref ref-type="bibr" rid="B39">Hanan et al., 2000</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B101">Stracke et al., 2003</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B103">Thirlwall et al., 2006</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>; <xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>). On the Reykjanes Peninsula, linear isotopic trends and correlations between isotopes and trace element indicators of enrichment have been interpreted as near-binary mixing between mantle sources (<xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). The presence of up to six mantle endmembers has been suggested by previous workers (<xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). The nature and origin of the mantle heterogeneity is discussed by numerous workers, but many posit that there are enriched components related to the plume and the alkalic source and depleted components related to the ambient mantle (<xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>). Here, we use simple binary mixing equations (<xref ref-type="bibr" rid="B59">Langmuir et al., 1978</xref>) to calculate mixing curves among four endmembers: two enriched mantle compositions are defined by the enriched plume (represented by Eldgja (E) and alkalic Snaefellsnes (S) lavas) and two depleted mantle sources that are similarly depleted in trace elements but show different isotopic compositions (<xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B104">Thirlwall et al., 2004</xref>; <xref ref-type="bibr" rid="B57">Kokfelt et al., 2006</xref>).</p>
<p>The Undirhl&#xed;&#xf0;ar Pb-Pb isotope data create a linear array that we interpret as mixing between two mantle source compositions. The mixing trends are best seen on the &#x2206;<sup>207</sup>Pb and <sup>207</sup>Pb/<sup>204</sup>Pb plots, where the mixing lines between the Eldgj&#xe1; and depleted endmembers are most distinct (<xref ref-type="fig" rid="F10">Figure 10</xref>). The Undirhl&#xed;&#xf0;ar data form a binary mixing line between two mantle compositions that are intermediate between the endmembers. The less-enriched samples trend toward one endmember that is a mix of Eldgj&#xe1; and D2. The more-enriched sample trends toward the second endmember that is a mix between Eldgj&#xe1; and D1. Because the Sn&#xe6;fellsnes endmember is itself intermediate between Eldgj&#xe1; and D1, it is difficult to determine the role of the Sn&#xe6;fellsnes source using the isotope data. The location of Sn&#xe6;fellsnes on a mixing line between Eldgja and D1 suggests that the alkalic source may make a bigger contribution to the more-enriched samples. This is consistent with observations on plots of trace element ratios, where binary mixing creates hyperbolas whose curvatures are determined by a ratio of the endmember denominators (<xref ref-type="fig" rid="F9">Figure 9</xref>). On plots of La<sub>N</sub>/Sm<sub>N</sub> versus Zr/Y and Nb/Zr versus Zr/Y, all of the Undirhl&#xed;&#xf0;ar ridge data fall within a multi-component mixing array defined by the Eldgj&#xe1;, Sn&#xe6;fellsnes, and depleted mantle components. The more-enriched samples fall toward an enriched endmember that is intermediate between Sn&#xe6;fellsnes and the depleted endmembers. The less-enriched samples fall toward an endmember that is intermediate between the Eldgj&#xe1; and depleted endmembers.</p>
<p>To test whether a heterogeneous mantle source can produce the range of La<sub>N</sub>/Sm<sub>N</sub> values that we observe in the Undirhl&#xed;&#xf0;ar ridge data, we modeled polybaric continuous melting for two mantle sources under the same conditions using AlphaMelts. One mantle source is the depleted mantle (DMM) from <xref ref-type="bibr" rid="B110">Workman and Hart (2005)</xref>. The other mantle source is DMM that has been enriched in pyroxenite (<xref ref-type="bibr" rid="B58">Koornneef et al., 2012</xref>). Melts from the two mantle sources reproduce REE patterns observed at Undirhl&#xed;&#xf0;ar ridge (<xref ref-type="fig" rid="F7">Figure 7</xref>). The depleted mantle melt overlaps with REE for the less-enriched group. The melt from the DMM enriched with pyroxenite overlaps with REE for the more-enriched group. This suggests that the difference in La<sub>N</sub>/Sm<sub>N</sub> ratio can be generated by different mantle source compositions that melt under similar conditions. To generate the trace element trends with comparatively constant degrees of melting, the more-enriched samples require a higher amount of the enriched mantle component, which we also observe in our isotopic and trace element ratio data.</p>
<p>Our understanding of the nature of the magma plumbing system can be informed by the relationship between crystallization and mixing of heterogeneous mantle melts. Because the curvature of a mixing hyperbola in plots of incompatible trace element ratios depends on the denominators of the endmembers, mixing should result in a linear array on a plot of 1/Y versus Zr/Y (<xref ref-type="bibr" rid="B59">Langmuir et al., 1978</xref>). Undirhl&#xed;&#xf0;ar ridge data fall off a linear array as a result of variable degrees of crystallization, with the most evolved lavas extending to the lowest values of 1/Y (<xref ref-type="fig" rid="F9">Figure 9D</xref>). Mixing must have occurred prior to crystallization. This is consistent with major elements trends, where the compositional groups must have had parent magma compositions that differed in CaO, SiO<sub>2</sub>, and K<sub>2</sub>O (<xref ref-type="fig" rid="F8">Figure 8</xref>). The magma plumbing system preserves mantle source signatures on small spatial scales. Within the area exposed by Undirhl&#xed;&#xf0;ar quarry, we observe more-enriched lavas intruded by less-enriched magmas. Vatnsskar&#xf0; quarry is dominated by the less-enriched group but shows geographic shifts in LREE enrichment within the northernmost exposures. The mixed group is the most evolved, suggesting that it was cooled to greater degrees. Because this compositional variability is preserved, even at the local scale, there must be no large-scale efficient mixing processes to homogenize the magma. We propose that the magmatic plumbing system consisted of separately evolving crustal melt bodies and that original model from <xref ref-type="bibr" rid="B83">Pollock et al. (2014)</xref> extends to the entire ridge.</p>
</sec>
<sec id="s5-2">
<title>5.2 Paleo-ice conditions</title>
<p>Paleo-ice conditions for Undirhl&#xed;&#xf0;ar ridge are constrained by the measurements of water in quenched glassy pillow rims. Glass textures and variations in volatile content show evidence of volatile saturation and degassing. The glasses show abundant vesicles, suggesting degassing of a volatile saturated magma (<xref ref-type="bibr" rid="B106">Tuffen et al., 2010</xref>). Because CO<sub>2</sub> degasses more readily than H<sub>2</sub>O, and measured CO<sub>2</sub> concentrations are at or below the detection limits, CO<sub>2</sub> was essentially entirely degassed when the glasses were quenched (<xref ref-type="bibr" rid="B11">Dixon and Stolper, 1995</xref>). Although it is possible that vesicles represent predominately CO<sub>2</sub> bubbles that formed before H<sub>2</sub>O degassing, samples with low H<sub>2</sub>O/Ce ratios indicate that H<sub>2</sub>O degassing has occurred in the Undirhl&#xed;&#xf0;ar suite. Post-emplacement hydration has not affected H<sub>2</sub>O contents presented in this study. Although higher H<sub>2</sub>O concentrations were observed in the fractures, we avoided fractures while measuring. The lack of measurable H<sub>2</sub>O<sub>m</sub> peaks and low H<sub>2</sub>O<sub>m</sub>/H<sub>2</sub>O<sub>t</sub> ratios suggest that molecular water was not enriched by secondary hydration. Thus, we infer that the Undirhl&#xed;&#xf0;ar ridge magmas degassed prior to quenching and that H<sub>2</sub>O concentrations are indicative of pressures during emplacement.</p>
<p>Calculated saturation pressures suggest that Undirhl&#xed;&#xf0;ar ridge formed within ice at least 200&#xa0;m thick. The range of water contents and emplacement pressures at Undirhl&#xed;&#xf0;ar ridge is similar to those observed in other subglacial edifices on the Reykjanes Peninsula (<xref ref-type="bibr" rid="B78">Nichols et al., 2002</xref>; <xref ref-type="bibr" rid="B90">Schopka et al., 2006</xref>). At Helgafell, a Pleistocene-age hyaloclastite ridge &#x223c;1&#xa0;km east of this study, ice thickness was estimated to be &#x223c;500&#xa0;m at the time of eruption, although volatile contents indicated lower emplacement pressures caused by meltwater drainage and ice subsidence (<xref ref-type="bibr" rid="B90">Schopka et al., 2006</xref>). Estimates of ice thickness on the Reykjanes Peninsula during the last glacial maximum range from 250&#xa0;m to 500&#xa0;m (<xref ref-type="bibr" rid="B19">Einarsson et al., 1988</xref>; <xref ref-type="bibr" rid="B62">Licciardi et al., 2007</xref>; <xref ref-type="bibr" rid="B60">Le Breton et al., 2010</xref>; <xref ref-type="bibr" rid="B80">Patton et al., 2017</xref>).</p>
<p>A major change in water contents at Undirhl&#xed;&#xf0;ar ridge correlates with a shift in the magmatic system. The more-enriched lavas show higher H<sub>2</sub>O contents than the less-enriched lavas, which is likely due to differences in magma composition. The geochemical groups have similar H<sub>2</sub>O/Ce ratios, indicating that the mixed and more-enriched samples have not experienced more degassing than the less-enriched samples. The positive linear correlation between H<sub>2</sub>O and Ce suggests that water is behaving as an incompatible element. We interpret the shift from wetter, more-enriched lavas to less-wet, less-enriched lavas as a result of a shift in melts from a more enriched mantle to a more depleted mantle.</p>
<p>However, within the less-enriched group, lavas show variable extents of degassing. Less-enriched lavas with lower H<sub>2</sub>O/Ce ratios have undergone more degassing than those with higher values. Many of the less-enriched samples show saturation pressures lower than expected for glaciostatic conditions. These less-enriched lavas show wide variations in water contents, saturation pressures, and H<sub>2</sub>O/Ce ratios over short distances (&#x223c;100&#xa0;s of m) at mid-elevations along the ridge. For this group of less-enriched lavas, hydrologic conditions were dynamic during emplacement.</p>
<p>Ice conditions varied during construction of Undirhl&#xed;&#xf0;ar ridge. Saturation pressures suggest that Undirhl&#xed;&#xf0;ar ridge erupted under thin ice, similar to conditions at Gr&#xed;msv&#xf6;tn and Eyjafjallaj&#xf6;kull (<xref ref-type="bibr" rid="B67">Magn&#xfa;sson et al., 2012</xref>). The initial summit eruption in the 2010 Eyjafjallaj&#xf6;kull event occurred under &#x223c;200&#xa0;m thick ice, leading to high subglacial water pressures associated with localized glacier uplift and accumulation of meltwater in an ice cauldron (<xref ref-type="bibr" rid="B67">Magn&#xfa;sson et al., 2012</xref>). Accumulated water was released in supraglacial flooding that lowered water levels and reduced emplacement pressures (<xref ref-type="bibr" rid="B67">Magn&#xfa;sson et al., 2012</xref>). Within days, flank eruptions extending &#x223c;1&#xa0;km from the summit experienced different hydrologic conditions. Flank eruptions occurred on steeper slopes under thinner (50&#x2013;100&#xa0;m thick) ice, resulting in rapid drainage of meltwater through high volume, short duration flood events (<xref ref-type="bibr" rid="B67">Magn&#xfa;sson et al., 2012</xref>) that created localized water-drained areas with low emplacement pressures (<xref ref-type="bibr" rid="B109">Woodcock et al., 2016</xref>). The dynamic variability in hydrologic conditions at Eyjafjallaj&#xf6;kull over km-long spatial scales and days-long temporal scales is consistent with the variable extents of degassing observed in the less-enriched lavas that comprise the bulk of the ridge at Undirhl&#xed;&#xf0;ar. Saturation pressures return to values consistent with glaciostatic conditions in the upper elevations of Undirhl&#xed;&#xf0;ar ridge, suggesting that the upper portions of the edifice were emplaced beneath ice or in a stable englacial lake. The presence of ice at the upper reaches of the ridge is also illustrated by the diamict that drapes over Vatnsskar&#xf0; quarry, which is consistent with a recovery or return of ice after eruptions ceased.</p>
</sec>
<sec id="s5-3">
<title>5.3 Model for undirhl&#xed;&#xf0;ar ridge construction</title>
<p>Our detailed study of the compositions and lithostratigraphic relationships allows us to propose several revisions to the existing models for the construction of glaciovolcanic fissure-fed eruptions. We observe a full vertical section of Undirhl&#xed;&#xf0;ar ridge in Vatnsskar&#xf0; quarry. The basal contact of the ridge lies uncomformably over older palagonitized tuff-breccia, pillow lavas and local glaciofluvial deposits. The sandy and muddy diamict units draping over the central and southern walls of the quarry, in addition to the remnant till deposits scattered along the length of the ridge top, suggest that the pillow ridge was covered by a glacier after the eruption. We infer that the &#x223c;3&#xa0;km length of the ridge was emplaced in an ice-confined environment through a series of fissure eruptions.</p>
<p>Eruptions were fed by multiple vents (<xref ref-type="fig" rid="F12">Figure 12</xref>). Plunges reveal that many of the pillows were erupted from vents that parallel the strike of the ridge, but exposures in quarry walls also show eruptive vents and pillow emplacement that were ridge-perpendicular (<xref ref-type="fig" rid="F6">Figure 6</xref>). An example of this is the north wall of the Vatnsskar&#xf0; quarry, in which the plunge directions in the north wall pillows suggest that this is an isolated &#x201c;nose&#x201d; of pillows that erupted off the main ridge axis. The north wall pillow lavas are also compositionally distinct from the other eruptive units in Vatnsskar&#xf0; quarry, suggesting that the north wall pillows form their own distinct pillow mound within the broader ridge structure.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Schematic cartoon showing the important, newly identified components of tindar ridge construction. The main fissure system produces pillow lavas (green) that generally plunge downslope perpendicular to the axis of the fissure. Subsidiary, smaller fissures parallel but adjacent to main fissure produce flank pillow mounds that are eventually incorporated into the overall ridge structure. Locally fissures open orthogonal to the main fissure and produce secondary pillow ridges that form perpendicular to the overall fissure structure. Intrusions (red) within the ridge system are part of the lava distributary system within the ridge.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g012.tif"/>
</fig>
<p>Within the growing edifice, magma was transported in a complex intrusive system (<xref ref-type="fig" rid="F12">Figure 12</xref>). Some dykes are ridge-parallel and cut through pillows that belong to a different compositional group, suggesting that dykes played an important role in transporting magma along-axis. Irregular intrusions are exposed in both Undirhl&#xed;&#xf0;ar ridge and in Vatnsskar&#xf0; quarry. Some have open tube structures and others show evidence of collapsed tube structures, such as shelves and lava drips that are typical of lava tubes in subaerial and glaciovolcanic systems (<xref ref-type="bibr" rid="B45">Hungerford et al., 2014</xref>). The irregular and massive intrusions frequently are the same composition as the lavas into which they intrude. We interpret these to be part of the shallow plumbing system of the growing pillow edifice, which were important for distributing magma locally.</p>
<p>Emplacement conditions and the magma source changed as the edifice grew. Eruptions forming the lowermost units were fed by more-enriched mantle melts emplaced into a &#x223c;200&#xa0;m thick ice sheet under glaciostatic conditions. Eruptions forming the bulk of the ridge were fed by less-enriched mantle melts. These less-enriched lavas degassed to variable extents under dynamically shifting hydrologic conditions along the length of the ridge. Less-enriched melts continued to feed eruptions forming the uppermost units, where emplacement conditions were glaciostatic.</p>
<p>We originally proposed a sequence of events for the construction of the volcanic succession exposed at Undirhl&#xed;&#xf0;ar quarry that included multiple eruptive and intrusive phases (<xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>). This study expands on previous work by adding detailed lithostratigraphic mapping of Vatnskar&#xf0; quarry, additional major and trace element data, and new volatile and isotope analyses. Using the field relationships and geochemical findings from this study, we extend the model to the formation of Undirhl&#xed;&#xf0;ar ridge that is summarized as follows (<xref ref-type="fig" rid="F13">Figure 13</xref>):<list list-type="simple">
<list-item>
<p>1. The entire ridge was emplaced upon a glaciated surface of pre-existing glaciovolcanic deposits, presumably from an early glaciation. Limited exposures show palagonitized tuff-breccia unconformably overlain by discontinuous gravels.</p>
</list-item>
<list-item>
<p>2. The lower units at the northern extent of Undirhl&#xed;&#xf0;ar ridge were emplaced in an initial eruptive phase under ice at least &#x223c;200&#xa0;m thick. These lavas (Lp1-2) were fed from a cooling crustal magma reservoir supplied by melts from a more-enriched mantle source. The eruptive events were mainly effusive, punctuated by pauses and collapse events that deposited stratified layers of vitric tuff and tuff-breccia at the fronts of advancing pillow mounds. At both quarries the lower two pillow units show similar relationships (<xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>; <xref ref-type="fig" rid="F10">Figure 10</xref>) and are overlain locally by lapilli tuff and tuff-breccia. Intrusions are also present in Lp2 at both quarries, although in Vatnskar&#xf0; the within ridge plumbing is better exposed.</p>
</list-item>
<list-item>
<p>3. The bulk of the ridge was emplaced in subsequent eruptive phases under dynamically changing ice conditions. At Undirlhi&#xf0;ar quarry this phase is mainly preserved as Lp3 (<xref ref-type="bibr" rid="B83">Pollock et al., 2014</xref>) but in Vatnskar&#xf0; quarry the ridge is higher and shows the emplacement of three more pillow units (Lp3-Lp5). This phase was triggered by the injection of melts from a less-enriched mantle source into the crust. In this primary ridge-building phase, separate crustal melt reservoirs fed multiple eruptive vents along the fissure. Draining melt channels and an ephemeral englacial lake created rapidly changing emplacement pressures along the length of the ridge. Eruption style shifted between effusive and explosive, combining with localized pauses in volcanic activity to deposit lenses of tephra between growing pillow mounds. Magma was transported to the margins of the growing edifice through an internal plumbing system of shallow, irregularly shaped intrusions.</p>
</list-item>
<list-item>
<p>4. A final eruptive phase smaller than the others emplaced the final pillow lava unit (Lp6) as well as dykes near the center of the ridge. These lavas were fed by a crustal melt reservoir containing mixed magma that had cooled and crystallized to a greater degree in the crust.</p>
</list-item>
<list-item>
<p>5. The eruption ceased and the edifice was covered by ice, producing the capping layer of glaciofluvial diamict.</p>
</list-item>
</list>
</p>
<fig id="F13" position="float">
<label>FIGURE 13</label>
<caption>
<p>Formation sequence for Undirhli&#xf0;ar tindar based on exposures in Vatnskar&#xf0; quarry. Panels are labeled with main eruption events. Unit colors are the same as in the legend for <xref ref-type="fig" rid="F3">Figure 3</xref>.</p>
</caption>
<graphic xlink:href="feart-11-1095135-g013.tif"/>
</fig>
<p>By sampling and mapping Undirhl&#xed;&#xf0;ar ridge at a high-resolution, we are able to test general models for the construction of tindar ridges. Our study confirms some aspects of the theoretical models, namely, that 1) pillow-dominated tindar ridges are built through a complex sequence of eruptive phases from multiple eruptive vents that show changing eruptive styles (effusive vs. explosive) and 2) hydrologic conditions are dynamic on small spatial scales. Our study also adds new insights into the enigmatic aspects of the theoretical models, namely, that shallow-level intrusions are important to distributing lava within the growing pillow edifice.</p>
</sec>
<sec id="s5-4">
<title>5.4 Comparison to subaerial Fagradalsfjall eruption</title>
<p>The 2021&#x2013;22 eruptions at Fagradalsfjall, which is located on the volcanic system adjacent to the western side of Kr&#xfd;suv&#xed;k, allows us to use direct observations of a subaerial fissure eruption to surmise details that cannot be observed in subglacial environments. At Undirhl&#xed;&#xf0;ar ridge, pillow orientations and compositions provide evidence for multiple eruptive vents, but it is not possible to know the number or spacing of active vents. Variations in stratigraphic packages are consistent with numerous eruptive pulses, but it is difficult to determine the duration of the Undirhl&#xed;&#xf0;ar ridge eruption. Volcanic activity at Fagradalsfjall lasted for &#x223c;6&#xa0;months, followed by a &#x223c;2-week eruption nearly a year later (<xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). At least five eruptive vents opened along a &#x223c;2&#xa0;km long fissure segment (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>). Volcanic activity pulsated and eruption style shifted between effusive lava extrusion and more explosive fire fountaining (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). The resulting lava field covers an area of &#x223c;5&#xa0;km<sup>2</sup> with a DRE volume of &#x223c;0.1&#xa0;km<sup>3</sup> (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>) and an average estimated thickness of 30&#xa0;m (<xref ref-type="bibr" rid="B82">Pedersen et al., 2022</xref>) Like Fagradalsfjall, Undirhl&#xed;&#xf0;ar ridge was built by a moderately-sized eruption that occurred along a fissure segment on the order of 3&#x2013;4&#xa0;km long, and has an area of about 4.3&#xa0;km<sup>2</sup>. Pillow-dominated tindars like Undirhl&#xed;&#xf0;ar ridge are interpreted to be the result of short-duration, small-volume monogenetic events (<xref ref-type="bibr" rid="B47">Jakobsson and Johnson, 2012</xref>). Such events have been observed in modern glaciovolcanic eruptions at Eyjafjallaj&#xf6;kull (2010) and Gjalp (1996) (<xref ref-type="bibr" rid="B105">Thordarson and Larsen, 2007</xref>; <xref ref-type="bibr" rid="B36">Gudmundsson et al., 2012</xref>). Despite the difference in eruptive environments, the spatial and temporal scales of the Fagradalsfjall eruption may be similar to the tindar-building fissure eruption that constructed Undirhl&#xed;&#xf0;ar ridge.</p>
<p>Direct geophysical and petrological observations at Fagradalsfjall yield insights into the processes that initiated the Undirhl&#xed;&#xf0;ar ridge eruption. At Undirhl&#xed;&#xf0;ar ridge, lavas with different mantle source signatures were erupted sequentially from separate crustal melt reservoirs, suggesting that the main ridge-building event was triggered by injection of magma into the crustal plumbing system. At Fagradalsfjall, the eruption was fed from a lower crustal magma reservoir at near-Moho (&#x223c;15&#x2013;20&#xa0;km) depths, supplied with chemically variable melts from a heterogeneous mantle (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). Erupted lava compositions at Fagradalsfjall progressively transitioned to more enriched mantle melts (<xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>; <xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). The addition of enriched melts to a deep crustal magma reservoir may have caused a mixing event that initiated magma ascent and eruption (<xref ref-type="bibr" rid="B38">Halld&#xf3;rsson et al., 2022</xref>). In the months leading up to the Fagradalsfjall eruption, seismic swarms and surface inflation were attributed to subsurface magma migration (<xref ref-type="bibr" rid="B9">Cubuk-Sabuncu et al., 2021</xref>; <xref ref-type="bibr" rid="B26">Geirsson et al., 2021</xref>; <xref ref-type="bibr" rid="B91">Sigmundsson et al., 2022</xref>). At least a year prior to the geophysical signals of volcano-tectonic unrest, the deep magma chamber experienced a disequilibrium event (<xref ref-type="bibr" rid="B54">Kahl et al., 2022</xref>). Diffusion modeling of olivine and plagioclase crystals suggests that the onset of disequilibrium in the deep magma chamber was related to magma injection and mush disaggregation (<xref ref-type="bibr" rid="B54">Kahl et al., 2022</xref>). At both Fagradalsfjall and Undirhl&#xed;&#xf0;ar ridge, the supply of heterogeneous mantle melts to the deep parts of the magmatic system played a critical role in initiating eruptions (e.g., <xref ref-type="bibr" rid="B54">Kahl et al., 2022</xref>).</p>
<p>The relative locations of the Kr&#xfd;suv&#xed;k andFagradalsfjall volcanic systems allows us to comment on spatial variations in mantle composition under the Reykjanes Peninsula. <xref ref-type="bibr" rid="B2">Bindeman et al. (2022)</xref> identified at least three different mantle components in the Fagradalsfjall lavas and proposed a lateral gradient in degree of mantle enrichment, in the context of the &#x201c;plume sheath&#x201d; suggested by previous researchers (<xref ref-type="bibr" rid="B23">Fitton et al., 1997</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>). The laterally variable plume sheath model predicts that Kr&#xfd;suv&#xed;k should erupt lavas more enriched in incompatible trace elements and radiogenic isotopes (<xref ref-type="bibr" rid="B23">Fitton et al., 1997</xref>; <xref ref-type="bibr" rid="B55">Kempton et al., 2000</xref>; <xref ref-type="bibr" rid="B76">Murton et al., 2002</xref>; <xref ref-type="bibr" rid="B2">Bindeman et al., 2022</xref>). We find no evidence for a systematic change in mantle composition between Fagradalsfjall and Undirhl&#xed;&#xf0;ar ridge. Undirhl&#xed;&#xf0;ar ridge has more radiogenic <sup>206</sup>Pb/<sup>204</sup>Pb and <sup>208</sup>Pb/<sup>204</sup>Pb than Fagradalsfjall, but Sr-Nd isotopes do not show the same enrichment. Fagradalsfjall incompatible trace element ratios overlap with and extend beyond the Undirhl&#xed;&#xf0;ar ridge data. The Undirhl&#xed;&#xf0;ar ridge and Fagradalsfjall eruptions capture magmatic conditions for moments in time, reflecting complex interactions among the scale of mantle source heterogeneity, the region of melt generation, and the mechanism of melt extraction (e.g., <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>). A more appropriate evaluation of the lateral plume sheath model should examine the full range of trace element and isotope compositions erupted at each of the volcanic systems on the Reykjanes Peninsula over the longest available time frames (e.g., <xref ref-type="bibr" rid="B25">Gee et al., 1998</xref>; <xref ref-type="bibr" rid="B81">Peate et al., 2009</xref>).</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s6">
<title>6 Conclusion</title>
<p>Our work presents one of the most comprehensive geochemical and physical investigations of a single pillow-dominated tindar to date. We add to existing models for tindar formation by addressing details not easily identified in natural erosional exposures. We provide evidence for magmatic processes that produce geochemical diversity within the ridge stratigraphy and intrusions that play a significant role in ridge growth. The nearby eruption at Fagradalsfjall provides a modern analogue that is useful for understanding the events at Undirhl&#xed;&#xf0;ar ridge. Despite the difference in eruption environment, the Fagradalsfjall and Undirhl&#xed;&#xf0;ar ridge eruptions may have been triggered by similar mixing events and occurred over comparable spatial and temporal scales. Overall, we confirm that tindar ridges are built through a complex series of extrusive and intrusive events under changing hydrologic conditions.</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s7">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s12">Supplementary Material</xref>, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s8">
<title>Author contributions</title>
<p>MP: Conceptualization, methodology, investigation, analysis, writing (all phases), visualization, supervision, project administration, funding acquisition. BE: Conceptualization, methodology, investigation, analysis, writing (all phases), visualization, supervision, project administration, funding acquisition. SJ: Analysis, data curation, visualization. CW, AH, AP, and EW: Investigation, visualization. SH: Resources, visualization.</p>
</sec>
<sec id="s9">
<title>Funding</title>
<p>This work was supported by The College of Wooster Luce Fund, the Keck Geology Consortium (NSF EAR 2050697-MP), NSF EAR 0958928 (MP), NSF EAR 1220176 (MP), the Dickinson College Research and Development Committee, and NSF EAR 1220403 (BE).</p>
</sec>
<ack>
<p>We thank G. Dwyer for ICP-MS and DCP analyses, D. Coleman and R. Mills for isotope analyses, and S. Seaman for FTIR analyses. Thanks to GAIN for help with manuscript preparation and G. Einarsson (&#xcd;SOR) for supplying information for <xref ref-type="fig" rid="F1">Figure 1</xref>. For their assistance in the field and lab, we thank J. Ciarrocca, J. Franceschi, W. Kochtitzky, B. Kumpf, E. Plascencia, M. Reinthal, A. Silverstein, T. Spillman, M. Williams, and the 2016 Keck Iceland Team. This paper benefited from inspiring discussions with K. S&#xe6;mundsson and M.T. Gudmundsson.</p>
</ack>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s note</title>
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<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2023.1095135/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2023.1095135/full&#x23;supplementary-material</ext-link>
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