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<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Complex Syst.</journal-id>
<journal-title>Frontiers in Complex Systems</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Complex Syst.</abbrev-journal-title>
<issn pub-type="epub">2813-6187</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
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<article-meta>
<article-id pub-id-type="publisher-id">1617092</article-id>
<article-id pub-id-type="doi">10.3389/fcpxs.2025.1617092</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Complex Systems</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Unsettling the settled: simple musings on the complex climatic system</article-title>
<alt-title alt-title-type="left-running-head">Koutsoyiannis and Tsakalias</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/fcpxs.2025.1617092">10.3389/fcpxs.2025.1617092</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Koutsoyiannis</surname>
<given-names>Demetris</given-names>
</name>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/293774/overview"/>
<role content-type="https://credit.niso.org/contributor-roles/data-curation/"/>
<role content-type="https://credit.niso.org/contributor-roles/supervision/"/>
<role content-type="https://credit.niso.org/contributor-roles/conceptualization/"/>
<role content-type="https://credit.niso.org/contributor-roles/software/"/>
<role content-type="https://credit.niso.org/contributor-roles/investigation/"/>
<role content-type="https://credit.niso.org/contributor-roles/methodology/"/>
<role content-type="https://credit.niso.org/contributor-roles/writing-original-draft/"/>
<role content-type="https://credit.niso.org/contributor-roles/Writing - review &#x26; editing/"/>
<role content-type="https://credit.niso.org/contributor-roles/resources/"/>
<role content-type="https://credit.niso.org/contributor-roles/project-administration/"/>
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</contrib>
<contrib contrib-type="author">
<name>
<surname>Tsakalias</surname>
<given-names>George</given-names>
</name>
<uri xlink:href="https://loop.frontiersin.org/people/3091285/overview"/>
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<aff>
<institution>Department of Water Resources and Environmental Engineering</institution>, <institution>School of Civil Engineering</institution>, <institution>National Technical University of Athens</institution>, <addr-line>Athens</addr-line>, <country>Greece</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/2937343/overview">Ning Wang</ext-link>, Ministry of Emergency Management, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/3056666/overview">Stavros Alexandris</ext-link>, Agricultural University of Athens, Greece</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/3056830/overview">Patrice Poyet</ext-link>, Independent Researcher, Moorea, French Polynesia</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Demetris Koutsoyiannis, <email>dk@itia.ntua.gr</email>
</corresp>
</author-notes>
<pub-date pub-type="epub">
<day>12</day>
<month>08</month>
<year>2025</year>
</pub-date>
<pub-date pub-type="collection">
<year>2025</year>
</pub-date>
<volume>3</volume>
<elocation-id>1617092</elocation-id>
<history>
<date date-type="received">
<day>23</day>
<month>04</month>
<year>2025</year>
</date>
<date date-type="accepted">
<day>23</day>
<month>07</month>
<year>2025</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2025 Koutsoyiannis and Tsakalias.</copyright-statement>
<copyright-year>2025</copyright-year>
<copyright-holder>Koutsoyiannis and Tsakalias</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>Our revisit of fundamental issues of climate challenges the notion and term of the &#x201c;greenhouse effect&#x201d;, and attempts a scientific reevaluation using minimal assumptions, such as Newton&#x2019;s laws, maximum entropy and gas spectroscopy. It replaces terms like &#x201c;greenhouse gas&#x201d; with &#x201c;radiatively active gas&#x201d; (RAG) and &#x201c;greenhouse effect&#x201d; with &#x201c;atmospheric radiative effect&#x201d; (ARE). While ARE exists in several planets&#x2019; atmospheres, on Earth it is primarily driven by water vapor and clouds, with CO<sub>2</sub> playing a minor role (especially anthropogenic CO<sub>2</sub> which represents 4% of total emissions). Equilibrium thermodynamics, via entropy maximization or molecular collision simulation, leads to an isothermal atmosphere at about 250&#xa0;K (the average temperature of the troposphere and stratosphere) irrespective of RAG presence or not. It is the troposphere&#x2019;s 6.5&#xa0;K/km temperature gradient (lapse rate), partly shaped by moist adiabatic processes, that drives the atmosphere away from this equilibrium and warms the surface to about 288&#xa0;K on average, with ARE (mainly water vapor and clouds) contributing to the warming, but only when this gradient exists. The temperature gradient varies spatially and temporally and, since 1950, has weakened in the tropics and grown in the polar areas, resulting in a decrease of the surface equator-to-pole gradient, as expected in global warming conditions.</p>
</abstract>
<kwd-group>
<kwd>climate</kwd>
<kwd>climatic system</kwd>
<kwd>atmosphere</kwd>
<kwd>thermodynamics</kwd>
<kwd>greenhouse</kwd>
</kwd-group>
<custom-meta-wrap>
<custom-meta>
<meta-name>section-at-acceptance</meta-name>
<meta-value>Multi- and Cross-Disciplinary Complexity</meta-value>
</custom-meta>
</custom-meta-wrap>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Do we live in a greenhouse? Most people would give an affirmative reply given the enormous campaign to promote the climate initiatives that are founded on the concepts of greenhouse gases (GHG) and greenhouse effect (GHE). Systematic searches in Google Books (<ext-link ext-link-type="uri" xlink:href="https://books.google.com/ngrams/">https://books.google.com/ngrams/</ext-link>) and Internet Archive (<ext-link ext-link-type="uri" xlink:href="https://archive.org/">https://archive.org/</ext-link>) show that, while the term &#x2018;greenhouse&#x2019; is old (already appearing in the 18th century with its literal meaning), the terms GHG and GHE are newer. Following Poynting (1907) who used the term GHE for planetary atmospheres (even though he was criticized by <xref ref-type="bibr" rid="B63">Very, 1908</xref>; see <xref ref-type="sec" rid="s11">Supplementary Appendix SA</xref>), the term GHE as it relates to planetary atmospheres was popularized in 1960s by NASA (<xref ref-type="bibr" rid="B54">Samuelson, 1965</xref>; <xref ref-type="bibr" rid="B65">Wildt, 1965</xref>). Since the late 1970s, however, the usage of GHE has changed to closely associate it with carbon dioxide (CO<sub>2</sub>) and its emission into the atmosphere from the burning of fossil fuels, but also to imply that this causes disastrous effects on climate, economy and every aspect of life (<xref ref-type="bibr" rid="B47">Murray, 1979</xref>; <xref ref-type="bibr" rid="B4">Bernard Jr, 1980</xref>; <xref ref-type="bibr" rid="B12">EXXON, 1982</xref>; <xref ref-type="bibr" rid="B18">Gribbin, 1982</xref>; <xref ref-type="bibr" rid="B2">Barth and Titus, 1984</xref>; <xref ref-type="bibr" rid="B59">U.S. House of Representatives, 1984</xref>; <xref ref-type="bibr" rid="B5">Bolin et al., 1986</xref>; <xref ref-type="bibr" rid="B13">Gay, 1986</xref>).</p>
<p>From a scientific perspective, clarity in terminology is essential (cf. the Aristotelian notion of sapheneia; <xref ref-type="bibr" rid="B31">Koutsoyiannis, 2024a</xref>). In strict scientific terms, the reply to the question whether we live in a greenhouse is negative: The Earth&#x2019;s atmosphere does not function like a greenhouse. A simple revisit of the definition of a greenhouse (a structure that is designed to regulate the temperature and humidity of the environment inside) suffices to see this, even though effects such as those that the term GHE purports to describe are present on Earth, as well as on other planets in the solar system with atmospheres (see <xref ref-type="sec" rid="s3-2">section 3.2</xref>). Hence, the term GHE can be misleading as further explained in <xref ref-type="sec" rid="s11">Supplementary Appendix SA</xref>.</p>
<p>For scientific clarity and accuracy, we propose replacing the term GHG with <italic>radiatively active gas</italic> (RAG), comprising water vapor (WV) and non-condensing radiatively active gases (NC-RAGs). We also propose replacing the term GHE with <italic>atmospheric radiative effect</italic> (ARE). ARE is the influence of RAGs on the energy balance in the atmosphere by absorbing, emitting, and scattering radiation across both shortwave (SW) and longwave (LW) spectra. These processes influence the flow of energy between the Earth&#x2019;s surface, the atmosphere, and space. While the term GHE is often associated primarily with heat-trapping, ARE explicitly recognizes all radiative interactions in the atmosphere. It avoids the misleading analogy of a greenhouse and is more applicable to a scientific framework that considers both SW and LW radiation. For the reader&#x2019;s convenience, these acronyms are listed and explained in <xref ref-type="table" rid="T1">Table 1</xref>, along with all other abbreviations used in this paper.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>List of acronyms used in this paper.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Acronym</th>
<th align="left">Explanation and comments</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">ACS</td>
<td align="left">American Chemical Society</td>
</tr>
<tr>
<td align="left">AIP</td>
<td align="left">American Institute of Physics</td>
</tr>
<tr>
<td align="left">ARE</td>
<td align="left">Atmospheric Radiative Effect (proposed to replace GHE)</td>
</tr>
<tr>
<td align="left">CERES</td>
<td align="left">Clouds and the Earth&#x2019;s Radiant Energy System</td>
</tr>
<tr>
<td align="left">CLIMEXP</td>
<td align="left">Climate Explorer (by the Koninklijk Nederlands Meteorologisch Instituut)</td>
</tr>
<tr>
<td align="left">ECMWF</td>
<td align="left">European Centre for Medium-Range Weather Forecasts</td>
</tr>
<tr>
<td align="left">ERA5</td>
<td align="left">Fifth generation ECMWF ReAnalysis</td>
</tr>
<tr>
<td align="left">GHCN-D</td>
<td align="left">Global Historical Climatology Network &#x2013; Daily</td>
</tr>
<tr>
<td align="left">GHE</td>
<td align="left">Greenhouse Effect (proposed to be replaced by ARE)</td>
</tr>
<tr>
<td align="left">GHG</td>
<td align="left">Greenhouse Gas (proposed to be replaced by RAG)</td>
</tr>
<tr>
<td align="left">HITRAN</td>
<td align="left">High-Resolution Transmission (a molecular spectroscopic database)</td>
</tr>
<tr>
<td align="left">ICAO</td>
<td align="left">International Civil Aviation Organization</td>
</tr>
<tr>
<td align="left">IPCC</td>
<td align="left">Intergovernmental Panel on Climate Change</td>
</tr>
<tr>
<td align="left">LW</td>
<td align="left">Longwave (radiation)</td>
</tr>
<tr>
<td align="left">NASA</td>
<td align="left">National Aeronautics and Space Administration (United States)</td>
</tr>
<tr>
<td align="left">NC-RAG</td>
<td align="left">Non-Condensing Radiatively Active Gas (e.g., CO&#x2082;)</td>
</tr>
<tr>
<td align="left">NOAA</td>
<td align="left">National Oceanic and Atmospheric Administration (United States)</td>
</tr>
<tr>
<td align="left">RAG</td>
<td align="left">Radiatively active gas (proposed to replace GHG)</td>
</tr>
<tr>
<td align="left">REIS</td>
<td align="left">Radiative Energy Imbalance Slope</td>
</tr>
<tr>
<td align="left">RRTM</td>
<td align="left">Rapid Radiative Transfer Model</td>
</tr>
<tr>
<td align="left">SW</td>
<td align="left">Shortwave (radiation)</td>
</tr>
<tr>
<td align="left">TOA</td>
<td align="left">Top-of-Atmosphere</td>
</tr>
<tr>
<td align="left">WMO</td>
<td align="left">World Meteorological Organization</td>
</tr>
<tr>
<td align="left">WRIT</td>
<td align="left">Web-based Reanalyses Intercomparison Tools (by NOAA)</td>
</tr>
<tr>
<td align="left">WV</td>
<td align="left">Water Vapor</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>Notably, WV and clouds (for which WV is responsible) dominate ARE, while CO<sub>2</sub> contributes only 4%&#x2013;5% to it (<xref ref-type="bibr" rid="B32">Koutsoyiannis, 2024b</xref>). Also, anthropogenic CO<sub>2</sub> emissions are only 4% of the total, with the vast majority (96%) being natural (<xref ref-type="bibr" rid="B35">Koutsoyiannis et al., 2023</xref>). Additionally, evidence suggests that changes in temperature precede those in CO<sub>2</sub> concentration, thus challenging the assumption that CO<sub>2</sub> drives temperature (<xref ref-type="bibr" rid="B34">Koutsoyiannis et al., 2022</xref>; <xref ref-type="bibr" rid="B35">2023</xref>). For this reason, here we avoid using popular terms such as &#x201c;radiative forcing&#x201d; (e.g., <xref ref-type="bibr" rid="B48">Myhre et al., 1998</xref>) which imply that CO<sub>2</sub> is the temperature driver.</p>
<p>These recent developments, summarized in <xref ref-type="bibr" rid="B33">Koutsoyiannis (2024c)</xref> and in a review paper led by a chatbot (large language model), <xref ref-type="bibr" rid="B9">Grok 3 beta et al. (2025)</xref>, question the mainstream view that climate science is settled, particularly with respect to the CO<sub>2</sub> and the human contribution to the increase of its atmospheric concentration in the last decades. Arguably, science can never be settled (cf. <xref ref-type="bibr" rid="B25">Koonin, 2021</xref>), particularly that dealing with one of the most complex systems on Earth, the climatic system, which remains under active investigation. It is recalled that the climatic system consists of the atmosphere, the hydrosphere (including its solid phase&#x2014;the cryosphere), the lithosphere and the biosphere, which mutually interact and respond to external influences (system inputs).</p>
<p>It is thus healthy to question even the fundamental ideas about climate, leaving aside the fact that they are established or settled. In this respect, this paper examines (in <xref ref-type="sec" rid="s3">Section 3</xref>) the following fundamental questions, using empirical data and minimal assumptions, and aiming to clarify the roles of ARE and atmospheric dynamics without preconceived notions:<list list-type="simple">
<list-item>
<p>1. Is there an empirically verified ARE in the atmosphere?</p>
</list-item>
<list-item>
<p>2. What would be the atmospheric temperature profile in equilibrium?</p>
</list-item>
<list-item>
<p>3. What is the empirically observed temperature profile, and does it differ from the equilibrium profile?</p>
</list-item>
<list-item>
<p>4. Is the ARE responsible for the observed temperature profile in the atmosphere?</p>
</list-item>
<list-item>
<p>5. What factors can explain the observed temperature profile?</p>
</list-item>
<list-item>
<p>6. What is the relative importance of ARE and temperature gradient in climate dynamics?</p>
</list-item>
<list-item>
<p>7. What are the recent changes in the atmospheric temperature gradient?</p>
</list-item>
</list>
</p>
<p>Note that the terms &#x201c;temperature gradient&#x201d; or simply &#x201c;gradient&#x201d; are used above and below as shortcuts for &#x201c;(minus) vertical gradient of temperature in the troposphere&#x201d; (also known as &#x201c;lapse rate&#x201d;). Whenever a different gradient direction is assumed, we specify it (e.g., surface equator-to-pole temperature gradient).</p>
</sec>
<sec id="s2">
<title>2 Data and software</title>
<p>The temperature data used here are taken from the ERA5 Reanalysis on a monthly scale. ERA5 stands for the fifth generation atmospheric reanalysis of the European Centre for Medium-Range Weather Forecasts (ECMWF; ECMWF ReAnalysis). Its data are publicly available for the period 1940 onwards at a spatial resolution of 0.5&#x00B0;. The data sets used here were retrieved from the Physical Sciences Laboratory platform of the US National Oceanic and Atmospheric Administration (NOAA) (WRIT: Monthly Timeseries; NOAA Physical Sciences Laboratory, <ext-link ext-link-type="uri" xlink:href="https://psl.noaa.gov/cgi-bin/data/atmoswrit/timeseries.pl">https://psl.noaa.gov/cgi-bin/data/atmoswrit/timeseries.pl</ext-link>). For the period 1950 onwards, they are also accessible from the Climate Explorer (CLIMEXP) platform (<ext-link ext-link-type="uri" xlink:href="https://climexp.knmi.nl/">https://climexp.knmi.nl/</ext-link>) which in addition allows extended processing of the data.</p>
<p>Radiation data from satellites were retrieved from NASA&#x2019;s ongoing project Clouds and the Earth&#x2019;s Radiant Energy System (<xref ref-type="bibr" rid="B8">CERES, 2021</xref>) from the Terra platform (operational since January 2001). The specific product used here is the CERES SSF1deg monthly averaged TOA LW radiative fluxes at a 1&#xb0;-regional grid, constant-meteorology-temporally-interpolated. The top-of-atmosphere (TOA) fluxes are provided for clear-sky and all-sky conditions and are available online.</p>
<p>The main software tool used here is RRTM (standing for rapid radiative transfer model), a hybrid physical/statistical approximation of the full line-by-line models, developed for climate studies. Its results have been extensively evaluated and rigorously validated (<xref ref-type="bibr" rid="B46">Mlawer et al., 1997</xref>). The model implementation used here is an interactive web application hosted by the University of Chicago (<ext-link ext-link-type="uri" xlink:href="https://climatemodels.uchicago.edu/rrtm/">https://climatemodels.uchicago.edu/rrtm/</ext-link>) that simulates the radiation flux through Earth&#x2019;s atmosphere at a range of altitudes, calculating both SW (incoming and reflected sunlight) and LW (emitted by the ground and atmosphere), both upward and downward. Users can adjust parameters such as solar input, albedo, and atmospheric composition in order to study their effects on Earth&#x2019;s energy balance, revealing whether the planet gains or loses energy and enabling the parameters that lead to energy balance to be found.</p>
<p>Additional software was developed in-house to simulate the thermal equilibrium dynamics of a gas and to determine the altitude-dependent distribution of air density and temperature under gravity. The simulation is based solely on molecular collisions treated as perfectly elastic hard-sphere interactions, without any assumptions beyond Newton&#x2019;s laws. A detailed description is provided in <xref ref-type="sec" rid="s11">Supplementary Appendix SD</xref>, and the software is available online as Supplementary Software, allowing interested readers to review the code, replicate the calculations, or simply view the simulation videos (see Supplementary Video).</p>
</sec>
<sec id="s3">
<title>3 Analysis of questions</title>
<sec id="s3-1">
<title>3.1 Is there an empirically verified ARE in the atmosphere?</title>
<p>The reply to this question is definitely affirmative and is based on observations. As noted by <xref ref-type="bibr" rid="B1">&#xc5;ngstr&#xf6;m (1915)</xref>, a pioneer of the measurement and modelling of radiation, the first observations relating to the problem of Earth&#x2019;s (LW) radiation to space were made between the years 1780 and 1850. &#xc5;ngstr&#xf6;m (1915, p. 16) cites some sporadic measurements by several researchers for the period 1887-1912. From these measurements and from experiments in the 19th century, it was understood that the major constituents of the atmosphere, i.e., nitrogen (N<sub>2</sub>) and oxygen (O<sub>2</sub>), are transparent to LW radiation. In contrast, some minor constituents, particularly WV, carbon dioxide (CO<sub>2</sub>) and ozone (O<sub>3</sub>), absorb and reemit LW radiation, thus being RAG. <xref ref-type="bibr" rid="B58">Tyndall (1865)</xref> pioneered our understanding of the dominance of WV in this process, of the importance of its presence for climate and life, and of the minor contribution of CO<sub>2</sub> in the ARE.</p>
<p>&#xc5;ngstr&#xf6;m (1915, p. 16) provided his own systematic measurements, as well as a rough quantification of ARE in the following way:</p>
<disp-quote>
<p>a surface at 15&#xb0;C temperature ought to radiate 0.526&#xa0;cal. If the observed effective radiation does not amount to more, for instance, than 0.15 cal, this must depend upon the fact that 0.376&#xa0;cal is radiated to the surface from some other source of radiation. In the case of the earth this other source of radiation is probably to a large extent its own atmosphere.</p>
</disp-quote>
<p>Since the introduction of <xref ref-type="bibr" rid="B52">Penman&#x2019;s (1948)</xref> celebrated equation for natural evaporation from an open water surface, the quantification of the ARE has become part of the routine hydrological calculations for real-world problems, such as those of the hydrological balance (of which evaporation represents a substantial component) and the irrigation needs in agricultural applications. <xref ref-type="bibr" rid="B52">Penman&#x2019;s (1948)</xref> equation is based on the presence of WV in the atmosphere and disregards that of NC-RAGs such as CO<sub>2</sub>. Notably, while the role of CO<sub>2</sub> in photosynthesis is important in biochemical terms, it becomes negligible in terms of its contribution to the surface energy balance. A recent study by <xref ref-type="bibr" rid="B36">Koutsoyiannis and Vournas (2024)</xref> analyzed a large set of LW radiation measurements distributed in time across a century, in which CO<sub>2</sub> has escalated from 300 to about 420&#xa0;ppm. They concluded that the observed increase of the atmospheric CO<sub>2</sub> concentration has not altered the ARE in any discernible way. Thus, the ARE continues to be dominated by the quantity of WV in the atmosphere and CO<sub>2</sub> remains insignificant in the ARE.</p>
<p>Since the 1960s, detailed spectroscopic studies of RAGs were conducted, initially developed for military purposes and subsequently expanded to cover broader scientific use, evolving into an essential tool for atmospheric and astrophysical research. The results of these studies were compiled into HITRAN (High-Resolution Transmission), a molecular spectroscopic database designed to support the study of electromagnetic transmission and emission in gaseous media (<xref ref-type="bibr" rid="B44">McClatchey et al., 1973</xref>; <xref ref-type="bibr" rid="B53">Rothman et al., 1987</xref>; <xref ref-type="bibr" rid="B15">Goldman et al., 1988</xref>; <xref ref-type="bibr" rid="B17">Gordon et al., 2022</xref>). The database includes detailed line-by-line spectroscopic parameters for various molecular species.</p>
<p>Experimental verification of the theory at laboratory has been provided by <xref ref-type="bibr" rid="B20">Harde and Schnell (2022)</xref> and <xref ref-type="bibr" rid="B56">Schnell and Harde (2023)</xref> (see <xref ref-type="sec" rid="s11">Supplementary Appendix SA</xref>). Empirical atmospheric data for testing the applicability of the theory had been provided early by <xref ref-type="bibr" rid="B19">Hanel and Conrath (1970)</xref> based on a Michaelson interferometer in a satellite. Recently, <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref> and <xref ref-type="bibr" rid="B62">van Wijngaarden and Happer (2025)</xref> using these data showed that theory is impressively consistent with the observations, as shown in <xref ref-type="fig" rid="F1">Figure 1</xref>, reproduced from the latter publications.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Reproduction of Figure 9 in <xref ref-type="bibr" rid="B62">van Wijngaarden and Happer (2025)</xref> (or Figure 10 in <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer, 2023</xref>): Vertical intensities <italic>&#x12a;</italic>(0) at the top of the atmosphere observed with a Michaelson interferometer in a satellite (<xref ref-type="bibr" rid="B19">Hanel and Conrath, 1970</xref>), and modeled with radiation transfer theory for the Sahara desert, Mediterranean and Antarctica. The &#x201c;frequency&#x201d; referred to in the horizontal axis should better read as &#x201c;wavenumber&#x201d;. The intensity unit in the vertical axis is 1 i. u. &#x3d; 1&#xa0;mW&#xa0;m<sup>&#x2212;1</sup>&#xa0;cm sr<sup>&#x2212;1</sup>. The labels <bold>(a-f)</bold> are explained in each of the panels.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g001.tif">
<alt-text content-type="machine-generated">Six line graphs compare modeled and observed spectral intensities across different regions. Graphs a and b show Sahara data; c and d present Mediterranean data; e and f depict Antarctica data. Each row compares modeled data (black lines, with dashed red reference curves) on the left with observed data on the right. Frequencies range from 400 to 1600 cm&#x207B;&#xB9;, and intensity is measured in arbitrary units. Models show characteristic patterns for each climate region.</alt-text>
</graphic>
</fig>
<p>Some discrepancy appears in the Antarctica case, as the observed radiation is higher than that emitted by the Earth&#x2019;s surface. The explanation given by <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref> and <xref ref-type="bibr" rid="B62">van Wijngaarden and Happer (2025)</xref> is this:</p>
<disp-quote>
<p>Radiative forcing is negative over wintertime Antarctica since the relatively warm greenhouse gases in the troposphere, mostly CO<sub>2</sub>, O<sub>3</sub> and H<sub>2</sub>O radiate more to space than the cold ice surface at a temperature of <italic>T</italic> &#x3d; 190 K, could radiate through a transparent atmosphere.</p>
</disp-quote>
<p>We note though that the <italic>T</italic> &#x3d; 190&#xa0;K, as well as the entire atmospheric profile, are estimated, rather than observed. <xref ref-type="bibr" rid="B19">Hanel and Conrath (1970)</xref> mention that</p>
<disp-quote>
<p>no radiosonde data are available for comparison [&#x2026;] The profile can be anticipated intuitively from an examination of the spectrum [&#x2026;] The cold surface temperature results in the relatively low radiances found in the window region and between the water vapour lines.</p>
</disp-quote>
<p>Further examination of systematic ground temperature observations in the area shows that the assumed value of <italic>T</italic> &#x3d; 190&#xa0;K is unlikely. Specifically in the South Pole (station Amundsen-Scot; coordinates: 90&#xb0;S, 0&#xb0;E, prob: 2,770&#xa0;m), the lowest daily temperature in April 1970 (the month of the experiment) did not fall below 204K. The Vostok station (coordinates: 78.45&#xb0;S, 106.87&#xb0;E, 3,420.0&#xa0;m or prob: 3,468&#xa0;m) is the location with the lowest temperatures among 41 GHCN-D stations in Antarctica, and its temperatures in April are, on average, 7&#xa0;K lower than in Amundsen-Scot. Furthermore, the reconstructed vertical temperature profile given by <xref ref-type="bibr" rid="B19">Hanel and Conrath (1970)</xref> does not seem plausible as it has an abrupt increase of &#x3e;30&#xa0;K at the level of 700&#xa0;hPa.</p>
<p>On the other hand, the ERA5 Reanalysis data suggest that there is a permanent state of temperature inversion (increasing temperature with increased altitude) between the atmospheric levels of 700 and 600&#xa0;hPa (<xref ref-type="fig" rid="F2">Figure 2</xref>), albeit not that big. This explains the discrepancy seen in <xref ref-type="fig" rid="F1">Figure 1</xref>. The presence of the temperature inversion over the Antarctic Plateau has been studied by <xref ref-type="bibr" rid="B57">Sejas et al. (2018)</xref>, who found that, along with the scarcity of free tropospheric water vapor, it causes a negative greenhouse effect. In addition, <xref ref-type="bibr" rid="B39">Lindzen (2012)</xref> stated that in the case of temperature inversion, RAGs actually cool, rather than warm, the atmosphere. (See additional explanation in <xref ref-type="sec" rid="s3-4">Section 3.4</xref> below.).</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Evolution of mean monthly air temperature at the South Pole for the winter month that it is minimized at the indicated levels of the atmosphere. The inset on the right shows the average temperature vs. atmospheric pressure highlighting the inversion at pressure levels between 700 and 600&#xa0;hPa. The pressure levels higher than 700&#xa0;hPa (curves plotted as dashed lines) are not real as the altitudes are about 3,000&#xa0;m, corresponding to about 700&#xa0;hPa. Data from ERA5 Reanalysis retrieved through NOAA&#x2019;s WRIT.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g002.tif">
<alt-text content-type="machine-generated">Graph showing winter temperatures in Kelvin at the South Pole at different atmospheric pressure levels from 1940 to 2030. Lines represent temperatures at 1000, 850, 700, 600, 500, 400, 300, and 200 hPa, with a separate graph highlighting average temperature as a function of pressure between 200 and 1000 hPa. Temperatures generally exhibit variation over time.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s3-2">
<title>3.2 What would be the atmospheric temperature profile in equilibrium?</title>
<p>In their recent work, <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref> stated: &#x201c;In the absence of greenhouse gases, the isothermal atmosphere will not change with time, since there is no thermal gradient to drive heat flow&#x201d;. They also asserted that &#x201c;without greenhouse gases, a thermally isolated adiabatic atmosphere would slowly evolve to an isothermal atmosphere because of conductive heat flow from the warmer lower atmosphere to the colder upper atmosphere&#x201d;. Here we examine these statements with a slightly different formulation as seen in the question in the heading of this subsection.</p>
<p>It is well known that a gas in equilibrium tends to become isothermal, but here we examine the question also including gravity in the analysis. In fact, this problem is very old and is known as the Loschmidt paradox after <xref ref-type="bibr" rid="B41">Loschmidt (1876)</xref> who asserted that gravity could counteract the temperature uniformity implied by the second law as the kinetic energy of the molecules of a gas should be lower at higher elevation in compensation for the higher potential energy. The paradox puzzled many for years, yet both James Clerk Maxwell and Ludwig Boltzmann reacted negatively, supporting the isothermal hypothesis, as detailed in a recent analysis by <xref ref-type="bibr" rid="B10">Darrigol (2021)</xref>.</p>
<p>Nonetheless, we deemed it useful to perform our own investigation in reply to this question independently of past arguments and using two methods. First, we maximize the entropy of a single molecule which is in motion in a vertical column under gravity. The single-molecule method has been successfully used before to derive the Clausius-Clapeyron equation (<xref ref-type="bibr" rid="B29">Koutsoyiannis, 2014</xref>). The development and application of the method to a spherical monoatomic and to a diatomic molecule are presented in <xref ref-type="sec" rid="s11">Supplementary Appendices SB, SC</xref>, respectively. In brief, the thermal (internal) energy per molecule turns out to be the same for all altitudes, equal to <inline-formula id="inf1">
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<label>(1)</label>
</disp-formula>where <italic>k</italic> is the Boltzmann constant. In other words, entropy maximization results in an isothermal atmosphere.</p>
<p>The same result emerges when we approach the problem with our second method, without invoking the principle of maximum entropy&#x2014;by instead simulating the motion of molecules, modeled as perfectly elastic hard spheres, using only Newton&#x2019;s laws. Once again, the temperature is found to remain constant with altitude, as shown in <xref ref-type="fig" rid="F3">Figure 3</xref> and discussed in detail in <xref ref-type="sec" rid="s11">Supplementary Appendix SD</xref>. In other words, none of the approaches predicts a decrease in temperature with altitude, which is the observed behavior as will be explained in <xref ref-type="sec" rid="s3-3">Section 3.3</xref>.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Reconstruction of the atmosphere&#x2019;s density and temperature profile, based on the molecular dynamics simulation results. Simulation consisted of 100,000 gas molecules, doing 1.2 billion collisions within a periodic box with reflective bottom boundary. The fluctuations at high altitudes are deemed as statistical effects due to small samples.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g003.tif">
<alt-text content-type="machine-generated">Graph showing the relationship between altitude and atmospheric temperature and density as resulting from simulation (motion of 100,000 gas molecules, doing 1.2 billion collisions), after rescaling.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s3-3">
<title>3.3 What is the empirically observed temperature profile, and does it differ from the equilibrium profile?</title>
<p>It is common knowledge that Earth&#x2019;s atmosphere is not isothermal. The temperature decreases with altitude in the troposphere, then it remains constant in the lowest layer of the stratosphere and continues to change at even higher altitudes. The typical atmospheric temperature profile is represented by the standard atmosphere adopted by the International Civil Aviation Organization (<xref ref-type="bibr" rid="B23">ICAO, 1993</xref>). According to the <xref ref-type="bibr" rid="B60">U.S. Standard Atmosphere (1976)</xref>, the standard atmosphere is &#x201c;A hypothetical vertical distribution of atmospheric temperature, pressure and density which, by international agreement, is roughly representative of year-round, midlatitude conditions.&#x201d; It is based on large inventories of observational data and is widely used for meteorological and engineering applications. The vertical profile of temperature vs. altitude and atmospheric pressure is shown in <xref ref-type="fig" rid="F4">Figure 4</xref>, with the temperature being 15&#xb0;C or 288.15&#xa0;K at the surface, linearly decreasing in the troposphere with the (minus) gradient <inline-formula id="inf6">
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</inline-formula> being 6.5&#xa0;K/km up to the altitude of 11&#xa0;km, and taking a constant value of 216.65&#xa0;K above this up to 20&#xa0;km.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Vertical profiles of the <xref ref-type="bibr" rid="B23">ICAO (1993)</xref> standard atmosphere: (left) temperature and pressure as functions of altitude; (right) temperature and altitude as functions of pressure.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g004.tif">
<alt-text content-type="machine-generated">Two graphs depict atmospheric altitude, temperature and pressure. The left graph the variation of temperature (in red) and pressure (in green) along various atmospheric layers: troposphere, stratosphere, and mesosphere. The right graph flips the axes of altitude and pressure, displaying these layers with pressure from 1000 to 0.001 hPa.</alt-text>
</graphic>
</fig>
<p>Clearly, the standard atmosphere is far from isothermal. Here we extensively use the standard atmosphere as satisfactorily representing reality, even though newer data and research (<xref ref-type="bibr" rid="B64">Wiencke, 2021</xref>) support slightly lower values of <italic>&#x393;</italic>, particularly at high latitudes. This will be verified below (<xref ref-type="sec" rid="s3-7">Section 3.7</xref>). It is interesting to note that the average temperature in the standard atmosphere, calculated (by numerical integration) from the coordinates of <xref ref-type="fig" rid="F4">Figure 4</xref>, is<disp-formula id="e2">
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</disp-formula>where, by the ideal gas law, the air density <inline-formula id="inf7">
<mml:math id="m9">
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</inline-formula> denoting air pressure.</p>
<p>
<xref ref-type="fig" rid="F5">Figure 5</xref> shows that temperature gradients appear in other planets and satellites in our solar system, and even in extrasolar planets (for additional rocky exoplanets see also <xref ref-type="bibr" rid="B43">Malik et al., 2019</xref>). In other words, isothermal atmospheres never seem to actually exist in planets.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Vertical temperature profiles in the atmospheres of the indicated planets, the satellite Titan, and the extrasolar planet HD209458b (continuous lines), reproduced from <xref ref-type="bibr" rid="B55">S&#xe1;nchez-Lavega et al. (2004)</xref>, (Figure 3) with the permission of AIP Publishing. Saturation vapor pressure curves for the indicated condensates (substances forming clouds) for each planet are also plotted (dashed lines), details of which are given in the original publication.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g005.tif">
<alt-text content-type="machine-generated">Graphs depicting pressure-temperature profiles for Venus, Earth, Mars, Jupiter, Saturn, Titan, Uranus, Neptune, and the exoplanet HD209458b. Each graph shows pressure versus temperature with labels indicating the presence of various gases, such as H&#x2082;SO&#x2084;, H&#x2082;O, CO&#x2082;, NH&#x2083;, and CH&#x2084;. Dashed lines represent the condensation curves of these gases, illustrating atmospheric conditions across different celestial bodies.</alt-text>
</graphic>
</fig>
<p>Another important case, additional to the isothermal, is the isentropic atmosphere, where the per-molecule entropy is constant, independent of altitude. Following <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref> here we use the adjectives adiabatic and isentropic interchangeably, even though under some conditions, adiabatic processes can differ from isentropic processes. It is well known that in the absence of water vapor (dry conditions) the atmosphere has a constant temperature gradient equal to<disp-formula id="e3">
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</inline-formula> m/s is the gravity acceleration (typical value for the troposphere) and <inline-formula id="inf11">
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</inline-formula> J&#xa0;kg<sup>&#x2013;1</sup> K<sup>&#x2212;1</sup> is the specific heat capacity of the dry air for constant pressure. This is depicted in <xref ref-type="fig" rid="F6">Figure 6</xref> for the troposphere and lower stratosphere.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Comparison of different models of temperature profiles of Earth&#x2019;s troposphere, in terms of (left) altitude and (right) pressure (in logarithmic axis).</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g006.tif">
<alt-text content-type="machine-generated">Graphs showing altitude versus temperature on the left and pressure versus temperature on the right. Lines represent different lapse rates: isothermal, dry adiabatic, moist adiabatic, and standard, with temperature ranging from 170 to 290 Kelvin.</alt-text>
</graphic>
</fig>
<p>Another limiting case is the moist (pseudo-)isotropic profile, also shown in <xref ref-type="fig" rid="F6">Figure 6</xref>. To calculate it we have used the following equation (Beers, 1945, p. 359; <xref ref-type="bibr" rid="B26">Koutsoyiannis, 2000</xref>) which gives a satisfactory approximation for both the isentropic change of saturated air (in which the liquid water remains in the space considered) and saturated pseudo-adiabatic change (in which the liquid water precipitates immediately):<disp-formula id="e4">
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<mml:mi>p</mml:mi>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x2b;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
<mml:mi>T</mml:mi>
</mml:mfrac>
<mml:mo>&#x3d;</mml:mo>
<mml:mtext>const</mml:mtext>
</mml:mrow>
</mml:math>
<label>(4)</label>
</disp-formula>
</p>
<p>In this, <inline-formula id="inf12">
<mml:math id="m16">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mi mathvariant="normal">d</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>287</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> J kg<sup>&#x2013;1</sup> K<sup>&#x2212;1</sup> is the gas constant of dry air, <inline-formula id="inf13">
<mml:math id="m17">
<mml:mrow>
<mml:mi>&#x3bb;</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mn>3.139</mml:mn>
<mml:mo>&#xd7;</mml:mo>
<mml:msup>
<mml:mn>10</mml:mn>
<mml:mn>6</mml:mn>
</mml:msup>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>2336</mml:mn>
<mml:mi>T</mml:mi>
<mml:mo>/</mml:mo>
<mml:mi mathvariant="normal">K</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> J&#xa0;kg<sup>&#x2013;1</sup> is the latent heat of vaporization, and <inline-formula id="inf14">
<mml:math id="m18">
<mml:mrow>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf15">
<mml:math id="m19">
<mml:mrow>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> are the saturation water vapor pressure and mixing ratio, respectively, for temperature <italic>T</italic>. By taking derivatives in <xref ref-type="disp-formula" rid="e4">Equation 4</xref>, setting <inline-formula id="inf16">
<mml:math id="m20">
<mml:mrow>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>, and performing algebraic manipulations we readily find as a special case <xref ref-type="disp-formula" rid="e3">Equation 3</xref> for dry conditions.</p>
<p>The saturation water vapor pressure <inline-formula id="inf17">
<mml:math id="m21">
<mml:mrow>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:math>
</inline-formula> is given by the Clausius-Clapeyron equation, as reformulated for water vapor by <xref ref-type="bibr" rid="B27">Koutsoyiannis (2012)</xref>:<disp-formula id="e5">
<mml:math id="m22">
<mml:mrow>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>e</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x2061;</mml:mo>
<mml:mi>exp</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mn>24.921</mml:mn>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mtext>&#x2009;</mml:mtext>
<mml:msup>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mrow>
<mml:mn>5.06</mml:mn>
</mml:mrow>
</mml:msup>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mrow>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mi>T</mml:mi>
</mml:mrow>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>273.16</mml:mn>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mi mathvariant="normal">K</mml:mi>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>e</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>6.11657</mml:mn>
<mml:mtext>&#x2009;hPa</mml:mtext>
</mml:mrow>
</mml:math>
<label>(5)</label>
</disp-formula>with <italic>T</italic>
<sub>0</sub> and <italic>e</italic>
<sub>0</sub> representing the coordinates of the triple point of water. The mixing ratio is<disp-formula id="e6">
<mml:math id="m23">
<mml:mrow>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mi>&#x3b5;</mml:mi>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:mi>p</mml:mi>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>e</mml:mi>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>T</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:math>
<label>(6)</label>
</disp-formula>where <italic>&#x3b5;</italic> &#x3d; 0.622 is the ratio of molar masses of water vapor and dry air.</p>
<p>It is seen in <xref ref-type="fig" rid="F6">Figure 6</xref> that the moist adiabatic atmosphere does not have a constant temperature gradient. Rather the gradient is low (4.9&#xa0;K/km) at the surface and becomes equal to the dry adiabatic rate (9.8&#xa0;K/km) at high altitudes. This is a consequence of the fact that at low temperatures the saturation vapor pressure is close to zero and, as already explained, <xref ref-type="disp-formula" rid="e4">Equation 4</xref> switches to <xref ref-type="disp-formula" rid="e3">Equation 3</xref>. The standard atmosphere has a profile close, but not identical, to that of the moist adiabatic one. Its slope is constant (6.5&#xa0;K/km) for the entire troposphere. The differences become large at high altitudes near the tropopause and above.</p>
<p>It is useful to compare these profiles with observational data. To this aim, we enroll in the ERA5 reanalysis over the period 1940 &#x2013; 2024 and find the global average temperature over this period at the available pressure levels, as well as the global average geopotential heights for these pressure levels. The results, areally averaged over the torrid and the north frigid zones, are shown in <xref ref-type="fig" rid="F7">Figure 7</xref>. To adapt the standard profile to the conditions of <xref ref-type="fig" rid="F7">Figure 7</xref> we take the following steps: (a) we replace the standard ground temperature of 288.15&#xa0;K with the average temperature of the zone at 1,000&#xa0;hPa, (b) we apply the standard gradient <italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km up to the altitude where the temperature takes the standard stratospheric value of 216.65 K, and (c) we keep a constant value of 216.65&#xa0;K above this altitude up to 20&#xa0;km.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Comparison of temperature profile models of Earth&#x2019;s troposphere with the mean annual observed temperature profile as given by ERA5 reanalysis, temporally averaged over the period 1940 &#x2013; 2024 and areally averaged over (left) the torrid zone and (right) the north frigid zone.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g007.tif">
<alt-text content-type="machine-generated">Graphs showing altitude versus temperature with different lapse rates. Lines represent isothermal, dry adiabatic, moist adiabatic, standard, and observed data from ERA5. Labeled rates include 9.8, 6.5, and 4 K/km. Green dots indicate observed values. The left graph is for the torrid zone and right for the north frigid zone.</alt-text>
</graphic>
</fig>
<p>We observe that in the tropics the actual average temperature profile is located between those of the moist adiabatic and the standard atmosphere, but above 12.5&#xa0;km it is closer to the former than the latter. However, in the polar area, observations are totally irrelevant to the moist adiabatic profile. Notice that the moist adiabatic conditions would suggest greater gradients in colder conditions (right panel) than in hotter (left panel) because of the Clausius-Clapeyron equation which results in lower WV quantities for lower temperatures (compare the gradients at the surface level, 4.0 and 7.7&#xa0;K/km in the two panels). The reality is the exact opposite as seen in <xref ref-type="fig" rid="F7">Figure 7</xref> (see also <xref ref-type="fig" rid="F12">Figures 12</xref>, <xref ref-type="fig" rid="F13">13</xref> below). This means that the moist adiabatic process, despite often being invoked in the literature to explain atmospheric conditions, is not sufficient a tool to describe and explain what happens in reality. All these support the conclusion that the standard atmosphere, despite its empirical basis and its low explanatory power, is more representative for the entire range of conditions on Earth, while the moist adiabatic profile is representative only for the tropics. The dry adiabatic profile is always very different from average conditions. For this reason, the analyses that follow are based on the standard atmosphere.</p>
</sec>
<sec id="s3-4">
<title>3.4 Is the ARE responsible for the observed temperature profile in the atmosphere?</title>
<p>To address the question in the heading, we apply the established greenhouse theory, without considering doubts that have been cast on the validity of the theory or alternative hypotheses (e.g., <xref ref-type="bibr" rid="B49">Nikolov and Zeller, 2017</xref>; <xref ref-type="bibr" rid="B45">Miskolczi, 2023</xref>). Rather, we enroll the RRTM software, which calculates at each atmospheric level <italic>z</italic> the SW and LW radiation going up and down, namely, the four quantities <inline-formula id="inf18">
<mml:math id="m24">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. The algebraic sum of the four quantities for <inline-formula id="inf19">
<mml:math id="m25">
<mml:mrow>
<mml:mi>z</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> equal to the ground level is the net radiation balance at the surface, which is used in evaporation calculations. While, due to its &#x201c;rapid&#x201d; characteristic this software is not the most accurate, we deem it satisfactory for the exploratory character of this research. Taking the differences at two adjacent levels <inline-formula id="inf20">
<mml:math id="m26">
<mml:mrow>
<mml:msub>
<mml:mi>z</mml:mi>
<mml:mn>1</mml:mn>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>z</mml:mi>
<mml:mn>2</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> we calculate the quantities <inline-formula id="inf21">
<mml:math id="m27">
<mml:mrow>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, the total radiative energy imbalance <inline-formula id="inf22">
<mml:math id="m28">
<mml:mrow>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mtext>tot</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, and finally the radiative energy imbalance slope, REIS, based on the following equations.<disp-formula id="e7">
<mml:math id="m29">
<mml:mrow>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mtext>tot</mml:mtext>
</mml:msub>
<mml:mo>&#x2254;</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>&#x2b;</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">S</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>&#x2b;</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>up</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>&#x2b;</mml:mo>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mrow>
<mml:mi mathvariant="normal">L</mml:mi>
<mml:msub>
<mml:mi mathvariant="normal">W</mml:mi>
<mml:mtext>down</mml:mtext>
</mml:msub>
</mml:mrow>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:mtext>REIS</mml:mtext>
<mml:mo>&#x2254;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mo>&#x394;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mtext>tot</mml:mtext>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x394;</mml:mo>
<mml:mi>z</mml:mi>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:math>
<label>(7)</label>
</disp-formula>
</p>
<p>By convention, <inline-formula id="inf23">
<mml:math id="m30">
<mml:mrow>
<mml:mi>R</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula> quantities directed up are taken as positive and those directed down as negative. If REIS turns out to be positive at a certain layer, between the levels <inline-formula id="inf24">
<mml:math id="m31">
<mml:mrow>
<mml:msub>
<mml:mi>z</mml:mi>
<mml:mn>1</mml:mn>
</mml:msub>
<mml:mo>,</mml:mo>
<mml:msub>
<mml:mi>z</mml:mi>
<mml:mn>2</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, this means that the layer receives energy of another type, such as sensible or latent thermal energy. This should be equal to REIS, so that the total energy balance be reinstated.</p>
<p>
<xref ref-type="fig" rid="F8">Figure 8</xref> depicts examples of these quantities between the elevations <italic>z</italic> &#x3d; 0 and <italic>z</italic> &#x3d; 426&#xa0;m (the fourth altitude given as output by RRTM) and for conditions specified in the figure caption, which include both RAGs and clouds. Two cases are examined, an isothermal atmosphere (<italic>&#x393;</italic> &#x3d; 0) and the standard atmosphere (<italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km). In the former case, REIS is almost zero, which means that no forcing appears to drive the atmospheric state away of the equilibrium. Therefore, the atmosphere would remain at the equilibrium (isothermal) state, despite the presence of RAGs and clouds.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Radiative energy change (SW and LW) between the elevations <italic>z</italic> &#x3d; 0 and <italic>z</italic> &#x3d; 426&#xa0;m and for the indicated cases with default values of RRTM plus clouds, both low and high, each with a fraction of 0.5. For an isothermal atmosphere (<italic>&#x393;</italic> &#x3d; 0) the REIS is almost zero, while for the standard atmosphere gradient (<italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km) there is a positive REIS, implying the presence of other energy forms to balance energy.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g008.tif">
<alt-text content-type="machine-generated">Bar graph showing radiative energy change (W/m&#xB2;/km) across different categories: SWdown, SWup, LWdown, LWup, and Total (REIS). Red bars represent a temperature lapse rate (&#x393;) of 6.5 K/km, while blue bars indicate isothermal conditions (&#x393; = 0). Total (REIS) change is around 15 for red and slightly negative for blue.</alt-text>
</graphic>
</fig>
<p>In contrast, for the standard atmosphere gradient a positive REIS appears, which means that the total energy balance needs to be reinstated by other energy forms. These forms are indeed present and are the sensible heat due to warm air parcels moving from the Earth&#x2019;s surface up, and the latent heat due to evaporation, again moving from the surface up.</p>
<p>A more complete picture is provided in <xref ref-type="fig" rid="F9">Figure 9</xref>, where REIS is calculated and plotted for the entire range of altitudes modeled by RRTM, for four different cases of ARE (RAG with clouds, RAG without clouds, no NC-RAG with clouds, no NC-RAG without clouds) and for two cases of temperature gradient, <italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km (standard atmosphere; upper row of panels) and <italic>&#x393;</italic> &#x3d; 0 (isothermal atmosphere, lower row of panels). What was discussed with respect to <xref ref-type="fig" rid="F8">Figure 8</xref> is confirmed in <xref ref-type="fig" rid="F9">Figure 9</xref> for all cases examined and for all altitudes in the troposphere. The isothermal case yields almost zero REIS in the entire troposphere (<italic>z</italic> &#x3c; 11&#xa0;km) in all cases, which means that the presence of RAGs, whether NC or WV, is not enough for the observed gradient to emerge, nor for the ARE to appear.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Total (SW and LW) radiative energy imbalance as a function of altitude for the indicated cases. In the upper row the gradient is <italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km, as in the standard atmosphere, while in the lower row there is no gradient (isothermal atmosphere, <italic>&#x393;</italic> &#x3d; 0). The temperature at the surface (T_s) and the top of atmosphere (T_TOA) are determined by the RRTM so as to equilibrate the incoming net SW (incoming minus outgoing) and the outgoing LW radiation at the top of atmosphere (R_TOA). The default values of RRTM parameters are used wherever it is not noted otherwise. In cases A1, A3, B1 and B3 the clouds referred to are both low and high, each with a fraction of 0.5. The spikes appearing at altitudes around 1&#xa0;km are due to low clouds. Although in an isothermal atmosphere, clouds would not be formed, for comparison the imaginary cases B1 and B3 assume the existence of clouds, similar to cases A1 and A3.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g009.tif">
<alt-text content-type="machine-generated">Eight-panel graph comparing radiation balance scenarios. Top four panels, labeled A1 to A4, use red lines depicting radiative energy imbalance slope (REIS) with and without clouds and radiative active gases (RAG). Bottom four panels, labeled B1 to B4, use blue lines, showing similar scenarios but for isothermal conditions. Each panel displays altitude versus radiation emission intensity. Specific temperature and radiation values are noted: T_s, T_TOA, and R_TOA, representing surface temperature, temperature at the top of the atmosphere, and radiation at the top of the atmosphere, respectively.</alt-text>
</graphic>
</fig>
<p>The last observation may sound counterintuitive to many who regard the presence of RAGs as a sufficient reason for the temperature gradient. However, our finding is consistent with experimental evidence reported by <xref ref-type="bibr" rid="B20">Harde and Schnell (2022)</xref>, who stated:</p>
<disp-quote>
<p>the greenhouse effect is mainly the result of a temperature difference over the propagation path of the radiation and thus the lapse rate in the atmosphere.</p>
</disp-quote>
<p>It further agrees with the following two statements by <xref ref-type="bibr" rid="B39">Lindzen (2012)</xref> and <xref ref-type="bibr" rid="B38">Lindzen (2018)</xref>, respectively):</p>
<disp-quote>
<p>It should be emphasized that if dynamical mixing were to have led to an isothermal atmosphere, then there would be no warming due to added greenhouse gases. In the counterfactual case that mixing were to have lead to increasing temperature with altitude, then added greenhouse gases would actually cool the atmosphere. In brief, greenhouse warming depends crucially on the existence and properties of dynamic mixing within the troposphere, and not simply on the radiative picture.</p>
</disp-quote>
<disp-quote>
<p>It is an interesting curiosity that had convection produced a uniform temperature, there wouldn&#x2019;t be a greenhouse effect.</p>
</disp-quote>
<p>On the other hand, with the standard atmosphere gradient (<italic>&#x393;</italic> &#x3d; 6.5&#xa0;K/km) there is a positive REIS in the entire troposphere, which leaves room for sensible and latent heat to act, reinstating the total energy balance and stabilizing the temperature gradient.</p>
</sec>
<sec id="s3-5">
<title>3.5 What factors can explain the observed temperature profile?</title>
<p>Given the analysis of the previous subsection, it becomes clear that it is not the ARE that creates and maintains the temperature gradient. Rather the mechanisms responsible for the temperature gradient are:<list list-type="simple">
<list-item>
<p>&#x2022; the warming of the soil and liquid water by the sunshine during the day and their cooling during the night;</p>
</list-item>
<list-item>
<p>&#x2022; the water evaporation and transpiration at the surface level and condensation aloft;</p>
</list-item>
<list-item>
<p>&#x2022; the convection, and the implied vertical transfer of sensible and latent heat;</p>
</list-item>
<list-item>
<p>&#x2022; the winds caused by spatial temperature differences and influenced by Coriolis forces.</p>
</list-item>
</list>
</p>
<p>These are not static forcings, but processes, i.e., perpetual changes in the climatic system. The processes occur on different time scales, some of which are too small to drive the atmosphere to the equilibrium (isothermal) state. It is noted that the processes occur at a macroscopic level, with the motion of masses of air, typically referred to as parcels. And as noted by <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref>, because of the very small thermal conductivity of air, it takes a very long time for appreciable heat to flow into or out of a parcel of reasonable size.</p>
<p>The driving mechanisms of these processes are the following:<list list-type="simple">
<list-item>
<p>1. Clouds form and disappear, strongly affecting the SW and LW radiation processes.</p>
</list-item>
<list-item>
<p>2. The Earth&#x2019;s surface is not homogeneous in terms of radiation absorption and reflection (varying albedo). The massive presence of water in liquid and solid phases with different albedo values, both on the Earth&#x2019;s surface (hydrosphere, cryosphere) and in the atmosphere (clouds) is responsible for spatial and temporal variations in the albedo, as well as in the thermodynamic properties of different parts of the Earth.</p>
</list-item>
<list-item>
<p>3. Earth is round (not flat) and the sunrays come with different slopes at different places.</p>
</list-item>
<list-item>
<p>4. Earth rotates around its axis on a daily basis.</p>
</list-item>
<list-item>
<p>5. Earth rotates around the Sun on an annual basis.</p>
</list-item>
<list-item>
<p>6. Earth&#x2019;s orbit around the Sun is elliptical, resulting in changes in the distance between the two bodies.</p>
</list-item>
<list-item>
<p>7. The climatic system is complex and is subject to irregular changes.</p>
</list-item>
</list>
</p>
<p>A rough quantification of changes produced by these mechanisms is shown in <xref ref-type="table" rid="T2">Table 2</xref>, where it is seen that some of them are of the order of 100%, reaching the absolute maximum of 200% on a daily scale. This quantification is just indicative and is unable to quantitatively predict the observed temperature profiles as seen in <xref ref-type="fig" rid="F7">Figure 7</xref>. It is also unable to produce the standard temperature gradient of 6.5&#xa0;K/km, which here we regard as an empirical model with satisfactory accuracy in representing the average conditions over the entire globe. It incorporates all mechanisms discussed here, but it can hardly be inferred from them by deduction. Sometimes the literature connects it to the moist adiabatic profile but the data above (particularly the right panel in <xref ref-type="fig" rid="F7">Figure 7</xref>) do not support this idea.</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Typical changes that cause departure from the isothermal atmosphere and their quantified effect on SW radiation processes. <italic>R</italic>
<sub>1</sub> and <italic>R</italic>
<sub>2</sub> denote the downwelling solar radiation at the surface level for the specified conditions 1 and 2, respectively; <italic>&#x3c6;</italic>, <italic>&#x3b1;</italic> and <italic>C</italic> denote the latitude, albedo and cloudiness, respectively. The calculations are based on <xref ref-type="bibr" rid="B26">Koutsoyiannis (2000)</xref> and <xref ref-type="bibr" rid="B61">van Wijngaarden and Happer (2023)</xref>.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">&#x0023;</th>
<th align="left">Reason</th>
<th align="left">Time scale</th>
<th align="left">Assumptions</th>
<th align="left">Condition 1</th>
<th align="left">Condition 2</th>
<th align="left">
<inline-formula id="inf25">
<mml:math id="m32">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>1</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> (W/m<sup>2</sup>)</th>
<th align="left">
<inline-formula id="inf26">
<mml:math id="m33">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>2</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> (W/m<sup>2</sup>)</th>
<th align="left">% change<xref ref-type="table-fn" rid="Tfn1">
<sup>a</sup>
</xref>
</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">1</td>
<td align="left">Change from clear to cloudy sky</td>
<td align="left">Hours</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 45&#xb0;, <italic>&#x3b1;</italic> &#x3d; 0.3, January</td>
<td align="left">Clear sky (<italic>C</italic> &#x3d; 0)</td>
<td align="left">Cloudy sky (<italic>C</italic> &#x3d; 1)</td>
<td align="left">74</td>
<td align="left">25</td>
<td align="left">100</td>
</tr>
<tr>
<td align="left">2</td>
<td align="left">Spatial change of albedo<xref ref-type="table-fn" rid="Tfn2">
<sup>b</sup>
</xref>
</td>
<td align="left">Hours</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 45&#xb0;, <italic>C</italic> &#x3d; 0, January</td>
<td align="left">Land (<italic>&#x3b1;</italic> &#x3d; 0.3)</td>
<td align="left">Sea (<italic>&#x3b1;</italic> &#x3d; 0.05)</td>
<td align="left">74</td>
<td align="left">100</td>
<td align="left">30</td>
</tr>
<tr>
<td align="left">3</td>
<td align="left">Change of latitude<xref ref-type="table-fn" rid="Tfn2">
<sup>b</sup>
</xref>
</td>
<td align="left">Hours</td>
<td align="left">
<italic>&#x3b1;</italic> &#x3d; 0.3, <italic>C</italic> &#x3d; 0, January</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 45&#xb0;</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 46&#xb0;</td>
<td align="left">74</td>
<td align="left">70</td>
<td align="left">5</td>
</tr>
<tr>
<td align="left">4</td>
<td align="left">Change from daylight to night</td>
<td align="left">Daily</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 45&#xb0;, <italic>&#x3b1;</italic> &#x3d; 0.3, <italic>C</italic> &#x3d; 0, January</td>
<td align="left">Daylight</td>
<td align="left">Night</td>
<td align="left">197</td>
<td align="left">0</td>
<td align="left">200</td>
</tr>
<tr>
<td align="left">5</td>
<td align="left">Change in the angle of incidence of the sun&#x2019;s rays</td>
<td align="left">Annual</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 45&#xb0;, <italic>&#x3b1;</italic> &#x3d; 0.3, <italic>C</italic> &#x3d; 0</td>
<td align="left">January</td>
<td align="left">July</td>
<td align="left">74</td>
<td align="left">245</td>
<td align="left">107</td>
</tr>
<tr>
<td align="left">6</td>
<td align="left">Changing distance between Earth and Sun</td>
<td align="left">Annual</td>
<td align="left">
<italic>&#x3c6;</italic> &#x3d; 0&#xb0;, <italic>&#x3b1;</italic> &#x3d; 0.3, <italic>C</italic> &#x3d; 0</td>
<td align="left">January</td>
<td align="left">July</td>
<td align="left">220</td>
<td align="left">206</td>
<td align="left">7</td>
</tr>
<tr>
<td align="left">7</td>
<td align="left">Recent global warming</td>
<td align="left">Decades</td>
<td align="left">Global average conditions</td>
<td align="left">Before</td>
<td align="left">After</td>
<td align="left">160.6</td>
<td align="left">161</td>
<td align="left">0.2</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="Tfn1">
<label>
<sup>a</sup>
</label>
<p>
<inline-formula id="inf27">
<mml:math id="m34">
<mml:mrow>
<mml:mn>2</mml:mn>
<mml:mrow>
<mml:mfenced open="|" close="|" separators="|">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>1</mml:mn>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>2</mml:mn>
</mml:msub>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>/</mml:mo>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>1</mml:mn>
</mml:msub>
<mml:mo>&#x2b;</mml:mo>
<mml:msub>
<mml:mi>R</mml:mi>
<mml:mn>2</mml:mn>
</mml:msub>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#xd7;</mml:mo>
<mml:mn>100</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>.</p>
</fn>
<fn id="Tfn2">
<label>
<sup>b</sup>
</label>
<p>Spatial changes are translated into temporal changes assuming wind velocity of 10&#xa0;m/s.</p>
</fn>
</table-wrap-foot>
</table-wrap>
</sec>
<sec id="s3-6">
<title>3.6 What is the relative importance of ARE and temperature gradient in climate dynamics?</title>
<p>The information provided in the different panels of <xref ref-type="fig" rid="F9">Figure 9</xref> includes the surface temperature at each of the cases examined (A1-A4, B1-B4). A summary of the results is given in <xref ref-type="fig" rid="F10">Figure 10</xref>, along with some additional hypothetical cases. The first imaginary-world case is a planet shaped as a disk perpendicular to the Sun&#x2019;s rays, without an atmosphere and receiving the average radiative energy that the Earth does. In this case, the so-called effective temperature is easy to calculate from the Stefan-Boltzmann law, i.e.,<disp-formula id="e8">
<mml:math id="m35">
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msup>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mi>I</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mn>4</mml:mn>
</mml:mrow>
</mml:mfrac>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mfrac>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>&#x3b1;</mml:mi>
</mml:mrow>
<mml:mrow>
<mml:mi>&#x3b5;</mml:mi>
<mml:mi>&#x3c3;</mml:mi>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mn>1</mml:mn>
</mml:mrow>
<mml:mrow>
<mml:mn>4</mml:mn>
</mml:mrow>
</mml:mfrac>
</mml:msup>
</mml:mrow>
</mml:math>
<label>(8)</label>
</disp-formula>where <italic>I</italic> &#x3d; 1360&#xa0;W/m<sup>2</sup> is the solar irradiance with <italic>I</italic>/4 &#x3d; 340&#xa0;W/m<sup>2</sup> representing the average solar energy received by (the spherical) Earth&#x2019;s surface, while <italic>&#x3c3;</italic> &#x3d; 5.67 &#xd7; 10<sup>&#x2212;8</sup>&#xa0;W&#xa0;m<sup>&#x2212;2</sup>&#xa0;K<sup>&#x2212;4</sup> is the Stefan&#x2013;Boltzmann constant, <italic>&#x3b5;</italic> is the emissivity of the radiating body and <italic>&#x3b1;</italic> is its albedo. Taking <italic>&#x3b5;</italic> &#x3d; 1 and using the Earth&#x2019;s current albedo <inline-formula id="inf28">
<mml:math id="m36">
<mml:mrow>
<mml:mi>&#x3b1;</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>0.3</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula>, so that <inline-formula id="inf29">
<mml:math id="m37">
<mml:mrow>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mi>I</mml:mi>
<mml:mo>/</mml:mo>
<mml:mn>4</mml:mn>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mrow>
<mml:mfenced open="(" close=")" separators="|">
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>&#x3b1;</mml:mi>
</mml:mrow>
</mml:mfenced>
</mml:mrow>
<mml:mo>&#x3d;</mml:mo>
<mml:mn>238</mml:mn>
</mml:mrow>
</mml:math>
</inline-formula> W/m<sup>2</sup>, the result is <inline-formula id="inf30">
<mml:math id="m38">
<mml:mrow>
<mml:msub>
<mml:mi>T</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> 254.5&#xa0;K.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Surface temperature for the cases shown in <xref ref-type="fig" rid="F9">Figure 9</xref> (A1-A4, B1-B4), in comparison with four additional hypothetical cases: the three cases on the left are for no atmosphere, no RAGs at all and no WV (and hence no clouds); the rightmost case is similar to A1/B1 but with doubled NC-RAGs, resulting in zero change for the isothermal atmosphere (compared to B1) and 1.5&#xa0;K increase for an atmosphere with standard gradient (compared to A1).</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g010.tif">
<alt-text content-type="machine-generated">Bar and line chart showing surface temperature variations in Kelvin under different atmospheric conditions. Bars represent a standard temperature gradient, while the line indicates an isothermal atmosphere. Scenarios include no atmosphere, radiation absorption, (RAG) presence or absence, cloud conditions, and water vapor (WV) effects, labeled from A1 to A4 and B1 to B4.</alt-text>
</graphic>
</fig>
<p>About the same (<italic>T</italic> &#x3d; 252&#xa0;K) would be the temperature in the imaginary-world case where there is an atmosphere but no ARE (no RAG and no clouds; second&#xa0;bar in <xref ref-type="fig" rid="F10">Figure 10</xref>) or even with NC-RAGs, but without WV and clouds and without a temperature gradient. If the gradient of 6.5&#xa0;K/km is present (third bar in <xref ref-type="fig" rid="F10">Figure 10</xref>) the temperature increases to 262&#xa0;K. Therefore, the effect of the NC-RAGs is zero for an isothermal atmosphere and 10&#xa0;K for an atmosphere with temperature gradient of 6.5&#xa0;K/km. By no means is it close to about 30&#xa0;K as typically implied in the literature.</p>
<p>In general, in an isothermal atmosphere, the effect of RAGs, including NC-RAGs, WV and clouds, is practically zero, as shown by the continuous (blue) line in <xref ref-type="fig" rid="F10">Figure 10</xref>, which fluctuates only slightly, from 249 to 256&#xa0;K. In contrast, if there is a gradient of 6.5&#xa0;K/km, the temperature increases up to &#x223c;288&#xa0;K in the realistic case A1, in which the atmosphere contains all RAGs and clouds.</p>
<p>Hence, it is the temperature gradient that makes the surface-level temperature increase from about 252&#xa0;K (which is close to the average <inline-formula id="inf31">
<mml:math id="m39">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>T</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
<mml:mo>&#x3d;</mml:mo>
</mml:mrow>
</mml:math>
</inline-formula> 250&#xa0;K of <xref ref-type="disp-formula" rid="e2">Equation 2</xref>) to about 288&#xa0;K (i.e., by 36&#xa0;K). This increase is usually attributed to the &#x201c;greenhouse effect&#x201d;, but it is mainly the result of the temperature gradient, whose origin is not the ARE but the processes described in <xref ref-type="sec" rid="s3-5">section 3.5</xref>. This is another reason why it is necessary to stop using the term &#x201c;greenhouse effect&#x201d; when talking about the climatic system.</p>
<p>We stress that, among the various cases shown in <xref ref-type="fig" rid="F10">Figure 10</xref>, only cases A1 and A2 are realistic, while all the others are hypothetical. A final hypothetical case shown at the rightmost end of the figure is where the NC-RAGs are doubled. This results in a temperature increase of zero in comparison to case B1 or 1.5&#xa0;K in comparison to case A1.</p>
<p>While the temperature gradient is the determinant factor that maintains the Earth&#x2019;s temperature much higher than the effective temperature of 254.5 K, with the mechanisms causing this gradient being also causes of maintaining warm conditions, the RAGs also play a significant role as can be inferred from <xref ref-type="fig" rid="F10">Figure 10</xref>. An atmosphere free of RAGs (both WV and NC) and clouds would keep the temperature close to the average, i.e. 252&#xa0;K (second bar in <xref ref-type="fig" rid="F10">Figure 10</xref>). However, this case is equally imaginary as that of no atmosphere (first bar in <xref ref-type="fig" rid="F10">Figure 10</xref>) and does not represent planet Earth. For Earth is massively (71%) covered by water, which evaporates, thus giving rise to WV and clouds in the atmosphere. Even without NC-RAGs but with WV and clouds, the surface temperature would be 277&#xa0;K (case A3)&#x2014;a substantial increase with respect to the effective temperature.</p>
<p>While <xref ref-type="fig" rid="F10">Figure 10</xref> provides information on the importance of different agents of Earth&#x2019;s warming, it should be stressed that the figure compares the realistic cases (A1, A2) with several imaginary-world cases (all others). Hence, it cannot be a basis for understanding the importance of each factor in real-world conditions. The scientific approach for the latter task is to determine the partial derivatives of a suitable multivariate function representing the ARE, such as the downwelling or outgoing LW radiation, at the point of the current conditions and compare them. Such an analysis has been done in <xref ref-type="bibr" rid="B32">Koutsoyiannis (2024b)</xref> with the following resulting percent contributions: (a) for downwelling LW radiation, WV and clouds 95%, CO<sub>2</sub> 4%, all other 1%; (b) for outgoing LW radiation, WV and clouds 87%, CO<sub>2</sub> 5%, all other 8% (primarily due to the influence of the stratospheric ozone).</p>
<p>Water vapor, besides being the determinant RAG and the cause of clouds, also has overwhelmingly more impact than CO<sub>2</sub> because its quantity in the atmosphere varies substantially over time and space. This makes WV an agent of perpetual change on all time scales. Relevant changes, mostly on hourly to annual time scales, have already been described in <xref ref-type="sec" rid="s3-5">Section 3.5</xref>. However, changes also occur at decadal, centennial scales and beyond. These long-term changes are inherent in all geophysical processes, including hydroclimatic ones, and are described in stochastic terms by the so-called Hurst-Kolmogorov dynamics (<xref ref-type="bibr" rid="B28">Koutsoyiannis, 2013</xref>; <xref ref-type="bibr" rid="B30">Koutsoyiannis, 2021</xref>; <xref ref-type="bibr" rid="B31">Koutsoyiannis, 2024a</xref>; <xref ref-type="bibr" rid="B51">O&#x2019;Connell et al., 2016</xref>; <xref ref-type="bibr" rid="B11">Dimitriadis et al., 2021</xref>).</p>
<p>As far as long-term changes are concerned, the CERES satellite data show a decline in the albedo of about 0.004 for the entire observation period (post 2000), which translates to 1.4&#xa0;W/m<sup>2</sup> (higher than the average imbalance of 0.4&#xa0;W/m<sup>2</sup> shown in case 7 of <xref ref-type="table" rid="T2">Table 2</xref>). This is consistent with an observed decline in cloud area fraction (<xref ref-type="bibr" rid="B35">Koutsoyiannis et al., 2023</xref>; Appendix A.2, <xref ref-type="bibr" rid="B36">Koutsoyiannis and Vournas, 2024</xref>; Appendix B; see also <xref ref-type="bibr" rid="B16">Goode et al., 2021</xref>; <xref ref-type="bibr" rid="B50">Nikolov and Zeller, 2024</xref>). Interestingly, a recent study by <xref ref-type="bibr" rid="B14">Goessling et al. (2025)</xref> identifies a record-low planetary albedo in 2023, apparently caused largely by a reduced low-cloud cover in the northern mid-latitudes and tropics, in continuation of a multi-annual trend, all of which contributing to the recent global temperature surge.</p>
<p>Coming back to the results shown in <xref ref-type="fig" rid="F10">Figure 10</xref>, a relevant issue to stress is that the analysis made is unidimensional. Is that representative for the average condition of Earth, which is spherical? A negative reply has been suggested by <xref ref-type="bibr" rid="B49">Nikolov and Zeller (2017)</xref>, who showed that the mean physical temperature of a spherical body is always lower than its effective radiating temperature computed from the globally integrated absorbed solar flux. This happens because of H&#xf6;lder&#x2019;s inequality between integrals and the fact that Stefan-Boltzmann law is a power law with an exponent 4.</p>
<p>This suggestion indeed makes sense for the condition of a planet without an atmosphere (first bar in <xref ref-type="fig" rid="F10">Figure 10</xref>), where an integration over the Earth&#x2019;s sphere would result in a lower value than shown in the figure. However, if we consider the realistic conditions of Earth, in particular cases A1 and A2 of <xref ref-type="fig" rid="F10">Figure 10</xref>, rather than the imaginary-world conditions, the cautionary note by Nikolov and Zeller does not apply. For the relationship between outgoing radiation and temperature is no longer a power law but a virtually linear relationship, as shown in <xref ref-type="fig" rid="F11">Figure 11</xref>, constructed from CERES radiation data and ERA5 Reanalysis near-surface temperature data. Additional information on this linear relationship is provided by <xref ref-type="bibr" rid="B24">Koll and Cronin (2018)</xref>, Figure 1 and <xref ref-type="bibr" rid="B32">Koutsoyiannis (2024b)</xref>, Figure 6, which in essence confirm early observations and analyses by <xref ref-type="bibr" rid="B6">Budyko (1969)</xref>. Hence, the quantities depicted in <xref ref-type="fig" rid="F10">Figure 10</xref> are representative of average conditions for the (spherical) Earth, at least for the realistic cases A1 and A2, albeit not for the imaginary case of an atmosphere-free Earth.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Outgoing LW radiation vs. ground temperature. Each point refers to the zonal average of LW radiation (for clear sky and all sky) averaged from 2000 to 2022 as given by the CERES data and the zonal average of ground temperature as given by ERA5 Reanalysis; the resolution is 1&#xb0; (180 points in total). Temperature data from ERA5 Reanalysis retrieved from the CLIMEXP platform; radiation data retrieved from <ext-link ext-link-type="uri" xlink:href="https://ceres-tool.larc.nasa.gov/ordtool/jsp/SSF1degEd41Selection.jsp">https://ceres-tool.larc.nasa.gov/ordtool/jsp/SSF1degEd41Selection.jsp</ext-link>.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g011.tif">
<alt-text content-type="machine-generated">Graph showing the relationship between temperature in Kelvin and outgoing longwave flux in watts per square meter. Blue circles and lines represent all sky conditions for Southern and Northern Hemispheres. Red triangles and lines represent clear sky conditions. Temperature ranges from 220 to 310 Kelvin, and flux ranges from 120 to 320 W/m&#xB2;.</alt-text>
</graphic>
</fig>
</sec>
<sec id="s3-7">
<title>3.7 What are the recent changes in the atmospheric temperature gradient?</title>
<p>Once we have recognized that the temperature gradient is a result of macroscopic changes on Earth (<xref ref-type="sec" rid="s3-5">Section 3.5</xref>) and that it is a critical factor determining the climate (<xref ref-type="sec" rid="s3-6">Section 3.6</xref>), it is useful to monitor and analyze its changes, which are certainly much more influential than the famed changes in CO<sub>2</sub> concentration. To this end, <xref ref-type="fig" rid="F12">Figure 12</xref> (upper) shows the variation of the atmospheric temperature averaged over the five geographical zones at two pressure levels, 1,000 and 200&#xa0;hPa, as given by the ERA5 reanalysis.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>(upper) Evolution of mean annual air temperature averaged over the five geographical zones at the levels of 1,000 and 200&#xa0;hPa. (lower) Evolution of the (minus) vertical temperature gradient per geographical zone, calculated from differences of temperatures and geopotential heights between these two levels. Data from ERA5 Reanalysis retrieved through NOAA&#x2019;s WRIT.</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g012.tif">
<alt-text content-type="machine-generated">Two line graphs depict changes in temperature from 1940 to 2030. The top graph shows annual average temperatures in Kelvin for different zones: torrid, temperate, and frigid in both hemispheres at two pressure levels (1000 hPa and 200 hPa). The bottom graph illustrates temperature gradients in Kelvin per kilometer over the same period, with similar zonal and hemispheric distinctions.</alt-text>
</graphic>
</fig>
<p>By using the geopotential height at these pressure levels, also available in the ERA5 dataset, we determined and plotted in <xref ref-type="fig" rid="F12">Figure 12</xref> (lower) the evolution of the vertical temperature gradient per geographical zone, calculated as the (minus) ratio of differences of temperature and geopotential heights between these two levels.</p>
<p>It is clear from <xref ref-type="fig" rid="F12">Figure 12</xref> that, as we move from the equator to the poles and the surface temperatures decrease, so do the temperature gradients. This is fully compatible with the analyses of <xref ref-type="sec" rid="s3-4">Sections 3.4&#x2013;</xref>
<xref ref-type="sec" rid="s3-6">3.6</xref>, according to which higher gradients lead to higher surface temperatures (see also <xref ref-type="fig" rid="F13">Figure 13</xref>, left).</p>
<fig id="F13" position="float">
<label>FIGURE 13</label>
<caption>
<p>(left) Average temperature gradient per geographical zone (calculated as indicated in the caption of <xref ref-type="fig" rid="F12">Figure 12</xref>) vs. average temperature. (right) Change in temperature gradient per geographical zone over the 85-year period of ERA5 data availability (calculated from the slope of linear trends fitted to the curves of <xref ref-type="fig" rid="F12">Figure 12</xref>, lower).</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g013.tif">
<alt-text content-type="machine-generated">Two scatter plots show temperature gradients. The left plot illustrates the average temperature gradient (K/km) versus average temperature at 1000 hPa (K) for different climate zones: Frigid NH, Frigid SH, Temperate NH, Temperate SH, and Torrid. The right plot shows the change in temperature gradient (K/km/85 years) versus average temperature gradient (K/km), highlighting similar zones. Data points are labeled accordingly.</alt-text>
</graphic>
</fig>
<p>Surface temperatures present increasing trends over time in all zones. In contrast, the temperatures at the level of 200&#xa0;hPa do not show geographical or temporal changes. It is interesting to examine the temporal trends of temperature gradients, visualized in <xref ref-type="fig" rid="F12">Figure 12</xref> (lower) and summarized in <xref ref-type="fig" rid="F13">Figure 13</xref> (right). At the torrid zone we observe a falling trend, which can be viewed as negative feedback to the increasing surface temperatures. In contrast, at the frigid zones the trends are increasing, and hence we would expect greater warming. In the temperate zones no notable trends appear.</p>
<p>Indeed, the zonal distribution of the climatic surface temperature differences between the latest and oldest 30-year periods (for which ERA5 Reanalysis data are available in the CLIMEXP platform), seen in <xref ref-type="fig" rid="F14">Figure 14</xref>, confirm these observations. The figure plots show that for the greatest part of Earth, between latitudes 50&#xb0;S and 50&#xb0;N there has been a warming trend of about 1.4&#xa0;K/century, slightly increasing as we move north, as the percentage of land increases. Between 50&#xb0;N and the Arctic Circle there is a further warming trend, while between 50&#xb0;S and the Antarctic Circle the trend becomes cooling. The greatest increases of surface temperature are observed in the frigid zones, where we have increasing temperature gradient trends.</p>
<fig id="F14" position="float">
<label>FIGURE 14</label>
<caption>
<p>Difference of average surface temperatures, as a function of the sine of latitude, of two 30-year climatic periods, namely, of the most recent 1995 &#x2013; 2024 minus the 1950 &#x2013; 1979. Continuous line represents the average over the globe, while dashed line represents the average over the area between longitudes 155&#xb0;E and 130&#xb0;W, mostly covered by sea (Pacific, Arctic and Southern Oceans). The sine of latitude was chosen as the horizontal axis so that increments be proportional to the respective areas on Earth. Data from ERA5 reanalysis; data retrieval and processing from the CLIMEXP platform (processing steps: (a) subsetting for each of the two periods; (b) aggregation to annual (Jan-Dec) time resolution; (c) compute zonal mean; (d) compute mean, s.d. [standard deviation], or extremes).</p>
</caption>
<graphic xlink:href="fcpxs-03-1617092-g014.tif">
<alt-text content-type="machine-generated">Graph showing temperature difference of two 30-year climatic periods (namely, of the most recent 1995 &#x2013; 2024 minus the 1950 &#x2013; 1979), and resulting trend across latitudes, labeled Frigid, Temperate, and Torrid zones. The red line refers to the entire globe, and the green dashed line refers to a part of the globe mostly covered by sea, with significant increases in the Frigid zones near the poles.</alt-text>
</graphic>
</fig>
<p>All the above observations are consistent with the evidence from paleoclimatic studies, which suggests that the surface equator-to-pole temperature gradients were weaker during warm periods, while tropical temperatures changed very little (<xref ref-type="bibr" rid="B7">Budyko, 1977</xref>, p. 17; <xref ref-type="bibr" rid="B21">Huber et al., 2000</xref>, p. 289; <xref ref-type="bibr" rid="B22">Huber, 2008</xref>; <xref ref-type="bibr" rid="B37">Lee, 2014</xref>; <xref ref-type="bibr" rid="B40">Lindzen, 2020</xref>). They are also consistent with the recent study by <xref ref-type="bibr" rid="B42">Ma et al. (2025)</xref>, which identified wind stilling (compatible with the decrease in the surface equator-to-pole temperature gradient), resulting in weaker evaporation in two-thirds of the ocean and a slight decreasing trend in global-averaged ocean evaporation during 2008&#x2013;2017. In addition, as already mentioned, the falling multiyear trend in the planetary albedo, largely caused by a reduced low-cloud cover, has been a main driver of the recent global temperature.</p>
</sec>
</sec>
<sec id="s4">
<title>4 Discussion and conclusions</title>
<p>The research presented here challenges the ideas that we live in a greenhouse and that science can be settled, and revisits the most fundamental topics related to climate. This is attempted in the simplest possible way and using the fewest premises, such as Newton&#x2019;s laws, the principle of maximum entropy and the spectroscopic properties of gases. Additionally, the study proposes that commonly used vocabulary should be replaced by rigorous scientific terminology, the main examples being &#x201c;greenhouse gas&#x201d; and &#x201c;greenhouse effect&#x201d;, which could be replaced by &#x201c;radiatively active gas&#x201d; (RAG, comprising water vapor&#x2014;WV&#x2014;and non-condensing radiatively active gases&#x2014;NC-RAGs) and &#x201c;atmospheric radiative effect&#x201d; (ARE), respectively.</p>
<p>The conclusions of the analyses presented here can be summarized as follows:<list list-type="simple">
<list-item>
<p>&#x2022; There is an empirically verified ARE in the atmosphere, not only on Earth but also on the other planets. On Earth, ARE is dominated by WV and clouds, with CO<sub>2</sub> playing a very minor role&#x2014;let alone human added CO<sub>2</sub> which represents only 4% of the total emissions to the atmosphere.</p>
</list-item>
<list-item>
<p>&#x2022; Equilibrium thermodynamics clearly show (either using the principle of maximum entropy, or stochastic simulation of molecule collisions) that Earth&#x2019;s atmosphere would be isothermal at the equilibrium, with or without RAGs. In an isothermal atmosphere the temperature would be slightly higher than 250&#xa0;K, a value which represents the vertically average temperature of the standard atmosphere over the troposphere and stratosphere.</p>
</list-item>
<list-item>
<p>&#x2022; The fact is that the atmosphere is not isothermal. Rather, the troposphere has a vertical temperature gradient of about 6.5&#xa0;K/km, which is imprinted in the standard atmosphere. The gradient is resultant of macroscopic changes that drive the atmosphere out of equilibrium. While the moist adiabatic changes play a role in shaping this gradient, they cannot fully predict real atmospheric conditions.</p>
</list-item>
<list-item>
<p>&#x2022; The mean surface temperature of 288&#xa0;K, also imprinted in the standard atmosphere, is much higher than the equilibrium temperature. While RAGs (mostly WV and clouds) play a role in yielding this temperature, the critical factor is the vertical temperature gradient, without which the ARE alone would not be able to increase the equilibrium temperature.</p>
</list-item>
<list-item>
<p>&#x2022; Given the importance of the atmospheric temperature gradient, which is described by large-scale atmospheric thermodynamics, rather than radiative physics, it is puzzling that the emphasis in climate research has been on the latter. This gradient is not a universal constant, but it varies with space and time. It is therefore useful to monitor and analyze its changes. The data show that since 1950 the gradient has weakened in the tropics and grown in the polar areas resulting in decrease of the surface equator-to-pole gradient, as expected in global warming conditions.</p>
</list-item>
</list>
</p>
<p>A final point worth stressing is that in complex systems, such as the climatic system, observational data are the only scientific test bed for making hypotheses and assessing their validity. Focusing on one of the factors affecting the climatic system, namely, the anthropogenic CO<sub>2</sub> emissions, and basing on models that emphasize this factor, may distort our perception of the big picture and be detrimental to science, whose objective is to pursue the truth.</p>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s5">
<title>Data availability statement</title>
<p>The datasets presented in this study can be found in online repositories, namely in the links given in section 2 and the references cited there.</p>
</sec>
<sec sec-type="author-contributions" id="s6">
<title>Author contributions</title>
<p>DK: Data curation, Supervision, Conceptualization, Software, Investigation, Methodology, Writing &#x2013; original draft, Writing &#x2013; review and editing, Resources, Project administration, Validation, Formal Analysis. GT: Validation, Visualization, Writing &#x2013; review and editing, Methodology, Formal Analysis, Investigation, Software.</p>
</sec>
<sec sec-type="funding-information" id="s7">
<title>Funding</title>
<p>The author(s) declare that no financial support was received for the research and/or publication of this article.</p>
</sec>
<ack>
<p>We are grateful to the colleagues and organizations who have put their huge data sets online along with the data processing and computational systems they have developed. These include the CERES data, the ERA5 Reanalysis, the CLIMEXP and WRIT data and software platforms, and the RRTM software system. We thank two reviewers for the positive assessment of the paper and their detailed and constructive comments. We also thank the Guest Editors and Chief Editors for the processing of the paper and their suggestions, and for approving the paper for publication. We acknowledge useful comments (including points of disagreement) on a preprint of the paper (doi: <ext-link ext-link-type="uri" xlink:href="https://doi.org/10.13140/RG.2.2.14752.49923">10.13140/RG.2.2.14752.49923</ext-link>) which we received from Ned Nikolov, William Happer, Willis Eschenbach, Hermann Harde and Richard Cina. All the above helped us improve the final version of the paper.</p>
</ack>
<sec sec-type="other" id="s18">
<title>In memoriam</title>
<p>Dedicated to the memory of Anna (Annouska) Patrikiou&#x2013;Koutsoyiannis, who left this world while this research was conducted.</p>
</sec>
<sec sec-type="COI-statement" id="s8">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="ai-statement" id="s9">
<title>Generative AI statement</title>
<p>The author(s) declare that no Generative AI was used in the creation of this manuscript.</p>
</sec>
<sec sec-type="disclaimer" id="s10">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<sec sec-type="supplementary-material" id="s11">
<title>Supplementary material</title>
<p>The Supplementary Material for this article can be found online at: <ext-link ext-link-type="uri" xlink:href="https://www.frontiersin.org/articles/10.3389/fcpxs.2025.1617092/full#supplementary-material">https://www.frontiersin.org/articles/10.3389/fcpxs.2025.1617092/full&#x23;supplementary-material</ext-link>
</p>
<supplementary-material xlink:href="Supplementaryfile1.pdf" id="SM1" mimetype="application/pdf" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Supplementaryfile2.zip" id="SM2" mimetype="application/zip" xmlns:xlink="http://www.w3.org/1999/xlink"/>
<supplementary-material xlink:href="Video1.mp4" id="SM3" mimetype="application/mp4" xmlns:xlink="http://www.w3.org/1999/xlink"/>
</sec>
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