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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">892787</article-id>
<article-id pub-id-type="doi">10.3389/feart.2022.892787</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Formation of an Intracontinental Orogen Above the Permo-Triassic Mantle Convection Cell in the Paleo-Tethys Tectonic Realm due to Far-Field Stress Derived From Continental Margins</article-title>
<alt-title alt-title-type="left-running-head">Zhao et al.</alt-title>
<alt-title alt-title-type="right-running-head">Indosinian Intracontinental Orogeny of Cathaysia</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Zhao</surname>
<given-names>Lei</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1713185/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zhai</surname>
<given-names>Mingguo</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/981520/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zhou</surname>
<given-names>Xiwen</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>State Key Laboratory of Lithospheric Evolution</institution>, <institution>Institute of Geology and Geophysics</institution>, <institution>Chinese Academy of Science</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Institute of Geology</institution>, <institution>Chinese Academy of Geological Sciences</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1401736/overview">Tatsuki Tsujimori</ext-link>, Tohoku University, Japan</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1718620/overview">Akira Ishiwatari</ext-link>, Nuclear Regulation Authority, Japan</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1719797/overview">Daniel Pastor-Gal&#xe1;n</ext-link>, Tohoku University, Japan</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Lei Zhao, <email>zhaolei@mail.iggcas.ac.cn</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Geochemistry, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>10</day>
<month>05</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>10</volume>
<elocation-id>892787</elocation-id>
<history>
<date date-type="received">
<day>09</day>
<month>03</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>20</day>
<month>04</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Zhao, Zhai and Zhou.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Zhao, Zhai and Zhou</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The identification of intraplate orogens seemingly poses challenges to the plate tectonic theory. Delineating the formation processes of intraplate orogens can provide clues for the better understandings of the above issue. Although still controversial, the Indosinian (Permo-Triassic) orogeny in the South China Block (SCB) is potentially a good example of intracontinental orogen. In this paper, we carry out studies on the Indosinian high-grade rocks in the northeastern Cathaysia Block of the SCB, hoping to cast light on the features and formation processes of intraplate orogenic belts. These rocks exhibit HP/HT granulite facies mineral assemblages and reaction textures imply that they witnessed eclogite-facies metamorphism. Their clockwise P-T trajectories with isothermal decompression stages suggest significant crustal thickening followed by quick orogenic collapse. Immobile whole-rock trace elements indicate basaltic protoliths features, resembling E-MORB and OIB, respectively. SIMS zircon U-Pb age dating confirms Indosinian metamorphic ages of &#x223c;248&#xa0;Ma and a protolith age of &#x223c;953&#xa0;Ma. The mantle-like O isotopic compositions of the Neoproterozoic magmatic zircon cores further attest that they were primarily mantle derived rocks. The whole-rock Sm-Nd isotopic compositions show more enriched features because of metamorphic alteration, while zircon Lu-Hf isotopic results show primitive characteristics with Neoproterozoic model ages. These features suggest that the high-grade mafic rocks, as well as the metamorphosed early Precambrian metasedimentary rocks hosting them, are all continental crust components and juvenile oceanic crust components featuring plate margins are absent during the SCB Indosinian orogeny. Characteristics of these high-grade rocks and their spatial occurrences are both consistent with the proposal of an intracontinental orogen. After summarizations and comparisons of the Indosinian plate margin activities around the SCB, we suggest that this northeast-southwest trending orogenic belt is geometrically consistent with two mantle convection cells, with one conveying the SCB northward to collide with the North China Craton, and the other conveying the Paleo-Pacific plate northwestwards to form an active continental margin along the southeast SCB. The driving mechanism of the formation of the SCB Indosinian intracontinental orogenic belt could have broad implications for other intraplate orogens around the world.</p>
</abstract>
<kwd-group>
<kwd>retrograded eclogite</kwd>
<kwd>granulite</kwd>
<kwd>intraplate orogeny</kwd>
<kwd>far-field stress</kwd>
<kwd>south China block</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>The identification of intraplate orogenic belts in different parts of the world posed a challenge to the theory of plate tectonics because according to the theory, compressive stresses concentrate at plate margins where different plates interact while the interior regions of plates are rigid and hard to deform. The intraplate orogens refer to those formed at large distances from active plate boundaries, with driving forces from both plate-boundary and intraplate stress sources (<xref ref-type="bibr" rid="B90">Raimondo et al., 2014</xref>). Several examples of intraplate orogens have been proposed and studied in different parts of the world, like central Asia and central Australia (<xref ref-type="bibr" rid="B95">Sandiford and Hand, 1998</xref>; <xref ref-type="bibr" rid="B153">Yin et al., 1998</xref>; <xref ref-type="bibr" rid="B30">Hand and Sandiford, 1999</xref>; <xref ref-type="bibr" rid="B96">Sandiford et al., 2001</xref>). Intraplate orogens might also occur in oceanic plates, but examples are difficult to find due to their inaccessibility. Albeit these good examples, the occurrences of large-scale compressional intraplate orogens are relatively rare, especially in the Phanerozoic during which modern plate tectonics dominate geological processes. The Permo-Triassic deformation in the South China Block has long been termed as the Indosinian Movement in the Chinese literature (<xref ref-type="bibr" rid="B17">Cui and Li, 1983</xref>; <xref ref-type="bibr" rid="B39">Huang, 1984</xref>; <xref ref-type="bibr" rid="B93">Ren, 1984</xref>; <xref ref-type="bibr" rid="B131">Wang et al., 2013a</xref>; <xref ref-type="bibr" rid="B168">Zhang et al., 2013</xref>), and is potentially another good example of intraplate orogenic belt, although different opinions exist (<xref ref-type="bibr" rid="B37">Hs&#xfc; et al., 1988</xref>; <xref ref-type="bibr" rid="B29">Gupta et al., 1989</xref>; <xref ref-type="bibr" rid="B94">Rowley et al., 1989</xref>; <xref ref-type="bibr" rid="B36">Hs&#xfc; et al., 1990</xref>; <xref ref-type="bibr" rid="B22">Faure et al., 2018</xref>; <xref ref-type="bibr" rid="B72">Lin et al., 2018</xref>; <xref ref-type="bibr" rid="B102">Shu et al., 2018</xref>).</p>
<p>Researchers who proposed the intracontinental setting for the SCB Indosinian orogen believe that the SCB gained and retained its integrity ever since Neoproterozoic, and besides, they found that this orogeny caused mainly thin-skinned tectonics involving reactivation of only ancient continental components (<xref ref-type="bibr" rid="B7">Chen et al., 1991</xref>; <xref ref-type="bibr" rid="B71">Li, 1998</xref>; <xref ref-type="bibr" rid="B70">Li and Li, 2007</xref>; <xref ref-type="bibr" rid="B100">Shu et al., 2008b</xref>; <xref ref-type="bibr" rid="B56">Li S. et al., 2012</xref>; <xref ref-type="bibr" rid="B98">Shu, 2012</xref>; <xref ref-type="bibr" rid="B24">Faure et al., 2016a</xref>; <xref ref-type="bibr" rid="B25">Faure et al., 2016b</xref>). On the contrary, other researchers suggested a plate margin setting for this orogenic belt (<xref ref-type="bibr" rid="B28">Guo et al., 1984</xref>; <xref ref-type="bibr" rid="B37">Hs&#xfc; et al., 1988</xref>; <xref ref-type="bibr" rid="B169">Zhao et al., 1996</xref>; <xref ref-type="bibr" rid="B154">Yin et al., 1999</xref>; <xref ref-type="bibr" rid="B72">Lin et al., 2018</xref>). <xref ref-type="bibr" rid="B37">Hs&#xfc; et al. (1988)</xref> proposed that the SCB Indosinian orogeny was the result of continental collisions between the Yangtze and Cathaysia Blocks, based mainly on the inference that the Banxi Group (mainly in the Jiangnan belt) is a tectonic m&#xe9;lange that accommodated significant crustal shortening through long-distance thrusting. However, other tectonic observations, as well as isotopic ages which show that the Banxi Group represents the Precambrian basement of the SCB, contradict this continental collisional model (<xref ref-type="bibr" rid="B29">Gupta et al., 1989</xref>; <xref ref-type="bibr" rid="B94">Rowley et al., 1989</xref>; <xref ref-type="bibr" rid="B7">Chen et al., 1991</xref>). Due to the lack of high-grade metamorphism, tectonic models like multiple-terrane accretion and soft-collision have also been proposed for the SCB Indosinian orogeny (<xref ref-type="bibr" rid="B28">Guo et al., 1984</xref>; <xref ref-type="bibr" rid="B154">Yin et al., 1999</xref>). <xref ref-type="bibr" rid="B72">Lin et al. (2018)</xref> suggested an Appalachian-style multi-terrane Wilson cycle model for the SCB, in which they argued that the Indosinian orogen was the result of continental collisions between the East and West Cathaysia Blocks. Even though criticisms exist (<xref ref-type="bibr" rid="B22">Faure et al., 2018</xref>; <xref ref-type="bibr" rid="B102">Shu et al., 2018</xref>), the Triassic high-grade metamorphic rocks, including retrograded eclogites and granulites in the northern Wuyi terrane of the Cathaysia Block, as well as their clockwise P-T trajectories, seem reminiscent those of continental margin orogenic belts (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>; <xref ref-type="bibr" rid="B143">Xia et al., 2021</xref>).</p>
<p>Continental crust, no matter intraplate or proximal to plate margins, will experience crust shortening, thickening, uplifting and exhumation of high-grade metamorphic rocks after accommodating strain (<xref ref-type="bibr" rid="B90">Raimondo et al., 2014</xref>). High-grade metamorphism, therefore, can be unhelpful in discriminating intraplate and plate margin orogenic belts. The occurrences of ophiolitic m&#xe9;lange, however, can directly demarcate plate boundaries. Besides, protolith features of high-grade metamorphic rocks and the spatial distributions of orogenic high-grade metamorphic rocks can also provide clues for the discriminating of an orogenic belt. In this paper, we present new studies on the Indosinian high-grade rocks in the northern Wuyi terrane of the Cathaysia Block which represent the uplifted orogenic core components. Based on this new data and a summarization of Indosinian orogenic events around the SCB, we proposed a new interpretation of the SCB Indosinian orogeny and the related deep geodynamic processes for its formation.</p>
</sec>
<sec id="s2">
<title>Geological Background</title>
<p>The SCB situated in the southeastern Eurasia continent is now demarcated by the Central China Orogenic belt in the north from the North China Craton and facing the Tibetan Plateau in the west, the Pacific plate in the east and south (<xref ref-type="fig" rid="F1">Figure 1</xref>). Such a triangular region is believed to receive stress from all directions since at least Mesozoic (<xref ref-type="bibr" rid="B56">Li S. et al., 2012</xref>), generating the current geometry of the SCB. This continental block is normally believed to have gained its integrity since Neoproterozoic through the amalgamation of the Yangtze and Cathaysia Blocks <xref ref-type="bibr" rid="B64">Li et al., 2009a</xref>; <xref ref-type="bibr" rid="B129">Wang X.-L. et al., 2014</xref>; <xref ref-type="bibr" rid="B135">Wang Y. et al., 2014</xref>; (<xref ref-type="bibr" rid="B54">Li L. et al., 2016</xref>; <xref ref-type="bibr" rid="B170">Zhao G. et al., 2018</xref>; <xref ref-type="bibr" rid="B171">Zhao J.-H. et al., 2018</xref>; <xref ref-type="bibr" rid="B103">Shu et al., 2019</xref>). This continental collisional event resulted in the formation of the Jiangnan belt hosting a great amount of the Neoproterozoic sequences of the SCB (<xref ref-type="bibr" rid="B64">Li et al., 2009a</xref>; <xref ref-type="bibr" rid="B129">Wang X.-L. et al., 2014</xref>; <xref ref-type="bibr" rid="B135">Wang Y. et al., 2014</xref>; <xref ref-type="bibr" rid="B54">Li L. et al., 2016</xref>; <xref ref-type="bibr" rid="B171">Zhao J.-H. et al., 2018</xref>; <xref ref-type="bibr" rid="B103">Shu et al., 2019</xref>). Two other episodes of tectonothermal events during Phanerozoic besides the Indosinian orogeny occurred in the SCB, termed as the South China Caledonian orogeny (Paleozoic) and the Yanshanian (Jura-Cretaceous) orogeny in the Chinese literature.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Simplified geological map showing major parts of the east Eurasia continent, with emphasize of the SCB. NM- Nangrim Massif; IB- Imjingang Belt; GM- Gyeonggi Massif; OB- Okcheon Belt; YM- Yeongnam Massif. The map is modified after <xref ref-type="bibr" rid="B86">Oh and Kim (2021)</xref>, <xref ref-type="bibr" rid="B167">Zhai et al. (2016)</xref> and Zhao et al. (2019., 2020).</p>
</caption>
<graphic xlink:href="feart-10-892787-g001.tif"/>
</fig>
<p>The SCB Caledonian orogeny affected many of the pre-Devonian sequences of the SCB and caused the unconformity between the Devonian sequences and the pre-Devonian metamorphic crystalline basement (<xref ref-type="bibr" rid="B10">Chen X. et al., 2012</xref>, <xref ref-type="bibr" rid="B8">Chen et al., 2014</xref>; <xref ref-type="bibr" rid="B52">Li J. et al., 2016</xref>; <xref ref-type="bibr" rid="B133">Wang Y. et al., 2012</xref>, <xref ref-type="bibr" rid="B131">Wang et al., 2013a</xref>; <xref ref-type="bibr" rid="B168">Zhang et al., 2013</xref>; <xref ref-type="bibr" rid="B98">Shu, 2012</xref>). Lines of evidence from lithofacies and biofacies suggested that the Paleozoic orogeny was initiated in the southeastern SCB and stepwisely developed toward the northwest direction (<xref ref-type="bibr" rid="B10">Chen X. et al., 2012</xref>; <xref ref-type="bibr" rid="B8">Chen et al., 2014</xref>). Paleozoic high-grade metamorphism and crustal anatexis widely occur in regions along the Jiangshan-Shaoxing (Jiang-Shao) fault (<xref ref-type="fig" rid="F1">Figure 1</xref>, <xref ref-type="bibr" rid="B162">Yu et al., 2003</xref>, <xref ref-type="bibr" rid="B161">Yu et al., 2005</xref>; <xref ref-type="bibr" rid="B164">Zeng et al., 2008</xref>; <xref ref-type="bibr" rid="B174">Zhao et al., 2016</xref>, <xref ref-type="bibr" rid="B172">Zhao et al., 2019</xref>, <xref ref-type="bibr" rid="B175">Zhao et al., 2020</xref>), usually interpreted to be the uplifted orogenic root sequences of the South China Caledonian orogenic belt (<xref ref-type="bibr" rid="B35">Hs&#xfc;, 1989</xref>). Geochronological studies of the Paleozoic metamorphism and anatexis constrain the duration of this event to be between &#x223c;460&#xa0;Ma and 410&#xa0;Ma, with most metamorphic ages from granulite-facies rocks peaking at &#x223c;450&#xa0;Ma and &#x223c;430&#xa0;Ma (<xref ref-type="bibr" rid="B162">Yu et al., 2003</xref>, <xref ref-type="bibr" rid="B161">2005</xref>; <xref ref-type="bibr" rid="B164">Zeng et al., 2008</xref>; <xref ref-type="bibr" rid="B174">Zhao et al., 2016</xref>; <xref ref-type="bibr" rid="B172">Zhao et al., 2019</xref>; <xref ref-type="bibr" rid="B175">Zhao et al., 2020</xref>). The metamorphic signatures of the SCB Yanshanian orogeny are mainly preserved along the southeastern coastal regions, represented by extensive migmatitic rocks (<xref ref-type="fig" rid="F1">Figure 1</xref>, <xref ref-type="bibr" rid="B77">Liu Q. et al., 2012</xref>; <xref ref-type="bibr" rid="B147">Xing et al., 2010</xref>, <xref ref-type="bibr" rid="B146">Xing et al., 2014</xref>).</p>
<p>The Indosinian orogeny affected large areas of the SCB, but the related high-grade metamorphic signatures occur mainly in the Wuyi terrane of the northeastern Cathaysia Block and are sandwiched by the Caledonian and Yanshanian high-grade metamorphic regions (<xref ref-type="fig" rid="F1">Figure 1</xref>). Earlier studies of the Wuyi terrane emphasized mainly the antiquity of the Precambrian sequences (<xref ref-type="bibr" rid="B68">Li, 1997</xref>; <xref ref-type="bibr" rid="B151">Yang and Jiang, 2019</xref>; <xref ref-type="bibr" rid="B160">Yu et al., 2007</xref>, <xref ref-type="bibr" rid="B158">Yu et al., 2009</xref>, <xref ref-type="bibr" rid="B156">Yu et al., 2010</xref>; <xref ref-type="bibr" rid="B178">Zhao et al., 2014</xref>), because they are the critical lithologies that can potentially solve the long-lasting controversy about whether the Cathaysia Block contains &#x201c;Oldland&#x201d; (ancient crystalline basement, <xref ref-type="bibr" rid="B26">Grabau, 1924</xref>; <xref ref-type="bibr" rid="B38">Hu and Ye, 2006</xref>; <xref ref-type="bibr" rid="B79">Lu, 2006</xref>; <xref ref-type="bibr" rid="B159">Yu et al., 2006</xref>). Besides the early Precambrian ages (mainly &#x223c;1900&#x2013;1800&#xa0;Ma), the Indosinian metamorphic ages are widely identified from these lithologies in these early studies, ranging from 260&#xa0;Ma to 230&#xa0;Ma (<xref ref-type="bibr" rid="B144">Xiang et al., 2008</xref>; <xref ref-type="bibr" rid="B158">Yu et al., 2009</xref>, <xref ref-type="bibr" rid="B157">2012</xref>; <xref ref-type="bibr" rid="B178">Zhao et al., 2014</xref>, <xref ref-type="bibr" rid="B177">2015</xref>; <xref ref-type="bibr" rid="B6">Chen et al., 1998</xref>). These early Precambrian lithologies have been defined as the Badu and Mayuan complexes and were not found in other parts of the Cathaysia Block (<xref ref-type="fig" rid="F1">Figure 1</xref>). Supracrustal sequences, as well as Paleoproterozoic granitoids of these two lithological units, also show Paleoproterozoic metamorphic alterations at &#x223c;1.85&#xa0;Ga, interpreted to be related to the supercontinent Columbia (<xref ref-type="bibr" rid="B158">Yu et al., 2009</xref>; <xref ref-type="bibr" rid="B142">Xia et al., 2012</xref>; <xref ref-type="bibr" rid="B157">Yu et al., 2012</xref>; <xref ref-type="bibr" rid="B178">Zhao et al., 2014</xref>). <xref ref-type="bibr" rid="B72">Lin et al. (2018)</xref>, as mentioned earlier, suggested that the Indosinian metamorphic ages represent the time of a continental collisional event between the East and West Cathaysia.</p>
<p>The Indosinian retrograded eclogites and mafic granulites of the SCB were found to occur mainly in the Wuyi terrane and they are entrained lenticular blocks within the metamorphosed supracrustal rocks of the Badu Complex, which occur to the south of the Jiang-Shao fault (<xref ref-type="fig" rid="F2">Figure 2</xref>, <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>; <xref ref-type="bibr" rid="B176">Zhao L. et al., 2018</xref>). Rocks of this lithological unit occurring close to the fault exhibit both Paleozoic (&#x223c;450&#xa0;Ma) and Indosinian metamorphism (<xref ref-type="bibr" rid="B9">Chen et al., 2015</xref>; <xref ref-type="bibr" rid="B177">Zhao et al., 2015</xref>; <xref ref-type="bibr" rid="B123">Wang JG. et al., 2014</xref>). Rocks occurring further south, like those Paleoproterozoic supracrustal rocks and granitoids in the Suichang-Shilian area, show Indosinian high-grade metamorphism and the Caledonian overprinting is absent (<xref ref-type="bibr" rid="B157">Yu et al., 2012</xref>; <xref ref-type="bibr" rid="B178">Zhao et al., 2014</xref>). Permo-Triassic (254&#xa0;Ma, 232&#x2013;215&#xa0;Ma) syenites and A-type granites interpreted to represent post-orogenic extensional setting have also been reported from this area within the Indosinian metamorphic belt defined in <xref ref-type="fig" rid="F1">Figure 1</xref> (<xref ref-type="bibr" rid="B125">Wang Q. et al., 2005</xref>; <xref ref-type="bibr" rid="B110">Sun et al., 2011</xref>; <xref ref-type="bibr" rid="B61">Li W. et al., 2012</xref>; <xref ref-type="bibr" rid="B108">Sun et al., 2017</xref>).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Detailed geological map of the study area showing relations with the Jiang-Shao fault. Right to the south of the fault, both Caledonian and Indosinian metamorphism can be seen. Modified after (<xref ref-type="bibr" rid="B180">Zhejiang GBMR, 1980</xref>).</p>
</caption>
<graphic xlink:href="feart-10-892787-g002.tif"/>
</fig>
</sec>
<sec id="s3">
<title>Samples</title>
<p>In order to get a better understanding of the protolith features as well as the driving mechanism of the Indosinian orogenic processes in the SCB, the retrograded eclogite and mafic granulite samples occurring in the Wuyi terrane of the Cathaysia Block were collected and studied in this paper, including five retrograded eclogite samples, and five mafic granulite samples (<xref ref-type="sec" rid="s13">Supplementary Table S1</xref>). The metamorphism of these rocks has been presented in a previous paper (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). The retrograded eclogite occurs as entrained lenticular blocks within the pelitic granulites of the Badu Complex, whose sizes ranging from tens of centimeters to several meters (<xref ref-type="fig" rid="F3">Figure 3</xref>). The long axes of the retrograded eclogite blocks are always parallel with the foliations of the hosting pelitic granulite gneiss. The mafic granulites occur either as deformed dykes or lenticular bodies with varying dimensions hosted by the pelitic granulite gneisses of the Badu Complex (<xref ref-type="fig" rid="F3">Figure 3D</xref>).</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Field photographs <bold>(A&#x2013;D)</bold>, photomicrographs <bold>(E&#x2013;J)</bold> showing field occurrences, representative mineral assemblages and reaction textures, and P-T trajectories of the Indosinian high-grade rocks in the Wuyi terrane of the Cathaysia Blocks. Field and micrographic photos are from <xref ref-type="bibr" rid="B176">Zhao L. et al. (2018)</xref> and <xref ref-type="bibr" rid="B173">Zhao L. et al. (2017)</xref>. Numbers in <bold>(K)</bold>, 1 and 2 are P-T trajectories for retrograded eclogite and mafic granulite samples, respectively (from <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>); 3 is P-T trajectory for retrograded eclogite presented by <xref ref-type="bibr" rid="B143">Xia et al. (2021)</xref>. Mineral abbreviates, Amp, amphibole; Cpx, clinopyroxene; Pl, plagioclase; Ilm, ilmenite; Qtz, quartz; Ab, albite; Ru, rutile; Tit, titanite; Grt, garnet; Opx, orthopyroxene.</p>
</caption>
<graphic xlink:href="feart-10-892787-g003.tif"/>
</fig>
<p>Mineral assemblages of the retrograded eclogite samples are garnet &#x2b; plagioclase &#xb1; clinopyroxene &#x2b; amphibole &#x2b; biotite &#x2b; quartz and some accessary minerals like ilmenite, rutile, titanite and zircon (<xref ref-type="sec" rid="s13">Supplementary Table S1</xref>; <xref ref-type="fig" rid="F3">Figures 3E&#x2013;G</xref>). Two of the retrograded eclogite samples (WY10-1, and -2) experienced stronger metamorphic retrogression whose clinopyroxene grains have been replaced by amphibole. Except for these two samples, clinopyroxene grains are present in all other samples and garnet grains in all the samples develop symplectites composed of fine-grained minerals of clinopyroxene &#x2b; plagioclase, indicating isothermal decompressions during metamorphism (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). Diagnostic eclogite facies mineral of omphacite is absent in all the retrograded eclogite samples, but symplectites of omphacite grains can be seen. The intergrowth of clinopyroxene and albite (<xref ref-type="fig" rid="F3">Figure 3F</xref>) imply that they were replacement products of omphacite grains formed through retrograde decompressional metamorphism (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). Another petrographic sign implying eclogite facies metamorphism is the absence of plagioclase grains in the matrix. All the observed plagioclase grains occur within the symplectites, either as intergrowths together with clinopyroxene replacing omphacite, or around garnet grains together with clinopyroxene or orthopyroxene or amphibole replacing garnet (<xref ref-type="fig" rid="F3">Figures 3E&#x2013;G</xref>). High-pressure facies minerals like rutile, intergrowth of clinopyroxene and ilmenite can also be seen (<xref ref-type="fig" rid="F3">Figures 3E,G</xref>).</p>
<p>The mineral assemblages of the mafic granulite samples are garnet &#x2b; plagioclase &#x2b; orthopyroxene &#x2b; amphibole &#x2b; biotite &#x2b; quartz and some accessary minerals like rutile, ilmenite, titanite and zircon (<xref ref-type="sec" rid="s13">Supplementary Table S1</xref>). The mafic granulite samples can be further divided into two groups according to their consisting minerals. Compared with group A granulite samples, the two granulite samples in group B contain very few quartz grains and more garnet and amphibole grains. But the mineral assemblages and typical reaction textures of them are the same. The absence of plagioclase in the matrix implies that the mafic granulites might have also experienced eclogite facies metamorphism. Decompressional symplectitic textures can be observed around most garnet grains and they are mainly composed of fine-grained orthopyroxene &#x2b; plagioclase, and occasionally fine-grained amphibole &#x2b; plagioclase intergrowths (<xref ref-type="fig" rid="F3">Figures 3H&#x2013;J</xref>).</p>
<p>Previous metamorphic studies on these two kinds of rocks revealed clockwise P-T trajectories and Indosinian metamorphic ages of 251&#x2013;245&#xa0;Ma (<xref ref-type="fig" rid="F3">Figure 3K</xref>, <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). Retrograded eclogite samples record metamorphic pressure peak conditions of 500&#x2013;560&#xb0;C, 23&#x2013;24&#xa0;kbar and these for the granulite samples are 600&#x2013;720&#xb0;C, &#x3e;13&#xa0;kbar (<xref ref-type="fig" rid="F3">Figure 3K</xref>, <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). High-grade metamorphic rocks with similar metamorphic conditions and P-T trajectories have also been reported from the neighboring regions (<xref ref-type="bibr" rid="B46">Jiang et al., 2016</xref>; <xref ref-type="bibr" rid="B143">Xia et al., 2021</xref>). The metamorphic conditions of these rocks imply significant crustal thickening (doubled) based on a simple evaluation using lithostatic stresses. Therefore, there might be an orogenic plateau in this region during the Indosinian orogeny. In combination, the spatial occurrences of these Indosinian high-grade rocks define the northeast-southwest striking direction of the Indosinian orogenic belt of the Cathaysia Block, likely representing the uplifted orogenic core (<xref ref-type="fig" rid="F1">Figure 1</xref>).</p>
</sec>
<sec id="s4">
<title>Analytical Techniques</title>
<p>Most of the experiments of this study were carried out at the State Key Laboratory of Lithospheric Evolution of the Institute of Geology and Geophysics, Chinese Academy of Sciences (IGGCAS), except for the zircon CL images. The X-ray fluorescence (Shimadzu XRF-1700/1500) was used for major element analyses, after fusion of the samples with lithium tetraborate. After baking the samples for 1&#xa0;h under a constant temperature at 1000&#xb0;C, the loss-on-ignition (LOI) was measured as the weight loss of the samples. The Chinese national standard sample GBW07101-07114 is used for corrections. The precision of the results is better than 0.2&#xa0;wt%. Trace element analyses were performed using an ELEMENT ICP-MS after HNO<sub>3</sub> &#x2b; HF digestion of about 40&#xa0;mg sample powder for each specimen in a Teflon vessel. The Chinese national standard samples GSR1 (granite) and GSR3 (basalt) were used during analyses for accuracy and reproducibility. The relative standard deviation was better than 5% above the detection limits.</p>
<p>After crushing the samples, standard heavy-liquid and magnetic techniques were used in zircon grain separation and then the grains were handpicked under a binocular microscope. The zircon grains, together with zircon standards (see detailed descriptions below), were then cast in epoxy discs, and then were ground and polished to expose mid-sections of the grains for CL imaging, U-Pb dating, O (oxygen) and Lu-Hf isotope analyses. The internal zoning of zircons was examined using a CL detector (Garton Mono CL3&#x2b;) equipped on a Quanta 200F ESEM with 2-min scanning time at conditions of 15&#xa0;kV and 120&#xa0;nA at the Peking University.</p>
<p>The zircon oxygen isotope was analyzed using the CAMECA IMS 1280 SIMS. Detailed analytical procedures were described by <xref ref-type="bibr" rid="B67">Li et al. (2010c)</xref>. The Intensity of <sup>16</sup>O was typically no less than 1&#xd7;10<sup>9</sup> counts per second (cps). The instrumental mass fractionation factor (IMF) is corrected using zircon standard Penglai with a &#x3b4;<sup>18</sup>O (VSMOW) value of 5.3 &#xb1; 0.1&#x2030; (2&#x3c3;) (<xref ref-type="bibr" rid="B67">Li et al., 2010c</xref>). The standard data were collected regularly throughout the analytical session as the IMF drifted with time. The Qinghu zircon standard was measured as an unknown and yielded a standard deviation of 0.3 per mil (2&#x3c3;), which is used for least uncertainty for individual analysis. Uncertainty on individual analysis is usually better than 0.2&#x2013;0.3&#x2030; (2&#x3c3;).</p>
<p>SIMS zircon U-Pb dating was conducted using another CAMECA IMS 1280 SIMS. Detailed analytical procedures can be found in <xref ref-type="bibr" rid="B63">Li et al. (2010b)</xref> and <xref ref-type="bibr" rid="B66">Li et al. (2009b)</xref>. During analysis, the O<sub>2</sub>
<sup>&#x2212;</sup> primary ion beam was accelerated at 13&#xa0;kv. The ellipsoidal spot size is about 20 &#xd7; 30&#xa0;&#x3bc;m. Zircon standard Ple&#x161;ovice, with the age of 337&#xa0;Ma (<xref ref-type="bibr" rid="B104">Sl&#xe1;ma et al., 2008</xref>), was used to calibrate the measured Pb/U ratios. A long-term uncertainty of 1.5% (1RSD) for <sup>206</sup>Pb/<sup>238</sup>U measurements of the Ple&#x161;ovice standard was propagated to the unknowns, despite that the measured <sup>206</sup>Pb/<sup>238</sup>U error in a specific session is generally around 1% (1RSD) or less (<xref ref-type="bibr" rid="B67">Li et al., 2010c</xref>). The Pb isotopic compositions of each spot were corrected for common Pb using non-radiogenic <sup>204</sup>Pb. An average present-day crustal Pb composition (<xref ref-type="bibr" rid="B107">Stacey and Kramers, 1975</xref>) was used for common Pb assuming that the common Pb was largely due to surface contamination introduced during sample preparation. The data were processed using the ISOPLOT program (<xref ref-type="bibr" rid="B80">Ludwig, 2012</xref>). The analyzed standard Qinghu zircon as unknown gave a weighted mean <sup>206</sup>Pb/<sup>238</sup>U age of 159.9 &#xb1; 1.9&#xa0;Ma (MSWD &#x3d; 0.87), consistent with the recommended <sup>206</sup>Pb/<sup>238</sup>U age of 159.9 &#xb1; 0.2&#xa0;Ma (2 SE) (<xref ref-type="bibr" rid="B66">Li et al., 2009b</xref>).</p>
<p>Zircon Hf isotope analyses were carried out using a Neptune MC-ICPMS. The spot size of 40 or 60&#xa0;&#x3bc;m was applied during ablation with a 193&#xa0;nm laser, using a repetition rate of 10&#xa0;Hz in most cases. Detailed descriptions of the instrument and analytical procedures are similar to those in <xref ref-type="bibr" rid="B140">Wu et al. (2006)</xref>. Two zircon standards, GJ and Mud Tank, whose Hf isotope compositions have been proven to be quite uniform (<xref ref-type="bibr" rid="B139">Woodhead and Hergt, 2005</xref>; <xref ref-type="bibr" rid="B163">Zeh et al., 2007</xref>; <xref ref-type="bibr" rid="B145">Xie et al., 2008</xref>), were used to monitor the stability of the instrument during analyses. In the analytical sessions reported here, the weighted <sup>176</sup>Hf/<sup>177</sup>Hf (c) value of GJ is 0.2820035 &#xb1; 0.0000041, and the weighted <sup>176</sup>Hf/<sup>177</sup>Hf (c) of the Mud tank is 0.282495 &#xb1; 0.000005, which, after considering the analytical errors, are consistent with the values recommended previously (<xref ref-type="bibr" rid="B139">Woodhead and Hergt, 2005</xref>; <xref ref-type="bibr" rid="B163">Zeh et al., 2007</xref>; <xref ref-type="bibr" rid="B145">Xie et al., 2008</xref>). Model ages (T<sub>DM</sub>(Hf)) and &#x25b;<sub>Hf</sub>(t) of zircon grains were calculated based on depleted mantle and chondrite sources. The value of <sup>176</sup>Hf/<sup>177</sup>Hf and <sup>176</sup>Lu/<sup>177</sup>Hf of modeled depleted mantle are 0.28325 and 0.0384 (<xref ref-type="bibr" rid="B27">Griffin et al., 2002</xref>) and for chondrite 0.282772 and 0.0332, respectively (<xref ref-type="bibr" rid="B3">Blichert Toft and Albarede, 1997</xref>). The decay constant of <sup>176</sup>Lu adopted in this paper is 1.867 &#xd7; 10<sup>&#x2212;11</sup>per year (<xref ref-type="bibr" rid="B105">S&#xf6;derlund et al., 2004</xref>).</p>
<p>Detailed descriptions of instruments involved and analytical procedures for whole-rock Sm-Nd isotopic analyses are presented in <xref ref-type="bibr" rid="B50">Li C.-f. et al. (2011</xref>)), Li et al. (2011 C.-F.<xref ref-type="bibr" rid="B51">)</xref> and <xref ref-type="bibr" rid="B150">Yang et al. (2010)</xref>. Very fine-grained whole-rock powders for Nd isotopic analyses were dissolved in Savillex Teflon screw-top capsules after being spiked with mixed <sup>149</sup>Sm-<sup>150</sup>Nd tracers before HF &#x2b; HNO<sub>3</sub>&#x2b;HClO<sub>4</sub> dissolution. For Sm and Nd separation, we used the classical two-step ion-exchange chromatographic method. The samples were then measured using a Finnigan MAT262 multi-collector thermal ionization mass spectrometer. The blank during the whole procedure was lower than 100&#xa0;pg. The isotopic ratios were corrected for mass fractionation by normalizing to <sup>146</sup>Nd/<sup>144</sup>Nd &#x3d; 0.7219. The international standard, JNdi-1, was employed to evaluate instrument stability during the period of data collection. The measured values for JNdi-1 were <sup>143</sup>Nd/<sup>144</sup>Nd &#x3d; 0.512104 &#xb1; 0.000007 (<italic>n</italic> &#x3d; 3, MSWD &#x3d; 0.38). USGS reference material BCR-2 was measured to monitor the accuracy of the analytical procedure, and yielded the following result: <sup>143</sup>Nd/<sup>144</sup>Nd &#x3d; 0.512624 &#xb1; 0.000012, which is consistent with the suggested value of BCR-2 yielded by TIMS and MC-ICP-MS techniques (<xref ref-type="bibr" rid="B150">Yang et al., 2010</xref>; <xref ref-type="bibr" rid="B50">Li C.-f. et al., 2011</xref>; <xref ref-type="bibr" rid="B51">Li C.-F. et al., 2011</xref>).</p>
</sec>
<sec id="s5">
<title>Analytical Results</title>
<p>All the ten samples in <xref ref-type="sec" rid="s13">Supplementary Table S1</xref> were analyzed for whole-rock chemical compositions, while six of them were analyzed for whole-rock Sm-Nd isotopic compositions, and only two representative retrograded eclogite samples (WY1215 and WY1216) and one granulite sample (WY11) were chosen for zircon U-Pb, O and Lu-Hf isotopic analyses.</p>
<sec id="s5-1">
<title>Whole-Rock Geochemistry</title>
<p>Major and trace element concentrations of the analyzed samples are presented in <xref ref-type="sec" rid="s13">Supplementary Table S2</xref> and <xref ref-type="fig" rid="F4">Figure 4</xref>. The retrograded eclogite samples have SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub> contents of 47.52&#x2013;49.35&#xa0;wt%, 12.25&#x2013;15.13&#xa0;wt%, respectively. They plot within the basalt field and sub-alkaline basalt field in TAS and Nb/Y <italic>vs</italic>. Zr/TiO<sub>2</sub>&#x2a;0.0001 diagrams (<xref ref-type="fig" rid="F4">Figures 4A,B</xref>). In other diagrams, the retrograded eclogite samples show tholeiitic and E-MORB compositions (<xref ref-type="fig" rid="F4">Figures 4C,D</xref>), and they belong to ocean floor basalts (<xref ref-type="fig" rid="F4">Figure 4E</xref>). The spider diagram and chondrite normalized REE distribution patterns of the retrograded eclogite samples exhibit similarities with E-MORB (<xref ref-type="fig" rid="F4">Figures 4F,H</xref>).</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Major and trace element plots of the studied high-grade rocks from the Wuyi terrane of the Cathaysia Block. <bold>(A)</bold> is after <xref ref-type="bibr" rid="B82">Middlemost (1994)</xref>; <bold>(B)</bold> is after <xref ref-type="bibr" rid="B137">Winchester and Floyd (1977)</xref>; <bold>(C)</bold> is after <xref ref-type="bibr" rid="B40">Irvine and Baragar (1971)</xref>; <bold>(D)</bold> is after <xref ref-type="bibr" rid="B138">Wood (1980)</xref>; <bold>(E)</bold> is after <xref ref-type="bibr" rid="B89">Pearce (1975)</xref>; Primitive mantle and Chondrite normalization factors, as well as the values for N-MORB, E-MORB and OIB are after <xref ref-type="bibr" rid="B109">Sun and McDonough (1989)</xref>.</p>
</caption>
<graphic xlink:href="feart-10-892787-g004.tif"/>
</fig>
<p>The mafic granulite samples exhibit large variations in major elements, and they plot in picro-basalt&#x2014;basalt&#x2014;andesite fields (<xref ref-type="fig" rid="F4">Figure 4A</xref>). Group A granulite samples have higher SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, and lower MgO, Fe<sub>2</sub>O<sub>3</sub>T contents compared with samples of Group B, consistent with the above observations that the ferromagnesian mineral contents of Group A granulite samples are lower than those of Group B. In the Nb/Y <italic>vs</italic>. Zr/TiO<sub>2</sub>&#x2a;0.0001 diagram, these samples plot within the sub-alkaline&#x2014;andesite&#x2014;dacite fields (<xref ref-type="fig" rid="F4">Figure 4B</xref>). The mafic granulite samples are also tholeiitic and belong to ocean floor basalts as shown in discrimination diagrams (<xref ref-type="fig" rid="F4">Figures 4C&#x2013;E</xref>). The spider diagram and chondrite normalized REE distribution patterns of the mafic granulite samples exhibit similarities with OIB (<xref ref-type="fig" rid="F4">Figures 4F,H</xref>).</p>
</sec>
<sec id="s5-2">
<title>Zircon U-Pb Age Dating</title>
<p>The three high-grade rocks have all been dated in a previous study, using the LA-ICPMS zircon U-Pb method, which gave metamorphic ages of 245&#x2013;251&#xa0;Ma, and also a protolith age of 997 &#xb1; 27&#xa0;Ma for the mafic granulite sample (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). In this study, zircons of the two retrograded eclogite samples exhibit similar appearance and internal structures (<xref ref-type="fig" rid="F5">Figure 5</xref>). The zircon grains are rounded, small ellipsoidal and are multi-faceted. They are unzoned or show fir-tree zoning patterns, implying metamorphic origins (<xref ref-type="bibr" rid="B119">Vavra, 1990</xref>). These two retrograded eclogite samples give uniform apparent <sup>206</sup>Pb/<sup>238</sup>U ages with low Th/U ratios and they constrain metamorphic ages of 248&#x2013;249&#xa0;Ma (<xref ref-type="fig" rid="F5">Figure 5</xref>; <xref ref-type="sec" rid="s13">Supplementary Table S3</xref>). Some of the zircon grains of the mafic granulite sample show core-rim structures with cores exhibiting oscillatory zoning while rims without zoning or showing fir-tree zoning (<xref ref-type="fig" rid="F5">Figure 5</xref>). The zircon cores that do not show core-rim structures are mostly unzoned or show fir-tree zoning or sector zoning. The analytical results define a Discordia with an upper intercept age at 953 &#xb1; 17&#xa0;Ma and a lower intercept age of 246 &#xb1; 6&#xa0;Ma. The zircon grains with ages of &#x223c;246&#xa0;Ma show uniformly low Th/U ratios while those with older ages have high Th/U ratios (<xref ref-type="fig" rid="F5">Figure 5</xref> and <xref ref-type="sec" rid="s13">Supplementary Table S3</xref>), which imply their metamorphic and magmatic origins. These results are consistent with previous studies that the high-grade metamorphism occurred during the Early Triassic (<xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>; <xref ref-type="bibr" rid="B143">Xia et al., 2021</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>SIMS zircon U-Pb dating results, Th/U ratio <italic>vs</italic>. U-Pb ages plots and zircon O isotopic results of the studies samples.</p>
</caption>
<graphic xlink:href="feart-10-892787-g005.tif"/>
</fig>
</sec>
<sec id="s5-3">
<title>Zircon O-Hf Isotopic Compositions</title>
<p>The zircon grains of the two retrograded eclogite samples show significant differences in O isotopic compositions (<xref ref-type="sec" rid="s13">Supplementary Table S4</xref> and <xref ref-type="fig" rid="F5">Figure 5</xref>). The &#x3b4;<sup>18</sup>O (V-SMOW) values are 3.85&#x2013;6.08 for zircons from the sample WY1215-2, and 8.46&#x2013;11.34 for those of the sample WY1216-3. The distinct O isotopic compositions of these metamorphic zircons suggest zircon precipitation from different metamorphic fluids. The &#x3b4;<sup>18</sup>O (V-SMOW) values of zircon cores and rims from the mafic granulite sample show large variations, with cores having low &#x3b4;<sup>18</sup>O values of &#x223c;5.5 while rims having high &#x3b4;<sup>18</sup>O values around &#x223c;8 (<xref ref-type="sec" rid="s13">Supplementary Table S4</xref> and <xref ref-type="fig" rid="F5">Figure 5</xref>).</p>
<p>The zircon Hf isotopic compositions of the two retrograded eclogite samples are relatively homogenous, with <sup>176</sup>Hf/<sup>177</sup>Hf ratios of 0.282646&#x2013;0.282521 for WY1215-1 and of 0.281223&#x2013;0.282806 for WY1216-2 (mostly within the range of 0.282605&#x2013;0.282798, <xref ref-type="sec" rid="s13">Supplementary Table S5</xref>). &#x190;<sub>Hf</sub>(t) values are all negative for zircons from the sample WY1215-1 (ranging from &#x2212;5.9 to &#x2212;3.4) and mostly positive for zircons from the sample WY1216-2 (ranging from &#x2212;16.1 to &#x2b;6.6, mostly ranging from 0.9 to 6.6). The single-stage depleted mantle model ages of the sample WY1215-1 are 1011&#x2013;1088&#xa0;Ma and 619&#x2013;2787&#xa0;Ma (mostly within the range of 619&#x2013;892&#xa0;Ma). For the reason that the zircons from the granulite sample exhibit complex internal structures, their Hf isotopic compositions also show large variations, with <sup>176</sup>Hf/<sup>177</sup>Hf ratios ranging from 0.281980 to 0.282654 and related &#x190;<sub>Hf</sub>(t) values ranging from &#x2212;22 to &#x2b;5.6 (<xref ref-type="sec" rid="s13">Supplementary Table S5</xref>). The single-stage depleted mantle model ages are 829&#x2013;1772&#xa0;Ma. In the zircon U-Pb age <italic>vs</italic>. &#x190;<sub>Hf</sub>(t) value diagram, the analyzed results plot above and below the CHUR evolutionary line, based on calculations using apparent zircon U-Pb ages (<xref ref-type="fig" rid="F6">Figure 6</xref>). However, if using the protolith age of the mafic granulite (&#x223c;960&#xa0;Ma) as the starting age, &#x190;<sub>Hf</sub>(t) values of most analyses plot above the CHUR evolutionary line (<xref ref-type="fig" rid="F6">Figure 6</xref>).</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>&#x3b5;<sub>Hf</sub>(t) value <italic>vs</italic>. zircon U-Pb age plots of the studied samples.</p>
</caption>
<graphic xlink:href="feart-10-892787-g006.tif"/>
</fig>
</sec>
<sec id="s5-4">
<title>Whole-Rock Sm-Nd Isotopic Compositions</title>
<p>The six analyzed samples show quite different whole-rock Sm-Nd isotopic compositions (<xref ref-type="sec" rid="s13">Supplementary Table S6</xref>). The retrograded eclogite have higher <sup>143</sup>Nd/<sup>144</sup>Nd ratios (0.512487&#x2013;0.512694) than the granulite samples (0.511343&#x2013;0.512144). The single-stage depleted mantle model ages are mostly Mesoproterozoic for the retrograded eclogite samples (1360&#x2013;1790&#xa0;Ma), except one sample with an Archean model age of &#x223c;2620&#xa0;Ma, while those of the mafic granulite samples are older, at 1860&#x2013;3020&#xa0;Ma. The &#x190;<sub>Nd</sub>(t) values (assuming that the protolith ages are Neoproterozoic based on the protolith age of the mafic granulite, <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>) of the retrograded eclogite samples are positive, ranging from 1.94 to 5.46 while those of the two mafic granulite samples are negative, one at &#x2212;1.35 and the other at &#x2212;7.74.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s6">
<title>Discussions</title>
<sec id="s6-1">
<title>Indosinian Metamorphism in and Around the SCB</title>
<p>As mentioned earlier, the Indosinian orogeny affected large areas of the SCB. Although previous studies claimed that many of the Neoproterozoic sequences belonging to the Banxi Group represent the Precambrian basement of the SCB, Indosinian reworking of these sequences are significant, represented by folding, shearing and long-distance thrusting within the Jiangnan belt (<xref ref-type="bibr" rid="B12">Chu et al., 2012a</xref>; <xref ref-type="bibr" rid="B13">Chu et al., 2012b</xref>; <xref ref-type="bibr" rid="B14">Chu et al., 2012c</xref>; <xref ref-type="bibr" rid="B76">Liu L. et al., 2012</xref>; <xref ref-type="bibr" rid="B136">Wang Y. et al., 2005</xref>). These deformation features are typical of thin-skinned tectonics, involving only upper crustal components. The occurrences of the high-grade rocks in the northern Wuyi terrane suggest that the orogeny of this region affected deep lower crustal components. The peak pressure conditions of the retrograded eclogite samples indicate the crustal thickness of the northern Wuyi terrane was almost doubled during the orogeny. The decompressional reaction textures and the isothermal (or slow heating) decompressional P-T stage in the P-T trajectories imply that the orogenic belt experienced quick collapse and the high-grade rocks experienced fast uplifting during the late thermal relaxation stage (<xref ref-type="fig" rid="F3">Figure 3</xref>, <xref ref-type="bibr" rid="B173">Zhao L. et al., 2017</xref>). The metamorphic features of these high-grade rocks are strongly reminiscent of those found in plate margin contractional settings (<xref ref-type="bibr" rid="B4">Brown, 2009</xref>; <xref ref-type="bibr" rid="B85">O&#x27;Brien, 1993</xref>). New SIMS zircon U-Pb dating results confirm the time of metamorphism at 246&#x2013;249&#xa0;Ma (<xref ref-type="fig" rid="F5">Figure 5</xref>). Indosinian metamorphism has also been reported from the Yunkai terrane in the southwestern Cathaysia Block (<xref ref-type="fig" rid="F1">Figures 1</xref>, <xref ref-type="fig" rid="F7">7</xref>, <xref ref-type="bibr" rid="B5">Chen C.-H. et al., 2012</xref>; <xref ref-type="bibr" rid="B73">Lin et al., 2008</xref>; <xref ref-type="bibr" rid="B122">Wan et al., 2010</xref>). However, the occurrences of Indosinian metamorphism are not continuous from the Wuyi terrane to the Yunkai terrane, implying that they might not belong to the same Indosinian orogenic belt. Tectonic geometry as well as metamorphic features of the Yunkai terrane exhibit close affinities to the Indosinian tectonothermal events in southwestern SCB and Indochina, which are inconsistent with those of the Wuyi terrane (<xref ref-type="bibr" rid="B73">Lin et al., 2008</xref>; <xref ref-type="bibr" rid="B23">Faure et al., 2014</xref>; <xref ref-type="bibr" rid="B52">Faure et al., 2016a</xref>; <xref ref-type="bibr" rid="B54">Faure et al., 2016b</xref>).</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>A summarization and comparison of major magmatic, metamorphic and early Precambrian basement rocks in different parts of the orogenic belts in and around the SCB. Related references can be found in the main text.</p>
</caption>
<graphic xlink:href="feart-10-892787-g007.tif"/>
</fig>
<p>The Indosinian high-grade metamorphism in east Eurasia that attracted the most international interests occurs along the Central China Orogenic belt, which is further divided into small segments of the Qinling, Tongbai, Hong&#x2019;an, Dabie and Sulu (<xref ref-type="fig" rid="F1">Figure 1</xref>). This composite orogenic belt records the complete amalgamation history of the two major continental parts of east Eurasia, namely the SCB and the North China Craton, and besides, the identification of ultrahigh-pressure metamorphic minerals like coesite and diamond from eclogites with continental crustal chemical compositions imply deep subduction of the SCB continental crust (<xref ref-type="bibr" rid="B19">Dong et al., 2016</xref>; <xref ref-type="bibr" rid="B87">Okay and Celal &#x15e;eng&#xf6;r, 1992</xref>; <xref ref-type="bibr" rid="B130">Wang et al., 1989</xref>; <xref ref-type="bibr" rid="B141">Wu and Zheng, 2013</xref>; <xref ref-type="bibr" rid="B148">Xu et al., 1992</xref>; <xref ref-type="bibr" rid="B165">Zhai et al., 1995</xref>; <xref ref-type="bibr" rid="B179">Zhao Z.-F. et al., 2017</xref>). Multiple geochronological studies constrain the time of eclogite facies metamorphism of the Sulu and Dabie segments to be at 255&#x2013;200&#xa0;Ma, mostly Triassic (<xref ref-type="fig" rid="F7">Figure 7</xref>, <xref ref-type="bibr" rid="B1">An et al., 2018</xref>; <xref ref-type="bibr" rid="B11">Cheng et al., 2011</xref>; <xref ref-type="bibr" rid="B55">Li S. et al., 2017</xref>; <xref ref-type="bibr" rid="B75">Liu et al., 2004</xref>, <xref ref-type="bibr" rid="B74">Liu et al., 2006</xref>; <xref ref-type="bibr" rid="B141">Wu and Zheng, 2013</xref>), synchronous with these of the Wuyi terrane. As to the Qinling segment of the Central China Orogenic belt, its high-grade metamorphism occurred mainly during Paleozoic and Triassic overprintings are not very strong (<xref ref-type="fig" rid="F7">Figure 7</xref>, <xref ref-type="bibr" rid="B20">Dong et al., 2011</xref>). The influence of such an extreme contractional orogen is significant and many of the Indosinian metamorphic events in East Asia have been correlated with this orogenic belt, like those in the Korean Peninsula and Japan (<xref ref-type="bibr" rid="B49">Kwon et al., 2009</xref>; <xref ref-type="bibr" rid="B78">Liu, 1993</xref>; <xref ref-type="bibr" rid="B86">Oh and Kim, 2021</xref>; <xref ref-type="bibr" rid="B92">Ree et al., 1996</xref>; <xref ref-type="bibr" rid="B116">Tsujimori, 2002</xref>; <xref ref-type="bibr" rid="B21">Ernst et al., 2007</xref>). As shown in <xref ref-type="fig" rid="F1">Figure 1</xref>, the striking direction of the Sulu segment of the Central China Orogenic belt is parallel with the Indosinian orogenic belt in the Wuyi terrane of the Cathaysia Block, both following northeast-southwest direction. Almost synchronously, the collision between the SCB and the Indochina Peninsula resulted in high-grade metamorphism in southwest SCB and also Indochina (<xref ref-type="bibr" rid="B23">Faure et al., 2014</xref>, <xref ref-type="bibr" rid="B24">2016a</xref>, <xref ref-type="bibr" rid="B25">b</xref>), whose major tectonic geometry is, however, mainly northwest-southeast (<xref ref-type="bibr" rid="B25">Faure et al., 2016b</xref>).</p>
<p>Another important plate that greatly affected the Phanerozoic SCB and which has been overlooked in many previous studies is the one facing its southeastern continental margin, the Paleo-Pacific plate (<xref ref-type="fig" rid="F1">Figure 1</xref>). Although still controversial, many geologists suggested the onset of the SCB active continental margin facing the Pacific plate during Mesozoic (<xref ref-type="bibr" rid="B181">Zhou and Li, 2000</xref>; <xref ref-type="bibr" rid="B182">Zhou et al., 2006</xref>), or during Paleozoic (<xref ref-type="bibr" rid="B69">Li et al., 2006</xref>; <xref ref-type="bibr" rid="B70">Li and Li, 2007</xref>; <xref ref-type="bibr" rid="B110">Sun et al., 2011</xref>). However, pre-Triassic geological records of interactions with the Pacific oceanic plate are now absent in the southeastern SCB continental margin, which is mainly composed of late Mesozoic magmatic rocks (volcanics and intrusive rocks, <xref ref-type="bibr" rid="B98">Shu, 2012</xref>; <xref ref-type="bibr" rid="B149">Xu et al., 2007</xref>). The Japanese islands, which preserve various geological records of oceanic subduction, accretion, subduction erosion and the formation of the continental crust due to interactions with the Pacific plate, ranging from Paleozoic to Cenozoic, have been suggested to show consanguineous with the SCB (<xref ref-type="fig" rid="F8">Figure 8</xref>, <xref ref-type="bibr" rid="B111">Taira, 2001</xref>; <xref ref-type="bibr" rid="B120">Wakita, 2013</xref>; <xref ref-type="bibr" rid="B88">Pastor-Gal&#xe1;n et al., 2021</xref>; <xref ref-type="bibr" rid="B43">Isozaki et al., 2010</xref>; <xref ref-type="bibr" rid="B121">Wallis et al., 2020</xref>). Indeed some of the early Precambrian lithologies in the Hida belt of Southwest Japan show consanguineous with those of the North China Craton as previously suggested (<xref ref-type="fig" rid="F8">Figure 8</xref>, <xref ref-type="bibr" rid="B33">Horie et al., 2010</xref>; <xref ref-type="bibr" rid="B47">Kawabata et al., 2021</xref>; <xref ref-type="bibr" rid="B31">Harada et al., 2021a</xref>, <xref ref-type="bibr" rid="B32">2021b</xref>; <xref ref-type="bibr" rid="B48">Kimura et al., 2019</xref>), but these sporadically occurred Paleoproterozoic intrusive rocks (&#x223c;1.85&#xa0;Ga) as well as the Archean-Paleoproterozoic detrital and/or inherited zircon grains are also comparable to those of the Badu Complex in the Wuyi terrane of the Cathaysia Block (<xref ref-type="bibr" rid="B65">Li et al., 2014</xref>; <xref ref-type="bibr" rid="B158">Yu et al., 2009</xref>, <xref ref-type="bibr" rid="B157">2012</xref>; <xref ref-type="bibr" rid="B177">Zhao et al., 2015</xref>; <xref ref-type="bibr" rid="B42">Isozaki, 2019</xref>). Besides, the Paleozoic (&#x223c;450&#x2013;410&#xa0;Ma) and/or Indosinian metamorphic overprintings, as well as the Neoproterozoic lithologies of the Wuyi terrane in northeast Cathaysia Block also provide arguments for a close consanguinity of Japan with the SCB (<xref ref-type="bibr" rid="B174">Zhao et al., 2016</xref>, <xref ref-type="bibr" rid="B175">Zhao et al., 2020</xref>; <xref ref-type="bibr" rid="B149">Xu et al., 2007</xref>; <xref ref-type="bibr" rid="B99">Shu et al., 2008a</xref>, <xref ref-type="bibr" rid="B100">Shu et al., 2008b</xref>; <xref ref-type="bibr" rid="B33">Horie et al., 2010</xref>; <xref ref-type="bibr" rid="B48">Kimura et al., 2019</xref>; <xref ref-type="bibr" rid="B32">Harada et al., 2021b</xref>). These correlations support the inference that the ancient continental fragments preserved in Japan probably originated from the SCB (<xref ref-type="bibr" rid="B2">Aoki et al., 2015</xref>; <xref ref-type="bibr" rid="B43">Isozaki et al., 2010</xref>, <xref ref-type="bibr" rid="B44">Isozaki et al., 2014</xref>; <xref ref-type="bibr" rid="B117">Tsutsumi et al., 2017</xref>; <xref ref-type="bibr" rid="B42">Isozaki, 2019</xref>; <xref ref-type="bibr" rid="B88">Pastor-Gal&#xe1;n et al., 2021</xref>). Besides, the Paleozoic and Mesozoic geological components, like the Paleozoic accretionary complexes, the Mesozoic accretionary complexes, as well as the arc batholiths and ophiolitic m&#xe9;lange in Japan, are quite likely to be the missing continental marginal components of the SCB during the Indosinian orogeny(<xref ref-type="bibr" rid="B43">Isozaki et al., 2010</xref>, <xref ref-type="bibr" rid="B44">Isozaki et al., 2014</xref>; <xref ref-type="bibr" rid="B42">Isozaki, 2019</xref>; <xref ref-type="bibr" rid="B88">Pastor-Gal&#xe1;n et al., 2021</xref>). Metamorphism of the Japanese islands are mainly low-temperature, high-pressure subduction type and continuous from Paleozoic onwards (<xref ref-type="fig" rid="F7">Figure 7</xref>, <xref ref-type="bibr" rid="B41">Ishiwatari and Tsujimori, 2003</xref>; Erst et al., 2007; <xref ref-type="bibr" rid="B81">Matsunaga et al., 2021</xref>; <xref ref-type="bibr" rid="B112">Takahashi et al., 2018</xref>; <xref ref-type="bibr" rid="B116">Tsujimori, 2002</xref>; <xref ref-type="bibr" rid="B114">Tsujimori et al., 2006</xref>; <xref ref-type="bibr" rid="B115">Tsujimori and Liou, 2004</xref>). Alongside with these subduction zone metamorphism, the low (and medium) dP/dT metamorphism can also often be seen (<xref ref-type="bibr" rid="B112">Takahashi et al., 2018</xref>), which collectively termed as the &#x2018;paired metamorphic belts&#x2019; (<xref ref-type="bibr" rid="B83">Miyashiro, 1961</xref>, <xref ref-type="bibr" rid="B84">1973</xref>). One thing worthy of noticing is the preservation of geological records for an accreted oceanic plateau in Southwest Japan (<xref ref-type="bibr" rid="B113">Tatsumi et al., 2000</xref>). These geological records are critical for a better understanding the geological history of the Phanerozoic SCB.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Simplified geological map of major parts of East Asia and Southwest Japan. Modified after <xref ref-type="bibr" rid="B86">Oh and Kim (2021)</xref>, <xref ref-type="bibr" rid="B116">Tsujimori (2002)</xref> and <xref ref-type="bibr" rid="B88">Pastor-Gal&#xe1;n et al. (2021)</xref>.</p>
</caption>
<graphic xlink:href="feart-10-892787-g008.tif"/>
</fig>
</sec>
<sec id="s6-2">
<title>Characteristics of the Protoliths of the High-Grade Rocks</title>
<p>The eclogite and granulite facies mineral assemblages indicate that the studied mafic rocks experienced high-grade metamorphism which might render their whole-rock chemical compositions unreliable, especially the major elements and the fluid-mobile elements like Th, K, etc. The large spread of these samples in <xref ref-type="fig" rid="F4">Figure 4A</xref> partly attests to this inference. However, some overall variation trends can still be extracted from the relatively immobile element plots (<xref ref-type="fig" rid="F4">Figure 4</xref>), like their sub-alkaline basaltic and tholeiitic compositions. They show close affinities to oceanic crust, with the retrograded eclogite samples resembling E-MORB while the mafic granulite samples resembling OIB. The protoliths of these rocks, therefore, are interpreted to represent the remnants of a disappeared ocean.</p>
<p>Zircon O-Hf isotopic compositions of these metamorphosed mafic rocks exhibit large variations as well, but the magmatic zircon cores preserved in the mafic granulite sample have mantle-like O isotopic signatures (<xref ref-type="fig" rid="F5">Figure 5</xref>, <xref ref-type="bibr" rid="B118">Valley et al., 1994</xref>). The Neoproterozoic age of 946&#xa0;Ma constrained by these magmatic zircon cores is interpreted to represent the protolith age of the mafic granulite. Both the zircon Lu-Hf and whole-rock Sm-Nd isotopic compositions of these mafic rocks show large variations. Considering that the hosting rocks of these mafic rocks are the Paleoproterozoic sedimentary rocks of the Badu Complex, any influence from which during high-grade metamorphism will elevate model ages while lowering &#x190;(t) values for both Lu-Hf and Sm-Nd isotopic systems, the high-grade samples of this study with the youngest single-stage model ages and the highest &#x190; (t) values should be regarded to give the best constraints on the features of these meta-mafic rocks. As described above, the youngest single-stage Hf model ages for both the retrograded eclogite and mafic granulite samples are Neoproterozoic, 619&#x2013;892&#xa0;Ma for the retrograded eclogite, and 829&#x2014;&#x223c;1000&#xa0;Ma for the mafic granulite. Whole-rock Sm-Nd isotopic compositions for these high-grade rocks seem to have been disturbed during metamorphism because they exhibit large variations on one hand and on the other hand, the single-stage model ages are Mesoproterozoic to Archean, significantly older than the Hf model ages. The Neoproterozoic protolith ages (990&#x2013;950&#xa0;Ma) for these metamorphosed mafic blocks are, therefore, supported by both the magmatic zircon core U-Pb age of the mafic granulite, and the Hf - Nd isotopic compositions.</p>
<p>Previous studies have revealed the occurrences of two episodes of Neoproterozoic magmatism in the Cathaysia Block, one at &#x223c;970&#xa0;Ma and the other at 860&#x2013;800&#xa0;Ma (<xref ref-type="bibr" rid="B99">Shu et al., 2008a</xref>; <xref ref-type="bibr" rid="B97">Shu et al., 2011</xref>; <xref ref-type="bibr" rid="B135">Wang Y. et al., 2014</xref>). They have been interpreted to occur in the active continental margin and within plate rifting environments, respectively (<xref ref-type="bibr" rid="B99">Shu et al., 2008a</xref>; <xref ref-type="bibr" rid="B97">Shu et al., 2011</xref>). If taking the zircon core age of &#x223c;950&#xa0;Ma as the protolith age, the metamorphosed blocks of this study can correlate well with the &#x223c;970&#xa0;Ma magmatism in the Cathaysia Block, representing continental margin components. The protoliths of these metamorphosed mafic blocks, generated during Neoproterozoic, can also be compared with the widespread Neoproterozoic lithologies in the Jiangnan belt (<xref ref-type="bibr" rid="B134">Wang et al., 2013b</xref>; <xref ref-type="bibr" rid="B135">Wang Y. et al., 2014</xref>; <xref ref-type="bibr" rid="B152">Yao et al., 2014</xref>). All these Neoproterozoic magmatic rocks are related to the tectonothermal events that amalgamated the Yangtze and Cathaysia Blocks, and the subsequent rifting (Nanhua Rift) (<xref ref-type="bibr" rid="B64">Li et al., 2009a</xref>; <xref ref-type="bibr" rid="B62">Li W. X. et al., 2010</xref>; <xref ref-type="bibr" rid="B128">Wang X.-L. et al., 2012</xref>). Anyway, the Neoproterozoic magmatic rocks are important components of the continental crust of the SCB during the Indosinian orogeny, rather than newly generated oceanic crustal component (<xref ref-type="bibr" rid="B155">Yu et al., 2008</xref>; <xref ref-type="bibr" rid="B101">Shu, 2006</xref>, <xref ref-type="bibr" rid="B98">2012</xref>).</p>
</sec>
<sec id="s6-3">
<title>Formation of the Indosinian SCB Intraplate Orogenic Belt and Broad International Implications</title>
<p>If based solely on the Indosinian high-grade metamorphism of the Wuyi terrane in northeastern Cathaysia Block, the conclusion of a continental margin orogenic belt can be assigned to the SCB Indosinian orogen, because these metamorphic rocks show identical features with those developed in continental margin orogenic belts (<xref ref-type="bibr" rid="B4">Brown, 2009</xref>; <xref ref-type="bibr" rid="B85">O&#x27;Brien, 1993</xref>). But the geological implications of high-grade metamorphism are not always exclusive and as pointed out by <xref ref-type="bibr" rid="B90">Raimondo et al. (2014)</xref>, the crustal shortening and thickening, and exhumation high-grade metamorphic rocks from deep crustal levels of intraplate orogens are comparable with their plate-margin counterparts. Therefore, the eclogite and the granulite facies metamorphism such as these of the Wuyi terrane could suggest both intraplate and plate marginal settings.</p>
<p>The spatial occurrence of orogenic metamorphism has been suggested to be a powerful tool in discriminating styles of orogens (<xref ref-type="bibr" rid="B90">Raimondo et al., 2014</xref>; <xref ref-type="bibr" rid="B166">Zhai, 2009</xref>; <xref ref-type="bibr" rid="B59">Li et al., 2016c</xref>, <xref ref-type="bibr" rid="B58">Li et al., 2016d</xref>). As summarized by <xref ref-type="bibr" rid="B177">Zhao et al. (2015)</xref> and shown in <xref ref-type="fig" rid="F1">Figure 1</xref>, the occurrences of the Indosinian high-grade metamorphism are found to occur only in the northeastern Cathaysia Block (Wuyi terrane) and are absent in the Nanling area. In other words, their distribution is not continuous and does not form a complete belt that can demarcate the continental boundaries. Such a distribution pattern of high-grade metamorphism is inconsistent with those developed in continental marginal settings, but rather indicates an intracontinental setting. Besides the mafic blocks studied in this paper which show continental crust characteristics, other lithologies in the Cathaysia Block exhibiting Indosinian high-grade metamorphic alterations mainly belong to the Paleoproterozoic Badu and Mayuan Complexes of the Wuyi terrane (<xref ref-type="bibr" rid="B157">Yu et al., 2012</xref>; <xref ref-type="bibr" rid="B177">Zhao et al., 2015</xref>; <xref ref-type="bibr" rid="B176">Zhao L. et al., 2018</xref>). The occurrences of all these rocks indicate that the Indosinian orogeny affected only the ancient continental crust components, without the addition of any juvenile components newly generated from mantle which is, however, usually normal for continental marginal orogenic belts due to the consumption of oceanic crust before the final collision (e.g. <xref ref-type="bibr" rid="B45">Jamieson and Beaumont, 2013</xref>; <xref ref-type="bibr" rid="B57">Li et al., 2016e</xref>; <xref ref-type="bibr" rid="B34">Hou et al., 2021</xref>). In summary, although the high-grade rocks in the Wuyi terrane record metamorphism similar to those seen in continental margin settings, they are more likely to have occurred in the intracontinental environment.</p>
<p>The development of intracontinental orogens normally requires the existence of weak lithospheric zones within the continental block (<xref ref-type="bibr" rid="B15">Collins et al., 2011</xref>; <xref ref-type="bibr" rid="B90">Raimondo et al., 2014</xref>; <xref ref-type="bibr" rid="B106">Sokoutis and Willingshofer, 2011</xref>). As mentioned earlier, a Neoproterozoic rifted system termed the Nanhua rift developed in the SCB, as indicated by the wide occurrences of Neoproterozoic magmatism (860&#x2013;800&#xa0;Ma) (<xref ref-type="bibr" rid="B99">Shu et al., 2008a</xref>, <xref ref-type="bibr" rid="B97">Shu et al., 2011</xref>; <xref ref-type="bibr" rid="B60">Li et al., 2005</xref>; <xref ref-type="bibr" rid="B124">Wang and Li, 2003</xref>; <xref ref-type="bibr" rid="B126">Wang et al., 2007</xref>). This rift system is also known to be a failed rift because it aborted soon afterwards and no new ocean was developed. The South China Caledonian orogeny should have solidified most of the failed rift and formed another basin (foreland?) in the Wuyi terrane which behaved as a branch of the Paleo-Tethys Ocean and provided the weak lithospheric zone in the Cathaysia Block (<xref ref-type="fig" rid="F9">Figure 9A</xref>). Another critical cause of the intraplate orogen is the driving force. Stress source of orogenic belts, either occurring in the intraplate or plate margin settings, are originally derived from the viscous mantle convections, which operate as conveyors and transport the lithosphere to different places of the Earth, resulting in the formation of convergent and divergent plate margins (<xref ref-type="bibr" rid="B16">Collins, 2003</xref>; <xref ref-type="bibr" rid="B15">Collins et al., 2011</xref>). The driving forces of intraplate orogens have been more specifically suggested to include far-field stress from plate margins, and intraplate stress largely related to vertical tectonic processes (<xref ref-type="bibr" rid="B90">Raimondo et al., 2014</xref>). The geometry of the Indosinian orogen is inconsistent with intraplate stress and implies stress sources from continental margins. The mantle convection cell in the Paleo-Tethys tectonic realm transported the SCB northward (today&#x2019;s orientation), closing the Paleo-Tethys Ocean and forming the Central China Orogenic belt during Permo-Triassic (<xref ref-type="bibr" rid="B15">Collins et al., 2011</xref>; <xref ref-type="bibr" rid="B91">Ratschbacher et al., 2003</xref>; <xref ref-type="bibr" rid="B141">Wu and Zheng, 2013</xref>). The subduction of the paleo-Pacific plate underneath the SCB (including Japan) during the Paleozoic represents another mantle convection cell with a northwestward (today&#x2019;s orientation) conveying direction (<xref ref-type="fig" rid="F9">Figure 9A</xref>, <xref ref-type="bibr" rid="B69">Li et al., 2006</xref>; <xref ref-type="bibr" rid="B70">Li and Li, 2007</xref>). Previous studies on the Indosinian deformation and magmatic activities of the SCB revealed that during &#x223c;260&#x2013;250&#xa0;Ma, an oceanic plateau arrived at the subduction zone which choked the magmatic arc and besides, the stress, that used to localize on the southeastern continental margin of the SCB, propagated from the continental margin northwestward to inland regions (<xref ref-type="fig" rid="F9">Figure 9B</xref>, <xref ref-type="bibr" rid="B70">Li and Li, 2007</xref>; <xref ref-type="bibr" rid="B113">Tatsumi et al., 2000</xref>). Based on these discussions, we suggest that the far-field stress from the southeast margin of the SCB due to interactions with the paleo-Pacific plate must have facilitated the formation of the SCB Indosinian intraplate orogen. The spatial distribution of the Indosinian high-grade metamorphism in the Cathaysia Block is parallel with the Sulu orogenic belt (<xref ref-type="fig" rid="F1">Figure 1</xref>) and the metamorphic ages of the high-grade rocks within these two orogenic belts greatly overlap (<xref ref-type="fig" rid="F7">Figure 7</xref>), implying that this segment of the Central China Orogenic belt along the northern margin of the SCB is another stress source for the Indosinian intraplate orogeny of the SCB (<xref ref-type="fig" rid="F9">Figure 9B</xref>). This inference is consistent with previous studies which have already proposed that the Indosinian orogeny of the SCB is closely related to the far-field stress from the Central China Orogenic belt (<xref ref-type="bibr" rid="B168">Zhang et al., 2013</xref>; <xref ref-type="bibr" rid="B53">Li J. et al., 2017</xref>; <xref ref-type="bibr" rid="B132">Wang et al., 2021</xref>).</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Proposed tectonic evolutionary model for the formation of the Indosinian intraplate orogen in the SCB.</p>
</caption>
<graphic xlink:href="feart-10-892787-g009.tif"/>
</fig>
<p>A complete model for the formation of the Indosinian intraplate orogen in the SCB is, therefore, proposed based on the above discussions (<xref ref-type="fig" rid="F9">Figure 9</xref>). After the amalgamation of the Yangtze and Cathaysia Blocks during Neoproterozoic, the SCB soon witnessed rifting and formed the Nanhua Rift (<xref ref-type="bibr" rid="B62">Li W. X. et al., 2010</xref>; <xref ref-type="bibr" rid="B60">Li et al., 2005</xref>; <xref ref-type="bibr" rid="B127">Wang X.-C. et al., 2012</xref>, <xref ref-type="bibr" rid="B128">Wang X.-L. et al., 2012</xref>). This rift system aborted soon afterwards without the formation of open oceans. During Paleozoic, the South China Caledonian orogeny closed solidified this rift system and likely formed a foreland basin in the Cathaysia Block which remained there until Permo-Triassic (<xref ref-type="fig" rid="F9">Figure 9A</xref>, <xref ref-type="bibr" rid="B99">Shu et al., 2008a</xref>; <xref ref-type="bibr" rid="B97">Shu et al., 2011</xref>), providing the lithospheric weak zone for the intraplate orogenic events. The onset of the active continental margin of the SCB facing the paleo-Pacific (Panthalassa) plate dates back to the Paleozoic and during Permo-Triassic, the arrival of an oceanic plateau at the subduction zone choked the magmatic arc and the stress propagated to the inland regions of the SCB. Almost simultaneously, the collisional events between the SCB and the North China Craton slowed the northward moving of the SCB, providing another retroactive stress source to the SCB (<xref ref-type="fig" rid="F9">Figure 9B</xref>). Therefore, stress from both the northwest (Sulu orogenic belt) and southwest (paleo-Pacific) margins during Permo-Triassic acted within the SCB, forming a super-contraction zone in the Wuyi terrane of the northeast Cathaysia Block. The weak lithospheric zone of the Cathaysia Block accommodated the strain and witnessed strong deformation and significant crustal thickening, termed as the Indosinian Wuyi orogenic belt (<xref ref-type="fig" rid="F9">Figure 9B</xref>). After the collision of the SCB with the North China Craton, the major driving force for the convergence of these two continental blocks is believed to be the dragging of the eclogitized mafic crust of northern South China (<xref ref-type="bibr" rid="B18">Dong et al., 2013</xref>), providing an extensional environment in the Cathaysia Block which resulted in orogenic collapse and the formation of post-orogenic magmatism (<xref ref-type="fig" rid="F9">Figure 9C</xref>, <xref ref-type="bibr" rid="B61">Li W. et al., 2012</xref>; <xref ref-type="bibr" rid="B110">Sun et al., 2011</xref>, <xref ref-type="bibr" rid="B108">Sun et al., 2017</xref>). This new model is not only consistent with the geological records in and around the SCB but also has geological implications for interpreting intraplate orogens worldwide.</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s7">
<title>Conclusion</title>
<p>Based on the above descriptions and discussions, the following conclusions can be reached.<list list-type="simple">
<list-item>
<p>1) The occurrences of the Indosinian high-grade metamorphism define the northeast-southwest trending orogenic belt in the Cathaysia Block, southeast SCB, representing the uplifted Indosinian orogenic core components.</p>
</list-item>
<list-item>
<p>2) Whole-rock major and trace element compositions of the high-grade rocks vary significantly, due to metamorphic alterations. The overall trend of their variations constrains the protoliths to be emplaced in plate margin settings, showing E-MORB and OIB compositions by relatively immobile elements.</p>
</list-item>
<list-item>
<p>3) SIMS zircon U-Pb age dating confirm the metamorphic age of 246&#x2013;249&#xa0;Ma and an early Neoproterozoic protolith age of 946&#xa0;Ma. The magmatic zircon cores still preserve mantle-like O isotopic compositions of &#x223c;5.5 (&#x3b4;<sup>18</sup>O (V-SMOW)). Metamorphic zircons exhibit large variations in O isotopic compositions. Compared with whole-rock Sm-Nd isotopic compositions, zircon Lu-Hf isotopic compositions can better trace the features of the protoliths, confirming their generation during the early Neoproterozoic.</p>
</list-item>
<list-item>
<p>4) The protoliths of these metamorphic rocks were generated during the early Neoproterozoic and were continental crustal components during the Indosinian orogeny. Combined with the spatial distributions of the Indosinian metamorphism in the Cathaysia Block, we suggest that this orogen formed in the intraplate environment.</p>
</list-item>
<list-item>
<p>5) A summarization of Indosinian plate margin activities of the SCB led us to conclude that the driving stress for the formation of the SCB Indosinian orogen in the Wuyi terrane is from both the interactions with the paleo-Pacific plate in the southeast and the North China Craton in the north. In other words, the mantle convection cell that closed the Paleo-Tethys, and the one conveying the paleo-Pacific plate to the SCB continental margin both facilitated the formation of the Indosinian orogen in the Wuyi terrane of the Cathaysia Block. This Indosinian intraplate orogenic belt was primarily a lithospheric weak zone formed during the South China Caledonian orogeny.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec id="s8">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the <xref ref-type="sec" rid="s13">Supplementary Material</xref>, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s9">
<title>Author Contributions</title>
<p>LZ carried out all the analyses, processed the data and wrote the manuscript. MZ the leader of the research project, planned the blueprint of the research and provided corrections on the different versions of the manuscript. XZ Initiated the research, funded the field trip and the lab work, and helped preparing the manuscript.</p>
</sec>
<sec id="s10">
<title>Funding</title>
<p>This work was funded by the research programs (Grant Nos. 41872197, 41890832 and 41890834) supported by the National Nature Science Foundation of China and research programs (Grant Nos. DD20201116 and DD20211116) supported by the Chinese Geological Survey.</p>
</sec>
<sec sec-type="COI-statement" id="s11">
<title>Conflict of Interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s12">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ack>
<p>We are also grateful to Drs. Liu Yu, Tang Guoqiang, Ling Xiao and Prof Yang Yueheng for their help with SIMS zircon U-Pb age dating and O isotopic analysis, as well as zircon Lu-Hf isotopic analyses. Prof. Li Xianhua is greatly thanked for his very helpful discussions.</p>
</ack>
<sec id="s13">
<title>Supplementary Material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2022.892787/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2022.892787/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material>
<label>Supplementary Table S1</label>
<caption>
<p>Information of the studied samples of this study.</p>
</caption>
</supplementary-material>
<supplementary-material>
<label>Supplementary Table S2</label>
<caption>
<p>Whole-rock geochemical compositions of the studied samples.</p>
</caption>
</supplementary-material>
<supplementary-material>
<label>Supplementary Table S3</label>
<caption>
<p>SIMS zircon U-Pb age dating results of the studied samples.</p>
</caption>
</supplementary-material>
<supplementary-material>
<label>Supplementary Table S4</label>
<caption>
<p>SIMS zircon O isotope results of the studied samples.</p>
</caption>
</supplementary-material>
<supplementary-material>
<label>Supplementary Table S5</label>
<caption>
<p>Zircon Lu-Hf isotopic compositions of the studied samples.</p>
</caption>
</supplementary-material>
<supplementary-material>
<label>Supplementary Table S6</label>
<caption>
<p>Whole-rock Sm-Nd isotopic compositions of the studied samples.</p>
</caption>
</supplementary-material>
<supplementary-material xlink:href="Table1.XLS" id="SM1" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table4.XLS" id="SM2" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table2.XLS" id="SM3" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table5.XLS" id="SM4" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table3.XLS" id="SM5" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table6.XLS" id="SM6" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
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