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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Astron. Space Sci.</journal-id>
<journal-title>Frontiers in Astronomy and Space Sciences</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Astron. Space Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-987X</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.3389/fspas.2017.00021</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Astronomy and Space Sciences</subject>
<subj-group>
<subject>Perspective</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>The MEXSAS2 Sample and the Ensemble X-ray Variability of Quasars</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name><surname>Serafinelli</surname> <given-names>Roberto</given-names></name>
<xref ref-type="aff" rid="aff1"><sup>1</sup></xref>
<xref ref-type="aff" rid="aff2"><sup>2</sup></xref>
<xref ref-type="author-notes" rid="fn001"><sup>&#x0002A;</sup></xref>
<uri xlink:href="http://loop.frontiersin.org/people/460113/overview"/>
</contrib>
<contrib contrib-type="author">
<name><surname>Vagnetti</surname> <given-names>Fausto</given-names></name>
<xref ref-type="aff" rid="aff1"><sup>1</sup></xref>
<uri xlink:href="http://loop.frontiersin.org/people/161461/overview"/>
</contrib>
<contrib contrib-type="author">
<name><surname>Chiaraluce</surname> <given-names>Elia</given-names></name>
<xref ref-type="aff" rid="aff1"><sup>1</sup></xref>
<uri xlink:href="http://loop.frontiersin.org/people/483575/overview"/>
</contrib>
<contrib contrib-type="author">
<name><surname>Middei</surname> <given-names>Riccardo</given-names></name>
<xref ref-type="aff" rid="aff3"><sup>3</sup></xref>
<uri xlink:href="http://loop.frontiersin.org/people/483786/overview"/>
</contrib>
</contrib-group>
<aff id="aff1"><sup>1</sup><institution>Dipartimento di Fisica, Universit&#x000E0; di Roma Tor Vergata</institution>, <addr-line>Rome</addr-line>, <country>Italy</country></aff>
<aff id="aff2"><sup>2</sup><institution>Dipartimento di Fisica, Universit&#x000E0; di Roma Sapienza</institution>, <addr-line>Rome</addr-line>, <country>Italy</country></aff>
<aff id="aff3"><sup>3</sup><institution>Dipartimento di Matematica e Fisica, Universit&#x000E0; Roma Tre</institution>, <addr-line>Rome</addr-line>, <country>Italy</country></aff>
<author-notes>
<fn fn-type="edited-by"><p>Edited by: Paola Marziani, Osservatorio Astronomico di Padova (INAF), Italy</p></fn>
<fn fn-type="edited-by"><p>Reviewed by: Edi Bon, Belgrade Astronomical Observatory, Serbia; Isabel Marquez Perez, Instituto de Astrof&#x000ED;sica de Andaluc&#x000ED;a (CSIC), Spain</p></fn>
<fn fn-type="corresp" id="fn001"><p>&#x0002A;Correspondence: Roberto Serafinelli <email>roberto.serafinelli&#x00040;roma2.infn.it</email></p></fn>
<fn fn-type="other" id="fn002"><p>This article was submitted to Milky Way and Galaxies, a section of the journal Frontiers in Astronomy and Space Sciences</p></fn></author-notes>
<pub-date pub-type="epub">
<day>11</day>
<month>10</month>
<year>2017</year>
</pub-date>
<pub-date pub-type="collection">
<year>2017</year>
</pub-date>
<volume>4</volume>
<elocation-id>21</elocation-id>
<history>
<date date-type="received">
<day>17</day>
<month>07</month>
<year>2017</year>
</date>
<date date-type="accepted">
<day>26</day>
<month>09</month>
<year>2017</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#x000A9; 2017 Serafinelli, Vagnetti, Chiaraluce and Middei.</copyright-statement>
<copyright-year>2017</copyright-year>
<copyright-holder>Serafinelli, Vagnetti, Chiaraluce and Middei</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/"><p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p></license>
</permissions>
<abstract><p>We present the second Multi-Epoch X-ray Serendipitous AGN Sample (MEXSAS2), extracted from the 6th release of the XMM Serendipitous Source Catalog (XMMSSC-DR6), cross-matched with Sloan Digital Sky Survey quasar Catalogs DR7Q and DR12Q. Our sample also includes the available measurements for masses, bolometric luminosities, and Eddington ratios. Analyses of the ensemble structure function and spectral variability are presented, together with their dependences on such parameters. We confirm a decrease of the structure function with the X-ray luminosity, and find a weak dependence on the black hole mass. We introduce a new spectral variability estimator, taking errors on both fluxes and spectral indices into account. We confirm an ensemble softer when brighter trend, with no dependence of such estimator on black hole mass, Eddington ratio, redshift, X-ray and bolometric luminosity.</p></abstract>
<kwd-group>
<kwd>Catalogs</kwd>
<kwd>quasars</kwd>
<kwd>spectral variability</kwd>
<kwd>structure function</kwd>
<kwd>X-rays</kwd>
</kwd-group>
<counts>
<fig-count count="3"/>
<table-count count="0"/>
<equation-count count="3"/>
<ref-count count="16"/>
<page-count count="4"/>
<word-count count="2427"/>
</counts>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1. The MEXSAS2 Catalog</title>
<p>We present here the MEXSAS2 Catalog, obtained from the sixth release of the XMM Newton Serendipitous Source Catalog (XMMSSC-DR6, Rosen et al., <xref ref-type="bibr" rid="B9">2016</xref>), combined with both SDSS-DR7Q (Schneider et al., <xref ref-type="bibr" rid="B10">2010</xref>) and SDSS-DR12Q quasar Catalogs (P&#x000E2;ris et al., <xref ref-type="bibr" rid="B7">2017</xref>). The MEXSAS2 Catalog is the updated version of MEXSAS (Multi-Epoch XMM Serendipitous AGN Sample), published by Vagnetti et al. (<xref ref-type="bibr" rid="B15">2016</xref>). It contains 9,735 X-ray observations for 3,366 quasars, which increases by about 25% the numbers of the previous version (7,837 observations, 2,700 quasars). It only contains sources with more than one observation, and it is therefore ideal for variability studies.</p>
<p>We complement the Catalog with measurements of black hole masses, bolometric luminosities and Eddington ratios, which are available for 3,138 quasars (93%) from the Catalogs by Shen et al. (<xref ref-type="bibr" rid="B12">2011</xref>) for the sources listed in SDSS-DR7Q, and by Koz&#x00142;owski (<xref ref-type="bibr" rid="B5">2017</xref>) for SDSS-DR12Q. We use homogeneous criteria to derive the masses and bolometric luminosities from the two Catalogs, adapting their criteria, which are slightly different for the redshift intervals where two different broad lines and two continuum luminosities are available. In fact, Shen et al. (<xref ref-type="bibr" rid="B12">2011</xref>) adopts different single-epoch virial estimates sharply dividing at redshift <italic>z</italic> &#x0003D; 0.7 for choosing between H&#x003B2; and MgII(2,798&#x000C5;) relations, and at <italic>z</italic> &#x0003D; 1.9 for Mg II(2,798&#x000C5;) and C IV(1,549&#x000C5;). A similar option is adopted for computing bolometric luminosities from the continua at 5,100&#x000C5; or 3,000&#x000C5; dividing at <italic>z</italic> &#x0003D; 0.7, and at 3,000&#x000C5; or 1,350&#x000C5; dividing at <italic>z</italic> &#x0003D; 1.9. The criteria adopted by Koz&#x00142;owski (<xref ref-type="bibr" rid="B5">2017</xref>) are instead to prefer the Mg II black hole mass estimate when available, rather than that from C IV, which is biased from various effects, and to compute bolometric luminosity as a weighted average of those derived from two different available continua. However, Koz&#x00142;owski (<xref ref-type="bibr" rid="B5">2017</xref>) also find that the DR7Q line widths (which are derived from detailed fits of spectral components) are generally more reliable than the DR12Q ones (which are derived from principal component analysis), thus they are to be preferred, when available. To apply the same criteria to the mass and luminosity data from both DR7Q and DR12Q, we adopt the following choice: (i) for quasars included only inDR12Q and not in DR7Q, we take the estimates by Koz&#x00142;owski (<xref ref-type="bibr" rid="B5">2017</xref>) (2178 objects); (ii) for quasars included in both Catalogs or only in DR7Q, and in redshift intervals with only one broad line and one continuum luminosity available (<italic>z</italic> &#x02272; 0.35, 0.9 &#x02272; <italic>z</italic> &#x02272; 1.5, <italic>z</italic> &#x02273; 2.25), we take the estimates by Shen et al. (<xref ref-type="bibr" rid="B12">2011</xref>) (442 objects); (iii) for quasars included in both Catalogs or only in DR7Q, in redshift intervals with two broad lines and continua (0.35 &#x02272; <italic>z</italic> &#x02272; 0.9, 1.5 &#x02272; <italic>z</italic> &#x02272; 2.25), we apply the Koz&#x00142;owski (<xref ref-type="bibr" rid="B5">2017</xref>) criteria to the DR7Q data, deriving new estimates (518 objects).</p>
<p>The Catalog, including X-ray measurements from XMMSSC and quasar data from SDSS and from our elaboration, will be published elsewhere (Vagnetti et al, in preparation). Here we provide preliminary results of our ensemble analyses of the X-ray variability.</p>
</sec>
<sec id="s2">
<title>2. Flux variability and structure function</title>
<p>We compute the structure function according to Vagnetti et al. (<xref ref-type="bibr" rid="B15">2016</xref>), as a r.m.s. difference of the X-ray flux measured at two epochs differing by &#x003C4; in the rest-frame, and corrected for the noise contribution,</p>
<disp-formula id="E1"><label>(1)</label><mml:math id="M1"><mml:mrow><mml:mi>S</mml:mi><mml:mi>F</mml:mi><mml:mo stretchy='false'>(</mml:mo><mml:mi>&#x003C4;</mml:mi><mml:mo stretchy='false'>)</mml:mo><mml:mo>&#x02261;</mml:mo><mml:msqrt><mml:mrow><mml:mo>&#x02329;</mml:mo><mml:msup><mml:mrow><mml:mo stretchy='false'>[</mml:mo><mml:mi>log</mml:mi><mml:msub><mml:mi>f</mml:mi><mml:mi>X</mml:mi></mml:msub><mml:mo stretchy='false'>(</mml:mo><mml:mi>t</mml:mi><mml:mo>+</mml:mo><mml:mi>&#x003C4;</mml:mi><mml:mo stretchy='false'>)</mml:mo><mml:mo>&#x02212;</mml:mo><mml:mi>log</mml:mi><mml:msub><mml:mi>f</mml:mi><mml:mi>X</mml:mi></mml:msub><mml:mo stretchy='false'>(</mml:mo><mml:mi>t</mml:mi><mml:mo stretchy='false'>)</mml:mo><mml:mo stretchy='false'>]</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msup><mml:mo>&#x0232A;</mml:mo><mml:mo>&#x02212;</mml:mo><mml:msubsup><mml:mi>&#x003C3;</mml:mi><mml:mrow><mml:mi>n</mml:mi><mml:mi>o</mml:mi><mml:mi>i</mml:mi><mml:mi>s</mml:mi><mml:mi>e</mml:mi><mml:mo>,</mml:mo><mml:mi>S</mml:mi><mml:mi>F</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msubsup></mml:mrow></mml:msqrt><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
<p>where <inline-formula><mml:math id="M2"><mml:msubsup><mml:mrow><mml:mi>&#x003C3;</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi><mml:mi>o</mml:mi><mml:mi>i</mml:mi><mml:mi>s</mml:mi><mml:mi>e</mml:mi><mml:mo>,</mml:mo><mml:mi>S</mml:mi><mml:mi>F</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msubsup><mml:mo>=</mml:mo><mml:mrow><mml:mo>&#x02329;</mml:mo><mml:mrow><mml:msubsup><mml:mrow><mml:mi>&#x003C3;</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msubsup><mml:mrow><mml:mo stretchy="false">(</mml:mo><mml:mrow><mml:mi>t</mml:mi></mml:mrow><mml:mo stretchy="false">)</mml:mo></mml:mrow><mml:mo>&#x0002B;</mml:mo><mml:msubsup><mml:mrow><mml:mi>&#x003C3;</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msubsup><mml:mrow><mml:mo stretchy="false">(</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>&#x0002B;</mml:mo><mml:mi>&#x003C4;</mml:mi></mml:mrow><mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:mrow><mml:mo>&#x0232A;</mml:mo></mml:mrow></mml:math></inline-formula> is the quadratic contribution of the photometric noise to the observed variations, &#x003C3;<sub><italic>n</italic></sub> being the error on log<italic>f</italic><sub><italic>X</italic></sub> at each given time.</p>
<p>We use mainly EPIC X-ray fluxes in the XMM-Newton band 9 (0.5&#x02013;4.5 KeV), as in our previous papers (Vagnetti et al., <xref ref-type="bibr" rid="B16">2011</xref>, <xref ref-type="bibr" rid="B15">2016</xref>).</p>
<p>The SF can be fitted by a power-law SF&#x0221D;&#x003C4;<sup><italic>b</italic></sup>. For the whole sample we find a slope <italic>b</italic> &#x0003D; 0.11&#x000B1;0.01. The SFs in bins of X-ray luminosity and black hole mass are shown in Figure <xref ref-type="fig" rid="F1">1</xref>. We confirm a strong anti-correlation with X-ray luminosity, approximately as <inline-formula><mml:math id="M3"><mml:msubsup><mml:mrow><mml:mi>L</mml:mi></mml:mrow><mml:mrow><mml:mi>X</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mn>0</mml:mn><mml:mo>.</mml:mo><mml:mn>22</mml:mn></mml:mrow></mml:msubsup></mml:math></inline-formula>, with correlation coefficient <italic>r</italic> &#x0003D; &#x02212;0.92 and null probability <italic>p</italic>(&#x0003E;<italic>r</italic>) &#x0003D; 0.04, and no dependence on redshift, similarly to Vagnetti et al. (<xref ref-type="bibr" rid="B15">2016</xref>). There is an apparent decrease of the SF with black hole mass, approximately as <inline-formula><mml:math id="M4"><mml:msubsup><mml:mrow><mml:mi>M</mml:mi></mml:mrow><mml:mrow><mml:mi>B</mml:mi><mml:mi>H</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mn>0</mml:mn><mml:mo>.</mml:mo><mml:mn>15</mml:mn></mml:mrow></mml:msubsup></mml:math></inline-formula>, with <italic>r</italic> &#x0003D; &#x02212;0.97 and <italic>p</italic>(&#x0003E;<italic>r</italic>) = 0.03, but partial correlation analysis suggests that this is due to the strong correlation of mass with X-ray luminosity. Limiting the analysis to the luminosity interval <inline-formula><mml:math id="M5"><mml:mn>1</mml:mn><mml:msup><mml:mrow><mml:mn>0</mml:mn></mml:mrow><mml:mrow><mml:mn>44</mml:mn></mml:mrow></mml:msup><mml:mtext>erg</mml:mtext><mml:mo>/</mml:mo><mml:mtext>s</mml:mtext><mml:mo>&#x0003C;</mml:mo><mml:msub><mml:mrow><mml:mi>L</mml:mi></mml:mrow><mml:mrow><mml:mi>X</mml:mi></mml:mrow></mml:msub><mml:mo>&#x0003C;</mml:mo><mml:mn>1</mml:mn><mml:msup><mml:mrow><mml:mn>0</mml:mn></mml:mrow><mml:mrow><mml:mn>45</mml:mn></mml:mrow></mml:msup><mml:mtext>erg</mml:mtext><mml:mo>/</mml:mo><mml:mtext>s</mml:mtext></mml:math></inline-formula>, the mass-luminosity correlation reduces (<italic>r</italic> &#x0003D; &#x02212;0.83, <italic>p</italic>(&#x0003E;<italic>r</italic>) = 0.06), and the dependence of the SF on black hole mass is weaker, <inline-formula><mml:math id="M6"><mml:mo>&#x0221D;</mml:mo><mml:msubsup><mml:mrow><mml:mi>M</mml:mi></mml:mrow><mml:mrow><mml:mi>B</mml:mi><mml:mi>H</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mn>0</mml:mn><mml:mo>.</mml:mo><mml:mn>06</mml:mn></mml:mrow></mml:msubsup></mml:math></inline-formula>. We find neither dependence on bolometric luminosity nor on Eddington ratio.</p>
<fig id="F1" position="float">
<label>Figure 1</label>
<caption><p>The structure function in bins of X-ray luminosity <italic>L</italic><sub><italic>X</italic></sub> and black hole mass <italic>M</italic><sub><italic>BH</italic></sub> (data and continuous lines) with power-law fits (dashed lines). <bold>Left panel:</bold> Black, 43 &#x0003C; log <italic>L</italic><sub><italic>X</italic></sub> &#x02264; 43.5; blue, 43.5 &#x0003C; log <italic>L</italic><sub><italic>X</italic></sub> &#x02264; 44; green, 44 &#x0003C; log <italic>L</italic><sub><italic>X</italic></sub> &#x02264; 44.5; yellow, 44.5 &#x0003C; log <italic>L</italic><sub><italic>X</italic></sub> &#x02264; 45; red, 45 &#x0003C; log <italic>L</italic><sub><italic>X</italic></sub> &#x02264; 45.5. <bold>Right panel:</bold> Black, 6.5 &#x02272; log <italic>M</italic><sub><italic>BH</italic></sub> &#x02264; 8; blue, 8 &#x0003C; log <italic>M</italic><sub><italic>BH</italic></sub> &#x02264; 8.5; green, 8.5 &#x0003C; log <italic>M</italic><sub><italic>BH</italic></sub> &#x02264; 9; yellow, 9 &#x0003C; log <italic>M</italic><sub><italic>BH</italic></sub> &#x02264; 9.5; red, 9.5 &#x0003C; log <italic>M</italic><sub><italic>BH</italic></sub> &#x02272; 10.5.</p></caption>
<graphic xlink:href="fspas-04-00021-g0001.tif"/>
</fig>
</sec>
<sec id="s3">
<title>3. Spectral variability</title>
<p>We update the analysis of the spectral variability parameter, initially introduced by Trevese and Vagnetti (<xref ref-type="bibr" rid="B14">2002</xref>) and recently adapted to the X-ray band by Serafinelli et al. (<xref ref-type="bibr" rid="B11">2017</xref>)</p>
<disp-formula id="E2"><label>(2)</label><mml:math id="M7"><mml:mrow><mml:mi>&#x003B2;</mml:mi><mml:mo>=</mml:mo><mml:mo>&#x02212;</mml:mo><mml:mfrac><mml:mrow><mml:mo>&#x00394;</mml:mo><mml:mo>&#x00393;</mml:mo></mml:mrow><mml:mrow><mml:mo>&#x00394;</mml:mo><mml:mi>log</mml:mi><mml:msub><mml:mi>f</mml:mi><mml:mi>X</mml:mi></mml:msub></mml:mrow></mml:mfrac><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
<p>relating variations of the photon index &#x00393; with those of the X-ray flux in a given band.</p>
<p>The spectra of most Seyfert galaxies with Eddington ratios above 0.01 typically become steeper in their brighter phases (e.g., Markowitz et al., <xref ref-type="bibr" rid="B6">2003</xref>; Sobolewska and Papadakis, <xref ref-type="bibr" rid="B13">2009</xref>; Connolly et al., <xref ref-type="bibr" rid="B1">2016</xref>), as well as for many galactic black hole binary systems (e.g., Remillard and McClintock, <xref ref-type="bibr" rid="B8">2006</xref>; Done et al., <xref ref-type="bibr" rid="B2">2007</xref>; Dong et al., <xref ref-type="bibr" rid="B3">2014</xref>). This is known as &#x0201C;softer when brighter&#x0201D; behavior and translates to a negative &#x003B2; value according to Equation 2. We also found this &#x0201C;softer when brighter&#x0201D; behavior, obtaining &#x003B2; &#x0003D; &#x02212;0.69&#x000B1;0.03 in our ensemble analysis, for the previous version of the MEXSAS sample, using fluxes in the soft X-ray band 0.5&#x02013;2 keV, and computing variations with respect to the mean values of each source (Serafinelli et al., <xref ref-type="bibr" rid="B11">2017</xref>).</p>
<p>Since the ensemble correlation between &#x00394;&#x00393; and &#x00394;log<italic>f</italic><sub><italic>X</italic></sub> contains a large scatter, also due to the large measurement errors for the fainter sources, we fit a linear relation &#x00394;&#x00393; &#x0221D; &#x00394;log<italic>f</italic><sub><italic>X</italic></sub> to the MEXSAS2 data set taking the uncertainties in both variables into account. We run a high number of linear fits replacing original data with Gaussian distributed values within the associated error box. Moreover, following Isobe et al. (<xref ref-type="bibr" rid="B4">1990</xref>), we computed both ordinary least squares regressions OLS(<italic>Y</italic>|<italic>X</italic>) of the dependent variable <italic>Y</italic> on the independent variable <italic>X</italic> (which result we call for brevity &#x003B2;<sub><italic>xy</italic></sub>), the inverse regression OLS(<italic>X</italic>|<italic>Y</italic>) (&#x003B2;<sub><italic>yx</italic></sub>), and the bisector:</p>
<disp-formula id="E3"><label>(3)</label><mml:math id="M8"><mml:mrow><mml:msub><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>b</mml:mi><mml:mi>i</mml:mi><mml:mi>s</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mfrac><mml:mrow><mml:msub><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mi>y</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:mo>&#x02212;</mml:mo><mml:mn>1</mml:mn><mml:mo>+</mml:mo><mml:msqrt><mml:mrow><mml:mo stretchy='false'>(</mml:mo><mml:mn>1</mml:mn><mml:mo>+</mml:mo><mml:msubsup><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mi>y</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msubsup><mml:mo stretchy='false'>)</mml:mo><mml:mo stretchy='false'>(</mml:mo><mml:mn>1</mml:mn><mml:mo>+</mml:mo><mml:msubsup><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mi>x</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msubsup><mml:mo stretchy='false'>)</mml:mo></mml:mrow></mml:msqrt></mml:mrow><mml:mrow><mml:msub><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>x</mml:mi><mml:mi>y</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>&#x003B2;</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mfrac><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
<p>For the whole sample, we find ensemble values &#x003B2;<sub><italic>xy</italic></sub> &#x0003D; &#x02212;0.22&#x000B1;0.04 and &#x003B2;<sub><italic>bis</italic></sub> &#x0003D; &#x02212;1.22&#x000B1;0.05, confirming the &#x0201C;softer when brighter&#x0201D; behavior for both spectral variability parameters (see Figure <xref ref-type="fig" rid="F2">2</xref>).</p>
<fig id="F2" position="float">
<label>Figure 2</label>
<caption><p>The ensemble correlation between the variations of the photon index &#x00394;&#x00393; and the variations of the logarithmic flux &#x00394;log<italic>F</italic> are shown. The dotted line represents &#x003B2;<sub><italic>xy</italic></sub>, the dashed line represents &#x003B2;<sub><italic>yx</italic></sub>, while the bisector &#x003B2;<sub><italic>bis</italic></sub> is shown as a continuous line.</p></caption>
<graphic xlink:href="fspas-04-00021-g0002.tif"/>
</fig>
<p>We then divide our sample in bins of soft X-ray flux, to show that the resulting &#x003B2; does not change within the errors (see Figure <xref ref-type="fig" rid="F3">3</xref>). In fact this was expected, because measurement errors do affect the estimate of &#x003B2;, but this must reflect an intrinsic relation between the flux and slope variations which should not change with an observational parameter like the average flux of the sources.</p>
<fig id="F3" position="float">
<label>Figure 3</label>
<caption><p>The dependence of &#x003B2;<sub><italic>xy</italic></sub> and &#x003B2;<sub><italic>bis</italic></sub> in bins of soft X-ray flux <bold>(Left panel)</bold> and black hole mass <bold>(Right panel)</bold>. No dependence is found, and all the values of &#x003B2;<sub><italic>xy</italic></sub> (empty circles) and &#x003B2;<sub><italic>bis</italic></sub> (filled circles) are compatible with the corresponding ensemble values &#x003B2;<sub><italic>xy</italic></sub> &#x0003D; &#x02212;0.22&#x000B1;0.04 and &#x003B2;<sub><italic>bis</italic></sub> &#x0003D; &#x02212;1.22&#x000B1;0.05, which are indicated respectively by the red and blue lines, and by the lighter bands for the uncertainties. The horizontal bars indicate bin widths, not errors.</p></caption>
<graphic xlink:href="fspas-04-00021-g0003.tif"/>
</fig>
<p>We also divide our sample in bins of black hole mass, <italic>M</italic><sub><italic>BH</italic></sub>, and show the result in Figure <xref ref-type="fig" rid="F3">3</xref>. Both &#x003B2;<sub><italic>xy</italic></sub> and &#x003B2;<sub><italic>bis</italic></sub> are independent of <italic>M</italic><sub><italic>BH</italic></sub> within the errors, and always compatible with their overall ensemble values.</p>
<p>We similarly analyse possible dependencies on Eddington ratio, redshift, X-ray and bolometric luminosities, finding no evidence of change. This analysis will be reported in an upcoming paper (Vagnetti et al., in preparation).</p>
</sec>
<sec id="s4">
<title>4. Summary</title>
<list list-type="simple">
<list-item><p>- We have updated our X-ray quasar Catalog MEXSAS to MEXSAS2.</p></list-item>
<list-item><p>- We have confirmed our previous results for the structure function dependence on X-ray luminosity, and no dependence on redshift; we find a weak dependence on black hole mass, and no dependence on bolometric luminosity and Eddington ratio.</p></list-item>
<list-item><p>- We have developed new spectral variability estimators, by computing ordinary least squares and bisector fits with errors in both variables.</p></list-item>
<list-item><p>- We obtain &#x0201C;softer when brighter&#x0201D; trends for the new MEXSAS2 sample using both estimators.</p></list-item>
<list-item><p>- Our spectral variability estimates, that also take errors on both fluxes and spectral indices into account, do not present a dependence on the flux.</p></list-item>
<list-item><p>- No trend with black hole mass, Eddington ratio, redshift, X-ray and bolometric luminosities is found, in agreement with our previous results (Serafinelli et al., <xref ref-type="bibr" rid="B11">2017</xref>).</p></list-item>
</list>
</sec>
<sec id="s5">
<title>Author contributions</title>
<p>RS performed the spectral variability analysis and wrote part of the text, FV was responsible for the idea that resulted in the paper and also contributed to the text, EC built the dataset of the MEXSAS2 Catalog, RM performed the structure function analysis.</p>
<sec>
<title>Conflict of interest statement</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
</sec>
</body>
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