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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">887154</article-id>
<article-id pub-id-type="doi">10.3389/feart.2022.887154</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Metamorphic <italic>P&#x2013;T</italic> Evolution and <italic>In Situ</italic> Biotite Rb&#x2013;Sr Geochronology of Garnet&#x2013;Staurolite Schist From the Ramba Gneiss Dome in the Northern Himalaya</article-title>
<alt-title alt-title-type="left-running-head">Gou et al.</alt-title>
<alt-title alt-title-type="right-running-head">The Ramba Gneiss Dome</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Gou</surname>
<given-names>Long-Long</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1511930/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Long</surname>
<given-names>Xiao-Ping</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Yan</surname>
<given-names>Hao-Yu</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Shu</surname>
<given-names>Tian-Chu</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Wang</surname>
<given-names>Jing-Yu</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Xu</surname>
<given-names>Xiao-Fei</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zhou</surname>
<given-names>Feng</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Tian</surname>
<given-names>Zhi-Bo</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>State Key Laboratory of Continental Dynamics</institution>, <institution>Department of Geology</institution>, <institution>Northwest University</institution>, <addr-line>Xi&#x2019;an</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Department of Earth and Environmental Sciences</institution>, <institution>RC Centre of Excellence for Core to Crust Fluid Systems</institution>, <institution>Macquarie University</institution>, <addr-line>Sydney</addr-line>, <addr-line>NSW</addr-line>, <country>Australia</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/144151/overview">Yi Chen</ext-link>, Institute of Geology and Geophysics (CAS), China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1182223/overview">Hao Wang</ext-link>, Institute of Geology and Geophysics (CAS), China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1700542/overview">Jia-Min Wang</ext-link>, Institute of Geology and Geophysics (CAS), China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Xiao-Ping Long, <email>longxp@nwu.edu.cn</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Petrology, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>01</day>
<month>07</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>10</volume>
<elocation-id>887154</elocation-id>
<history>
<date date-type="received">
<day>01</day>
<month>03</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>23</day>
<month>05</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Gou, Long, Yan, Shu, Wang, Xu, Zhou and Tian.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Gou, Long, Yan, Shu, Wang, Xu, Zhou and Tian</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>The North Himalayan gneiss domes provide a window for looking into the deeper crust and record abundant clues of continent collisional orogenesis. This study carried out detailed petrology, <italic>in situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr dating, and phase equilibrium modeling on garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome in order to constrain metamorphic <italic>P&#x2013;T</italic> evolution and the timing of metamorphism. A clock-wise <italic>P&#x2013;T</italic> path, involving an early prograde process that evolves from &#x223c;540&#xb0;C at &#x223c;4.4&#xa0;kbar to &#x223c;630&#xb0;C at &#x223c;6.0&#xa0;kbar, was constructed for garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome. <italic>In situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr analysis yielded two metamorphic ages of 37.17 &#xb1; 5.66 and 5.27 &#xb1; 3.10&#xa0;Ma, corresponding to the timing of retrograde cooling and the cooling age of the dome following the thermal resetting by the emplacement of ca. 8&#xa0;Ma leucogranite pluton in the core of the dome, respectively. The peak metamorphism is inferred to be older than ca. 37&#xa0;Ma. Based on these results and the data previously published, the garnet&#x2013;staurolite&#x2013;two-mica schist recorded the Eocene crustal thickening, following the India&#x2013;Asia collision and later the exhumation process.</p>
</abstract>
<kwd-group>
<kwd>phase equilibrium modeling</kwd>
<kwd>P&#x2013;T path</kwd>
<kwd>Ramba gneiss dome</kwd>
<kwd>E&#x2013;W extension</kwd>
<kwd>northern Himalaya</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Gneiss domes are ubiquitous structures in exhumed orogens (<xref ref-type="bibr" rid="B70">Whitney et al., 2004</xref>). During orogenesis, gneiss domes vertically transfer large volumes of deep-seated material into the upper crustal level (<xref ref-type="bibr" rid="B56">Teyssier and Whitney, 2002</xref>; <xref ref-type="bibr" rid="B47">Rey et al., 2017</xref>) and, thus, provide a window to investigate the orogenic process in the middle-to-lower crust. In addition, gneiss domes are often formed by the superposition of several dome-forming mechanisms or in several different tectonic settings (<xref ref-type="bibr" rid="B76">Yin, 2004</xref>). Therefore, gneiss domes were used to investigate the fundamental orogenic process and geodynamics of continental collision orogen, such as crustal thickening or shortening (<xref ref-type="bibr" rid="B75">Yin, 2006</xref>; <xref ref-type="bibr" rid="B53">Smit et al., 2014</xref>; <xref ref-type="bibr" rid="B5">Ding et al., 2016a</xref>) and extension (<xref ref-type="bibr" rid="B35">Lister and Davis, 1989</xref>; <xref ref-type="bibr" rid="B4">Chen et al., 1990</xref>; <xref ref-type="bibr" rid="B33">Lee and Whitehouse, 2007</xref>; <xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>).</p>
<p>The Himalayan orogen, as the result of the ongoing collision between the Indian and Asian plates, is one of the largest collisional orogens on the Earth (<xref ref-type="fig" rid="F1">Figure 1</xref>), which played a central role in understanding the continent&#x2013;continent collisional orogenesis (<xref ref-type="bibr" rid="B77">Yin and Harrison, 2000</xref>; <xref ref-type="bibr" rid="B3">Beaumont et al., 2001</xref>; <xref ref-type="bibr" rid="B13">Harris, 2007</xref>; <xref ref-type="bibr" rid="B49">Searle et al., 2009</xref>; <xref ref-type="bibr" rid="B42">Palin et al., 2014</xref>; <xref ref-type="bibr" rid="B63">Wang et al., 2016</xref>). The northern Himalayan belt is characterized by extension structures, including the north Himalayan gneiss domes (NHGDs), the south Tibet detachment system (STDS), and the north&#x2013;south trending rifts (NSTR) (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). During the past few decades, the formation mechanisms of the NHGD have been the subject of intensive studies (<xref ref-type="bibr" rid="B4">Chen et al., 1990</xref>; <xref ref-type="bibr" rid="B30">Lee et al., 2000</xref>, <xref ref-type="bibr" rid="B31">2004</xref>, <xref ref-type="bibr" rid="B32">2006</xref>; <xref ref-type="bibr" rid="B2">Aoya et al., 2006</xref>; <xref ref-type="bibr" rid="B45">Quigley et al., 2008</xref>; <xref ref-type="bibr" rid="B55">Stearns et al., 2013</xref>; <xref ref-type="bibr" rid="B81">Zhang et al., 2004</xref>, <xref ref-type="bibr" rid="B83">2012</xref>; <xref ref-type="bibr" rid="B5">Ding et al., 2016a</xref>, <xref ref-type="bibr" rid="B6">b</xref>; <xref ref-type="bibr" rid="B23">Jessup et al., 2019</xref>) as the NHGDs are the window to the middle-to-lower crust in the northern Himalayan belt and are the key to understand not only the tectonic evolution of the Himalayan orogen but also the geodynamic processes within the middle-to-lower crust of continent&#x2013;continent collisional orogens. Different geodynamic settings have been proposed to interpret the formation of the NHGD, such as north&#x2013;south extension with the top-to-north movement along the STDS (<xref ref-type="bibr" rid="B4">Chen et al., 1990</xref>; <xref ref-type="bibr" rid="B30">Lee et al., 2000</xref>, <xref ref-type="bibr" rid="B31">2004</xref>, <xref ref-type="bibr" rid="B32">2006</xref>; <xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>), diapirism of buoyant anatexis (<xref ref-type="bibr" rid="B29">LeFort et al., 1987</xref>; <xref ref-type="bibr" rid="B40">Harrison et al., 1997</xref>), and east&#x2013;west extension related to the NSTR (<xref ref-type="bibr" rid="B82">Zhang and Guo, 2007</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B8">Fu et al., 2016</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Generalized geological map of the Himalayan orogen (modified from <xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>). Abbreviations of metamorphic complexes: GT, Gangdese thrust; GCT, Greater Counter thrust; GKT, Gyirong&#x2013;Kangmar thrust; STDS, south Tibetan detachment system; MCT, main central thrust; MBT, main boundary thrust.</p>
</caption>
<graphic xlink:href="feart-10-887154-g001.tif"/>
</fig>
<p>The Ramba gneiss dome, which is dominated by the top-to-E shear structure, was considered to have been formed by the E&#x2013;W extension along the NSTR (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). However, due to the lack of metamorphic data for the Ramba gneiss dome up to now, the similarities and differences of the metamorphic <italic>P&#x2013;T&#x2013;t</italic> evolution between the Ramba gneiss dome and other famous gneiss domes (the Mabja dome and the Yardoi gneiss dome) are unclear.</p>
<p>In this article, the metamorphic <italic>P&#x2013;T</italic> evolution and the timing of metamorphism for garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome were constrained, with the evidence from detailed petrology, <italic>in situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr dating, and phase equilibrium modeling. Based on these results, the tectonic implications and the differences in metamorphic evolution between the E&#x2013;W and the N&#x2013;S extensional North Himalayan gneiss domes were discussed.</p>
</sec>
<sec id="s2">
<title>Geological Setting and Samples</title>
<p>The Himalayan orogen includes the northern Himalayas and the southern Himalayas, which are separated by the high crest line (<xref ref-type="bibr" rid="B75">Yin, 2006</xref>). The STDS is a network of detachment faults, juxtaposing the Tethys Himalayan sequences (THSs) in the hanging wall over the Greater Himalayan Crystallines (GHC) in the footwall (<xref ref-type="bibr" rid="B50">Searle and Godin, 2003</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). The southern Himalayas is composed of the GHC, the Lesser Himalayan sequences (LHSs), and the Siwalik group (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="fig" rid="F1">Figure 1</xref>). The GHC is characterized by the ca. 40&#x2013;30&#xa0;Ma high pressure (HP) granulite-facies rocks (<xref ref-type="bibr" rid="B26">Kohn and Corrie, 2011</xref>; <xref ref-type="bibr" rid="B46">Regis et al., 2014</xref>; <xref ref-type="bibr" rid="B20">Iaccarino et al., 2015</xref>; <xref ref-type="bibr" rid="B84">Zhang et al., 2015</xref>), the ca. 17&#x2013;14&#xa0;Ma granulitized eclogites (<xref ref-type="bibr" rid="B65">Wang Y. et al., 2017</xref>, <xref ref-type="bibr" rid="B59">2021</xref>; <xref ref-type="bibr" rid="B34">Li et al., 2019</xref>; <xref ref-type="bibr" rid="B80">Zhang et al., 2021</xref>; <xref ref-type="bibr" rid="B73">Wu et al., 2022</xref>), Barrovian metamorphic belts (<xref ref-type="bibr" rid="B64">Wang et al., 2013</xref>, <xref ref-type="bibr" rid="B60">2015</xref>; <xref ref-type="bibr" rid="B21">Iaccarino et al., 2017</xref>; <xref ref-type="bibr" rid="B52">Shrestha et al., 2017</xref>), and abundant ca. 33&#x2013;7&#xa0;Ma leucogranites (<xref ref-type="bibr" rid="B51">Searle et al., 1999</xref>; <xref ref-type="bibr" rid="B50">Searle and Godin, 2003</xref>; <xref ref-type="bibr" rid="B74">Wu et al., 2015</xref> and references therein; <xref ref-type="bibr" rid="B11">Gou et al., 2016</xref>; <xref ref-type="bibr" rid="B18">Hopkinson et al., 2017</xref>; <xref ref-type="bibr" rid="B36">Liu et al., 2022a</xref>). It underwent a long-lived partial melting from ca. 40 to 8&#xa0;Ma (e.g., <xref ref-type="bibr" rid="B64">Wang et al., 2013</xref>, <xref ref-type="bibr" rid="B60">2015</xref>, <xref ref-type="bibr" rid="B62">Wang et al., 2017 J.-M.</xref>; <xref ref-type="bibr" rid="B84">Zhang et al., 2015</xref>; <xref ref-type="bibr" rid="B57">Tian et al., 2019</xref>; <xref ref-type="bibr" rid="B37">Liu et al., 2022b</xref>). Within the GHC, tectono-metamorphic discontinuities have been recognized in the recent decade (<xref ref-type="bibr" rid="B63">Wang et al., 2016</xref>, and references therein).</p>
<p>The northern Himalayan belt is dominated by the THS, consisting of unmetamorphosed to low-grade metasedimentary rocks (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="fig" rid="F1">Figure 1</xref>). This belt is characterized by the NHGD cored by granite plutons (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>) and the crystallization ages of granites or leucogranites in the northern Himalayan belt ranging from ca. 48 to 8&#xa0;Ma (<xref ref-type="bibr" rid="B1">Aikman et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>; <xref ref-type="bibr" rid="B78">Zeng et al., 2011</xref>; <xref ref-type="bibr" rid="B9">Gao et al., 2012</xref>; <xref ref-type="bibr" rid="B74">Wu et al., 2015</xref>; <xref ref-type="bibr" rid="B79">Zeng and Gao, 2017</xref> and references). The dome geometry at the Mabja gneiss dome was formed by middle-Miocene southward-directed thrust faulting upward and southward, which are similar to those of the Kangmar dome (<xref ref-type="bibr" rid="B30">Lee et al., 2000</xref>, <xref ref-type="bibr" rid="B31">2004</xref>, <xref ref-type="bibr" rid="B32">2006</xref>). The peak metamorphic condition of the migmatite sample from the sillimanite-zone in the Mabja gneiss dome is 8.2&#xa0;kbar/705&#xb0;C (<xref ref-type="bibr" rid="B31">Lee et al., 2004</xref>), and the timing of peak metamorphism was constrained to be 35.0 &#xb1; 0.8&#xa0;Ma (<xref ref-type="bibr" rid="B33">Lee and Whitehouse, 2007</xref>). The structural, metamorphic, and intrusive histories in middle crustal rocks exposed in these NHGD are similar to those in the GHC, suggesting that the middle crust was continuous from beneath the northern Himalayas southward to the high Himalayas (<xref ref-type="bibr" rid="B32">Lee et al., 2006</xref>; <xref ref-type="bibr" rid="B33">Lee and Whitehouse, 2007</xref>). The garnet&#x2013;kyanite&#x2013;staurolite schists of the Yardoi gneiss dome in the eastern Himalaya record peak <italic>P&#x2013;T</italic> conditions of 7&#x2013;8&#xa0;kbar and 630&#x2013;660&#xb0;C. Zircon U&#x2013;Pb dating yielded metamorphic ages of 44.8 &#xb1; 1.1&#xa0;Ma, 46.7 &#xb1; 1.8&#xa0;Ma, and 48.2 &#xb1; 2.0&#xa0;Ma (<xref ref-type="bibr" rid="B5">Ding et al., 2016a</xref>), which were considered as the timing of prograde metamorphism (<xref ref-type="bibr" rid="B6">Ding et al., 2016b</xref>), and <xref ref-type="bibr" rid="B61">Wang et al. (2018)</xref> obtained metamorphic ages of 18&#x2013;17&#xa0;Ma using SHRIMP monazite U/Th-Pb analysis and suggested that north&#x2013;south extension in a convergent geodynamic setting during Early Miocene accounts for the formation of the Yardoi dome.</p>
<p>The Ramba gneiss dome is located on the west of the north&#x2013;south trending Yadong&#x2013;Gulu rift and near the Yarlung&#x2013;Zanbo suture (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>, <xref ref-type="bibr" rid="B39">2019</xref>; <xref ref-type="fig" rid="F1">Figures 1</xref>, <xref ref-type="fig" rid="F2">2</xref>). The dominant deformation was attributed to the E&#x2013;W extension of the NSTR (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). <xref ref-type="bibr" rid="B38">Liu et al. (2014)</xref> revealed that there were three epidotes (ca. 44&#xa0;Ma, ca. 28&#xa0;Ma, and ca. 8&#xa0;Ma) of granitic magmatism. The granitic rocks of ca. 44&#xa0;Ma and ca. 28&#xa0;Ma occur as strongly deformed porphyritic two-mica granite gneiss dykes, which intruded into the margin of the dome (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>, <xref ref-type="bibr" rid="B39">2019</xref>). The ca. 8&#xa0;Ma leucogranites include two-mica granite occupying the core of the dome and garnet-bearing granite dykes in the margin of the dome (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>), and the former has biotite and muscovite <sup>40</sup>Ar/<sup>39</sup>Ar ages of ca. 6&#xa0;Ma (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>
<bold>(A)</bold> Schematic geological map showing the Ramba gneiss dome and <bold>(B)</bold> cross-section (modified from <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>).</p>
</caption>
<graphic xlink:href="feart-10-887154-g002.tif"/>
</fig>
<p>Here, two representative samples (RB12-19 and RB12-24) selected for this study are garnet&#x2013;staurolite&#x2013;two-mica schist, belonging to the base of the THS on the basis of rock association in a previous study, which experienced detachment shear of STDS (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). These samples display porphyroblastic texture and are in gray color (<xref ref-type="fig" rid="F3">Figure 3</xref>). Pegmatites that are parallel to foliation can be observed (<xref ref-type="fig" rid="F3">Figure 3A</xref>), and garnet porphyroblasts are obvious on the outcrop (<xref ref-type="fig" rid="F3">Figure 3B</xref>).</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Field photographs of garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome.</p>
</caption>
<graphic xlink:href="feart-10-887154-g003.tif"/>
</fig>
</sec>
<sec id="s3">
<title>Petrography and Mineral Chemistry</title>
<p>Mineral compositions were analyzed using the JEOL JXA-8230 electron microprobe at the State Key Laboratory of Continental Dynamics (SKLCD), Northwest University, Xi&#x2019;an. The operating conditions were 2&#xa0;&#x3bc;m beam size, 15&#xa0;kV acceleration voltage, and 10&#xa0;nA beam current. Mineral abbreviations in this study follow <xref ref-type="bibr" rid="B69">Whitney and Evans (2010)</xref>. Compositional maps illustrating the distributions of Fe, Mg, Ca, and Mn were obtained for representative garnet porphyroblasts using the Quanta450 FEG field-emission environmental scanning electron microscope coupled with the X-MaxN 50 X-ray energy dispersive spectrometer at the SKLCD.</p>
<sec id="s3-1">
<title>Sample RB12-19</title>
<p>This sample consists of garnet (10%), staurolite (20%), biotite (25%), muscovite (10%), plagioclase (5%), and quartz (30%) and accessory minerals, including zircon, graphite, and ilmenite (<xref ref-type="fig" rid="F4">Figures 4A, B</xref>). Garnet occurs as euhedral to subhedral porphyroblasts with grain sizes of 0.4&#x2013;1.1&#xa0;mm in diameter (<xref ref-type="fig" rid="F4">Figures 4A, B</xref>), with minor quartz inclusions. Staurolite is present as a subhedral porphyroblast with grain sizes of 0.4&#x2013;1.0&#xa0;mm and is generally in contact with garnet (<xref ref-type="fig" rid="F4">Figures 4A, B</xref>); it displays a yellow-to-black color due to abundant graphite inclusion. Biotite and muscovite occur in the matrix and define the foliation (<xref ref-type="fig" rid="F4">Figure 4A</xref>). Plagioclase occurs as relatively small crystals in the matrix, and quartz occurs as small grains in the matrix or as mineral inclusions in garnet (<xref ref-type="fig" rid="F4">Figures 4A&#x2013;C</xref>). As a result, the peak metamorphic mineral assemblage is inferred to be garnet&#x2013;biotite&#x2013;muscovite&#x2013;plagioclase&#x2013;staurolite&#x2013;ilmenite&#x2013;quartz&#x2013;H<sub>2</sub>O.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Mineral assemblages and microstructures of garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome. <bold>(A,B)</bold> Photomicrographs to show garnet and staurolite porphyroblasts and matrix minerals, including biotite, muscovite, plagioclase, and quartz in sample RB12-19 (plane-polarized light). <bold>(C)</bold> Photomicrograph to show biotite, muscovite, quartz, and plagioclase in sample RB12-19 (back-scattered electron image). <bold>(D)</bold> Photomicrograph to show garnet porphyroblasts and matrix minerals, including biotite, muscovite, plagioclase, and quartz in the sample RB12-24 (plane-polarized light). <bold>(E)</bold> Photomicrographs to show garnet and staurolite porphyroblasts and matrix minerals, including biotite, muscovite, plagioclase, and quartz in sample RB12-24 (plane-polarized light).</p>
</caption>
<graphic xlink:href="feart-10-887154-g004.tif"/>
</fig>
<p>Mineral compositions and the mole fractions of end-members for sample RB12-19 are given in <xref ref-type="sec" rid="s13">Supplementary Table S1</xref>. The garnet is almandine-rich (<italic>X</italic>
<sub>Alm</sub> &#x3d; 0.72&#x2013;0.83), with low concentrations of spessartine (<italic>X</italic>
<sub>Sps</sub> &#x3d; 0.07&#x2013;0.18), pyrope (<italic>X</italic>
<sub>Prp</sub> &#x3d; 0.04&#x2013;0.09), and grossular (<italic>X</italic>
<sub>Grs</sub> &#x3d; 0.04&#x2013;0.06). The zoning profile of a representative garnet grain shows obvious compositional variation from core to rim (<xref ref-type="fig" rid="F5">Figure 5A</xref>), with increasing almandine and decreasing spessartine but relatively flat pyrope and grossular, which are consistent with distributions of Fe, Mg, Ca, and Mn on garnet compositional maps (<xref ref-type="fig" rid="F6">Figure 6A</xref>). Staurolite has homogeneous compositions, with <italic>X</italic>
<sub>Mg</sub> of 0.08&#x2013;0.10. Biotite and muscovite also exhibit homogeneous compositions, with <italic>X</italic>
<sub>Mg</sub> of 0.40&#x2013;0.41, Ti of 0.10&#x2013;0.12 cations per formula unit (cpfu), and Si of 3.09&#x2013;3.13&#xa0;cpfu, respectively. Plagioclase displays no compositional variation between different grains, with <italic>X</italic>
<sub>An</sub> of 0.27&#x2013;0.31.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Compositional mapping images of garnets in schist samples RB12-19 <bold>(A)</bold> and RB12-24 <bold>(B)</bold>.</p>
</caption>
<graphic xlink:href="feart-10-887154-g005.tif"/>
</fig>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Compositional profiles of garnet porphyroblasts from garnet&#x2013;staurolite&#x2013;two&#x2010;mica schist samples RB12-19 <bold>(A)</bold> and RB12-24 <bold>(B)</bold>. <bold>(A,B)</bold> show garnet compositions matching those at the corresponding locations along the compositional profile of garnet in <xref ref-type="fig" rid="F4">Figure 4</xref>.</p>
</caption>
<graphic xlink:href="feart-10-887154-g006.tif"/>
</fig>
</sec>
<sec id="s3-2">
<title>Sample RB12-24</title>
<p>Sample RB12-24 is composed of garnet (10%), staurolite (10%), biotite (20%), muscovite (5%), plagioclase (20%), and quartz (35%) and accessory minerals, including zircon, graphite, and ilmenite (<xref ref-type="fig" rid="F4">Figures 4C,D</xref>). Garnet occurs as subhedral porphyroblasts with grain sizes ranging from 0.5 to 2.7&#xa0;mm (<xref ref-type="fig" rid="F4">Figure 4D</xref>), larger than garnet in sample RB12-19 (<xref ref-type="fig" rid="F4">Figures 4A,B</xref>); it contains mineral inclusions of quartz (<xref ref-type="fig" rid="F4">Figure 4D</xref>). Staurolite is present as subhedral porphyroblasts with grain sizes of 0.3&#x2013;1.4&#xa0;mm and displays yellow-to-black color due to abundant graphite inclusion (<xref ref-type="fig" rid="F4">Figures 4C,E</xref>). Both garnet and staurolite are wrapped by a continuous foliation delineated by biotite and muscovite in the matrix (<xref ref-type="fig" rid="F4">Figures 4D,E</xref>). Plagioclase occurs as small grains in the matrix, and quartz occurs as small grains in the matrix or as mineral inclusions in garnet (<xref ref-type="fig" rid="F4">Figures 4D,E</xref>). Therefore, the peak metamorphic mineral assemblage is inferred to be garnet&#x2013;biotite&#x2013;muscovite&#x2013;plagioclase&#x2013;staurolite&#x2013;ilmenite&#x2013;quartz&#x2013;H<sub>2</sub>O.</p>
<p>Mineral compositions and the mole fractions of end-members for sample RB12-24 are given in <xref ref-type="sec" rid="s13">Supplementary Table S2</xref>. The garnet is almandine-rich (<italic>X</italic>
<sub>Alm</sub> &#x3d; 0.75&#x2013;0.87), with low pyrope (<italic>X</italic>
<sub>Prp</sub> &#x3d; 0.03&#x2013;0.04), spessartine (<italic>X</italic>
<sub>Sps</sub> &#x3d; 0.01&#x2013;0.08), and grossular (<italic>X</italic>
<sub>Grs</sub> &#x3d; 0.09&#x2013;0.14) (<xref ref-type="fig" rid="F5">Figure 5B</xref>). Compared to those of the sample RB12-19, the pyrope is lower, whereas the grossular is higher (<xref ref-type="fig" rid="F5">Figures 5A,B</xref>). The compositional profile of a representative garnet porphyroblast shows moderate variation from the core to the rim (<xref ref-type="fig" rid="F5">Figure 5B</xref>), involving increasing almandine and decreasing spessartine but flat pyrope and grossular. These are consistent with distributions of Fe, Mg, Ca, and Mn on garnet compositional maps (<xref ref-type="fig" rid="F6">Figure 6B</xref>). Staurolite is uniform in composition, with <italic>X</italic>
<sub>Mg</sub> ranging from 0.07 to 0.08. Biotite and muscovite also have homogeneous compositions, with <italic>X</italic>
<sub>Mg</sub> of 0.33&#x2013;0.35, Ti of 0.10&#x2013;0.12&#xa0;cpfu, and Si of 3.08&#x2013;3.12&#xa0;cpfu, respectively. Plagioclase displays moderate compositional variation between different grains and is more calcic than that in sample RB12-19, with <italic>X</italic>
<sub>An</sub> of 0.38&#x2013;0.53.</p>
</sec>
</sec>
<sec id="s4">
<title>Phase Equilibrium Modeling</title>
<p>The bulk chemical compositions (<xref ref-type="table" rid="T1">Table 1</xref>) were determined by wavelength-dispersive X-ray fluorescence (XRF) spectrometry on a fused bead at the SKLCD, Northwest University, Xi&#x2019;an. The normalized molar proportions used for the phase equilibrium modeling are given in <xref ref-type="table" rid="T1">Table 1</xref>. H<sub>2</sub>O was set to be in excess. On the basis of low whole-rock Fe<sup>3&#x2b;</sup> contents as revealed that garnet, staurolite, biotite, and muscovite in two samples are low in Fe<sup>3&#x2b;</sup> (<xref ref-type="sec" rid="s13">Supplementary Tables S1, S2</xref>), O &#x3d; 0.010 was selected. The calculated <italic>P&#x2013;T</italic> pseudosection allows the mineral assemblages to be evaluated within <italic>P&#x2013;T</italic> conditions between 450 and 750&#xb0;C and 3&#x2013;9&#xa0;kbar (<xref ref-type="fig" rid="F7">Figures 7</xref>, <xref ref-type="fig" rid="F8">8</xref>). Phase equilibrium calculations were performed using Thermocalc version tc340 (<xref ref-type="bibr" rid="B44">Powell et al., 1998</xref>; updated October 2013) in the MnO&#x2013;Na<sub>2</sub>O&#x2013;CaO&#x2013;K<sub>2</sub>O&#x2013;FeO&#x2013;MgO&#x2013;Al<sub>2</sub>O<sub>3</sub>&#x2013;SiO<sub>2</sub>&#x2013;H<sub>2</sub>O&#x2013;TiO<sub>2</sub>&#x2013;O<sub>2</sub> (MNCKFMASHTO) system, with the internally consistent thermodynamic dataset ds62 (<xref ref-type="bibr" rid="B16">Holland and Powell, 2011</xref>). The activity&#x2013;composition (<italic>a&#x2013;x</italic>) models for garnet, staurolite, biotite, cordierite, and chlorite are from <xref ref-type="bibr" rid="B66">White et al. (2014a</xref>, <xref ref-type="bibr" rid="B68">b)</xref>, plagioclase from <xref ref-type="bibr" rid="B17">Holland and Powell (2003)</xref>, ilmenite from <xref ref-type="bibr" rid="B67">White et al. (2000)</xref>, epidote from <xref ref-type="bibr" rid="B16">Holland and Powell (2011)</xref>, and muscovite and paragonite from <xref ref-type="bibr" rid="B54">Smye et al. (2010)</xref>. Pure phases included sillimanite, kyanite, andalusite, quartz, and rutile. The mineral abbreviations in this study follow those by <xref ref-type="bibr" rid="B69">Whitney and Evans (2010)</xref>.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Bulk compositions used for phase equilibrium modeling.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th colspan="13" align="center">Whole-rock compositions (wt.%)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Sample</td>
<td align="center">SiO2</td>
<td align="center">TiO<sub>2</sub>
</td>
<td align="center">Al<sub>2</sub>O<sub>3</sub>
</td>
<td align="center">Fe<sub>2</sub>O<sub>3</sub>
</td>
<td align="center">MnO</td>
<td align="center">MgO</td>
<td align="center">CaO</td>
<td align="center">Na<sub>2</sub>O</td>
<td align="center">K<sub>2</sub>O</td>
<td align="center">P<sub>2</sub>O<sub>5</sub>
</td>
<td align="center">LOI</td>
<td align="center">Total</td>
</tr>
<tr>
<td align="left">RB12-19</td>
<td align="char" char=".">59.37</td>
<td align="char" char=".">0.82</td>
<td align="char" char=".">20.56</td>
<td align="char" char=".">10.10</td>
<td align="char" char=".">0.28</td>
<td align="char" char=".">1.87</td>
<td align="char" char=".">0.50</td>
<td align="char" char=".">0.54</td>
<td align="char" char=".">3.12</td>
<td align="char" char=".">0.11</td>
<td align="char" char=".">2.60</td>
<td align="char" char=".">99.87</td>
</tr>
<tr>
<td align="left">RB12-24</td>
<td align="char" char=".">55.45</td>
<td align="char" char=".">0.95</td>
<td align="char" char=".">21.09</td>
<td align="char" char=".">9.47</td>
<td align="char" char=".">0.11</td>
<td align="char" char=".">1.57</td>
<td align="char" char=".">4.31</td>
<td align="char" char=".">2.03</td>
<td align="char" char=".">1.98</td>
<td align="char" char=".">0.13</td>
<td align="char" char=".">2.59</td>
<td align="char" char=".">99.68</td>
</tr>
</tbody>
</table>
<table>
<tbody valign="top">
<tr>
<td colspan="13" align="center">
<bold>Normalized molar proportion used for phase equilibrium modeling</bold>
</td>
</tr>
<tr>
<td align="left">Sample</td>
<td align="center">Figures</td>
<td align="center">H2O</td>
<td align="center">SiO<sub>2</sub>
</td>
<td align="center">Al<sub>2</sub>O<sub>3</sub>
</td>
<td align="center">CaO</td>
<td align="center">MgO</td>
<td align="center">FeO</td>
<td align="center">K<sub>2</sub>O</td>
<td align="center">Na<sub>2</sub>O</td>
<td align="center">TiO<sub>2</sub>
</td>
<td align="center">MnO</td>
<td align="center">O</td>
</tr>
<tr>
<td align="left">RB12-19</td>
<td align="center">7</td>
<td align="center">excess</td>
<td align="char" char=".">69.209</td>
<td align="char" char=".">14.123</td>
<td align="char" char=".">0.624</td>
<td align="char" char=".">3.250</td>
<td align="char" char=".">8.859</td>
<td align="char" char=".">2.320</td>
<td align="char" char=".">0.610</td>
<td align="char" char=".">0.719</td>
<td align="char" char=".">0.276</td>
<td align="char" char=".">0.010</td>
</tr>
<tr>
<td align="left">RB12-24</td>
<td align="center">8</td>
<td align="center">excess</td>
<td align="char" char=".">64.471</td>
<td align="char" char=".">14.449</td>
<td align="char" char=".">5.369</td>
<td align="char" char=".">2.721</td>
<td align="char" char=".">8.285</td>
<td align="char" char=".">1.468</td>
<td align="char" char=".">2.288</td>
<td align="char" char=".">0.831</td>
<td align="char" char=".">0.108</td>
<td align="char" char=".">0.010</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn>
<p>Notes: LOI, loss on ignition.</p>
</fn>
</table-wrap-foot>
</table-wrap>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>
<italic>P</italic>&#x2013;<italic>T</italic> pseudosections for the garnet&#x2013;staurolite&#x2013;two-mica schist sample RB12-19. <bold>(A)</bold> <italic>P</italic>&#x2013;<italic>T</italic> pseudosection that shows mineral assemblages. <bold>(B)</bold> <italic>P&#x2013;T</italic> pseudosection with isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> in garnet, <italic>X</italic>
<sub>Mg</sub> in staurolite, and <italic>X</italic>
<sub>Ti</sub> in biotite. The field of peak mineral assemblage is marked by grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O in red type.</p>
</caption>
<graphic xlink:href="feart-10-887154-g007.tif"/>
</fig>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>
<italic>P</italic>&#x2013;<italic>T</italic> pseudosections for the garnet&#x2013;staurolite&#x2013;two-mica schist sample RB12-24. <bold>(A)</bold> <italic>P</italic>&#x2013;<italic>T</italic> pseudosection that shows mineral assemblages. <bold>(B)</bold> <italic>P&#x2013;T</italic> pseudosection with isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> in garnet and <italic>X</italic>
<sub>Ti</sub> in biotite. The field of peak mineral assemblage is marked by grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O in red type.</p>
</caption>
<graphic xlink:href="feart-10-887154-g008.tif"/>
</fig>
<sec id="s4-1">
<title>Sample RB12-19</title>
<p>The peak phase assemblage is represented by the quinivariant field grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O, which has a wide <italic>P&#x2013;T</italic> range, with upper pressure and temperature of 670&#xb0;C and 7&#xa0;kbar, respectively (<xref ref-type="fig" rid="F7">Figure 7A</xref>). The chlorite-in and plagioclase-out assemblage field boundaries mark the low-temperature limit of this field. The upper temperature and pressure limits are the sillimanite-in and rutile-in assemblage field boundaries, respectively.</p>
<p>
<xref ref-type="fig" rid="F7">Figure 7B</xref> shows calculated isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> for garnet, <italic>X</italic>
<sub>Mg</sub> for staurolite, and <italic>X</italic>
<sub>Ti</sub> for biotite. In the peak phase assemblage field of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O, the <italic>X</italic>
<sub>Sps</sub> in garnet decreases significantly as pressure increases, and <italic>X</italic>
<sub>Ti</sub> in biotite increases as temperature increases. Isopleths of <italic>X</italic>
<sub>Ti(Bt)</sub> of 0.10&#x2013;0.12 are consistent with Ti contents of biotite (<xref ref-type="sec" rid="s13">Supplementary Table S1</xref>). The plotted isopleths of <italic>X</italic>
<sub>Grs</sub> for garnet are close to vertical and decrease as temperature increases. The <italic>X</italic>
<sub>Mg</sub> in staurolite ranges from 0.08 to 0.10 (<xref ref-type="sec" rid="s13">Supplementary Table S1</xref>), with corresponding isopleths plotted in the phase assemblage fields of grt&#x2013;ms&#x2013;chl&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O and grt&#x2013;bt&#x2013;ms&#x2013;chl&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O. As no prograde and retrograde metamorphic mineral assemblages were observed, isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> for garnet, <italic>X</italic>
<sub>Mg</sub> for staurolite, and <italic>X</italic>
<sub>Ti</sub> for biotite were used to constrain the <italic>P&#x2013;T</italic> evolution. Plagioclase is stable in the studied sample, and thus, mineral assemblages during the early prograde metamorphic stage should contain plagioclase. Therefore, the <italic>X</italic>
<sub>Mg</sub> isopleths of staurolite in the mineral assemblage fields that contain plagioclase can be used to constrain the <italic>P&#x2013;T</italic> conditions in the early stage of prograde metamorphism, although the defined <italic>P&#x2013;T</italic> range is relatively large (<xref ref-type="fig" rid="F7">Figure 7B</xref>). <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> in garnet and <italic>X</italic>
<sub>Ti</sub> in biotite constrain the peak metamorphic <italic>P&#x2013;T</italic> conditions to be &#x223c;630&#xb0;C at &#x223c;5.8&#xa0;kbar in the peak mineral assemblage field of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O. As a result, a prograde <italic>P&#x2013;T</italic> path that evolves roughly from &#x223c;540&#xb0;C at &#x223c;4&#xa0;kbar to &#x223c;630&#xb0;C at &#x223c;5.8&#xa0;kbar was defined for the sample RB12-19 (<xref ref-type="fig" rid="F7">Figure 7B</xref>).</p>
</sec>
<sec id="s4-2">
<title>Sample RB12-24</title>
<p>The peak phase assemblage of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O is represented by a quinivariant field, which occurs between 552 and 668&#xb0;C and 4.7&#x2013;6.9&#xa0;kbar (<xref ref-type="fig" rid="F8">Figure 8A</xref>). The sillimanite-in assemblage field boundary marks the upper-temperature limit of this field, and the rutile-in assemblage field boundary is the upper-pressure limit. The low temperature and pressure limits are the chlorite-in and muscovite-out assemblage field boundaries, respectively.</p>
<p>
<xref ref-type="fig" rid="F8">Figure 8B</xref> shows calculated isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> for garnet and <italic>X</italic>
<sub>Ti</sub> for biotite. The isopleths of <italic>X</italic>
<sub>Sps</sub> in garnet are horizontal and decrease as pressure increases, and the isopleths of <italic>X</italic>
<sub>Ti</sub> in biotite are vertical and increase as temperature increases, in the peak phase assemblage field (grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O). Ti contents of biotite correspond to isopleths of <italic>X</italic>
<sub>Ti(Bt)</sub> of 0.10&#x2013;0.12 (<xref ref-type="sec" rid="s13">Supplementary Table S2</xref>). In the phase assemblage field of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;chl&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O, the isopleths of <italic>X</italic>
<sub>Sps</sub> in garnet are close to horizontal and decrease as temperature increases. The plotted isopleths of <italic>X</italic>
<sub>Grs</sub> for garnet are near vertical and decrease as temperature increases. Similar to sample RB12-19, isopleths of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> for garnet and <italic>X</italic>
<sub>Ti</sub> for biotite were used to constrain the <italic>P&#x2013;T</italic> evolution. The <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> in the garnet core and mantle have crossover points in the mineral assemblage field grt&#x2013;bt&#x2013;ms&#x2013;chl&#x2013;pl&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O, which constrain the <italic>P&#x2013;T</italic> conditions in the early stage of prograde metamorphism to be &#x223c;540&#xb0;C at &#x223c;4.4&#xa0;kbar (<xref ref-type="fig" rid="F8">Figure 8B</xref>). In addition, the crossover points of <italic>X</italic>
<sub>Sps</sub> and <italic>X</italic>
<sub>Grs</sub> in the garnet rim fall into the peak phase assemblage field of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ilm&#x2013;qz&#x2013;H<sub>2</sub>O, which is close to or within the <italic>P&#x2013;T</italic> range defined by isopleths of <italic>X</italic>
<sub>Ti</sub> for biotite (<xref ref-type="fig" rid="F8">Figure 8B</xref>). As a result, a prograde <italic>P&#x2013;T</italic> path that evolves from &#x223c;540&#xb0;C at &#x223c;4.4&#xa0;kbar to &#x223c;620&#xb0;C at &#x223c;6.3&#xa0;kbar was acquired for the sample RB12-24 (<xref ref-type="fig" rid="F8">Figure 8B</xref>).</p>
</sec>
</sec>
<sec id="s5">
<title>LA&#x2013;ICP&#x2013;MS Biotite Rb&#x2013;Sr Geochronology</title>
<p>
<italic>In situ</italic> biotite Rb&#x2013;Sr dating was conducted on garnet&#x2013;staurolite&#x2013;two-mica schist samples RB12-19 and RB12-24. Biotite Rb&#x2013;Sr isotopic compositions were analyzed on thin sections (<xref ref-type="fig" rid="F9">Figure 9</xref>) using an NWR 193-nm ArF excimer laser-ablation (LA) system coupled to an inductively coupled plasma mass spectrometry (ICP-MS, iCAP TQ 00108) at the Guangzhou Tuoyan Analytical Technology Co., Ltd., Guangzhou, China. Ablation material was carried out with high-purity He gas, which was then mixed with Ar gas before introduction into the ICP-MS torch. The reaction gas N<sub>2</sub>O was used to suppress isobaric interferences as N<sub>2</sub>O is a highly potent reaction gas that reacts efficiently with Sr<sup>&#x2b;</sup> to form SrO<sup>&#x2b;</sup> ions but not with Rb<sup>&#x2b;</sup> (<xref ref-type="bibr" rid="B15">Hogmalm et al., 2017</xref>). The reaction rates are optimized by increasing N<sub>2</sub>O flow rates in the reaction cell and monitoring the sensitivity of Sr<sup>&#x2b;</sup> and SrO<sup>&#x2b;</sup> whilst ablating NIST SRM 610 and mica-Mg. It was found that the signals of SrO<sup>&#x2b;</sup> achieve maximum without significant loss in the Rb<sup>&#x2b;</sup> signal when using N<sub>2</sub>O at 25&#x2013;27% flow rates (0.25&#x2013;0.27&#xa0;ml&#xa0;min<sup>&#x2212;1</sup> of N<sub>2</sub>O).</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>
<italic>In situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr isochron diagrams and photos of biotite with the laser spot: <bold>(A)</bold> sample RB12-19 and <bold>(B)</bold> sample RB12-24.</p>
</caption>
<graphic xlink:href="feart-10-887154-g009.tif"/>
</fig>
<p>Before sample measurements, N<sub>2</sub>O was connected to the 4th mass flow controller in the iCAP TQ, and the lines were purged at a 25% flow rate (0.25&#xa0;ml&#xa0;min<sup>&#x2212;1</sup> of N<sub>2</sub>O) for 2&#xa0;h to maintain stability. This procedure washes out gas impurities and saturates the system, minimizing drift due to variations in the reaction rate. Then, the lens and cell parameters were tuned to maximize sensitivity by ablating NIST SRM 610 in the line scan mode (spot size, 30&#xa0;&#x3bc;m; pulse repetition rate, 10&#xa0;Hz; fluence, &#x223c;3.5&#xa0;J/cm<sup>2</sup>). Each analysis consists of 30&#xa0;s of background acquisition followed by 120&#xa0;s of ablation and 30&#xa0;s of washout. A dwell time of 50&#xa0;ms was used for the analysis of on-mass and mass-shifted Sr isotopes (<sup>86</sup>Sr, <sup>87</sup>Sr and <sup>88</sup>Sr, <sup>86</sup>Sr<sup>16</sup>O, <sup>87</sup>Sr<sup>16</sup>O, and <sup>88</sup>Sr<sup>16</sup>O) and <sup>85</sup>Rb. Typical laser settings during sample analysis are 110-&#x3bc;m spot size, &#x223c;7&#xa0;J/cm<sup>2</sup>, and 5-Hz pulse repetition. The detailed instrumentation and analytical conditions were set, following the method described by <xref ref-type="bibr" rid="B10">Gorojovsky and Alard (2020)</xref>. The raw data were exported offline, and the whole data reduction procedure was performed using an Excel macro program. The Mica-Mg was used as a primary reference standard for calibration of isotopic ratios of the samples. The standard NIST SRM 610 was used as secondary reference material to monitor the data quality, and the measured <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr ratios are 2.16 &#xb1; 0.08 (<italic>n</italic> &#x3d; 2, 2&#x3c3;) and 0.7110 &#xb1; 0.0048 (<italic>n</italic> &#x3d; 2, 2&#x3c3;), respectively. Compared with the recommended ratios for the standard NIST SRM 610 (<sup>87</sup>Rb/<sup>86</sup>Sr &#x3d; 2.33, <xref ref-type="bibr" rid="B10">Gorojovsky and Alard, 2020</xref>; <sup>87</sup>Sr/<sup>86</sup>Sr &#x3d; 0.709699 &#xb1; 0.000018, <xref ref-type="bibr" rid="B72">Woodhead and Hergt, 2001</xref>), the measured <sup>87</sup>Sr/<sup>86</sup>Sr ratio is similar within error, whereas the measured <sup>87</sup>Rb/<sup>86</sup>Sr ratio is slightly lower, which may be due to that the external standard Mica-Mg has a high <sup>87</sup>Rb/<sup>86</sup>Sr ratio (154&#x2013;155, <xref ref-type="bibr" rid="B10">Gorojovsky and Alard, 2020</xref>).</p>
<sec id="s5-1">
<title>Sample RB12-19</title>
<p>A total of 19 spot analyses were carried out on biotite in sample RB12-19. During a single spot analysis, spots 1, 6, and 7 yielded multiple intervals with obviously different ratios of <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr, which imply biotite may have inhomogeneous Rb&#x2013;Sr isotopic compositions. Thus, these spot analyses obtained more than one effective data (<xref ref-type="table" rid="T2">Table 2</xref>). The Rb&#x2013;Sr isotopic data of 3, 6.2, 7.2, 8, 14, 16, 17, and 18 were excluded during age calculation as these data are scattered on the <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr isochron diagram and cannot be well-included into an isochron (<xref ref-type="fig" rid="F9">Figure 9A</xref>). The remaining <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr ratios are 3.7942&#x2013;131.847 and 0.7062&#x2013;0.7866, respectively, which yielded an isochron age of 37.17 &#xb1; 5.66&#xa0;Ma (<italic>n</italic> &#x3d; 16, MSWD &#x3d; 1.5).</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr data for the garnet&#x2013;staurolite&#x2013;two-mica schist samples RB12-19 and RB12-24 of the Ramba gneiss dome.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Spot number</th>
<th align="center">
<sup>87</sup>Rb/<sup>86</sup>Sr</th>
<th align="center">&#xb1;1&#x3c3;</th>
<th align="center">
<sup>87</sup>Sr/<sup>86</sup>Sr</th>
<th align="center">&#xb1;1&#x3c3;</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">RB12-19-1.1</td>
<td align="char" char=".">4.1439</td>
<td align="char" char=".">0.1594</td>
<td align="char" char=".">0.7094</td>
<td align="char" char=".">0.0024</td>
</tr>
<tr>
<td align="left">RB12-19-1.2</td>
<td align="char" char=".">5.0593</td>
<td align="char" char=".">0.3273</td>
<td align="char" char=".">0.7148</td>
<td align="char" char=".">0.0041</td>
</tr>
<tr>
<td align="left">RB12-19-1.3</td>
<td align="char" char=".">3.7942</td>
<td align="char" char=".">0.0793</td>
<td align="char" char=".">0.7062</td>
<td align="char" char=".">0.0036</td>
</tr>
<tr>
<td align="left">RB12-19-1.4</td>
<td align="char" char=".">15.367</td>
<td align="char" char=".">0.931</td>
<td align="char" char=".">0.7080</td>
<td align="char" char=".">0.0081</td>
</tr>
<tr>
<td align="left">RB12-19-2</td>
<td align="char" char=".">10.427</td>
<td align="char" char=".">0.168</td>
<td align="char" char=".">0.7160</td>
<td align="char" char=".">0.0023</td>
</tr>
<tr>
<td align="left">RB12-19-3</td>
<td align="char" char=".">183.523</td>
<td align="char" char=".">6.350</td>
<td align="char" char=".">0.7565</td>
<td align="char" char=".">0.0131</td>
</tr>
<tr>
<td align="left">RB12-19-4</td>
<td align="char" char=".">49.214</td>
<td align="char" char=".">1.695</td>
<td align="char" char=".">0.7315</td>
<td align="char" char=".">0.0080</td>
</tr>
<tr>
<td align="left">RB12-19-5</td>
<td align="char" char=".">36.497</td>
<td align="char" char=".">1.044</td>
<td align="char" char=".">0.7317</td>
<td align="char" char=".">0.0042</td>
</tr>
<tr>
<td align="left">RB12-19-6.1</td>
<td align="char" char=".">10.901</td>
<td align="char" char=".">0.480</td>
<td align="char" char=".">0.7090</td>
<td align="char" char=".">0.0085</td>
</tr>
<tr>
<td align="left">RB12-19-6.2</td>
<td align="char" char=".">199.794</td>
<td align="char" char=".">7.703</td>
<td align="char" char=".">0.7130</td>
<td align="char" char=".">0.0108</td>
</tr>
<tr>
<td align="left">RB12-19-7.1</td>
<td align="char" char=".">42.885</td>
<td align="char" char=".">1.879</td>
<td align="char" char=".">0.7277</td>
<td align="char" char=".">0.0066</td>
</tr>
<tr>
<td align="left">RB12-19-7.2</td>
<td align="char" char=".">173.306</td>
<td align="char" char=".">8.544</td>
<td align="char" char=".">0.7473</td>
<td align="char" char=".">0.0157</td>
</tr>
<tr>
<td align="left">RB12-19-8</td>
<td align="char" char=".">185.504</td>
<td align="char" char=".">4.893</td>
<td align="char" char=".">0.7291</td>
<td align="char" char=".">0.0119</td>
</tr>
<tr>
<td align="left">RB12-19-9</td>
<td align="char" char=".">5.0690</td>
<td align="char" char=".">0.1682</td>
<td align="char" char=".">0.7078</td>
<td align="char" char=".">0.0025</td>
</tr>
<tr>
<td align="left">RB12-19-10</td>
<td align="char" char=".">32.900</td>
<td align="char" char=".">1.311</td>
<td align="char" char=".">0.7241</td>
<td align="char" char=".">0.0109</td>
</tr>
<tr>
<td align="left">RB12-19-11</td>
<td align="char" char=".">4.0210</td>
<td align="char" char=".">0.0361</td>
<td align="char" char=".">0.7113</td>
<td align="char" char=".">0.0028</td>
</tr>
<tr>
<td align="left">RB12-19-12</td>
<td align="char" char=".">131.847</td>
<td align="char" char=".">9.011</td>
<td align="char" char=".">0.7866</td>
<td align="char" char=".">0.0182</td>
</tr>
<tr>
<td align="left">RB12-19-13</td>
<td align="char" char=".">5.8127</td>
<td align="char" char=".">0.2173</td>
<td align="char" char=".">0.7153</td>
<td align="char" char=".">0.0026</td>
</tr>
<tr>
<td align="left">RB12-19-14</td>
<td align="char" char=".">410.698</td>
<td align="char" char=".">14.332</td>
<td align="char" char=".">0.7451</td>
<td align="char" char=".">0.0098</td>
</tr>
<tr>
<td align="left">RB12-19-15</td>
<td align="char" char=".">15.153</td>
<td align="char" char=".">0.254</td>
<td align="char" char=".">0.7078</td>
<td align="char" char=".">0.0025</td>
</tr>
<tr>
<td align="left">RB12-19-16</td>
<td align="char" char=".">4.4781</td>
<td align="char" char=".">0.2512</td>
<td align="char" char=".">0.7283</td>
<td align="char" char=".">0.0035</td>
</tr>
<tr>
<td align="left">RB12-19-17</td>
<td align="char" char=".">80.555</td>
<td align="char" char=".">5.304</td>
<td align="char" char=".">0.6933</td>
<td align="char" char=".">0.0093</td>
</tr>
<tr>
<td align="left">RB12-19-18</td>
<td align="char" char=".">5.9343</td>
<td align="char" char=".">0.1505</td>
<td align="char" char=".">0.7236</td>
<td align="char" char=".">0.0021</td>
</tr>
<tr>
<td align="left">RB12-19-19</td>
<td align="char" char=".">14.368</td>
<td align="char" char=".">0.379</td>
<td align="char" char=".">0.7115</td>
<td align="char" char=".">0.0055</td>
</tr>
<tr>
<td align="left">RB12-24-1</td>
<td align="char" char=".">27.899</td>
<td align="char" char=".">0.641</td>
<td align="char" char=".">0.7284</td>
<td align="char" char=".">0.0050</td>
</tr>
<tr>
<td align="left">RB12-24-2</td>
<td align="char" char=".">1.5530</td>
<td align="char" char=".">0.0572</td>
<td align="char" char=".">0.7108</td>
<td align="char" char=".">0.0035</td>
</tr>
<tr>
<td align="left">RB12-24-3</td>
<td align="char" char=".">82.637</td>
<td align="char" char=".">2.040</td>
<td align="char" char=".">0.7229</td>
<td align="char" char=".">0.0050</td>
</tr>
<tr>
<td align="left">RB12-24-4</td>
<td align="char" char=".">34.271</td>
<td align="char" char=".">0.808</td>
<td align="char" char=".">0.7292</td>
<td align="char" char=".">0.0061</td>
</tr>
<tr>
<td align="left">RB12-24-5</td>
<td align="char" char=".">17.226</td>
<td align="char" char=".">0.240</td>
<td align="char" char=".">0.7162</td>
<td align="char" char=".">0.0034</td>
</tr>
<tr>
<td align="left">RB12-24-6</td>
<td align="char" char=".">10.454</td>
<td align="char" char=".">0.259</td>
<td align="char" char=".">0.7143</td>
<td align="char" char=".">0.0022</td>
</tr>
<tr>
<td align="left">RB12-24-7</td>
<td align="char" char=".">2.5290</td>
<td align="char" char=".">0.0367</td>
<td align="char" char=".">0.7194</td>
<td align="char" char=".">0.0013</td>
</tr>
<tr>
<td align="left">RB12-24-8</td>
<td align="char" char=".">0.7626</td>
<td align="char" char=".">0.0269</td>
<td align="char" char=".">0.7154</td>
<td align="char" char=".">0.0019</td>
</tr>
<tr>
<td align="left">RB12-24-9</td>
<td align="char" char=".">7.5576</td>
<td align="char" char=".">0.1586</td>
<td align="char" char=".">0.7277</td>
<td align="char" char=".">0.0055</td>
</tr>
<tr>
<td align="left">RB12-24-10</td>
<td align="char" char=".">3.4705</td>
<td align="char" char=".">0.1246</td>
<td align="char" char=".">0.7159</td>
<td align="char" char=".">0.0033</td>
</tr>
<tr>
<td align="left">RB12-24-11</td>
<td align="char" char=".">40.928</td>
<td align="char" char=".">2.385</td>
<td align="char" char=".">0.7205</td>
<td align="char" char=".">0.0034</td>
</tr>
<tr>
<td align="left">RB12-24-12</td>
<td align="char" char=".">4.4946</td>
<td align="char" char=".">0.1882</td>
<td align="char" char=".">0.7162</td>
<td align="char" char=".">0.0014</td>
</tr>
<tr>
<td align="left">RB12-24-13</td>
<td align="char" char=".">24.686</td>
<td align="char" char=".">0.388</td>
<td align="char" char=".">0.7118</td>
<td align="char" char=".">0.0028</td>
</tr>
<tr>
<td align="left">RB12-24-14</td>
<td align="char" char=".">36.808</td>
<td align="char" char=".">0.581</td>
<td align="char" char=".">0.7259</td>
<td align="char" char=".">0.0046</td>
</tr>
<tr>
<td align="left">RB12-24-15</td>
<td align="char" char=".">2.5997</td>
<td align="char" char=".">0.0296</td>
<td align="char" char=".">0.7141</td>
<td align="char" char=".">0.0035</td>
</tr>
<tr>
<td align="left">RB12-24-16</td>
<td align="char" char=".">1.1962</td>
<td align="char" char=".">0.0594</td>
<td align="char" char=".">0.7174</td>
<td align="char" char=".">0.0010</td>
</tr>
<tr>
<td align="left">RB12-24-17.1</td>
<td align="char" char=".">2.7469</td>
<td align="char" char=".">0.0475</td>
<td align="char" char=".">0.7192</td>
<td align="char" char=".">0.0018</td>
</tr>
<tr>
<td align="left">RB12-24-17.2</td>
<td align="char" char=".">7.5095</td>
<td align="char" char=".">0.1211</td>
<td align="char" char=".">0.7202</td>
<td align="char" char=".">0.0033</td>
</tr>
<tr>
<td align="left">RB12-24-18</td>
<td align="char" char=".">2.0603</td>
<td align="char" char=".">0.0360</td>
<td align="char" char=".">0.7209</td>
<td align="char" char=".">0.0022</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s5-2">
<title>Sample RB12-24</title>
<p>Similar to sample RB12-19, 19 spot analyses were carried out on biotite in sample RB12-24. Spot 17 yielded multiple intervals with obviously different ratios of <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr, which obtained two effective datasets (<xref ref-type="table" rid="T2">Table 2</xref>). The <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr ratios of biotite in sample RB12-24 range from 0.763 to 82.637 and 0.711 to 0.729, respectively (<xref ref-type="table" rid="T2">Table 2</xref>). On the <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr isochron diagram, these data yielded an isochron age of 5.27 &#xb1; 3.10&#xa0;Ma (<italic>n</italic> &#x3d; 20, MSWD &#x3d; 1.9) (<xref ref-type="fig" rid="F9">Figure 9B</xref>). Obviously, this age is younger than that of sample RB12-19, although samples RB12-19 and RB12-24 were collected at the same outcrop, which may be due to limited spot analyses for each sample. In fact, sample RB12-19 has two Rb&#x2013;Sr isotopic trends (<xref ref-type="fig" rid="F9">Figure 9A</xref>). The first trend yielded an age of 37.17 &#xb1; 5.66&#xa0;Ma, whereas the second trend did not yield believable age due to the lack of low <sup>87</sup>Rb/<sup>86</sup>Sr data (<xref ref-type="fig" rid="F9">Figure 9A</xref>). We found that if the Rb&#x2013;Sr data within the second trend of sample RB12-19 were pooled together with the data of sample RB12-24, they could give a young age of 4.99 &#xb1; 1.30&#xa0;Ma (not shown), with a small error.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s6">
<title>Discussion</title>
<sec id="s6-1">
<title>Age of Metamorphism</title>
<p>Previous dating on Barrow-type metamorphic rocks in the NHGD generally yielded Oligocene to Miocene ages (<xref ref-type="bibr" rid="B55">Stearns et al., 2013</xref>; <xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>). For example, LA&#x2013;ICP&#x2013;MS monazite U/Th-Pb analysis constrained the timing of metamorphism to be 29&#x2013;14&#xa0;Ma for grt &#x2b; bt &#xb1; st &#xb1; ky &#xb1; sil schists from the Kangmar and Mabja gneiss domes (<xref ref-type="bibr" rid="B55">Stearns et al., 2013</xref>), and SHRIMP monazite U/Th-Pb analysis yielded ages of ca. 18&#xa0;Ma for grt &#x2b; bt &#x2b; st &#xb1; ky &#xb1; sil schists in the Yardoi gneiss dome (<xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>). These ages were interpreted as the timing of peak Barrow metamorphism recorded in the NHGD (<xref ref-type="bibr" rid="B55">Stearns et al., 2013</xref>; <xref ref-type="bibr" rid="B61">Wang et al., 2018</xref>), whereas prograde metamorphism occurred as early as 54&#x2013;49&#xa0;Ma based on garnet Lu&#x2013;Hf analysis (<xref ref-type="bibr" rid="B53">Smit et al., 2014</xref>). In addition, monazite U/Th-Pb geochronology of the Gianbul dome in the GHC yielded both Eocene (37&#x2013;33&#xa0;Ma) and Miocene (26&#x2013;22&#xa0;Ma) ages, which were interpreted as the timing of prograde Barrovian metamorphism and doming driven by upper-crustal extension and positive buoyancy of decompression melts, respectively (<xref ref-type="bibr" rid="B19">Horton et al., 2015</xref>).</p>
<p>In this study, <italic>in situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr dating yielded two metamorphic ages of 37.17 &#xb1; 5.66 and 5.27 &#xb1; 3.10&#xa0;Ma for the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome (<xref ref-type="fig" rid="F9">Figure 9</xref>). As the peak metamorphic temperatures of the garnet&#x2013;staurolite&#x2013;two-mica schists in the Ramba gneiss dome are higher than the closure temperature of the Rb&#x2013;Sr system in biotite (&#x223c;300&#x2013;400&#xb0;C) (<xref ref-type="bibr" rid="B58">Verschure et al., 1980</xref>; <xref ref-type="bibr" rid="B71">Willigers et al., 2004</xref> and references therein; <xref ref-type="bibr" rid="B48">Scibiorski et al., 2021</xref>), the age of 37.17 &#xb1; 5.66&#xa0;Ma is interpreted to represent the timing of retrograde cooling, rather than the peak metamorphism. This interpretation is obviously inconsistent with results from the Kangmar, Mabja, and Yardoi gneiss domes in the Northern Himalayas and the Gianbul dome in the GHC. However, <xref ref-type="bibr" rid="B28">Laskowski et al. (2016)</xref> have conducted geochronological research on HP meta-Tethyan rocks in the Lopu Range, located &#x223c;600&#xa0;km west of the city of Lhasa, yielding a garnet Lu-Hf age of 40.4 &#xb1; 1.4&#xa0;Ma and five Ar-Ar phengite ages between 39 and 34&#xa0;Ma, which were interpreted as the timing of prograde metamorphism and exhumation to mid-crustal depths (&#x223c;25&#xa0;km) and concomitant retrogression in the Himalayan orogen, respectively. <xref ref-type="bibr" rid="B25">Khanal et al. (2021)</xref> presented new monazite petrochronology for the Kathmandu Klippe in the central Nepalese Himalayas and revealed that Eocene prograde metamorphism and partial melting occurred at 44&#x2013;38&#xa0;Ma and 38&#x2013;35&#xa0;Ma, respectively (<xref ref-type="fig" rid="F10">Figure 10</xref>). Although the meta-Tethyan rocks in the Lopu Range underwent HP metamorphism and the Kathmandu Klippe belong to the upper or uppermost Greater Himalayan Crystallines, these results support that part of the middle-to-lower crustal rocks in the Himalayan orogen underwent exhumation and were not overprinted by Oligocene to Miocene peak Barrow metamorphism.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Summary of <italic>P&#x2013;T&#x2013;t</italic> paths of different Eocene units across the Himalayas, including the Ramba gneiss dome in this study, the Majba gneiss dome (<xref ref-type="bibr" rid="B31">Lee et al., 2004</xref>; <xref ref-type="bibr" rid="B33">Lee and Whitehouse, 2007</xref>; <xref ref-type="bibr" rid="B53">Smit et al., 2014</xref>), the Yardoi gneiss dome (<xref ref-type="bibr" rid="B6">Ding et al., 2016b</xref>), Hinterland GHC (<xref ref-type="bibr" rid="B20">Iaccarino et al., 2015</xref>), and the Kathmandu Klippe (<xref ref-type="bibr" rid="B25">Khanal et al., 2021</xref>). The boundary lines for metamorphic facies are modified from <xref ref-type="bibr" rid="B41">Palin et al. (2020)</xref>. UHT&#x2014;ultrahigh temperature; WBS&#x2014;wet basalt solidus.</p>
</caption>
<graphic xlink:href="feart-10-887154-g010.tif"/>
</fig>
<p>The age of 5.27 &#xb1; 3.10&#xa0;Ma is significantly younger than the crystallization ages (ca. 44&#xa0;Ma and ca. 28&#xa0;Ma) of granitic rocks that intruded into the margin of the Ramba gneiss dome (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>, <xref ref-type="bibr" rid="B39">2019</xref>). However, this age is slightly younger than the crystallization age (ca. 8&#xa0;Ma) of the leucogranite pluton occupying the core of the dome (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>) but is similar to <sup>40</sup>Ar/<sup>39</sup>Ar cooling ages (ca. 6&#xa0;Ma) of the leucogranite pluton (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>). Therefore, the age of 5.27 &#xb1; 3.10&#xa0;Ma is considered to represent the cooling age of the dome, following the emplacement of the ca. 8&#xa0;Ma leucogranites.</p>
</sec>
<sec id="s6-2">
<title>Metamorphic P&#x2013;T Paths</title>
<p>In this study, we have determined <italic>P&#x2013;T</italic> paths for the garnet&#x2013;staurolite&#x2013;two-mica schists in the Ramba gneiss dome (<xref ref-type="fig" rid="F7">Figures 7B</xref>, <xref ref-type="fig" rid="F8">8B</xref>). Sample RB12-19 recorded a prograde <italic>P&#x2013;T</italic> path that evolves roughly from &#x223c;540&#xb0;C at &#x223c;4&#xa0;kbar to &#x223c;630&#xb0;C at &#x223c;5.8&#xa0;kbar (<xref ref-type="fig" rid="F7">Figure 7B</xref>). The prograde <italic>P&#x2013;T</italic> path for sample RB12-24 evolves from &#x223c;540&#xb0;C at &#x223c;4.4&#xa0;kbar to &#x223c;620&#xb0;C at &#x223c;6.3&#xa0;kbar (<xref ref-type="fig" rid="F8">Figure 8B</xref>), which displays a slightly higher temperature than those of sample RB12-19&#xa0;at similar pressure (<xref ref-type="fig" rid="F7">Figures 7B</xref>, <xref ref-type="fig" rid="F8">8</xref>). When the results of the two samples are combined, it is clear that they experienced an obviously early heating burial path (<xref ref-type="fig" rid="F10">Figure 10</xref>). It can be noted that sample RB12-24 recorded a nearly isobaric heating path (<xref ref-type="fig" rid="F8">Figure 8B</xref>), and thus, a clock-wise <italic>P&#x2013;T</italic> evolution is inferred to the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome (<xref ref-type="fig" rid="F10">Figure 10</xref>).</p>
<p>Here, we compared this <italic>P&#x2013;T</italic> path with those retrieved from the Mabja and Yardoi gneiss domes in the northern Himalaya, the hinterland GHC, and the foreland Kathmandu Klippe (<xref ref-type="fig" rid="F10">Figure 10</xref>). The migmatite sample of the sillimanite zone in the Mabja gneiss dome has a peak metamorphic condition of 8.2&#xa0;kbar/705&#xb0;C (<xref ref-type="bibr" rid="B31">Lee et al., 2004</xref>), which is higher in both pressure and temperature than those of the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome (<xref ref-type="fig" rid="F10">Figure 10</xref>). The garnet&#x2013;staurolite&#x2013;kyanite schist in the Yardoi gneiss dome has a peak metamorphic mineral assemblage of grt&#x2013;bt&#x2013;ms&#x2013;pl&#x2013;st&#x2013;ky&#x2013;ilm&#x2013;qz, occurring in a narrow <italic>P&#x2013;T</italic> condition of 7.2&#x2013;8.0&#xa0;kbar and 640&#x2013;645&#xb0;C, and the prograde <italic>P&#x2013;T</italic> condition was constrained to be &#x223c;540&#xb0;C at &#x223c;4.6&#xa0;kbar using compositional isopleths <italic>X</italic>
<sub>Mg</sub> (0.07) and <italic>X</italic>
<sub>Mn</sub> (0.17) of the garnet core (<xref ref-type="bibr" rid="B6">Ding et al., 2016b</xref>). Combined with the retrograde metamorphic process constrained using the occurrence of sillimanite and biotite in the shear bands and the presence of chlorite, <xref ref-type="bibr" rid="B6">Ding et al. (2016b)</xref> obtained a clockwise <italic>P&#x2013;T</italic> path for the garnet&#x2013;staurolite&#x2013;kyanite schist in the Yardoi gneiss dome, which is similar to that constrained by <xref ref-type="bibr" rid="B61">Wang et al. (2018)</xref>. This <italic>P&#x2013;T</italic> path is characterized by a prograde process with both P and T increasing and a retrograde process with an early nearly isothermal decompression and late cooling and decompression. It is obvious that the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome has a similar prograde <italic>P&#x2013;T</italic> condition to that of the schist in the Yardoi gneiss dome but a lower pressure condition at <italic>P</italic>
<sub>max</sub> (<xref ref-type="fig" rid="F10">Figure 10</xref>). In this study, the retrograde <italic>P&#x2013;T</italic> evolution was not supported by the petrological evidence and was only inferred. The <italic>P&#x2013;T</italic> path of the Kathmandu Klippe in the central Nepalese Himalayas is clockwise, with peak <italic>P&#x2013;T</italic> conditions of 730&#x2013;760&#xb0;C and up to 10.5&#xa0;kbar, which is higher in both pressure and temperature than those of the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome but is similar to those from the GHC hinterland (<xref ref-type="fig" rid="F10">Figure 10</xref>) (<xref ref-type="bibr" rid="B20">Iaccarino et al., 2015</xref>).</p>
</sec>
<sec id="s6-3">
<title>Implications for the Formation of the Ramba Gneiss Dome</title>
<p>Ultrahigh pressure (UHP) metamorphic rocks at Kaghan Valley and Tso Morari in the west of the northern Himalayan belt have peak metamorphic ages of 46.2 &#xb1; 0.7&#xa0;Ma and ca. 47&#x2013;43&#xa0;Ma, respectively (<xref ref-type="bibr" rid="B24">Kaneko et al., 2003</xref>; <xref ref-type="bibr" rid="B7">Donaldson et al., 2013</xref>). These suggest deep subduction of the Indian continent at ca. 47&#x2013;43&#xa0;Ma. The crustal thickening in the Tibetan Himalaya is broadly synchronous with the Eocene collision between the Indian and Asian plates (<xref ref-type="bibr" rid="B53">Smit et al., 2014</xref>). Following the crustal thickening, the deeply buried Indian continental crust underwent a long-lived partial melting (<xref ref-type="bibr" rid="B64">Wang et al., 2013</xref>; <xref ref-type="bibr" rid="B84">Zhang et al., 2015</xref>), which formed the ca. 48 to 8&#xa0;Ma granites or leucogranites in the northern Himalayan belt (<xref ref-type="bibr" rid="B1">Aikman et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>; <xref ref-type="bibr" rid="B78">Zeng et al., 2011</xref>; <xref ref-type="bibr" rid="B9">Gao et al., 2012</xref>; <xref ref-type="bibr" rid="B74">Wu et al., 2015</xref>; <xref ref-type="bibr" rid="B79">Zeng and Gao, 2017</xref> and references). In the Ramba gneiss dome, the partial melting is reflected by three epidotes (ca. 44&#xa0;Ma, ca. 28&#xa0;Ma, and ca. 8&#xa0;Ma) of granitic magmatism (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>, <xref ref-type="bibr" rid="B39">2019</xref>). On the basis of the similarities in Eocene metamorphic conditions and timing of anatexis in the different Eocene units across the Himalayas, <xref ref-type="bibr" rid="B25">Khanal et al. (2021)</xref> concluded that an early-stage anatectic response to crustal thickening might be more common than previously thought.</p>
<p>The onset of extensional tectonics of the STDS occurred as early as ca. 36&#x2013;30&#xa0;Ma, which marks the initial thinning of thickened crust in the northern Himalayan belt (<xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B27">La Roche et al., 2016</xref>). In the Ramba gneiss dome, the STDS is represented by the first episode of deformation with top to-NNW sliding, indicated by S&#x2013;C fabric and NNW-convergent tight folds on the northwestern flank of the dome (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>). The clock-wise <italic>P&#x2013;T</italic> evolution of the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome, combined with the age of 37.17 &#xb1; 5.66&#xa0;Ma from the <italic>in situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr dating, is consistent with the Eocene crustal thickening (<xref ref-type="fig" rid="F10">Figure 10</xref>).</p>
<p>The ca. 8&#xa0;Ma leucogranites occupy the core of the Ramba gneiss dome (<xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>) and have <sup>40</sup>Ar/<sup>39</sup>Ar cooling ages of ca. 6&#xa0;Ma (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>). The Yadong&#x2013;Gulu rift, on the east of the dome, was active during the interval ca. 11&#x2013;5&#xa0;Ma, with its peak activity at ca. 8&#xa0;Ma (<xref ref-type="bibr" rid="B43">Pan and Kidd, 1992</xref>; <xref ref-type="bibr" rid="B14">Harrison et al., 1995</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>), which coincides with the diapir of the ca. 8&#xa0;Ma leucogranite pluton, formed the shape of the Ramba gneiss dome (<xref ref-type="bibr" rid="B12">Guo et al., 2008</xref>; <xref ref-type="bibr" rid="B83">Zhang et al., 2012</xref>; <xref ref-type="bibr" rid="B38">Liu et al., 2014</xref>).</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s7">
<title>Conclusion</title>
<p>The garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome followed a clock-wise <italic>P&#x2013;T</italic> path, involving an early prograde process that evolves from &#x223c;540&#xb0;C at &#x223c;4.4&#xa0;kbar to &#x223c;630&#xb0;C at &#x223c;6.0&#xa0;kbar. This prograde evolution is similar to the schist in the Yardoi gneiss dome but with lower <italic>T</italic> condition at <italic>P</italic>
<sub>max</sub> and reflects the crustal thickening, following the Indian-Asian collision. <italic>In situ</italic> LA&#x2013;ICP&#x2013;MS biotite Rb&#x2013;Sr analysis obtained two metamorphic ages of 37.17 &#xb1; 5.66 and 5.27 &#xb1; 3.10&#xa0;Ma for the garnet&#x2013;staurolite&#x2013;two-mica schist in the Ramba gneiss dome. The former corresponds to the timing of retrograde cooling. The latter is similar to <sup>40</sup>Ar/<sup>39</sup>Ar cooling ages (ca. 6&#xa0;Ma) of ca. 8&#xa0;Ma leucogranite and, thus, represents the cooling age of the dome, following the thermal resetting by the emplacement of ca. 8&#xa0;Ma leucogranite pluton in the core of the dome. The peak metamorphism should be older than ca. 37&#xa0;Ma.</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s8">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s13">Supplementary Material</xref>; further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s9">
<title>Author Contributions</title>
<p>L-LG: investigation, data curation, and writing&#x2014;original draft preparation. X-PL: conceptualization and investigation. H-YY, T-CS, and J-YW: investigation. X-FX, FZ, and Z-BT: visualization and editing.</p>
</sec>
<sec id="s10">
<title>Funding</title>
<p>This work is supported by a research grant from the State Key Laboratory of Continental Dynamics (SKLCD-04).</p>
</sec>
<sec sec-type="COI-statement" id="s11">
<title>Conflict of Interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s12">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ack>
<p>The authors thank editor YC for editorial handling work. HW and J-MW for their helpful comments that significantly improved the manuscript.</p>
</ack>
<sec id="s13">
<title>Supplementary Material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2022.887154/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2022.887154/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="Table1.docx" id="SM1" mimetype="application/docx" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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