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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">672119</article-id>
<article-id pub-id-type="doi">10.3389/feart.2021.672119</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Hints on the Late Miocene Evolution of the Tonale-Adamello-Brenta Region (Alps, Italy) Based on Allochtonous Sediments From Raponzolo Cave</article-title>
<alt-title alt-title-type="left-running-head">Sauro et&#x20;al.</alt-title>
<alt-title alt-title-type="right-running-head">Cave Sediments Record Paleolandscape Evolution</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Sauro</surname>
<given-names>Francesco</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1053231/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Fellin</surname>
<given-names>Maria Giuditta</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1275627/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Columbu</surname>
<given-names>Andrea</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1239293/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>H&#xe4;uselmann</surname>
<given-names>Philipp</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Borsato</surname>
<given-names>Andrea</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1246549/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Carbone</surname>
<given-names>Cristina</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>De Waele</surname>
<given-names>Jo</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/312121/overview"/>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>Department of Biological, Geological and Environmental Sciences, University of Bologna, <addr-line>Bologna</addr-line>, <country>Italy</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>Geological Institute, ETH Z&#xfc;rich, <addr-line>Z&#xfc;rich</addr-line>, <country>Switzerland</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>Swiss Institute for Speleology and Karst Studies (SISKA), <addr-line>La Chaux-de-Fonds</addr-line>, <country>Switzerland</country>
</aff>
<aff id="aff4">
<label>
<sup>4</sup>
</label>School of Environmental and Life Sciences, University of Newcastle, <addr-line>Callaghan</addr-line>, <addr-line>NSW</addr-line>, <country>Australia</country>
</aff>
<aff id="aff5">
<label>
<sup>5</sup>
</label>Department of Earth, Environmental and Life Sciences (DISTAV), Genoa University, <addr-line>Genoa</addr-line>, <country>Italy</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/268617/overview">Andrea Zerboni</ext-link>, University of Milan, Italy</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1251112/overview">Nadja Zupan Hajna</ext-link>, Research Center of the Slovenian Academy of Sciences and Arts, Slovenia</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/92091/overview">Fabio Matano</ext-link>, National Research Council, Italy</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1249273/overview">Fabrizio Berra</ext-link>, University of Milan, Italy</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Andrea Columbu, <email>andrea.columbu2@unibo.it</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Quaternary Science, Geomorphology and Paleoenvironment, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>28</day>
<month>05</month>
<year>2021</year>
</pub-date>
<pub-date pub-type="collection">
<year>2021</year>
</pub-date>
<volume>9</volume>
<elocation-id>672119</elocation-id>
<history>
<date date-type="received">
<day>25</day>
<month>02</month>
<year>2021</year>
</date>
<date date-type="accepted">
<day>10</day>
<month>05</month>
<year>2021</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2021 Sauro, Fellin, Columbu, H&#xe4;uselmann, Borsato, Carbone and De Waele.</copyright-statement>
<copyright-year>2021</copyright-year>
<copyright-holder>Sauro, Fellin, Columbu, H&#xe4;uselmann, Borsato, Carbone and De Waele</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these&#x20;terms.</p>
</license>
</permissions>
<abstract>
<p>Raponzolo is a paleo-phreatic cave explored in 2011 in the Brenta Dolomites (Trentino, Italy), at the remarkable altitude of 2,560&#xa0;m a.s.l. Differently to all other caves of the area, it hosts well-cemented fine to medium sands of granitic-metamorphic composition. The composition suggests a sediment source from the Adamello and Tonale Unit, separated from the Brenta by one of the most important tectonic lineaments of the Alps (Giudicarie Line). The fine-sand sediment was sampled to determine burial time and thus a minimum age of the cave. Cosmogenic isotopes (<sup>26</sup>Al and <sup>10</sup>Be) in quartz grains allowed to estimate a minimum burial age of 5.25&#xa0;Ma based on the mean sediment transport time at the surface and infer original altitude of the catchment area. Detrital apatite fission-track (AFT) and U-Pb dating on zircons provide information on the source, both from a regional and altitude (exhumation) perspective. Two populations of detrital AFT ages center at 17 (&#x2212;2.3&#x20;&#x2b; 2.6) Ma and 23 (&#x2212;3.3 &#x2b; 3.9) Ma, whereas the main detrital zircon U-Pb age populations are younger than 40&#xa0;Ma. These correspond to intrusive and metamorphic sources nowadays outcropping exclusively above 2,200&#x2013;2,300&#xa0;m a.s.l. in Northern Adamello and Tonale. The results point to a late Miocene erosion and infilling of the cave by allochtonous sediments, with important implications on the timing of cave speleogenesis, as well as the paleogeographical connection, tectonic evolution and uplift of different structural units of the Alps. The roundness and the well sorted size of the quartz grains suggest a fluvial or aeolian origin, possibly recycled by glacial activity related to cold events reported in high latitude areas of the world at 5.75 and 5.51&#xa0;Ma. These glacial phases have never been documented before in the Alps. This information confirms that the valleys dividing these geological units were not yet deeply entrenched during the onset of the Messinian Salinity Crisis (5.6&#x2013;5.5&#xa0;Ma), allowing an efficient transport of sediments across major tectonic lineaments of the Alps. This study shows the potential of cave sediments to provide information not only on the age of speleogenesis but also on the paleogeography of a wide area of the Alps during the late Miocene.</p>
</abstract>
<kwd-group>
<kwd>Al-Be isotopes</kwd>
<kwd>speleogenesis</kwd>
<kwd>paleogeography</kwd>
<kwd>cave sediments</kwd>
<kwd>AFT analysis</kwd>
<kwd>U-Pb zircon dating</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Understanding how the topography and physiography of the Alps evolved from the Eocene to the Miocene has been one of the main challenges in Alpine geology over the last decades (<xref ref-type="bibr" rid="B78">Schmid et&#x20;al., 2004</xref>; <xref ref-type="bibr" rid="B40">Garzanti and Malus&#xe0;, 2008</xref>; <xref ref-type="bibr" rid="B77">Schlunegger and Mosar, 2011</xref>; <xref ref-type="bibr" rid="B19">Campani et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B90">Winterberg and Willett, 2019</xref>). Paleogeographic reconstructions based on synorogenic detrital archives have resolved large-scale features of the surface evolution of the Alps (<xref ref-type="bibr" rid="B20">Carrapa and Di Giulio, 2001</xref>; <xref ref-type="bibr" rid="B57">Kuhlemann and Kempf, 2002</xref>). A detailed exhumation history of the metamorphic and igneous rocks of the Alps has been reconstructed based on a dense thermochronologic dataset (<xref ref-type="bibr" rid="B37">Fox et&#x20;al., 2016</xref>). However, carbonate massifs as those of the Southern Alps are difficult to integrate into paleogeographic and exhumation/uplift models, lacking powerful chronological, thermal and distinct compositional markers applicable to these geological terrains. While the evolution of the Southern Alps has been studied through structural mapping and tectonic reconstruction (<xref ref-type="bibr" rid="B32">Doglioni and Bosellini, 1987</xref>; <xref ref-type="bibr" rid="B22">Castellarin and Cantelli, 2000</xref>), scarce information is available on the absolute timing of the events, uplift, erosion rates and especially paleogeographic arrangements in pre-Quaternary times (<xref ref-type="bibr" rid="B82">Stefani et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B60">Malus&#xe0; et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B71">Potter and Szatmari 2009</xref>; <xref ref-type="bibr" rid="B37">Fox et&#x20;al., 2016</xref>). This information gap could be fulfilled by the study of karst system, which are abundant in the Southern Alps. Kartsic caves are often characterized by the presence of well-developed paleo-phreatic levels evolving in response to surface evolution and valley entrenchment (<xref ref-type="bibr" rid="B2">Audra et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B74">Sauro et&#x20;al., 2012</xref>). The arrangement of these cave levels can be correlated with the deepening of the water table due to uplift of karst massifs through time; however, constraining speleogenetic phases with absolute chronology remains challenging (<xref ref-type="bibr" rid="B75">Sauro et&#x20;al., 2013</xref>; <xref ref-type="bibr" rid="B26">Columbu et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B25">Columbu et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B5">Ballesteros et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B6">Bella et&#x20;al., 2019</xref>). The study of allochthonous sediments in ancient cave systems can be a powerful tool to better understand the paleogeographic evolution in karst areas (<xref ref-type="bibr" rid="B85">Stock et&#x20;al., 2005b</xref>). While calcite speleothems can grow at any (usually air-filled) stage once the void is formed, and are mainly useful for paleoclimatic and paleo-environmental reconstructions (<xref ref-type="bibr" rid="B33">Fairchild et&#x20;al., 2006</xref>), the introduction of allochthonous sediments within cave systems is often synchronous or occurs shortly after the genesis of cave passages (<xref ref-type="bibr" rid="B47">H&#xe4;uselmann, 2007</xref>; <xref ref-type="bibr" rid="B18">Calvet et&#x20;al., 2015</xref>), i.e.,&#x20;when the base level is still more or less at the same altitude of the caves themselves (<xref ref-type="bibr" rid="B27">Columbu et&#x20;al., 2018</xref>). In this case, burial time corresponds to the approximate age of the phreatic karst network at specific water table levels (<xref ref-type="bibr" rid="B43">Granger et&#x20;al., 2001</xref>; <xref ref-type="bibr" rid="B49">H&#xe4;uselmann and Granger, 2005</xref>). Accordingly, cosmogenic dating on cave sediments has been successfully applied in the North-Western calcareous Alps (<xref ref-type="bibr" rid="B49">H&#xe4;uselmann and Granger, 2005</xref>), in the Eastern Austrian Alps (<xref ref-type="bibr" rid="B51">H&#xe4;uselmann et&#x20;al., 2020</xref>), in the Southern calcareous Alps of Slovenia (<xref ref-type="bibr" rid="B50">H&#xe4;uselmann et&#x20;al., 2015</xref>) and in other karst areas of the World (<xref ref-type="bibr" rid="B1">Anthony and Granger, 2007</xref>; <xref ref-type="bibr" rid="B30">De Waele et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B18">Calvet et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B44">Granger et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B24">Columbu et&#x20;al., 2021</xref>). Nonetheless, a set of conditions has to be satisfied to consider a cave as a potential site for sediment burial studies and to meaningfully link cave development to tectonic evolution: 1) The presence of quartz-rich terrains in the vicinity of the karst system, procuring the sediment source; 2) geological and environmental conditions able to transport these allogenic sediments from the source area to the karstified units; 3) the injection of the sediment into the phreatic or epiphreatic conduits, often developed close to the local water table. In addition, the sediment should not be re-eroded, moved and stored in younger conduits at lower levels without having been exposed at the surface again. If this later transport would happen the age obtained with cosmogenic dating could not be associated to the correct speleogenetic phase (<xref ref-type="bibr" rid="B51">H&#xe4;uselmann et&#x20;al., 2020</xref>).</p>
<p>The Brenta Dolomites Massif is one of the areas of the Southern Alps where information about uplift and tectonic evolution is scarce. This area is situated to the south-east of a crucial tectonic triple junction (<xref ref-type="bibr" rid="B32">Doglioni and Bosellini, 1987</xref>), at the intersection between the Periadriatic line and the Giudicarie South and North lines (<xref ref-type="fig" rid="F1">Figures 1</xref>, <xref ref-type="fig" rid="F2">2</xref>), close to the border between the Austroalpine and Southern Alps (<xref ref-type="bibr" rid="B52">Heberer et&#x20;al., 2017</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Geographic overview of the Adamello (A), Brenta (B), Tonale (T) massifs in the frame of the Southern and Central Alps. The dotted box is approximately the area of <xref ref-type="fig" rid="F2">Figure&#x20;2</xref>. (Modified from <xref ref-type="bibr" rid="B72">Reverman et&#x20;al., 2012</xref>). PAL &#x3d; Periadriatic Line; NGL &#x3d; Northern Giudicarie Line; SGL &#x3d; Southern Giudicarie Line; VT &#x3d; Valsugana Thrust.</p>
</caption>
<graphic xlink:href="feart-09-672119-g001.tif"/>
</fig>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Regional geology of the study area and location of Raponzolo Cave (simplified from <xref ref-type="bibr" rid="B7">Bigi and Carrozzo, 1992</xref>).</p>
</caption>
<graphic xlink:href="feart-09-672119-g002.tif"/>
</fig>
<p>The Brenta Dolomites Massif represents the northern area of a mainly carbonatic mountain chain region of the Southern Alps, within the Giudicarie tectonic Belt. Permian volcano-sedimentary deposits are exposed in a few outcrops in the valley entrenchment of the Giudicarie South line (between Rendena Valley and Sabion Line, <xref ref-type="fig" rid="F2">Figure&#x20;2</xref>), but the most widespread formation in the Brenta Massif is the Upper Triassic &#x201c;Dolomia Principale&#x201d; (blue in <xref ref-type="fig" rid="F2">Figure&#x20;2</xref>), a carbonate shelf succession made up of a &#x223c;1,000&#xa0;m thick sequence of massive and laminated dolostones (<xref ref-type="bibr" rid="B14">Borsato et&#x20;al., 1994</xref>; <xref ref-type="bibr" rid="B21">Carton and Baroni, 2017</xref>). The Brenta Massif is characterized by a well-developed karst landscape with several deep vadose vertical caves and some subterranean networks presenting paleophreatic morphologies (<xref ref-type="bibr" rid="B28">Conci and Galvagni, 1952</xref>; <xref ref-type="bibr" rid="B11">Borsato, 1991</xref>; <xref ref-type="bibr" rid="B13">Borsato et&#x20;al., 2003</xref>; <xref ref-type="bibr" rid="B3">Audra et&#x20;al., 2006</xref>). This makes the Brenta Massif one of the most important karst areas in the Dolomites, with a well-articulate subsurface drainage network discharging in large karst springs along its perimeter at elevations between 1,400&#x2013;1,600&#xa0;m a.s.l. (perched aquifers) and 400&#x2013;600&#xa0;m a.s.l. (base level springs) (<xref ref-type="bibr" rid="B9">Borsato, 2001</xref>; <xref ref-type="bibr" rid="B10">Borsato, 2007</xref>). The Brenta karst area is bordered by metamorphic and intrusive units. Indeed, to the north-west, the region is characterized by the metamorphic nappes of Tonale, formed by high pressure mineral assemblages (<xref ref-type="bibr" rid="B83">Stipp et&#x20;al., 2002</xref>; <xref ref-type="bibr" rid="B80">Spalla et&#x20;al., 2003</xref>).To the west there is the Adamello Batholith, one of the most investigated areas of the Alps (<xref ref-type="bibr" rid="B15">Brack 1983</xref>; <xref ref-type="bibr" rid="B62">Martin et&#x20;al., 1993</xref>; <xref ref-type="bibr" rid="B34">Fellin et&#x20;al., 2002</xref>). Adamello is mostly composed of igneous rocks belonging to a large batholith formed by tonalite, granodiorite and gabbro (<xref ref-type="bibr" rid="B17">Callegari and Brack, 2002</xref>). It is the largest intrusive body of Alpine Tertiary magmatism emplaced during the Eocene to the early Oligocene. Adamello and Brenta both exhumed from 2 to 3&#xa0;km depth relatively to the modern surface since the late Miocene (<xref ref-type="bibr" rid="B72">Reverman et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B52">Heberer et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B81">Stalder et&#x20;al., 2018</xref>). Both Adamello and Tonale are now separated from Brenta Massif by deep glacial valleys entrenched along the main tectonic lines (<xref ref-type="fig" rid="F1">Figure&#x20;1</xref>).</p>
<p>Until a few decades ago, the caves of the Brenta Massif were considered mostly related to the last glacial phases (<xref ref-type="bibr" rid="B65">Nicod, 1976</xref>); the discovery of extensive phreatic galleries at 2,100&#xa0;m a.s.l., 1,300&#xa0;m above the present-day local groundwater table (<xref ref-type="bibr" rid="B11">Borsato, 1991</xref>; <xref ref-type="bibr" rid="B12">Borsato, 2012</xref>), suggested that speleogenetic processes were indeed more ancient and complex. In fact, several U/Th dating of speleothems from the Brenta Massif as well as on the nearby Paganella mountain are in secular equilibrium for <sup>238</sup>U/<sup>234</sup>U isotopes attesting an age older than 1&#xa0;Ma (<xref ref-type="bibr" rid="B8">Bini et&#x20;al., 1991</xref>; <xref ref-type="bibr" rid="B13">Borsato et&#x20;al., 2003</xref>; <xref ref-type="bibr" rid="B2">Audra et&#x20;al., 2007</xref>). However, no evidence of allochthonous cave sediments were known in the Brenta Massif until 2011, when the Gruppo Speleologico Trentino SAT Bindesi Villazzano discovered Raponzolo Cave, which represents a portion of a paleo-phreatic gallery of a presumably pre-Quaternary karst system given the high altitude occurrence (2,560&#xa0;m asl). The main cave passage was partially filled with allochthonous sandy sediments mainly composed of quartz and biotite. This discovery opened the possibility of performing sediment source and burial age studies in the area for the very first time. Consequently, the study of ancient Brenta karst systems and sediments trapped within cave conduits could represent a key for understanding the evolution of this massif.</p>
<p>This paper shows how a detailed analysis of cave sediments can provide valuable information on the geological and speleogenetic history of a cave, providing new hints on the paleogeography and tectonic evolution of a wide region of the&#x20;Alps.</p>
</sec>
<sec id="s2">
<title>Area of Study, Materials and Methods</title>
<sec id="s2-1">
<title>The Raponzolo Cave</title>
<p>Raponzolo Cave opens at 2,560&#xa0;m asl (46&#xb0;11&#x2032;55.1&#x2033;N, 10&#xb0;54&#x2032;40.7&#x2033;E), on the steep eastern flank of Cima Grost&#xe9; (2,898&#xa0;m a.s.l.), toward the upper end of the Tovel Valley, the widest valley of the Brenta Massif (3.5&#xa0;km of width, <xref ref-type="fig" rid="F2">Figure&#x20;2</xref>). The cave is a single sub-horizontal tunnel about 180&#xa0;m long, excavated in the Dolomia Principale formation. An initial W-trending ascending gallery paved with loose dolomitic sand is followed by a N-trending descending gallery partially filled with cemented medium-fine siliciclastic sand (<xref ref-type="fig" rid="F3">Figures 3</xref>, <xref ref-type="fig" rid="F4">4</xref>). Comparable sediments are not found anywhere else in the area. The sediments are present on the gallery floor as well as on walls and roofs, suggesting that the whole conduit was once filled (and then re-excavated). The cave presents typical phreatic morphologies with large scallops up to 0.5&#xa0;m in diameter, without traces of vadose morphologies (<xref ref-type="fig" rid="F3">Figure&#x20;3B</xref>).</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Cave morphologies and sediment: <bold>(A)</bold> The entrance of the Cave is a gallery truncated by erosion on the cliffs of Cima Grost&#xe9; (red arrow); <bold>(B)</bold> Typical paleophreatic conduit with elliptical shape and big scallops due to phreatic slow flow; <bold>(C)</bold> Remnants of cemented sandstone sediments on cave walls; <bold>(D)</bold> A sedimentary fracture infilling on the cave roof indicating that the whole gallery was originally filled and then re-excavated.</p>
</caption>
<graphic xlink:href="feart-09-672119-g003.tif"/>
</fig>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Topographic map of Raponzolo Cave (survey GST-SAT BV).</p>
</caption>
<graphic xlink:href="feart-09-672119-g004.tif"/>
</fig>
<p>The analyses targeted pristine and well cemented sediment samples from Raponzolo Cave. A multi-technique approach was used to obtain information about composition, provenance and burial time. These included: petrographic observation using an optical microscope, X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF), <sup>26</sup>Al and <sup>10</sup>Be cosmogenic isotopes, Apatite Fission Track (AFT) analyses and U-Pb dating on zircons.</p>
</sec>
<sec id="s2-2">
<title>Petrographic Observations and Grainsize</title>
<p>Petrographic observations were accomplished on three thin sections (&#x223c;25&#xa0;&#x3bc;m) with a LEICA Stereomicroscope and an OLYMPUS BX-41 optical microscope. Images have been obtained using a OLYMPUS COLOR VIEW II-SET camera and processed through OLYMPUS C-VIEW II-BUND-cell&#x5e;B software. For grainsize measurements, 300&#xa0;g of sample have been treated with a 70% acetic acid solution in order to dissolve the carbonate cement and release the insoluble fraction for grain size measurements through sieves. Pre- and post-dissolution weighing ascertained the cement/sediment ratio. Grainsize measurement utilized standard ASTM sieves 25, 40, 70, 100, 200, 230 and &#x3e;230, with meshes corresponding to 0.71, 0.425, 0.212, 0.15, 0.075, 0.063 and &#x3c;0.063&#xa0;mm, respectively. Analyses were accomplished at Bologna University (Italy).</p>
</sec>
<sec id="s2-3">
<title>XRF and XRD Analysis</title>
<p>The sample was ground to ultrafine powders and kept 24&#xa0;h at 110&#xb0;C. Ten grams of sample were mixed with 2.5&#x2013;5&#xa0;ml of Elvacite polymer resin, dissolved in acetone. The mixture was stirred to allow acetone evaporation and Elvacite distribution. The resultant powder was placed in a penny-shaped mold and compressed with a vertical pressure of 40&#xa0;MPa for 1&#xa0;min. A WD-XRF Axios&#x2013;Panalytical spectrometer equipped with five diffraction crystals was used for the analyses. The SuperQ software package provided by Panalytical was employed for calibration and data reduction. Calibration is based on 30 certified international standards. The precision of analyzed elemental abundances is better than&#x20;&#xb1; 0.2% for SiO<sub>2</sub>, and&#x20;&#xb1; 0.1% for the other major elements except for MnO<sub>2</sub> and P<sub>2</sub>O<sub>5</sub> that have concentration errors of approximately&#x20;&#xb1; 0.02%. For trace elements, relative errors are up to 10% for concentrations of 10&#x2013;100&#xa0;ppm, better than 5% for higher concentrations and reaching &#x223c;50% at levels below 10&#xa0;ppm. Therefore, the detection limit is approximately 5&#x2013;10&#xa0;ppm.</p>
<p>The mineralogical composition was investigated by a Philips PW3710&#x20;X-Ray diffractometer (current: 20&#xa0;mA, voltage: 40&#xa0;kV, range 2&#x3b8;: 5&#x2013;80&#xb0;, step size: 0.02&#xb0; 2&#x3b8;, time per step: 2&#xa0;s) operating at the University of Genua (Italy), which mounted a Co-anode. Acquisition and processing of data was carried out using the Philips High Score software package.</p>
</sec>
<sec id="s2-4">
<title>Cosmogenic Isotopes</title>
<p>The burial age method involves the measurement of two isotopes (<sup>26</sup>Al and <sup>10</sup>Be) that are produced by cosmic radiation in quartz near the surface prior to burial. <sup>26</sup>Al and <sup>10</sup>Be accumulate at a ratio of about 6.8:1 (<xref ref-type="bibr" rid="B4">Balco et&#x20;al., 2013</xref>) in quartz grains, with a rate of a few atoms per Gram of quartz per year. Sufficiently deep burial (more than 10&#xa0;m) of such quartz-rich sediments in a cave assures shielding from further cosmic rays. After burial, the <sup>26</sup>Al and <sup>10</sup>Be concentrations in the sample are only affected by their relative decay resulting in a decrease in the <sup>26</sup>Al/<sup>10</sup>Be ratio. This ratio can be used to derive a burial age (<xref ref-type="bibr" rid="B41">Gosse and Phillips, 2001</xref>; <xref ref-type="bibr" rid="B42">Granger, 2006</xref>). A prerequisite of the burial dating technique is that samples have been exposed long enough to cosmic rays and accumulated sufficient cosmogenic nuclides prior to burial. The upper limit for measurement of the <sup>26</sup>Al and <sup>10</sup>Be isotope pair is between 5 and 6&#xa0;Ma depending on the accumulated cosmogenic isotopes during surface exposure (<xref ref-type="bibr" rid="B51">H&#xe4;uselmann et&#x20;al., 2020</xref>).</p>
<p>The isotope concentrations can also be used to infer paleo-erosion rates of the source area prior to burial of the clasts. This is accomplished by backward modeling the quantity of nuclides present prior to the burial coupled with local production rate estimates. The pre-burial <sup>26</sup>Al/<sup>10</sup>Be ratio (&#x223c;6.8:1) is basically not influenced by production rate and thus elevation (<xref ref-type="bibr" rid="B66">Nishiizumi et&#x20;al., 1989</xref>; <xref ref-type="bibr" rid="B84">Stock et&#x20;al., 2005a</xref>) and therefore burial ages remain unaffected by altitude changes in the source&#x20;area.</p>
<p>The sediment sample was broken into smaller pieces and decarbonated using HCl; due to many accessory minerals, only 38.0062&#xa0;g of pure quartz could be recovered. Quartz was sieved and the fraction between 250 and 710&#xa0;&#xb5;m was physically concentrated (separation by form, magnet- and reverse magnet separation and heavy liquid) and then cleaned with HF-HNO<sub>3</sub> to remove intergrown feldspars to obtain a clean quartz concentrate. This concentrate was dissolved and cleaned by dissolution, precipitation, and ion exchange. <sup>26</sup>Al and <sup>10</sup>Be were separated, precipitated, oxidized, and measured on an AMS (in Purdue University). Chemical blanks were also measured to subtract laboratory influence. The AMS measures the <sup>10</sup>Be/<sup>9</sup>Be ratio and the <sup>26</sup>Al/<sup>27</sup>Al ratio; while <sup>9</sup>Be is added artificially, <sup>27</sup>Al normally abounds in quartz-rich samples.</p>
</sec>
<sec id="s2-5">
<title>Apatite Fission-Track Analyses</title>
<p>Fission-tracks in apatite are damage zones in the crystal lattice formed during the radioactive decay of <sup>238</sup>U. At temperatures above 120&#xb0;C tracks are quickly annealed, whereas at temperatures below 60&#xb0;C tracks are retained. The temperature range between retention and total annealing is called the partial annealing zone (PAZ). In this range fission tracks progressively narrow and shorten as a function of time and temperature (<xref ref-type="bibr" rid="B64">Naeser, 1979</xref>).</p>
<p>Fission-track sample preparation and analysis were performed on 100 apatite grains at ETH Zurich. Mounts of grains were polished and etched in 5.5&#xa0;N HNO<sub>3</sub> at 21&#xb0;C for 20&#xa0;s to reveal spontaneous tracks. Samples were irradiated with thermal neutrons in the reactor at the Radiation Center of Oregon State University with a nominal fluence of 1.2 &#xd7; 10<sup>16</sup>&#xa0;n/cm<sup>2</sup>. The CN-5 dosimeter was used to measure neutron fluence. After irradiation, induced fission tracks in the external detectors, low U muscovite sheets, were exposed through etching in 40% HF at 21&#xb0;C for 45&#xa0;min. AFT ages were calculated using the external-detector and the &#x3b6;-calibration methods (<xref ref-type="bibr" rid="B54">Hurford and Green, 1983</xref>) with IUGS standards (Durango and Fish Canyon) and a value of 0.5 for the 4p/2p geometry correction factor. The analyses were subjected to the &#x3c7;<sup>2</sup> test (<xref ref-type="bibr" rid="B38">Galbraith, 1981</xref>) to detect whether the data sets contained any extra-Poissonian age scatter. A &#x3c7;<sup>2</sup> probability of 5% denotes that the age distribution contains multiple age populations. AFT age distributions can be decomposed into age populations using kernel density estimate techniques: we used Binomfit by <xref ref-type="bibr" rid="B16">Brandon (1996)</xref> that is most suitable to deal with AFT samples with low density of spontaneous tracks.</p>
</sec>
<sec id="s2-6">
<title>U-Pb Zircon Chronology</title>
<p>U-Pb isotope intensities from 431 laser ablation spots in 371 zircon crystals were measured by inductively coupled plasma mass-spectrometry (LA-ICPMS) at ETH Zurich. The ablation areas with a spot diameter of 20&#xa0;&#x3bc;m were pre-selected with the aid of cathodoluminescence images in order to identify zonations and crystal defects, which were then avoided. Both the core and rim of zircons were measured in the suitable grains.</p>
<p>U and Pb were analyzed using a Resonetic Resolution 155 laser ablation system with a repetition rate of 5&#xa0;Hz and an energy density of 2&#xa0;J&#xa0;cm<sup>&#x2212;2</sup> coupled to a Thermo Element XR Sector-field ICP-MS measuring <sup>202</sup>Hg, <sup>204</sup>Pb, <sup>206</sup>Pb, <sup>207</sup>Pb, <sup>208</sup>Pb, <sup>232</sup>Th, <sup>235</sup>U, and <sup>238</sup>U intensities (<xref ref-type="bibr" rid="B45">Guillong et&#x20;al., 2014</xref>). GJ-1 (<xref ref-type="bibr" rid="B55">Jackson et&#x20;al., 2004</xref>) was used as primary reference material, and accuracy of the method was confirmed by four secondary standards (AUSZ7-5, OD-3, Temora2, and 91,500). Ages and ratios corrected for instrumental drift and down hole fractionation were obtained using the iolite 2.5 (<xref ref-type="bibr" rid="B67">Paton et&#x20;al., 2010</xref>) and VizualAge software (<xref ref-type="bibr" rid="B70">Petrus and Kamber, 2012</xref>). No common Pb correction was applied, since contaminated signals are recognized as discordant ages in the Concordia plots, which were produced with Isoplot 4.1 (<xref ref-type="bibr" rid="B59">Ludwig, 2001</xref>). Error ellipses represent 2&#xa0;s analytical errors of the <sup>207</sup>Pb/<sup>235</sup>U and <sup>206</sup>Pb/<sup>238</sup>U ratios, respectively.</p>
</sec>
</sec>
<sec sec-type="results" id="s3">
<title>Results</title>
<sec id="s3-1">
<title>Grainsize, Petrography and Composition</title>
<p>The sampled sediment from Raponzolo Cave is a fine (51.6%) to very fine (22.8%) sand with moderate mud (clay &#x2b; silt) fraction (18.2%); the carbonate cement and very few carbonatic grains, before dissolution, accounted for 54.4% of the original weight (<xref ref-type="fig" rid="F5">Figure&#x20;5</xref>). Thin section analyses have shown the presence of both monomineralic and polymineralic grains as following (<xref ref-type="fig" rid="F6">Figure&#x20;6</xref>; abundant: widespread in all observations; common: present in all observations; rare: only few grains detected):<list list-type="simple">
<list-item>
<p>&#x2022; Biotite (abundant) in form of elongated grains with rounded tips casually oriented within the sample.</p>
</list-item>
<list-item>
<p>&#x2022; Quartz (abundant) mainly rounded or sub-rounded</p>
</list-item>
<list-item>
<p>&#x2022; Plagioclase (common), mainly rounded and a few sub-angular grains, some with polysynthetic lamination</p>
</list-item>
<list-item>
<p>&#x2022; Zircon, mainly fractured (common)</p>
</list-item>
<list-item>
<p>&#x2022; K-Feldspar (rare)</p>
</list-item>
<list-item>
<p>&#x2022; Amphibole, green hornblende (rare)</p>
</list-item>
<list-item>
<p>&#x2022; Chalcedony (rare)</p>
</list-item>
<list-item>
<p>&#x2022; Apatite (rare)</p>
</list-item>
<list-item>
<p>&#x2022; Garnet (very rare)</p>
</list-item>
<list-item>
<p>&#x2022; Kyanite (very rare)</p>
</list-item>
</list>
</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Grainsize of the siliciclastic component of the samples: sand-size grains account for a total 81.8% while mud reached 18.2%. The siliciclastic component account for 46% of the total sample, while the total carbonate fraction (cement and few clasts) dissolved with acetic acid solution was 54% of the total sample.</p>
</caption>
<graphic xlink:href="feart-09-672119-g005.tif"/>
</fig>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Thin sections microphotographs [under polarizing microscope, <bold>(A,B)</bold> parallel polars, <bold>(C&#x2013;F)</bold> crossed polars] showing (red arrows): <bold>(A)</bold> elongated biotite; <bold>(B)</bold> rounded to subrounded quartz; <bold>(C)</bold> rounded K-feldspar; <bold>(D)</bold> subrounded plagioclase; <bold>(E)</bold> a lithic grain of amphibolite (quartz &#x2b; amphibole); <bold>(F)</bold> rounded chalcedony.</p>
</caption>
<graphic xlink:href="feart-09-672119-g006.tif"/>
</fig>
<p>In addition, a few polymineralic grains are representative of amphibolites, micaschists and gneiss. XRD analysis confirms thin section observations, although it was not able to define the specific amphibole as hornblende due to low lines at the limit of detection for these minerals. The composition of the sample obtained through XRF is reported in <xref ref-type="table" rid="T1">Table&#x20;1</xref>. High Ca content (&#x223c;34%) is related to the carbonate cement, while Si from quartz and Al from silicates reach respectively 25 and 9% of the sediment, with a relatively high Fe content (2.4%) (related to biotite and iron hidroxides). <italic>p</italic> (0.1 %wt, in form of P<sub>2</sub>O<sub>5</sub>) and Zr (84&#xa0;ppm) are due to the presence of apatites and zircons. Sub-rounded quartz grains are indication of transport by saltation and traction. Some of these grains show striking rounded morphologies, suggesting recycling through different erosion and transport phases. On the other hand, biotite is abundant and well preserved, with some rounded elongated morphologies related to limited transport by flotation (<xref ref-type="bibr" rid="B39">Garzanti et&#x20;al., 2011</xref>).</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>XRF results. Major elements are reported in weight percentage (%wt), Zr is reported in ppm. Other elements are considered irrelevant for this study, and thus omitted. LOI stands for loss of ignition.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Al<sub>2</sub>O<sub>3</sub>
</th>
<th align="left">CaO</th>
<th align="left">Fe<sub>2</sub>O<sub>3</sub>
</th>
<th align="left">K<sub>2</sub>O</th>
<th align="left">MgO</th>
<th align="left">MnO</th>
<th align="left">Na<sub>2</sub>O</th>
<th align="left">P<sub>2</sub>O<sub>5</sub>
</th>
<th align="left">SiO<sub>2</sub>
</th>
<th align="left">TiO<sub>2</sub>
</th>
<th align="left">LOI</th>
<th align="left">Zr</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">(wt%)</td>
<td align="center">%</td>
<td align="center">(ppm)</td>
</tr>
<tr>
<td align="char" char=".">9.44</td>
<td align="char" char=".">34.47</td>
<td align="char" char=".">2.40</td>
<td align="char" char=".">0.84</td>
<td align="char" char=".">1.87</td>
<td align="char" char=".">0.11</td>
<td align="char" char=".">0.22</td>
<td align="char" char=".">0.10</td>
<td align="char" char=".">25.02</td>
<td align="char" char=".">0.27</td>
<td align="char" char=".">25.26</td>
<td align="char" char=".">84</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-2">
<title>Burial Time From Cosmogenic Isotopes</title>
<p>The <sup>10</sup>Be/<sup>9</sup>Be ratio is very small (7.8 &#xd7; 10<sup>&#x2212;15</sup>), but in line with the relatively low amount of pure quartz dissolved. Nonetheless, the error of 10% can be considered acceptable for such low values. The measurement of the procedural blanks yielded a<sup>10</sup>Be/<sup>9</sup>Be ratio of 3.78 &#xd7; 10<sup>&#x2212;15</sup> and a<sup>26</sup>Al/<sup>27</sup>Al ratio of 6.41 &#xd7; 10<sup>&#x2212;15</sup>. The blanks thus show that the measurements were good and the standards clean. All results were normalized for a<sup>10</sup>Be half-life of 1.39&#xa0;Ma (<xref ref-type="bibr" rid="B23">Chmeleff et&#x20;al., 2010</xref>; <xref ref-type="bibr" rid="B56">Korschinek et&#x20;al., 2010</xref>). The uncertainties represent the analytical error only. The measurement of <sup>26</sup>Al/<sup>27</sup>Al yielded a value (2.78 &#xd7; 10<sup>&#x2212;15</sup>) below that of the blank (6.41 &#xd7; 10<sup>&#x2212;15</sup>). Therefore, there is no detectable <sup>26</sup>Al in the sample. The combined absence of <sup>26</sup>Al and presence of <sup>10</sup>Be demonstrates that the sediment was indeed once at the surface, but that the burial time was so long that all <sup>26</sup>Al decayed because of its shorter mean half-life. Since <sup>26</sup>Al is unavailable, the exact age of the sample cannot be given, as the initial concentration of isotopes prior to burial cannot be recalculated. Nonetheless, we can infer a range of possible burial ages based on the expected mean lifetime of the sediment at the surface and isotope production rate at the altitude of the original catchment area. This hypothesis is presented in the discussion (chapter&#x20;4.2).</p>
</sec>
<sec id="s3-3">
<title>Paleogeographic Provenance Inferred From AFT Thermochronology and Zircon U-Pb Ages</title>
<p>AFT analyses (<xref ref-type="sec" rid="s9">Supplementary Table S1</xref>) shows a distribution of dates between 4.5&#x20;&#xb1; 2.6&#xa0;Ma and 56&#x20;&#xb1; 17&#xa0;Ma (1&#x3c3;). Two distinct populations can be identified through standard kernel density estimate techniques (Binomfit by <xref ref-type="bibr" rid="B16">Brandon, 1996</xref>; <xref ref-type="sec" rid="s9">Supplementary Table S2</xref>): a minor and younger populations (P1) that includes 28% of the grains and centers at 17.6 (&#x2212;2,3 &#x2b; 2.6) Ma and a larger and older one (P2) that includes 72% of the grains and cetners at 23.3&#xa0;Ma (&#x2212;3.3 &#x2b; 3.9) (<xref ref-type="fig" rid="F7">Figure&#x20;7</xref>; <xref ref-type="sec" rid="s9">Supplementary Table S2</xref>). The 431&#x20;U-Pb dates (<xref ref-type="sec" rid="s9">Supplementary Table S3</xref>) show dates between 30 and &#x3e;1,000&#xa0;Ma old, including only two dates older than 1,000&#xa0;Ma. This wide distribution consists of two main populations, a larger one (91&#x20;&#xb1; 1%) with dates centered around 35&#xa0;Ma and a minor one between 270 and 600&#xa0;Ma (<xref ref-type="fig" rid="F8">Figure&#x20;8</xref>). While the first group is directly related to the emplacement of the Adamello batholith, the second is related to zircons from pre-alpine metamorphic rocks such as those of the Tonale Unit and south alpine basement, and/or to igneous zircons of the Adamello batholith with inherited&#x20;cores.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Apatite Fission Track dating distribution in the sample. The central age of the whole population is 21.68&#x20;&#xb1; 0.74&#xa0;Ma, which can be decomposed into two age populations (histogram below) using kernel density estimate techniques, showing a major peak (P2, 72%) at 23.3&#xa0;Ma and a minor one (P1; 28%) at 17.6&#xa0;Ma.</p>
</caption>
<graphic xlink:href="feart-09-672119-g007.tif"/>
</fig>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Concordia and isochron diagrams for U-Pb dating of zircons (above). Ellipses (correlated errors) correspond to two sigma -STERR of the mean ratios. Linear regression calculations were performed with ISOPLOT-3 (<xref ref-type="bibr" rid="B59">Ludwig, 2001</xref>). Distribution of ages in the last 50&#xa0;Ma show a peak at 36&#xa0;Ma (below).</p>
</caption>
<graphic xlink:href="feart-09-672119-g008.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="discussion" id="s4">
<title>Discussion</title>
<sec id="s4-1">
<title>Sediment Source</title>
<p>The petrographic composition of the sediment indicates a source situated mainly in the granitoid bodies of the Adamello Massif and in the metamorphic units of Tonale. Chalcedony is mostly related to the erosion of pseudotachylitic zones in Adamello-Presanella (<xref ref-type="bibr" rid="B68">Pennacchioni et&#x20;al., 2006</xref>) and minor cherts eroded from the carbonatic sequence of Brenta. Metamorphic clasts (amphibolite) and minerals (especially kyanite) indicate a provenance from the Tonale Unit, which is characterized by high-P mineral suites (<xref ref-type="bibr" rid="B29">Davide et&#x20;al., 2000</xref>).</p>
<p>AFT analysis provides additional indications on the source region (<xref ref-type="fig" rid="F9">Figure&#x20;9</xref>). In the Tonale Unit, AFT dates vary between 6 and 25&#xa0;Ma, and in the Adamello batholith between 8.3 and 23&#xa0;Ma (<xref ref-type="bibr" rid="B61">Martin et&#x20;al., 1998</xref>; <xref ref-type="bibr" rid="B88">Viola et&#x20;al., 2003</xref>; <xref ref-type="bibr" rid="B72">Reverman et&#x20;al., 2012</xref>). In both regions, AFT dates generally increase with elevation; although the AFT age-elevation relationships vary in age range and slope in different localities and in a few places they are disturbed by tectonic displacements. In the sediments from Raponzolo Cave, the largest fraction (72%) of the detrital AFT dates centers at 23.3&#xa0;Ma and the remaining fraction (28%) at 17.6&#xa0;Ma. Thus, the largest fraction of the detrital apatites (red area in <xref ref-type="fig" rid="F9">Figure&#x20;9</xref>) comes from the highest portions of the Tonale Unit and/or Adamello complex, at elevations above 2,300&#xa0;m a.s.l, at present time. Regarding the smaller fraction at 17.6&#xa0;Ma (blue area in <xref ref-type="fig" rid="F9">Figure&#x20;9</xref>), while for Tonale the altitude range of the source region is also above the present elevation of 2,300&#xa0;m a.s.l., for Adamello it is more difficult to constrain the altitude limit due to different profile distributions depending on the transect location (<xref ref-type="fig" rid="F9">Figure&#x20;9</xref>). To solve this uncertainty, another indication is provided by zircon U-Pb ages. Zircon U-Pb ages are related to the crystallization of the magma source, which is not synchronous in all areas of the Adamello. It is thus possible to better understand which part of the batholith the sediment was eroded from if specific age groups are dominant in the cave sediment. While the older zircon age group (<xref ref-type="fig" rid="F9">Figure&#x20;9</xref>) is related to recycling of crystals from the Permian basement and crustal rocks within the batholith (<xref ref-type="bibr" rid="B46">Hansmann and Oberli, 1991</xref>), the younger peak at 35&#xa0;Ma indicates that the sediment source was mainly situated in the northern sectors of the Adamello batholith (Adamello North, Genova Valley, <xref ref-type="fig" rid="F9">Figures 9</xref>, <xref ref-type="fig" rid="F10">10</xref>), as shown by previous U-Pb, K-Ar, and Rb/Sr dating from different areas (<xref ref-type="bibr" rid="B31">Del Moro et&#x20;al., 1983</xref>; <xref ref-type="bibr" rid="B76">Schaltegger et&#x20;al., 2019</xref>). Very few zircons in the dataset (&#x3c;10) are between 40&#x2013;42&#xa0;Ma indicating a negligible contribution from the southern area of the batholith (Daone, Rendena Valley; <xref ref-type="fig" rid="F9">Figures 9</xref>, <xref ref-type="fig" rid="F10">10</xref>; <xref ref-type="bibr" rid="B79">Schoene et&#x20;al., 2012</xref>). This information allows to define the source region of the sediment in the northern sector of Adamello where AFT ages around 17.6 are also above 2,200&#x2013;2,300&#xa0;m a.s.l. at present&#x20;time.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Different AFT Age/Altitude profiles compared with the two AFT populations detected in the sediment of Raponzolo Cave (blue 17.6&#xa0;Ma, red 23.3&#xa0;Ma). In the lower boxes, each transect is correlated with the U-Pb age of zircons in each area. DZ shows to which percentage of ages the populations in the Raponzolo sample are associated: ages between 29 and 36&#xa0;Ma (82%), ages between 40&#x2013;42 (9%), pre-Alpine ages (9%). AFT profiles: Tonale from <xref ref-type="bibr" rid="B61">Martin et&#x20;al. (1998)</xref>; Presanella from <xref ref-type="bibr" rid="B87">Viola et&#x20;al. (2001)</xref>; Genova and Daone valleys from <xref ref-type="bibr" rid="B72">Reverman et&#x20;al. (2012)</xref>; Rendena from <xref ref-type="bibr" rid="B61">Martin et&#x20;al. (1998)</xref>.</p>
</caption>
<graphic xlink:href="feart-09-672119-g009.tif"/>
</fig>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Graph plotting the <sup>10</sup>Be burial ages as a function of the catchment elevation based on a surface sediment exposure time of 9,300&#x20;&#xb1; 930&#xa0;years coupled with the calculated remaining <sup>26</sup>Al. The red dashed line at 5,000&#x20;<sup>26</sup>Al atoms/g defines the &#x201c;exclusion zone&#x201d; based on the absence of <sup>26</sup>Al in the sample. The line crosses the <sup>10</sup>Be age line at 5.25&#xa0;Ma corresponding to a minimum catchment elevation of 1,250&#xa0;m a.s.l.</p>
</caption>
<graphic xlink:href="feart-09-672119-g010.tif"/>
</fig>
<p>Therefore, the erosional phase producing the sediment filling Raponzolo cave occurred when the present valley network was not as deeply entrenched as today, and younger thermochronological units where not yet exposed in the source region.</p>
</sec>
<sec id="s4-2">
<title>Hypotheses on Age Based on Cosmogenic Nuclides</title>
<p>Due to the lack of <sup>26</sup>Al in the sediment, the exact age of burial cannot be calculated. However, it is possible to estimate a minimum age on the basis of the expected residence time at the surface and the cosmogenic production rate, which depends on the original altitude of the catchment area. The longer the sediment is at or near the surface (i.e.,&#x20;the smaller the erosion rate is), the more cosmogenic isotopes are produced. Once washed underground, these isotopes decay. If the sediment remained at the surface for a very short time, a little amount of isotopes is produced; it follows that after a comparable short burial time, the Al content would be no more measurable. The longer the sediment stayed at the surface, the more burial time is needed in order to completely deplete <sup>26</sup>Al. Therefore, in the case of the Raponzolo sediment, the main question is what a meaningful residence time at the surface could be. In order to provide a reasonable hypothesis on the residence time, we can consider the largest dataset available in the Alps: the data from Siebenhengste (<xref ref-type="bibr" rid="B48">H&#xe4;uselmann et&#x20;al., 2007</xref>). This dataset can be used as a reference for Raponzolo because of the similar settings, being Siebenhengste a karst system located within the higher ranges of the Alps (around 2000&#xa0;m a.s.l.) in an area which experienced glaciations, as is the case of the Brenta Dolomites. In Siebenhengste cosmogenic dating provided erosion rates ranging from 23 to 470&#xa0;m/Ma, while all but two have rates &#x3c;150&#xa0;m/Ma, indicating slower (pre- or interglacial) erosion. An averaged value yields 67&#xa0;m/Ma, which translates into an inherited <sup>10</sup>Be amount prior to burial of 169,000 at/g. Divided by the estimated production rate in that area of 18.09 at/g/a, this gives 9,300&#xa0;years residence time at the surface. The fastest, probably glacial, erosion rate gives a residence time of 1,300&#xa0;years.</p>
<p>Since production rate is dependent on altitude, the model should also consider the approximate height of the original catchment area of the Raponzolo sediment. In order to model altitudes, production rates and erosion rates, we can use as prerequisites the available data: 1) the amount of <sup>10</sup>Be remaining in the sample measured to be 8,800 at/g; 2) no measurable <sup>26</sup>Al is present due to its complete decay. The lack of <sup>26</sup>Al can be fixed to be less than 5,000 at/g, twice the value of the blank. Considering these values, it is possible to create a model and back-calculate catchment altitudes and ages (<xref ref-type="sec" rid="s9">Supplementary Table S4</xref>). This model shows that the fast erosion rate (surface residence time of 1,300&#xa0;years) can be excluded (red ages in <xref ref-type="sec" rid="s9">Supplementary Table S4</xref>) since it would give consistently measurable amounts of <sup>26</sup>Al (&#x3e;10,000 at/g) in the sample. Therefore, we hitherto used the mean erosion rate of 67&#xa0;m/Ma in the model (<xref ref-type="fig" rid="F10">Figure&#x20;10</xref>). With this erosion rate, the model provides the minimum elevation of the catchment area (which is 1,200&#xa0;m a.s.l.) and the minimum age that fulfills all prerequisites (around 5.25&#xa0;Ma) (<xref ref-type="fig" rid="F10">Figure&#x20;10</xref>). However, it is important to consider that this model output is based on the assumption that in Adamello and Brenta erosion and uplift were constant in time and space at the million-year timescale neglecting the effect of local differences as for instance fault displacement and differences in rock erodibility. This assumption is supported by thermochronologic data that in Adamello and Brenta do not resolve changes in the rate of exhumation after 4&#xa0;Ma (<xref ref-type="bibr" rid="B72">Revermann et&#x20;al., 2012</xref>) and that indicate possibly only little differential exhumation between the two massifs since 10&#xa0;Ma (<xref ref-type="bibr" rid="B52">Heberer et&#x20;al., 2017</xref>). Thus, our model points to the hypothesis that burial in the cave happened before 5.25&#xa0;Ma.</p>
</sec>
<sec id="s4-3">
<title>Hints of Late Miocene Glaciations and Recycling of Fluvial Sediments</title>
<p>The Raponzolo Cave presents morphologies consistent with a phreatic and/or epi-phreatic origin (<xref ref-type="fig" rid="F3">Figure&#x20;3B</xref>). The cave is probably only a fragment of an ancient karst system that has been eroded and uplifted to its present altitude (2,560&#xa0;m a.s.l.). The conduits originally formed close to the water table level, which could have been situated at the level of the late Miocene valley bottom. The catchment area was situated in the northern part of the Adamello batholith up to the Tonale Unit to the north of the Periadriatic line. At present, these areas are separated from the Tovel Valley by the Rendena and Meledrio Valleys developed along the South Giudicarie Line and culminating in the Campo Carlo Magno pass at 1,682&#xa0;m (<xref ref-type="fig" rid="F11">Figure&#x20;11</xref>). Unfortunately, the irregular layering of the granitic sediments in the cave is not diagnostic of the direction of water flow during the sediment deposition, so we cannot discern if the sediment was flushed within the karst system from the Tovel valley or from the Rendena valley. These two possibilities are represented in <xref ref-type="fig" rid="F11">Figures 11</xref>, <xref ref-type="fig" rid="F12">12</xref>. In the profile of <xref ref-type="fig" rid="F12">Figure&#x20;12</xref>, the present topography is projected at theoretical altitudes during the late Miocene considering, for simplicity, a constant and uniform erosion rate of 0.25&#xa0;km/Ma and rock uplift rate of 0.35&#xa0;km/Ma in agreement with several studies on the evolution of this alpine region (<xref ref-type="bibr" rid="B72">Revermann et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B52">Heberer et&#x20;al., 2017</xref> and references therein). This simplified assumption does not take into account differential erosion and uplift depending on lithologies and tectonic subdomains, but allows providing a general idea of the potential paleolandscape. Indeed, the Mediterranean salinity crisis and the base level dropdown during these times should have been the footprint of the present time hydrographic network in the Adamello-Brenta region, similar to what occurred in the Lepontine dome (<xref ref-type="bibr" rid="B40">Garzanti and Malus&#xe0;, 2008</xref>). If the sediment filled the karst system entering from the Rendena Valley, the clasts of the Tonale Unit had to be transported from the Sole Valley (766&#xa0;m at present-day Dimaro) uphill along the Meledrio Valley, and across Campo Carlo Magno Pass (1,682&#xa0;m at present day). If the sediments had to be transported inside the Tovel valley, they would have overcome also the Grost&#xe9; Pass (2,442&#xa0;m at present day, <xref ref-type="fig" rid="F11">Figure&#x20;11</xref>). From the data available and literature it is not possible to assess the hypothesis that the Meledrio or Tovel valleys were inverted at that time, allowing an efficient fluvial sediment transport from Tonale to Brenta. However, if the present topography should generally mirror the Miocene landscape, a relief inversion of these incisions after the Messinian sea level dropdown is unlikely suggesting that an uphill sediment transport from Tonale to Brenta would have been possible only by means of glaciers. The Adamello and Brenta massifs have been strongly affected by Quaternary glaciations, and during the Last Glacial Maximum, a glacial tongue from the Sole Valley filled the Meledrio Valley and surpassed the Campo Carlo Magno Pass where the reconstructed elevation of the glacier was around 2,100&#xa0;m (<xref ref-type="bibr" rid="B86">Trevisan, 1939</xref>; <xref ref-type="bibr" rid="B21">Carton and Baroni, 2017</xref>). Glaciers could have used the same transport route also during more ancient glaciations and remains the best candidates for the transport of sediments of the Tonale Unit from the Sole Valley up to the Raponzolo cave entrance. This hypothesis poses an interesting dilemma because Miocene glaciations in the Alps have never been documented. Instead, sedimentary evidence of localized latest Miocene&#x2013;Early Pliocene glaciations are known from Greenland (<xref ref-type="bibr" rid="B58">Larsen et&#x20;al., 1994</xref>) to South America (<xref ref-type="bibr" rid="B63">Mercer and Sutter, 1982</xref>). The North Atlantic records a major cooling episode and increase in global ice volume in the period from 6.26 to 5.5&#xa0;Ma that was marked by 18 glacial-to-interglacial oscillations, with the most prominent glacial phases at 5.75 and 5.51&#xa0;Ma (stages TG20 and TG12; <xref ref-type="bibr" rid="B53">Hodell et&#x20;al., 2001</xref>). These ages are within the possible range of the sediment infilling of Raponzolo being older than the minimum cosmogenic burial ages of the sediments calculated in the cosmogenic production model presented in chapter 4.2 (<xref ref-type="sec" rid="s9">Supplementary Table S4</xref>). Also, the expected altitude of the source between 1,200&#xa0;m (Rendena Valley sink, <xref ref-type="fig" rid="F12">Figure&#x20;12</xref>) and 1700&#xa0;m (Tovel Valley sink, <xref ref-type="fig" rid="F12">Figure&#x20;12</xref>) is in agreement with the minimum altitude catchment calculated by the&#x20;model.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Interpretation of sediment transport path from Adamello/Tonale toward Raponzolo Cave with the present hydrological network, major tectonic lines and U-Pb zircon ages from the different sectors.</p>
</caption>
<graphic xlink:href="feart-09-672119-g011.tif"/>
</fig>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>West-east profile across the Adamello and Brenta massifs with the theoretical reconstruction of the relief at 5.5&#xa0;Ma (dotted blue line). For simplicity the relief projection is based on a theoretical constant and uniform erosion rate of 0.25&#xa0;km/Ma and rock uplift rate of 0.35&#xa0;km/Ma, even if erosion and uplift have been surely acting with slightly different rates depending on lithologies and tectonic domains. This reconstruction is based on the assumption that nowadays valleys and prominent reliefs should have been following the footprint of the Messinian major base level drop during the Mediterranean salinity, similarly to other regions of the Alps (<xref ref-type="bibr" rid="B40">Garzanti and Malus&#xe0;, 2008</xref>). The theoretical vertical profiles of the Raponzolo cave are represented by bold purple line (catchment in the upper Tovel valley) and dotted purple line (catchment in the Rendena valley). The dashed blue line represents the ice extent in the Rendena Valley during the Last Glacial Maximum (<xref ref-type="bibr" rid="B86">Trevisan, 1939</xref>).</p>
</caption>
<graphic xlink:href="feart-09-672119-g012.tif"/>
</fig>
<p>The modest increases in global ice volume inferred from the benthic &#x3b4;<sup>18</sup>O signal (<xref ref-type="bibr" rid="B53">Hodell et&#x20;al., 2001</xref>) suggest that Late Miocene glaciations were not as widespread as the Quaternary ones. In this scenario, local Alpine glaciers were probably not able to reach the Po plain and, therefore, no glacial sediments have been preserved, aside of potential local traps like&#x20;caves.</p>
<p>A problem for this interpretation remains the roundness and well sorting of the Raponzolo sediment, which is in contrast with a glacial origin, pointing to a fluvial or aeolian transport instead. However, the first action of glacier flows is bulldozering the sediments already present at the valley bottoms (<xref ref-type="bibr" rid="B73">Rossato et&#x20;al., 2018</xref>), which are usually rich in fluvial components. Therefore, a recycling of fluvial sediment by glacier tongues is consistent with the grain size distribution and shape, as well as with the presence of well-preserved biotite, which has not been weathered after burial (<xref ref-type="bibr" rid="B69">Petersen and Rasmussen, 1980</xref>; <xref ref-type="bibr" rid="B36">F&#xf6;llmi et&#x20;al., 2009</xref>). However, we cannot exclude that the most rounded quartz grains could be related to recycling of aeolian sediments, which is also consistent with an arid-cold glacial environment and with the presence of silt sized grains in the Raponzolo cave sediments (<xref ref-type="bibr" rid="B91">Wright, 2001</xref>).</p>
</sec>
<sec id="s4-4">
<title>Implications for Paleogeography and Tectonic Evolution</title>
<p>Cosmogenic data do not constrain a definitive age of the sediment burial, but point to a minimum age of 5.25&#xa0;Ma. However, it is possible to advance additional hypotheses on the paleo-landscape during cave formation and subsequent infilling. Indeed, thermochronologic data indicate that during the late Miocene, from about 8&#xa0;Ma, the Adamello batholith was exhuming rapidly to near-surface depths at about 0.65&#xa0;km/Ma in response to uplift induced by tectonic activity, whereas during the Plio-Pleistocene exhumation proceeded on average at a lower rate of about 0.35&#xa0;km/Ma (<xref ref-type="bibr" rid="B72">Reverman et&#x20;al., 2012</xref>). In Brenta, on the other side of the Giudicarie line, thermochronologic data from flysch sediments on the eastern foot of the massif (Ponte Pi&#xe0; Formation, AFT &#x3d; 9&#x2013;10&#xa0;Ma) indicate 3 to 2&#xa0;km of rock removal since 10&#xa0;Ma, which corresponds to an average exhumation rate similar in range but possibly slightly lower than the one estimated for the Adamello massif during the late Miocene (<xref ref-type="bibr" rid="B52">Heberer et&#x20;al., 2017</xref>). Altogether, the thermochronologic data from Adamello and Brenta, and the new data gathered from Raponzolo Cave, indicate that during the late Miocene the exhumation of the two massifs was synchronous, but the pace was possibly slightly different. This means that Adamello was possibly exhuming faster than Brenta and that this evolution may have favored a potential transfer of sediments (fluvial or glacial) from Adamello-Presanella toward Brenta. A phase of uplift and exhumation might also have favored, at the same time or shortly later, a local base-level fall; accordingly, this would be a suitable scenario for the formation of an epiphreatic cave system and its infilling. Finally, the present-day elevation of Raponzolo Cave roughly corresponds to the lower limit of its sediment source in both Adamello and Tonale as indicated by the AFT ages. This suggests that the Raponzolo sediments represent a remnant uplifted late Miocene landscape including the high elevation reaches of Tonale and Adamello, and Brenta, which was probably slightly lower in elevation as it is still today as suggested by the Ponte Pia Formation AFT ages. In this paleo-landscape, the valleys separating different geological domains (Adamello, Tonale, Brenta) were likely not as deeply entrenched as today, allowing an efficient transfer of sediment from the north-west to south-east across major tectonic lineaments, partially by fluvial systems and occasionally by glaciation events. This observation is consistent with recent studies (<xref ref-type="bibr" rid="B89">Winterberg et&#x20;al., 2020</xref>) showing that major river valleys in inner parts of the Southern Alps (i.e.,&#x20;Adige Valley) were not all yet deeply carved during the Messinian sea-level drawdown.</p>
</sec>
</sec>
<sec sec-type="conclusion" id="s5">
<title>Conclusion</title>
<p>The study of the sediments discovered in Raponzolo Cave provides new hints on the geographic, tectonic and climatic evolution of the calcareous Southern Alps in the Brenta region, and its interconnection with the Adamello crystalline bodies and the Tonale metamorphic units. Even if cosmogenic dating has not been able to define a narrow age for the sediment burial, the obtained minimum age coupled with petrographic observations, AFT ages and U-Pb on zircons provided reliable information about the sediment source and transport. Our results, combined with the known evolution of Adamello, allows inferring new clues on paleogeography of the area during the late Miocene. The data obtained thorugh the detailed analysis of the cave sediment provide the following evidences:<list list-type="simple">
<list-item>
<p>&#x2022; The sediments were eroded from the higher (&#x3e;2,200&#xa0;m a.s.l) elevations of Tonale and northern Adamello-Presanella;</p>
</list-item>
<list-item>
<p>&#x2022; The lack of <sup>26</sup>Al doesn&#x2019;t allow determining an exact date for the sediment burial in the cave. However, our calculation considering the remaining <sup>10</sup>Be in the sample, the mean surface exposure times of sediments in the Alps and the inferred original altitude of the source during late Miocene, points to a burial older than 5.25&#xa0;Ma.</p>
</list-item>
</list>
</p>
<p>Based on these line of evidence and given the known evolution of this area of the Alps, the following hypotheses should be considered for future studies:<list list-type="simple">
<list-item>
<p>&#x2022; The sediments were transported into Raponzolo Cave possibly by a river network or through glacial transport</p>
</list-item>
<list-item>
<p>&#x2022; If the glacial transport would be confirmed, this could have happened during late Miocene when glaciations have been recorded in other areas of world but have been possibly overlooked in the Alps;</p>
</list-item>
<list-item>
<p>&#x2022; At the time of sediment burial into the cave, the valley bottoms were not yet deeply entrenched allowing an efficient sediment transport from Adamello-Tonale toward Brenta.</p>
</list-item>
</list>
</p>
<p>These clues open intriguing questions that could be refined by future studies, especially if other allochtonous sediments would be identified in other caves of Brenta. For example a Miocene fluvial-glacial interconnection between different areas of the Alps (Brenta-Adamello-Tonale) suggest that the Messinian Salinity Crisis sea-level drop and related accelerated fluvial erosion may not have reached the internal most elevated region of the Southern Alps (<xref ref-type="bibr" rid="B89">Winterberg et&#x20;al., 2020</xref>).</p>
<p>This is a nice case study on how a cave sediment, even from a single cave, can provide data with wide implications not only for the genesis of the cave itself but also for the complex settings and evolution of the paleo-environment of the surrounding areas. Sediments can be preserved in caves while they have been completely eroded or recycled on the surface. Therefore, the study of cave sediments in complex regions of the Alps represent a promising, still under-exploited, source of information on paleo-geography and tectonic evolution.</p>
</sec>
</body>
<back>
<sec id="s6">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/<xref ref-type="sec" rid="s9">Supplementary Material</xref>, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s7">
<title>Author Contributions</title>
<p>FS conceived the project. FS and AB carried out fieldwork. FS, MF, AC, AB wrote the draft, with contributions from PH, CC and JW. AC, MF, PH and CC accomplished lab analyses.</p>
</sec>
<sec sec-type="COI-statement" id="s8">
<title>Conflict of Interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<ack>
<p>This research was possible thanks to the logistical support of Gruppo Speleologico Trentino SAT Bindesi Villazzano especially to Walter Bronzetti and Daniele Sighel. The research was financially supported by Parco Naturale Adamello Brenta Geopark: our gratitude goes to Director Cristiano Trotte, and to Vajolet Mase and Alessia Scalfi for assistance. We are grateful to Enrico Dinelli and Valerio Funari for XRF analysis at UNIBO, and to Marcel Guillong for LA-ICP-MS U-Pb measurements and data reduction at ETH. Finally, thanks to Giulio Viola and Paolo Garofalo (UNIBO) for the access to the optical microscope laboratory, and the three reviewers for their insightful comments.</p>
</ack>
<sec id="s9">
<title>Supplementary Material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/feart.2021.672119/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/feart.2021.672119/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="Table2.XLSX" id="SM1" mimetype="application/XLSX" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table3.XLSX" id="SM2" mimetype="application/XLSX" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table4.XLS" id="SM3" mimetype="application/XLS" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Table1.XLSX" id="SM4" mimetype="application/XLSX" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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